• Title/Summary/Keyword: Carbon Content Analysis

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Improved of Mechanical Properties and Functionalization of Polycarbonate by Adding Carbon Materials (탄소재료 첨가에 의한 Polycarbonate의 기계적 물성 향상 및 기능화에 관한 연구)

  • Kim, Jeong-Keun;Choi, Sun-Ho;Go, Sun-Ho;Kwac, Lee-Ku;Kang, Sung-Soo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.10
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    • pp.59-67
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    • 2020
  • Polycarbonate thermoplastic composite materials are anisotropic and exhibit physical properties in the longitudinal direction. Therefore, the physical properties depend on the type and direction of reinforcements. The thermal conductivity, electrical conductivity, and resin impregnation can be controlled by adding carbon nanotubes to polycarbonate resin. However, the carbon fiber used as a reinforcing material is expensive, interfacial adhesion issues occur, and simulation values are different from actual values, making it difficult to perform mathematical analysis. However, carbon nanotubes have advantages such as light weight, rigidity, impact resistance, and reduced number of parts compared to metals. Due to these advantages, it has been applied to various products to reduce weight, improve corrosion resistance, and increase impact durability. As the content of carbon nanotubes or carbon fibers increases, the mechanical properties and antistatic and electromagnetic shielding performance improve. It is expected that the amount of carbon nanotubes or carbon fibers can be optimized and applied to various industrial products.

Effect of β-Resin of Petroleum-based Binder Pitch on Density of Carbon Block (석유계 바인더 피치의 β-resin이 탄소블럭의 밀도에 미치는 영향)

  • Kim, Kyung Hoon;Lee, Sangmin;An, Donghae;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.28 no.4
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    • pp.432-436
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    • 2017
  • Carbon blocks were prepared by compression molding process using the mixture of isotropic cokes and binder pitches, which were reformed with different ${\beta}$-resin contents from pyrolysis fuel oil. Physical and chemical properties and also thermal behavior of binder pitches were investigated through elemental analysis, FT-IR and thermogravimetric analysis, respectively. The adhesion of binder pitches to isotropic coke particles was evaluated from SEM images of the fracture surface of carbon blocks. From these results, it is shown that the adhesion between the cokes and binder was enhanced by increasing the ${\beta}$-resin content of binder pitches. The density of the carbon block after carbonization also increased from 1.325 to $1.383g/cm^3$ by increasing the ${\beta}$-resin content of binder pitches from 1.4 to 20.1%.

Soil Organic Carbon Determination for Calcareous Soils (석회암 유래 토양의 토양유기탄소 분석법 연구)

  • Jung, Won-Kyo;Kim, Yoo-Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.396-402
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    • 2006
  • Soil organic carbon has long been considered as the most critical factor to evaluate the soil quality, fertility, and fertilizer prescription. In addition, soil organic carbon may impact on greenhouse gas effects and global warming. Because of that, the management of soil organic carbon is increasingly important not only for improving soil quality but also for managing soil as a greenhouse gas source. Both wet and dry combustion have been used to determine soil organic carbon. Many benefits, such as automation and less labor, could the dry combustion method become more popular. Inorganic form of carbon could overestimate soil organic carbon when the dry combustion method was applied. Determination of soil inorganic carbon may contribute to the improved accuracy of soil organic carbon analysis using dry combustion method. Objectives of this research were 1) to develop soil inorganic carbon determination method using modified digital pressure calcimeter and 2) to evaluate soil organic carbon from calcareous soils using the dry and wet combustion method. Results showed that the significant linear relationship was found between soil inorganic carbon content and pressure calcimeter output. Inorganic carbon ranged from 22% to 28% of total carbon in the calcareous soil samples. Soil organic carbon content by dry combustion for calcareous soil was determined by subtracting inorganic carbon measured by the digital pressure calcimeter from total carbon. Soil organic carbon determined by dry combustion method was significantly correlated with that by wet combustion method. In conclusion, the digital pressure calcimeter may use to improve soil organic carbon determination for the calcareous soils by subtracting of soil inorganic carbon from total carbon determined by dry combustion method.

Microstructure investigation and component analysis of iron weapons found at Hadong-gun, Kyungnam Province (경남 하동군 발견 철제무구류의 금속조직 조사 및 성분분석)

  • Yu, Jae-Eun;Go, Hyeoung-Sun;Hwong, Jin-Ju
    • 보존과학연구
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    • s.21
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    • pp.177-206
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    • 2000
  • In the study of iron artifacts, microstructure investigation is an indispensable step to find out the manufacturing method and skill. The iron weapons that we have excavated and investigated at the ruins of Gohyun Castle site, Hadong-gun, Kyungnam Province are traced to the era of Choson Dynasty. By sampling specimens of some artifacts, we have made microstructure investigation and component analysis of them. For microstructure investigation we used metallographic microscopes, and for component analysis we used the methods of C/S analysis and Inductively coupled plasma emission spectrometry (ICP) analysis which is designed to verify components and contenets of a very small amount elememt. Microstructure of the artifacts is mainly divided into three parts. Inner part is Widmanstatten, a typical overheated structure, upon which we can see another part with fine grains and with extremely small quantities of carbon. And on the surface, there is a carbonized part. When the shape is formed through forging process at a high temperature the carbon content of the surface is getting down and the grains come to be finer. Next, carbonizing process is to be done for hardening the surface, which is followed by cooling process. Cooling rates seem to be different from artifacts to artifacts. All artifacts have clearly distinguishable grain boundaries in their unique structure. Since this kind of structure is rarely found, it seems to offer a clue to find out the manufacturing method. The outcome of component analysis is almost the same with that of microstructure investigation. As is demonstrated by C/S analysis, carbon content is 0.39-1.24% and sulfur is contained 0.0005-0.010%.

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Sub-bituminous Coal's Calorific Value Trend Analysis and Carbon Emission Factor Development (국내 아역청탄의 발열량 추이 분석과 탄소배출계수 개발)

  • Kim, Min wook;Cho, Changsang;Jeon, Youngjae;Yang, Jinhyuk;Sin, Hochul;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.8 no.2
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    • pp.145-151
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    • 2017
  • Korea's energy consumption has been constantly increasing. Final energy consumption was increased by anannual average of 2.9% compared to 2010. The consumption of all energy sources except for its oil was increased during the same time. While electric demand has increased coal consumption increased rapidly. Therefore, calorfic value and carbon emission factor development can improve the quality of Korea's greenhouse gas inventory. Calorific value is the amount of heat generated while burning coal. Caloric value is one of the most important factors in the development of carbon emission factors. Calorific value is used as the basis for the analysis of the various energy statistics. This study has calculated the sub-bituminous coal's calorfic value by the data received from domestic coal-fired power plants. Calorofic value's trend analysis period is the year of 2011~2015. Through analyzing the carbon content it was calculated the carbon emission factor. The sub-bituminous coal's uncertainty analysis was performed using a Monte Carlo simulation.

Carbon-Silica Membranes Derived from Polyimide/Silica Composites for Gas Separation

  • Lee, Young-Moo;Park, Ho-Bum;Kim, Myung-Jun;Jang, Jeong-Gyu
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.47-50
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    • 2003
  • Carbon-silica membranes were Prepared by Pyrolyzing polyimide/silica composite obtained from ill-situ polymerization of alkoxy silanes via sol-gel reaction. In this study, effects of silica content and silica network in polyimide matrix were focused on the gas permeation and separation properties of the final carbon-silica membrane. The membranes prepared were characterized with a field emission scanning electron microscopy (FE-SEM), a solid state $^{29}$ Si nuclear magnetic resonance spectroscopy ($^{29}$ Si-NMR), an electron spectroscopy for chemical analysis (ESCA), a thermogravimetric analysis (TGA) and gas permeation tests.

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Overview on The Measurement Methods of Unburned Carbon Contents in Coal Fly-Ash (석탄 비산회(Fly-Ash)의 미연탄소 함량 측정방법에 대한 고찰)

  • Hong, EunPyo;Kim, Jung Hyeun
    • Particle and aerosol research
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    • v.10 no.4
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    • pp.131-136
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    • 2014
  • The importance of waste treatments is increasing because of the lack of resources and environmental problems resulted from economic growth policy. Especially, the pollutant dust which is one of the wastes should be treated considerately because it could cause secondary damages on the human health as well as environmental systems. Recently, massive amount of coal fly-ash is being produced in thermoelectric power plants. In this study, we compared two general methods used in estimating the amount of unburned carbon in fly-ashes to categorize the coal fly-ashes into several groups following their carbon contents. One is the "loss on ignition(KS L 5405) method" which estimates the change of mass after combustion, and it is generally used. Another one is measuring $CO_2$ gas content by burning solid carbon in the fly-ash, and it is called "$CO_2$ analysis method."

Electrochemical Oxidation of Carbon Felt for Redox Flow Battery (Redox flow battery용 carbon felt 전극의 전기화학적 산화)

  • Jung, Young-Guan;Hwang, Gab-Jin;Kim, Jae-Chul;Ryu, Cheol-Hwi
    • Journal of Hydrogen and New Energy
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    • v.22 no.5
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    • pp.721-727
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    • 2011
  • All vanadium redox-flow battery (VRFB) has been studied actively as one of the most promising electrochemical energy storage systems for a wide rage of applications such as electric vehicles, photovoltaic arrays, and excess power generated by electric power plants at night time. In this study, carbon felt electrodes were treated by electrochemical oxidation with KOH, and the cyclic voltammetry were studied in order to investigate redox reactivity of vanadium ion species with carbon felt electrodes. Besides the effect of electrochemical oxidation on the surface chemistry of carbon felt electrodes were investigated using the X-ray photoelectron spectroscopy (XPS). After electrochemical oxidation, XPS analysis of PAN based GF20-3 carbon felt electrode revealed on increase in the overall surface oxygen content of the carbon felts after electrochemical oxidation. Redox reaction characteristics using cyclic voltammetry (CV) were ascertained that the electrochemical treated electrode were more reversible than the untreated electrode.

A Study of Characteristics on the Dissimilar Metals (STS 316L - Carbon Steel: ASTM A516-70) Welds made with GTAW (스테인리스강 STS 316L과 탄소강 A516-70의 이종금속 GTA 용접부 특성에 대한 연구)

  • Kim, Se Cheol;Shin, Tae Woo;Moon, In Joon;Jang, Bok Su;Koh, Jin Hyun
    • Journal of Welding and Joining
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    • v.33 no.4
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    • pp.37-43
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    • 2015
  • Characteristics of dissimilar metal welds between STS 316L and carbon steel ASTM A516 Gr.70 made with GTAW have been evaluated in terms of microstructure, ferrite content, chemical analysis, hardness and corrosion resistance. Three heat inputs of 9.00, 11.25, 13.00kJ/cm were employed to make joints of dissimilar metals with ER309 wire. Based on microstructural examination, the amount of vermicular type of ${\delta}$-ferrite was increased with increasing heat input due to the increase of Creq/Nieq in the second layer of welds. Based on the EDX analysis of weld metals, Cr and Ni content in the 2nd layer increased while those content in the first layer of welds decreased with heat inputs. Cellular solidification mode in the 1st layer and dendritic solidification mode in the 2nd layer due to different cooling rates were prevailed, respectively. Heat affected zone which formed hard microstructure showed higher hardness than the weld metal. The salt spray test of dissimilar metals weld joints showed that the carbon steel surfaces only corroded. The weight loss rate due to corrosion increased up to 100hours but it decreased above 100 hours. There was little difference in the weight loss caused by corrosion regardless of heat inputs.

Service Life Variation Considering Increasing Initial Chloride Content and Characteristics of Mix Proportions and Design Parameters (초기 염화물량의 증가와 배합 및 설계 변수 특성을 고려한 콘크리트 내구수명의 변동성)

  • Park, Sun-Kyung;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.236-245
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    • 2021
  • It is very important for structure designer to understand the service life variation since a wide range of service life is evaluated with changing exposure conditions and design parameters. Recently, for zero-carbon, waste plastic has been used for fuel for clinker production and this yields increase in chloride content in cement. This study is for evaluation of changing service life in the concrete with increasing initial chloride content due to usage of plastic-SRF(Solid Refuse Fuel) considering various exposure conditions and design parameters. For this, 4 levels of initial chloride content were assumed, and the service life was assessed using LIFE 365 program considering various environmental conditions including 3 levels of surface chloride content. As for analysis parameters, critical/initial chloride content, blast furnace slag powder replacement ratio, W/B(Water to Binder) ratio, cover depth, and unit mass for binder are adopted. Service life decreases with increasing initial chloride content and a significant reduction of service life is not evaluated permitting up to 1,000ppm of initial chloride content. With increasing slag replacement ratio, a longer service life can be secured since blast furnace slag powder has the effect of reducing the diffusion of external chloride ions and fixing the free chloride. It is thought that increasing initial chloride content up to European standard is helpful for enhancing sustainability and reducing carbon emission. Though the reduction in service life due to an increase in the initial chloride content is not significant in slag-concrete with low surface chloride content, careful consideration for mixing design should be paid for the exposure environment with high surface chloride content.