• 제목/요약/키워드: Carbon Corrosion

검색결과 643건 처리시간 0.033초

Recognition of damage pattern and evolution in CFRP cable with a novel bonding anchorage by acoustic emission

  • Wu, Jingyu;Lan, Chengming;Xian, Guijun;Li, Hui
    • Smart Structures and Systems
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    • 제21권4호
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    • pp.421-433
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    • 2018
  • Carbon fiber reinforced polymer (CFRP) cable has good mechanical properties and corrosion resistance. However, the anchorage of CFRP cable is a big issue due to the anisotropic property of CFRP material. In this article, a high-efficient bonding anchorage with novel configuration is developed for CFRP cables. The acoustic emission (AE) technique is employed to evaluate the performance of anchorage in the fatigue test and post-fatigue ultimate bearing capacity test. The obtained AE signals are analyzed by using a combination of unsupervised K-means clustering and supervised K-nearest neighbor classification (K-NN) for quantifying the performance of the anchorage and damage evolutions. An AE feature vector (including both frequency and energy characteristics of AE signal) for clustering analysis is proposed and the under-sampling approaches are employed to regress the influence of the imbalanced classes distribution in AE dataset for improving clustering quality. The results indicate that four classes exist in AE dataset, which correspond to the shear deformation of potting compound, matrix cracking, fiber-matrix debonding and fiber fracture in CFRP bars. The AE intensity released by the deformation of potting compound is very slight during the whole loading process and no obvious premature damage observed in CFRP bars aroused by anchorage effect at relative low stress level, indicating the anchorage configuration in this study is reliable.

A preliminary study of pilot-scale electrolytic reduction of UO2 using a graphite anode

  • Kim, Sung-Wook;Heo, Dong Hyun;Lee, Sang Kwon;Jeon, Min Ku;Park, Wooshin;Hur, Jin-Mok;Hong, Sun-Seok;Oh, Seung-Chul;Choi, Eun-Young
    • Nuclear Engineering and Technology
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    • 제49권7호
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    • pp.1451-1456
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    • 2017
  • Finding technical issues associated with equipment scale-up is an important subject for the investigation of pyroprocessing. In this respect, electrolytic reduction of 1 kg $UO_2$, a unit process of pyroprocessing, was conducted using graphite as an anode material to figure out the scale-up issues of the C anode-based system at pilot scale. The graphite anode can transfer a current that is 6-7 times higher than that of a conventional Pt anode with the same reactor, showing the superiority of the graphite anode. $UO_2$ pellets were turned into metallic U during the reaction. However, several problems were discovered after the experiments, such as reaction instability by reduced effective anode area (induced by the existence of $Cl_2$ around anode and anode consumption), relatively low metal conversion rate, and corrosion of the reactor. These issues should be overcome for the scale-up of the electrolytic reducer using the C anode.

불규칙 표면 시편을 이용한 Flexible 위상배열초음파기술 적용 연구 (Feasibility Study of Flexible Phased Array Ultrasonic Technology Using Irregular Surface Specimen)

  • 이승표;문용식;정남두
    • 비파괴검사학회지
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    • 제35권1호
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    • pp.52-60
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    • 2015
  • 원자력발전소에는 탄소강과 스테인리스강 용접을 위해 alloy600 용접재를 적용한 이종금속용접부가 다수 존재하며, 전 세계적으로 이종금속용접부에서 결함 발생 보고가 지속되고 있다. 주기적인 건전성 평가를 위해 이종금속용접부 초음파검사 일반절차서 (KPD-UT-10)를 적용하여 검사를 수행하고 있으며, 검사절차서에서는 탐촉자와 검사체 표면 사이의 간격을 최대 1/32"(0.8mm) 이내로 제한하고 있다. 국내의 일부 이종금속용접부는 테이퍼진 형상과 불규칙한 표면 형상을 가지고 있어, 가변형 위상배열초음파기술을 적용하여 검사 신뢰성을 높이고자 본 연구를 수행하였다. 연구 결과, 검사체 표면이 불규칙한 시편 내부의 인공결함에 대한 검출이 양호하였고, 이를 통해, 가변형 위상배열초음파기술의 현장 적용 가능성을 확인하였다.

다양한 표면형상에 따른 FRP 보강재의 부착특성 실험연구 (An Experimental Study on Bond Characteristics of FRP Reinforcements with Various Surface-type)

  • 정우태;박영환;박종섭
    • 대한토목학회논문집
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    • 제31권4A호
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    • pp.279-286
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    • 2011
  • FRP 긴장재는 PS 강연선의 부식 문제를 해결하기 위한 대안으로써 사용될 수 있으며, FRP 긴장재의 재료특성(부착강도, 인장강도, 전달길이 등)은 구조물에 적용하기 위해서 결정되어야 한다. 재료특성 중에 부착은 FRP 긴장재로 긴장된 PSC 구조물에 적용하기 위해 명확하게 요구되어야 한다. 이 연구는 다양한 표면형상을 갖는 FRP 보강재의 부착특성을 연구하였다. 콘크리트의 철근과 강연선 대신에 사용되는 FRP 재료의 부착특성을 결정하기 위해 CAN/CSA S806-02에서 제안된 직접인발 시험을 수행하였다. 강연선, 이형 철근, 6가지 다른 표면 형상을 갖는 탄소 또는 유리섬유 FRP 보강재에 대하여 총 40개의 시편이 제작되었다. 부착실험 결과 각 실험체의 다양한 부착응력-슬립 곡선을 나타냈고, 국내에서 제작된 CFRP 긴장재의 부착특성과 비교하였다.

탄소강 배관 티에서 편향 난류유동에 따른 속도성분과 국부감육의 상관관계 (Relationship Between Local Wall Thinning and Velocity Components of Deflected Turbulent Flow Inside the Tee Sections of Carbon Steel Piping)

  • 김경훈;황경모;강덕원
    • 대한기계학회논문집B
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    • 제35권7호
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    • pp.717-722
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    • 2011
  • 본 연구의 목적은 국부감육이 일어나고 있는 위치들을 분석하고, 그와 관련된 난류매개변수를 밝혀내는데 있다. 축소 제작된 배관계 티부분에서의 실험과 수치해석이 이루어졌으며, 실제로 배관계 부품내에서의 유동특성을 유추하기 위하여 그 결과들이 비교 검토되었다. 국부감육율과 난류 매개변수간의 상관관계를 결정하기 위하여 급수가열기 주 배관에서의 티 부품에 대한 수치해석이 수행되었고, 실제적인 국부감육 발생 위치를 찾아내기 위해 알칼리 금속염을 사용하여 감육 유로가시화 실험을 수행하였으며, 이를 기초로 한 난류매개 변수와 국부감육의 두께가 비교 분석되었다. 이러한 결과 값 비교를 통하여 얻어낸 바로는 기하학적 형태에 기인하는 배관 벽면에서의 박리로 인한 반경 방향 유속 Vr이 국부 감육 현상과 가장 연관성이 높은 것으로 나타났다.

고분자전해질 연료전지 내구성 향상을 위한 시동 기술 개발에 관한 연구 (Development of a Durable Startup Procedure for PEMFCs)

  • 김재홍;조유연;장종현;김형준;임태훈;오인환;조은애
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.288-294
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    • 2009
  • Various polymer electrolyte membrane fuel cell (PEMFC) startup procedures were tested to explore possible techniques for reducing performance decay and improving durability during repeated startup-shutdown cycles. The effects of applying a dummy load, which prevents cell reversal by consuming the air at the cathode, on the degradation of a membrane electrode assembly (MEA) were investigated via single cell experiments. The electrochemical results showed that application of a dummy load during the startup procedure significantly reduced the performance decay, the decrease in the electrochemically active surface area (EAS), and the increase in the charge transfer resistance ($R_{ct}$), which resulted in a dramatic improvement in durability. After 1200 startup-shutdown cycles, post-mortem analyses were carried out to investigate the degradation mechanisms via various physicochemical methods including FESEM, an on-line $CO_2$ analysis, EPMA, XRD, FETEM, SAED, FTIR. After 1200 startup-shutdown cycles, severe Pt particle sintering/agglomeration/dissolution and carbon corrosion were observed at the cathode catalyst layer when starting up a PEMFC without a dummy load, which significantly contributed to a loss of Pt surface area, and thus to cell performance degradation. However, applying a dummy load during the startup procedure remarkably mitigated such severe degradations, and should be used to increase the durability of MEAs in PEMFCs. Our results suggest that starting up PEMFCs while applying a dummy load is an effective method for mitigating performance degradation caused by reverse current under a repetition of unprotected startup cycles.

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Effect of Distribution System Materials and Water Quality on Heterotrophic Plate Counts and Biofilm Proliferation

  • 장영철;정권
    • Journal of Microbiology and Biotechnology
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    • 제14권6호
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    • pp.1114-1119
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    • 2004
  • The biofilms on pipe walls in water distribution systems are of interest since they can lead to chlorine demand, coliform growth, pipe corrosion, and water taste and odor problems. As such, the study described in this paper is part of an AWWARF and Tampa Bay Water tailored collaboration project to determine the effect of blending different source waters on the water quality in various distribution systems. The project was based on 18 independent pilot distribution systems (PDS), each being fed by a different water blend (7 finished waters blended in different proportions). The source waters compared were groundwater, surface water, and brackish water, which were treated in a variety of pilot distribution systems, including reverse osmosis (RO) (desalination), both membrane and chemical softening, and ozonation-biological activated carbon (BAC), resulting in a total of 7 different finished waters. The observations from this study consistently demonstrated that unlined ductile iron was more heavily colonized by a biomass than galvanized steel, lined ductile iron, and PVC (in that order) and that the fixed biomass accumulation was more influenced by the nature of the supporting material than by the water quality (including the secondary residual levels). However, although the bulk liquid water cultivable bacterial counts (i.e. heterotrophic plate counts or HPCs) did not increase with a greater biofilm accumulation, the results also suggested that high HPCs corresponded to a low disinfectant residual more than a high biofilm inventory. Furthermore, temperature was found to affect the biofilms, plus the AOC was important when the residual was between 0.6 and 2.0 mg $Cl_2/l$. An additional aspect of the current study was that the potential of the exoproteolytic activity (PEPA) technique was used along with a traditional so-called destructive technique in which the biofilm was scrapped off the coupon surface, resuspended, and cultivated on an R2A agar. Both techniques indicated similar trends and relative comparisons among the PDSs, yet the culturable biofilm values for the traditional method were several orders of magnitude lower than the PEPA values.

Axial behavior of CFRP wrapped RC columns of different shapes with constant slenderness ratio

  • Narule, Giridhar N.;Bambole, Abhay N.
    • Structural Engineering and Mechanics
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    • 제65권6호
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    • pp.679-687
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    • 2018
  • In composite materials technology, the fiber-reinforced polymers (FRP) have opened up new horizons in infrastructural engineering field for strengthening existing structures and components of structure. The Carbon fiber reinforced polymer (CFRP) sheets are well suited for RC columns to this application because of their high strength to weight ratio, good fatigue properties and excellent resistance to corrosion. The main focus of present experimental work is to investigate effect of shapes on axial behavior of CFRP wrapped RC columns having same cross-sectional area and slenderness ratio. The CFRP volumetric ratio and percentage of steel are also adopted constant for all the test specimens. A total of 18 RC columns with slenderness ratio four were cast. Nine columns were control and the rest of nine columns were strengthened with one layer of CFRP wrap having 35 mm of corner radius. Columns confined with CFRP wrap were designed using IS: 456:2000 and ACI 440.2R.08 provisions. All the test specimens were loaded for axial compression up to failure and failure pattern for each shaped column was investigated. All the experimental results were compared with analytical values calculated as per the ACI-440.2R-08 code. The test results clearly demonstrated that the axial behavior of CFRP confined RC columns is affected with the change in shapes. The axial deformation is higher in CFRP wrapped RC circular column as compared to square and rectangular columns. Stress-strain behaviour revealed that the yield strength gained from CFRP confinement was significant for circular columns as compare to square and rectangular columns. This behaviour may be credited due to effect of shape on lateral deformation in case of CFRP wrapped circular columns at effective confinement action.

Compressive behavior of galvanized steel wire mesh (GSWM) strengthened RC short column of varying shapes

  • Marthong, Comingstarful
    • Structural Monitoring and Maintenance
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    • 제7권3호
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    • pp.215-231
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    • 2020
  • In a reinforced concrete building different shapes of column are adopted depending on the structural orientation and the architectural aspect. When there is an increase in loading due to changes in usage or revision in the design codes these columns need to be strengthened for enhanced performance during their service life. Strengthening materials such as carbon fiber and glass fiber polymer has been successfully used however, due to high cost application other alternative materials need to be explore. Galvanized steel wire mesh (GSWM) is one of the suitable materials locally available. High tensile strength, low weight, corrosion resistance, easy installation, minimum change in dimensions of the sections and cost effectives are the advantages of GSWM. Therefore, in this paper, four different shapes of column such as circular, square, rectangular and L were wrapped with different layers GSWM and jacketed with mortar. All the specimens were tested under axial compression. The objective of the study is to investigate the effectiveness of GSWM as a confining material for strengthening of column having varying shape. Test results shows that the axial strength enhanced with wrapping of GSWM jacket and a circular column presented the highest load carrying capacity and ductility as compared to the others. From the study of 22 column specimens, it is found that axial load is increased upto 20% and 19% when circular and square column are strengthened with one wrap of GSWM respectively, while a rectangular and L column required a wraps of two and three layers respectively in order to achieved the same load capacity as that of a circular column. Based on the present study, it is concluded that GSWM can be effectively used for strengthening of different shapes of concrete columns economically.

상수관망에서 발생하는 이물질의 성분분석 (The Component Analysis of Foreign Substance Occurred in Water Distribution Networks)

  • 최민아;김도환;배철호;이두진;최두용
    • 대한환경공학회지
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    • 제36권9호
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    • pp.614-623
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    • 2014
  • 지방상수도에서 이물질에 의한 수질민원은 수돗물에 대한 불신을 초래하고 음용률을 저해하는 가장 큰 요인이라 할 수 있다. 본 연구에서는 수질민원 대상지역의 이물질 수집 및 시료의 정성 및 정량분석을 실시하여 이물질에 함유되어 있는 화합물과 원소성분을 검출함으로서 이물질 발생의 원인을 밝히고 해결방안을 모색하고자 하였다. 또한 상수관로 내부의 이물질로 인해 지속적으로 발생하는 수질민원을 해소하고 수돗물에 대한 신뢰성 향상 및 양질의 수돗물 공급을 위한 방안을 마련하고자 하였다. 민원지역에서 포집된 이물질은 관로의 내부부식 및 노후화로 인한 부식생성물의 무기화합물뿐만 아니라 탄소(C) 및 산소(O)성분을 다량 함유한 유기화합물도 포함하고 있었다. 이물질에 대한 정확한 판단과 저감을 위해 객관적인 대상지역의 관상태평가가 필요한 것으로 조사되었다.