• Title/Summary/Keyword: Carbon Conversion

Search Result 712, Processing Time 0.029 seconds

Biological nitrogen removal of ammonium-rich industrial wastewater by suspended bacterial growth

  • Im, Jun-Taek;Seong, Se-Hyeon;Hwang, Seok-Hwan
    • 한국생물공학회:학술대회논문집
    • /
    • 2002.04a
    • /
    • pp.399-402
    • /
    • 2002
  • Industrial wastewater with high ammonium concentration was treated in batch biological systems which was a modified Ludzack- Ettinger process. Up to 78% conversion of $NH_4\;^+-N$ to $NO_x\;^--N$ was achieved in batch culture condition. Under anoxic condition with methanol as the carbon source, the denitrifiers decreased $NO_x\;^--N$ concentration from 608 mg/L to 5.6 mg/L in 22 d. As well as anoxic denitrification of $NO_x\;^-$ to $N_2$, dissimilatory nitrate reduction to ammonium also occurred under the condition as respiratory denitrification.

  • PDF

Effect of the Molar H2O/ and the Molar O2/C Ratio on Long-Term Performance of Diesel Autothermal Reformer for Solid Oxide Fuel Cell (고체산화물 연료전지용 디젤 자열개질기의 장기성능에 미치는 H2O/C와 O2/C 몰 비의 영향)

  • Yoon, Sang-Ho;Kang, In-Yong;Bae, Gyu-Jong;Bae, Joong-Myeon
    • Journal of the Korean Electrochemical Society
    • /
    • v.10 no.2
    • /
    • pp.110-115
    • /
    • 2007
  • Solid oxide fuel cell(SOFC) has high fuel flexibility due to its high operating temperatures. Hydrocarbonaceous fuels such as diesel has several advantages such as high energy density and established infrastructure for fuel cell applications. However diesel reforming has technical problems like coke formation in a reactor, which results in catastrophic failure of whole system. Performance degradation of diesel autothermal reforming (ATR) leads to increase of undesirable hydrocarbons at reformed gases and subsequently degrades SOFC performance. In this study, we investigate the degradation of SOFC performance(OCV, open circuit voltage) under hydrocarbon(n-Butane) feeds and characteristics of diesel performing under various ratios of reactants($H_2O/C,\;O_2/C$ molar ratios) for improvement of SOFC performance. Especially we achieved relatively high performance of diesel ATR under $H_2O/C=0.8,\;O_2/C=3$ condition.

Biomineralization Processes Using Fly Ash for Carbon Sequestration (석탄회를 이용하는 탄소 격리용 생광물화 작용)

  • Yul Roh;Moon, Ji-Won;Yungoo Song;Moon, Hi-Soo
    • Journal of the Mineralogical Society of Korea
    • /
    • v.16 no.2
    • /
    • pp.171-180
    • /
    • 2003
  • The objective of this study is to investigate biogeochemical processes to sequester $CO_2$and metals utilizing metal-rich fly ash (MRFA). Microbial conversion of $CO_2$into sparingly soluble carbonate minerals has been studied using MRFA under different $pCO_2$and different bicarbonate concentrations. Scaling from test tube to fermentation vessels (up to 4-L) using metal-reducing bacteria and MRFA has proved successful at sequestering carbon dioxide and metals. $CO_2$sequestration via precipitation processes using MRFA may complement the process of $CO_2$capture from fossil fuel plants while potentially stabilizing fly ash wastes.

Oxidation Behavior of SiC Coated Carbon/carbon Composite by Pack-cementation Method (Pack-cementation 방법에 의해서 탄화규소로 도포된 탄소/탄소 복합재의 산화거동)

  • 김정일;박인서;주혁종
    • Composites Research
    • /
    • v.13 no.2
    • /
    • pp.22-29
    • /
    • 2000
  • Although C/C composites have excellent mechanical properties at high temperature, the disadvantage of oxidation in air restricts their applications. Thus a lot of investments have been studied to improve this drawback. In this study, SiC used as a thermal protective coating material possesses almost the same expansion coefficient compared to that of carbon, so SiC was coated on 4D C/C composites by Pack-Cementation process. For SiC-coated C/C composites, optical microscopy observations were performed to estimate the conversion mechanism involved and air oxidation tests were also performed to evaluate the improvement of oxidation resistance. Afterwards the optimum conditions of coating process were estimated from the results of several analysis and tests.

  • PDF

Microorganism lipid droplets and biofuel development

  • Liu, Yingmei;Zhang, Congyan;Shen, Xipeng;Zhang, Xuelin;Cichello, Simon;Guan, Hongbin;Liu, Pingsheng
    • BMB Reports
    • /
    • v.46 no.12
    • /
    • pp.575-581
    • /
    • 2013
  • Lipid droplet (LD) is a cellular organelle that stores neutral lipids as a source of energy and carbon. However, recent research has emerged that the organelle is involved in lipid synthesis, transportation, and metabolism, as well as mediating cellular protein storage and degradation. With the exception of multi-cellular organisms, some unicellular microorganisms have been observed to contain LDs. The organelle has been isolated and characterized from numerous organisms. Triacylglycerol (TAG) accumulation in LDs can be in excess of 50% of the dry weight in some microorganisms, and a maximum of 87% in some instances. These microorganisms include eukaryotes such as yeast and green algae as well as prokaryotes such as bacteria. Some organisms obtain carbon from $CO_2$ via photosynthesis, while the majority utilizes carbon from various types of biomass. Therefore, high TAG content generated by utilizing waste or cheap biomass, coupled with an efficient conversion rate, present these organisms as bio-tech 'factories' to produce biodiesel. This review summarizes LD research in these organisms and provides useful information for further LD biological research and microorganism biodiesel development.

Characteristics of Pore Development for Activated Carbon Fiber from Polyacrylonitrile(II) -Activation- (PAN계 활성탄소 섬유의 세공발달 특성(II) -활성화-)

  • Park, Jong-Hak;Cho, Byung-Rin
    • Applied Chemistry for Engineering
    • /
    • v.4 no.1
    • /
    • pp.113-124
    • /
    • 1993
  • Thermogravimetric analysis of copolymer of acrylonitrile(95%) and methyl acrylate(5%) have been carried out to investigate the activation under $H_2O$(30%) -$N_2$atmosphere at various heating rates. The kinetic equation [$f=1-\exp(-a{\Delta}T)^b$] which was derived on the basis of the nonisothermal activation process of carbon fiber in the $H_2O$(30%)-$N_2$system showed good agreement with experimetal results. The pore volume upon conversion was in good agreement with the model of theoretical pore volume. The pore structures of the activated carbon fiber were influenced by the heating rate, activation temperature and internal-external conversions.

  • PDF

Preparation of Boron Compounds from Calcium Borate, Colemanite : Synthesis of Hexagonal Boron Nitride from Boric Oxide(III) (Colemanite 붕산염으로부터 붕소화합물의 제조 : 무수붕산으로부터 육방정 질화붕소의 합성 (III))

  • Jee, Mi-Jung;Jang, Jae-Hun;Paik, Jong-Hoo;Lee, Mi-Jai;Lim, Hyung-Mi;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
    • /
    • v.41 no.11
    • /
    • pp.812-818
    • /
    • 2004
  • This study has been undertaken with objective of studying the mechanism and condition of formation of hexagonal boron nitride from reduction of boric okide in the presence of carbon under nitrogen atmosphere. It was found that the formation of hexagonal boron nitride was started at 1400$^{\circ}C$ and almost completed its conversion at 1550$^{\circ}C$. The morphology of boron nitride synthesized in this study was very fine and platelet. It was considered as reaction pathway of hexagonal boron nitride that boron oxide was reduced to born and evaporated by activated carbon, and then it was reacted with nitrogen.

Tunable Electrical Properties of Aligned Single-Walled Carbon Nanotube Network-based Devices: Metallization and Chemical Sensor Applications

  • Kim, Young Lae;Hahm, Myung Gwan
    • Journal of the Korean Ceramic Society
    • /
    • v.54 no.6
    • /
    • pp.535-538
    • /
    • 2017
  • Here we report the tunable electrical properties and chemical sensor of single-walled carbon nanotubes (SWCNTs) network-based devices with a functionalization technique. Formation of highly aligned SWCNT structures is made on $SiO_2/Si$ substrates using a template-based fluidic assembly process. We present a Platinum (Pt)-nanocluster decoration technique that reduces the resistivity of SWCNT network-based devices. This indicates the conversion of the semiconducting SWCNTs into metallic ones. In addition, we present the Hydrogen Sulfide ($H_2S$) gas detection by a redox reaction based on SWCNT networks functionalized with 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) as a catalyst. We summarize current changes of devices resulting from the redox reactions in the presence of $H_2S$. The semiconducting (s)-SWCNT device functionalized with TEMPO shows high gas response of 420% at 60% humidity level compared to 140% gas response without TEMPO functionalization, which is about 3 times higher than bare s-SWCNT sensor at the same RH. These results reflect promising perspectives for real-time monitoring of $H_2S$ gases with high gas response and low power consumption.

Hydrogen Production Technology (수소생산기술현황)

  • Joo, Oh-Shim
    • Korean Chemical Engineering Research
    • /
    • v.49 no.6
    • /
    • pp.688-696
    • /
    • 2011
  • Hydrogen is one of the few long-term sustainable clean energy carriers, emitting only water as by-products during its combustion or oxidation. The use of fossil fuels to produce hydrogen makes large amount of carbon dioxide (>7 kg $CO_{2}$/kg $H_{2}$) during the reforming processes. Hydrogen production can be environmentally benign only if the energy and the resource to make hydrogen is sustainable and renewable. Biomass is an attractive alternative to fossil fuels for carbon dioxide because of the hydrogen can be produced by conversion of the biomass and the carbon dioxide formed during hydrogen production is consumed by biomass generation process. Hydrogen production using solar energy also attracts great attention because of the potential to use abundance natural energy and water.