• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.159-159
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• 2016

Vertically-aligned carbon nanotubes (VCNT) have attracted much attention due to their unique structural, mechanical and electronic properties, and possess many advantages for a wide range of multifunctional applications such as field emission displays, heat dissipation and potential energy conversion devices. Surface modification of the VCNT plays a fundamental role to meet specific demands for the applications and control their surface property. Recent studies have been focused on the improvement of the electron emission property and the structural modification of CNTs to enable the mass fabrication, since the VCNT considered as an ideal candidate for various field emission applications such as lamps and flat panel display devices, X-ray tubes, vacuum gauges, and microwave amplifiers. Here, we investigate the effect of surface morphology of the VCNT by water vapor exposure and coating materials on field emission property. VCNT with various height were prepared by thermal chemical vapor deposition: short-length around $200{\mu}m$, medium-length around $500{\mu}m$, and long-length around 1 mm. The surface morphology is modified by water vapor exposure by adjusting exposure time and temperature with ranges from 2 to 10 min and from 60 to 120oC, respectively. Thin films of SiO2 and W are coated on the structure-modified VCNT to confirm the effect of coated materials on field emission properties. As a result, the surface morphology of VCNT dramatically changes with increasing temperature and exposure time. Especially, the shorter VCNT change their surface morphology most rapidly. The difference of field emission property depending on the coating materials is discussed from the point of work function and field concentration factor based on Fowler-Nordheim tunneling.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.468-468
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• 2011

Carbon nanotubes (CNTs) have been considered as one of the promising candidate for next-generation field emitters because of their unique properties, such as high field enhancement factor, good mechanical strength, and excellent chemical stability. So far, a lot of researchers have been interested in field emission properties of CNT itself. However, it is necessary to study proper field emitter shapes, as well as the fundamental properties of CNTs, to apply CNTs to real devices. For example, specific applications, such as x-ray sources, e-beam sources, and microwave amplifiers, need to get a focused electron beam from the field emitters. If we use planar-typed CNT emitters, it will need several focal lenses to reduce a size of electron beam. On the other hand, the point-typed CNT emitters can be an effective way to get a focused electron beam using a simple technique. Here, we introduce a fabrication of CNT fibers with nanoscale point tips which can be used as a point-typed emitter. The emitter made by the CNT fibers showed very low turn-on electric field, high current density, and large enhancement factor. In addition, it showed stable emission current during long operation period. The high performance of CNT point emitter indicated the potential e-beam source candidate for the applications requiring small electron beam size.

• Journal of the Korean Institute of Gas
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• v.21 no.2
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• pp.20-25
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• 2017

For the HCNG bus using fuel which is the mixture gas of hydrogen and natural gas, the fuel efficiency and $CO_2$ emission characteristics were analyzed based on the WHVC test results and compared with that of the CNG and diesel buses. $CO_2$ emission characteristics were also analyzed by contribution effects such as carbon emission factor and fuel consumption. As a result, the fuel economy of HCNG bus was evaluated to be 11.5% improvement compared to CNG bus, and it was also showed equivalent to diesel bus. In addition, the $CO_2$ emission of HCNG bus was reduced 20.4% and 34.5% compared to CNG bus and diesel bus respectively. It was concluded that the $CO_2$ emission characteristics were influenced by the carbon emission factor depending on fuel composition and the fuel consumption according to the engine performance.

• International Journal of Highway Engineering
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• v.18 no.5
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• pp.83-93
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• 2016

PURPOSES : The aim of this article is to compare and identify eco-friendly competitiveness between (regional) motorway and high-speed rail(HSR) from the perspective of $CO_2$ emission in the Republic of Korea. METHODS : In order for an analysis of low-carbon competitiveness between the two modes, $CO_2e$ emission, $CO_2eppk$ (equivalent $CO_2$ gram per passenger kilometer), is employed as a comparison index. As for HSR, the index is calculated based on the passenger transport data and the gross of $CO_2e$ produced by Kyungbu high-speed line in 2013. Additionally, the gross of $CO_2e$ is computed by the greenhouse gas emission factors of domestic electricity generation mix. Regarding the index of motorway, it is directly calculated using both the official $CO_2e$ emission factor and the passenger-car occupancy of motorway. RESULTS : The results revealed, in the case of inter-regional transport, that the $CO_2e$ emission of displacement-based cars is 54.9% less than that of HSR, as the domestic electric power systems heavily relies on the thermal power plants over 66%. Note that internal combustion engines commonly used for vehicles are more energy-efficient than steam-driven turbines usually utilized for thermal power generation. CONCLUSIONS : It can be seen, at the very least in our study, that HSR has no superiority over motorway in the case of $CO_2e$ emission under the situations of domestic electricity generation mix. In addition, advanced eco-friendly vehicles have strong advantages over HSR. Therefore, all-out efforts should be made to develop and harvest renewable energy sources in order to achieve low-carbon HSR, sparing fossil fuels.

• KIEAE Journal
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• v.13 no.6
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• pp.55-65
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• 2013

Korean Government has developed Sejong City as a new administration city. This city of future was planned and designed toward one of the most eco-friendly city on the basis of ICTs. To attain this object, a carbon emission monitoring system (CEMS) was designed and installed as a part of u-city service which provides various information anytime and anywhere to enrich the people's quality of life. In this paper, at first, the structure and functions of CEMS are introduced. This system is consist of 5 parts - data collection from user and linked public DBs, transforming data into meaningful information for the policy makers, system-user interfacing via statistical tables and graphs, and system maintenance. This system can be operated by the citizen participation through whole the process. With the help of GIS map and graphic interface, statistics of monitored data for both citizen and decision maker provided and after feed-back, they have affected on the behaviour of citizen's energy consumption and related policy as well. By the CEMS, energy consumption data of 124 agreed households were collected during 9 months in 2012. Electricity, gas and water consumption were remote-metered automatically by the system and analysed. This showed that more than 85% of CO2 emission is rely on electricity usage. Furthermore, number of family members and size of house influences on the emission of CO2 by each household together with the life-style of the occupants. Electricity and water consumption showed the seasonal factor while gas consumption represents the number of family members. Even this paper has limitations caused by 9 months of data collection, it shows the policy directions to reduce the emission of CO2 focusing on the house size and number of family members of each households. With the result of this research, life-style of the generation of dwellers should be investigated and the CO2 emission characteristics of other housing type as well for the data building for future policy making.

• Tunnel and Underground Space
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• v.25 no.4
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• pp.373-382
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• 2015

This study presents a method to calculate carbon dioxide emissions of diesel vehicles operated in an underground mine using Geographic Information Systems (GIS). An underground limestone mine in Korea was selected as the study area. A GIS database was constructed to represent the haulage roads as a 3D vector network. The speed of dump trucks at each haulage road was investigated to determine the carbon dioxide emission factor. The amount of carbon dioxide emissions related to the truck's haulage work could be calculated by considering the carbon dioxide emission factor at each haulage road and the haulage distance determined by GIS-based optimal route analysis. Because diesel vehicles are widely utilized in the mining industry, the method proposed in this study can be used and further improved to calculate the amount of carbon dioxide emissions in mining sites.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.6
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• pp.562-570
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• 2009

Although anthracite power plant acts as the important source of greenhouse gas emissions, relatively little is known about its emission potentials. Especially, because the emissions of Non-$CO_2$ greenhouse gas $CH_4$ and $N_2O$ are strongly dependent on fuel type and technology available, it is desirable to obtain the information concerning their emission pattens. In this study, the anthracite power plants in Korea were investigated and the emission gases were analyzed using GC/FID and GC/ECD to develop Non-$CO_2$ emission factors. The anthracite samples were also analyzed to quantity the amount of carbon and hydrogen using an element analyzer, while calorie was measured by an automatic calorie analyzer. The emission factor of $CH_4$ and $N_2O$ computed through the gas analysis corresponded to 0.73 and 1.98 kg/TJ, respectively. Compared with IPCC values, the $CH_4$ emission factor in this study was about 25% lower, while that of $N_2O$ was higher by about 40%. More research is needed to extend our database for emission factors of various energy-consuming facilities in order to stand on a higher position.

• Carbon letters
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• v.12 no.4
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• pp.207-217
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• 2011

We discuss the influence of few-walled carbon nanotubes (FWCNTs) treated with nitric acid and/or sulfuric acid on field emission characteristics. FWCNTs/tetraethyl orthosilicate (TEOS) thin film field emitters were fabricated by a spray method using FWCNTs/TEOS sol one-component solution onto indium tin oxide (ITO) glass. After thermal curing, they were found tightly adhered to the ITO glass, and after an activation process by a taping method, numerous FWCNTs were aligned preferentially in the vertical direction. Pristine FWCNT/TEOS-based field emitters revealed higher current density, lower turn-on field, and a higher field enhancement factor than the oxidized FWCNTs-based field emitters. However, the unstable dispersion of pristine FWCNT in TEOS/N,N-dimethylformamide solution was not applicable to the field emitter fabrication using a spray method. Although the field emitter of nitric acid-treated FWCNT showed slightly lower field emission characteristics, this could be improved by the introduction of metal nanoparticles or resistive layer coating. Thus, we can conclude that our spray method using nitric acid-treated FWCNT could be useful for fabricating a field emitter and offers several advantages compared to previously reported techniques such as chemical vapor deposition and screen printing.

• Carbon letters
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• v.14 no.4
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• pp.255-258
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• 2013

Flexible transparent conducting films (TCFs) were fabricated by dip-coating single-wall carbon nanotubes (SWCNTs) onto a flexible polyethylene terephthalate (PET) film. The amount of coated SWCNTs was controlled simply by dipping number. Because the performance of SWCNT-based TCFs is influenced by both electrical conductance and optical transmittance, we evaluated the film performance by introducing a film property factor using both the number of interconnected SWCNT bundles at intersection points, and the coverage of SWCNTs on the PET substrate, in field emission scanning electron microscopic images. The microscopic film property factor was in an excellent agreement with the macroscopic one determined from electrical conductance and optical transmittance measurements, especially for a small number of dippings. Therefore, the most crucial factor governing the performance of the SWCNT-based TCFs is a SWCNT-network structure with a large number of intersection points for a minimum amount of deposited SWCNTs.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.1
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• pp.69-76
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• 2010

While increased use of motor cycles in the recent years for various demands could worsen air quality, only few studies have been conducted on estimation of emission factors and characterization of emissions from motorcycle. In this study, emissions from selected six models of motorcycle based on largest market share and production rate were investigated. To investigate gaseous and carbonaceous air pollutants, such as carbon monoxide (CO), total hydrocarbon (THC), nitrogen oxide ($NO_x$), elemental carbon (EC) and organic carbon (OC), total 124 motorcycles between 2003 and 2007 model year were tested with regulatory driving conditions, such as CVS-40 and CVS-47 mode. These motorcycles were further sub-categorized based on their displacement (< 50 cc, 50~150 cc, and $\geq$ 150 cc), type of stroke (2- and 4 strokes) and model year (2003~2005 and 2006~2007). Tested motorcycles with recent model year (2006~2007) exhibited less emissions of regulatory gaseous and carbonaceous air pollutants compared to old model year (2003~2005). Chemical analysis showed that CO present in highest concentration followed by THC and $NO_x$ for all tested motorcycles. Interestingly, two strokes motorcycle produced higher THC emission but less CO and $NO_x$ than those of four strokes. For all types of displacement and stroke, emission factors (gram per kilometer) of THC and CO except $NO_x$ with recent model year (2006~2007) showed decreased trend compared to old model year (2003~2005). In addition to this, due to mixed combustion between gasoline fuel and lubricant, two strokes motorcycle showed OC > EC emission trend.