• Title/Summary/Keyword: Carbon Corrosion

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Experimental and numerical investigation of strengthened deficient steel SHS columns under axial compressive loads

  • Shahraki, Mehdi;Sohrabi, Mohammad Reza;Azizyan, Gholam Reza;Narmashiri, Kambiz
    • Structural Engineering and Mechanics
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    • v.67 no.2
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    • pp.207-217
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    • 2018
  • In past years, numerous problems have vexed engineers with regard to buckling, corrosion, bending, and overloading in damaged steel structures. This article sets out to investigate the possible effects of carbon fiber reinforced polymer (CFRP) and steel plates for retrofitting deficient steel square hollow section (SHS) columns. The effects of axial loading, stiffness, axial displacement, the position and shape of deficient region on the length of steel SHS columns, and slenderness ratio are examined through a detailed parametric study. A total of 14 specimens was tested for failure under axial compression in a laboratory and simulated using finite element (FE) analysis based on a numerical approach. The results indicate that the application of CFRP sheets and steel plates also caused a reduction in stress in the damaged region and prevented or retarded local deformation around the deficiency. The findings showed that a deficiency leads to reduced load-carrying capacity of steel SHS columns and the retrofitting method is responsible for the increase in the load-bearing capacity of the steel columns. Finally, this research showed that the CFRP performed better than steel plates in compensating the axial force caused by the cross-section reduction due to the problems associated with the use of steel plates, such as in welding, increased weight, thermal stress around the welding location, and the possibility of creating another deficiency by welding.

Strengthening of concrete damaged by mechanical loading and elevated temperature

  • Ahmad, Hammad;Hameed, Rashid;Riaz, Muhammad Rizwan;Gillani, Asad Ali
    • Advances in concrete construction
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    • v.6 no.6
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    • pp.645-658
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    • 2018
  • Despite being one of the most abundantly used construction materials because of its exceptional properties, concrete is susceptible to deterioration and damage due to various factors particularly corrosion, improper loading, poor workmanship and design discrepancies, and as a result concrete structures require retrofitting and strengthening. In recent times, Fiber Reinforced Polymer (FRP) composites have substituted the conventional techniques of retrofitting and strengthening of damaged concrete. Most of the research studies related to concrete strengthening using FRP have been performed on undamaged test specimens. This contribution presents the results of an experimental study in which concrete specimens were damaged by mechanical loading and elevated temperature in laboratory prior to application of Carbon Fiber Reinforced Polymer (CFRP) sheets for strengthening. The test specimens prepared using concrete of target compressive strength of 28 MPa at 28 days were subjected to compressive and splitting tensile testing up to failure and the intact pieces of the failed specimens were collected for the purpose of repair. In order to induce damage as a result of elevated temperature, the concrete cylinders were subjected to $400^{\circ}C$ and $800^{\circ}C$ temperature for two hours duration. Concrete cylinders damaged under compressive and split tensile loads were re-cast using concrete and rich cement-sand mortar, respectively and then strengthened using CFRP wrap. Concrete cylinders damaged due to elevated temperature were also strengthened using CFRP wrap. Re-cast and strengthened concrete cylinders were tested in compression and splitting tension. The obtained results revealed that re-casting of specimens damaged by mechanical loadings using concrete & mortar, and then strengthened by single layer CFRP wrap exhibited strength even higher than their original values. In case of specimens damaged by elevated temperature, the results indicated that concrete strength is significantly dropped and strengthening using CFRP wrap made it possible to not only recover the lost strength but also resulted in concrete strength greater than the original value.

Properties of Mortar with Polysilicon Sludge Based Active Loess Cement (활성황토 시멘트 기반 폴리실리콘 슬러지를 사용한 모르타르의 특성)

  • Kang, Jeon-Uk;Kim, Dae-Yeon;Shin, Jin-Hyeon;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.275-282
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    • 2018
  • This study examines the ways to address environmental issues by utilizing activated loess to reduce the amount of cements that emit a large amount of carbon dioxide during the process of manufacturing, and by reusing the polysilicon sludge produced as a result of manufacturing polysilicon, one of the components for solar power generation panels. The findings of the experiment showed that the optimal replacement ratio of the polysilicon sludge is 20%, 35% for W/B, and 20% for the ratio of the fine aggregate addition. As it is deemed that utilizing the polysilicon sludge for reinforced concrete may lead to rebar corrosion due to the $CI^-$ contained in the sludge, it can be considered to use for unreinforced concrete or bricks.

Study on the effect of long-term high temperature irradiation on TRISO fuel

  • Shaimerdenov, Asset;Gizatulin, Shamil;Dyussambayev, Daulet;Askerbekov, Saulet;Ueta, Shohei;Aihara, Jun;Shibata, Taiju;Sakaba, Nariaki
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.2792-2800
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    • 2022
  • In the core of the WWR-K reactor, a long-term irradiation of tristructural isotopic (TRISO)-coated fuel particles (CFPs) with a UO2 kernel was carried out under high-temperature gas-cooled reactor (HTGR)-like operating conditions. The temperature of this TRISO fuel during irradiation varied in the range of 950-1100 ℃. A fission per initial metal atom (FIMA) of uranium burnup of 9.9% was reached. The release of gaseous fission products was measured in-pile. The release-to-birth ratio (R/B) for the fission product isotopes was calculated. Aspects of fuel safety while achieving deep fuel burnup are important and relevant, including maintaining the integrity of the fuel coatings. The main mechanisms of fuel failure are kernel migration, silicon carbide corrosion by palladium, and gas pressure increase inside the CFP. The formation of gaseous fission products and carbon monoxide leads to an increase in the internal pressure in the CFP, which is a dominant failure mechanism of the coatings under this level of burnup. Irradiated fuel compacts were subjected to electric dissociation to isolate the CFPs from the fuel compacts. In addition, nondestructive methods, such as X-ray radiography and gamma spectrometry, were used. The predicted R/B ratio was evaluated using the fission gas release model developed in the high-temperature test reactor (HTTR) project. In the model, both the through-coatings of failed CFPs and as-fabricated uranium contamination were assumed to be sources of the fission gas. The obtained R/B ratio for gaseous fission products allows the finalization and validation of the model for the release of fission products from the CFPs and fuel compacts. The success of the integrity of TRISO fuel irradiated at approximately 9.9% FIMA was demonstrated. A low fuel failure fraction and R/B ratios indicated good performance and reliability of the studied TRISO fuel.

MODIFICATION OF METAL MATERIALS BY HIGH TEMPERATURE PULSED PLASMA FLUXES IRRADIATION

  • Vladimir L. Yakushin;Boris A. Kalin;Serguei S. Tserevitionov
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2000.05a
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    • pp.1-1
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    • 2000
  • The results of the modification of metal materials treated by high temperature pulst:d plasma fluxes (HTlPPF) with a specific power of incident flux changing in the $(3...100)10^5{]\;}W/cm^2$ range and a pulse duration lying from 15 to $50{\;}\mu\textrm{s}$ have been presented. The results of HTPPF action were studied on the stainless steels of 18Cr-l0Ni, 16Cr- 15Ni, 13Cr-2Mo types; on the structural carbon steels of (13...35)Cr, St. 3, St. 20, St. 45 types; on the tool steels of U8, 65G, ShHI5 types, and others; on nickel and high nickel alloy of 20Cr-45Ni type; on zirconium- and vanadium-base alloys and other materials. The microstructure and properties (mechanical, tribological, erosion, and other properties) of modified materials and surface alloying of metals exposed to HTPPF action have been investigated. It was found that the modification of materials by HTPPF resulted in a simultaneous increase of several properties of the treated articles: microhardness of the surface and layers of 40...60 $\mu\textrm{m}$ in depth, tribological characteristics (friction coefficient, wear resistance), mechanical properties ({\sigma_y}, {\;}{\sigma_{0.2}}.{\;}{\sigma_r}) on retention of the initial plasticity ($\delta$), corrosion resistance, radistanation erosion under ion irradiation, and others. The determining factor of the changes observed is the structural-phase modification of the near-surface layers, in particular, the formation of the fine cellular structure in the near-surface layers at a depth of $20{\;}{\mu\textrm{m}}$ with dimension of cells changing in the range from 0.1 to $1., 5{\;}\mu\textrm{m}$, depending on the kind of material, its preliminary treatment, and the parameters of plasma fluxes. The remits obtained have shown the possibility of purposeful surface alloying of metals exposed to HTPPF action over a depth up to 20...45 $\mu\textrm{m}$ and the concentration of alloying element (Ni, Cr, V) up to 20 wt.%. Possible industrial brunches for using the treatment have been also considered, as well as some results on modifying the serial industrial articles by HTPPF.

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Compressive behavior of concrete-filled square stainless steel tube stub columns

  • Dai, Peng;Yang, Lu;Wang, Jie;Ning, Keyang;Gang, Yi
    • Steel and Composite Structures
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    • v.42 no.1
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    • pp.91-106
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    • 2022
  • Concrete-filled square stainless steel tubes (CFSSST), which possess relatively large flexural stiffness, high corrosion resistance and require simple joint configurations and low maintenance cost, have a great potential in constructional applications. Despite that the use of stainless steel may result in high initial cost compared to their conventional carbon steel counterparts, the whole-life cost of CFSSST is however considered to be lower, which offers a competitive choice in engineering practice. In this paper, a comprehensive experimental and numerical program on 24 CFSSST stub column specimens, including 3 austenitic and 3 duplex stainless steel square hollow section (SHS) stub columns and 9 austenitic and 9 duplex CFSSST stub columns, has been carried out. Finite element (FE) models were developed to be used in parametric analysis to investigate the influence of the tube thickness and concrete strength on the ultimate capacities more accurately. Comparisons of the experimental and numerical results with the predictions made by design guides ACI 318, ANSI/AISC 360, Eurocode 4 and GB 50936 have been performed. It was found that these design methods generally give conservative predictions to the ultimate capacities of CFSSST stub columns. Improved calculation methods, developed based on the Continuous Strength Method, have been proposed to provide more accurate estimations of the ultimate resistances of CFSSST stub columns. The suitability of these proposals has been validated by comparison with the test results, where a good agreement between the predictions and the test results have been achieved.

Degradation of Aqueous Monoethanolamine Absorbent (모노에탄올아민 흡수제의 열화특성 분석)

  • Cho, Youngmin;Nam, Sung-Chan;Yoon, Yeo-Il;Moon, Sungjun;Baek, Il Hyun
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.195-199
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    • 2010
  • The reversible chemical absorption using MEA (monoethanolamine), one of alkanolamine, is generally used as a conventionally method for $CO_{2}$ capture. Even MEA absorbent has excellent reactivity with $CO_{2}$, it has been known to have the decrease of absorption capacity caused by $CO_{2}$, $O_{2}$ or other acid gases in flue gas, corrosion and thermal degradation. In this study, MEA solutions degraded in the steam reforming process of refinery used and the absorption performance were compared for the used of conventional MEA solution. In case of 30 wt% MEA and mixture of 20 wt% thermal degraded absorbent (DP) and 10 wt% PZ, the absorption capacities were $0.5365mol-CO_{2}$/mol-absorbent and $0.5939mol-CO_{2}$/mol-absorbent respectively. PZ added thermally degraded absorbent showed the enhanced absorption capacity. On the contrary, the absorption rates were $1.1610kg_{f}/cm^2{\cdot}min$ for 30 wt% MEA, $0.5310kg_{f}/cm^2{\cdot}min$ for mixture of 20 wt% thermal degraded absorbent (DP) and 10 wt% PZ and $0.3525kg_{f}/cm^2{\cdot}min$ for 30 wt% thermally degraded absorbent only. The absorption rates of PZ added thermally degraded absorbent was higher than that of thermally degraded absorbent only. Therefore, it can be confirmed that thermally degraded absorbent can be reused as an absorbent for $CO_{2}$ by the addition of suitable additives.

Products and pollutants of half dried sewage sludge and waste plastic co-pyrolysis in a pilot-scale continuous reactor (반 건조 하수슬러지와 폐플라스틱 혼합물의 파일롯 규모 연속식 열분해에 의한 생산물과 발생 오염물질)

  • Kim, YongHwa;Chun, Seung-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.327-337
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    • 2017
  • A continuous low temperature ($510^{\circ}C{\sim}530^{\circ}C$) pyrolysis experiment in a pilot-scale of 85.3 kg/hr was carried out by the mixed feedstock of half dried digested sewage sludge and waste plastics. As a result, the amount of pyrolysis gas generated was maximum 68.3% of input dry mass and scored $40.9MJ/Nm^3$ of lower heating value (LHV), and the percentage of air inflow caused by continuous pyrolysis was 19.6%. The oil was produced 4.2% of the input dry mass, and the LHV was 32.5 MJ/kg. The sulfur and chlorine contents, which could cause corrosion of the facility, were found to be 0.2% or more respectively. The carbide generated was 27.5% of the input dry mass which shows LHV of 10.2 MJ/kg, and did not fall under designated waste from the elution test. The concentration of carbon monoxide, sulfur oxides and hydrogen cyanide of emitted flu gas from pyrolysis gas combustion was especially high, and dioxin (PCDDs/DFs) was within the legal standards as $0.034ng-TEQ/Sm^3$. Among the 47 water pollutant contents of waste water generated from dry flue gas condensation, several contents such as total nitrogen, n-H extract and cyanide showed high concentration. Therefore, the merge treatment in the sewage treatment plants after pre-treatment could be considered.

Nondestructive Examination of Ferromagnetic Tube Using Magnetic Saturation Eddy Current Technique (자기포화 와전류기법에 의한 자성 튜브 비파괴검사)

  • Lee, Hee-Jong;Cho, Chan-Hee;Song, Seok-Yoon;Jee, Dong-Hyun;Jung, Jee-Hong
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.5
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    • pp.407-415
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    • 2008
  • The tubes in heat exchanger are typically made from copper alloy, stainless steel, carbon steel, titanium alloy material. type-439 ferritic stainless steel is ferromagnetic material, and furnish higher heat transfer rates than austenitic stainless steels and higher resistance to corrosion-induced flaws. Ferritic stainless steel can typically be found in low-pressure(LP) feedwater heaters and moisture separator reheaters(MSRs). LP feedwater heaters generally utilize thin wall type-439 stainless steel tubing, whereas MSRs typically employ a heavier wall tubing with integral fins. Service-induced damage can occur on the OD(outside diameter) surface of type-439 ferritic stainless steel tubing which is employed for MSRs tubing, and the most typical damage mechanism is vibration-induced tube-to-TSP(tube support plate) wear and fatigue cracking. The wear has been reported that occurs mainly on the OD surface. Accordingly, in this study, we have evaluated the flaw sizing capability of magnetic saturation eddy current technique using magnetic saturation probe and flawed specimen.

Prediction Model of Remaining Service Life of Concrete for Irrigation Structures by Measuring Carbonation (중성화 측정을 통한 콘크리트의 잔존수명 예측 모델)

  • Lee, Joon-Gu;Park, Kwang-Soo;Kim, Han-Joung;Lee, Joung-Jae
    • Journal of the Korea Concrete Institute
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    • v.15 no.4
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    • pp.529-540
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    • 2003
  • Recently, the researches on the durability design of concrete structures have been studied. As the examples, models to evaluate the service life prediction of the structure have been developed. The purpose of this article is to develop the model for predicting remaining service life. The final aim is to provide the user time for repairing the concrete structures. In addition, it makes possible to maintain the concrete structure economically. 70 reservoirs out of the inland concrete structures were selected and concrete structures of their components were surveyed. Two methods were used for measuring carbonation; TG/DTA method and Phenolphtalein indicator and, the value of pH was measured by the pH meter, After deriving correlations of calcium carbonate and used year, duration from completion year to 2002, pH value, and concrete cover depth the model was developed for predicting remaining service life by measuring data as small as possible. The conventional models had been developed on the basis of experiment data obtained from the restricted lab environment like as carbon gas exposure. On the other hand this model was developed on the basis of measuring data obtained from the real field that the complex deterioration actions are occurred such as freezing and thawing, carbonation, steel corrosion, and so on. The reliability of the developed model will be evaluated high in this point and this model can help to maintain concrete structures economically by providing the manager time to repair the deteriorated concrete structures in site of facility management.