• Title/Summary/Keyword: Carbon Coating

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Effect of Evaporative Pattern on the Surface Layer Structures of Carbon Steel and Gray Iron Castings. (소실모형이 탄소강 및 회주철 주물의 표면층 조직에 미치는 영향)

  • Kim, Ji-Youn;Cho, Nam-Don
    • Journal of Korea Foundry Society
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    • v.12 no.4
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    • pp.305-316
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    • 1992
  • Steel and iron castings made with expandable polystylene (referred to hereafter as EPS) patterns are often affected by distinctive defects associated with incomplete decomposition of the EPS as the molds are filled with metal. The effects of practical factors on carbon pick-up were investigated on the specimens, by taking successive layers of swarf and analysis, whereas the lustrous carbon is determined by using combustion analysis. The quality of the castings, with particular reference to carbon pick-up in low carbon steel and lustrous carbon on gray iron, is further influenced to a significant extent by such practical factors as reduced pressure, the pouring temperature, the density of EPS pattern, the additive in coating and in pattern and the casting thickness. The rate at which carbon pick-up and lustrous carbon deposites are formed can be reduced by reducing the density of the pattern and also reducing pressure, especially by adding $Na_2CO_3$ in coating and in pattern to promote $CO_2$ evolution. The upper parts of castings obtained using EPS patterns are slightly higher in carbon pick-up and in lustrous carbon than other parts.

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Characteristics of Silver Metal-mesh Electrodes Coated by Carbon Nanotubes (탄소 나노튜브가 코팅된 은 메탈-메쉬 전극의 특성)

  • Kim, Bu-Jong;Park, Jong-Seol;Hwang, Young-Jin;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.1
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    • pp.55-59
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    • 2015
  • This study demonstrates hybrid-type transparent electrodes for touch screen panels. The hybrid-type electrodes were fabricated by coating carbon nanotubes (CNTs) on metal meshes. To form the metal-meshes, thin films of silver (Ag) were deposited on glass substrates using the sputtering method and then patterned via photolithography to obtain mesh structures whose line width was $10{\mu}m$ and line-to-line spacing was $300{\mu}m$. CNTs were coated on Ag-meshes by using two different methods, such as spray coating and electrophoretic deposition (EPD). For the samples of a Ag-meshes and CNTs-coated Ag-meshes, their surface morphologies, electrical sheet resistances, and visible-range transmittances and reflectances were characterized and compared. The experimental results indicated that the reflectance of Ag-mesh electrodes was substantially reduced by coating of CNTs. Especially, the hybrid electrodes of Ag-meshes with EPD-coated CNTs showed excellent properties such as sheet resistance lower than $20{\Omega}/{\Box}$, transmittance higher than 90 %, and reflectance lower than 8%.

Property Evaluation of HVOF Sprayed Multi-walled Carbon Nanotube Aluminum Composite Coatings (고속 화염 용사를 통하여 형성된 다중벽 탄소 나노튜브 알루미늄 복합소재 코팅의 특성 평가)

  • Kang, Ki-Cheol;Park, Hyung-Kwon;Lee, Chang-Hee
    • Journal of the Korean institute of surface engineering
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    • v.45 no.1
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    • pp.1-7
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    • 2012
  • Multi-walled carbon nanotube (MWCNT) aluminum composite powders were deposited to form coatings using a high velocity oxygen fuel (HVOF) spraying process. High thermal energy and contact with atmospheric oxygen were supplied as the MWCNT aluminum composite particles were exposed to a gas flow field at high temperature (${\sim}3.0{\times}10^3$ K) during HVOF spraying. As a result, the particles underwent full or partial melting and rapid solidification due to the high thermal energy, and the exposure to oxygen induced the interfacial reaction of MWCNTs within the particle. The electrical and mechanical properties of MWCNT aluminum composite coatings were evaluated based on microstructure analysis. Electrical resistivity, elastic modulus, and micro-hardness, of the MWCNT aluminum composite coatings were higher than those of pure aluminum coating. The contribution of MWCNTs to the aluminum matrix can be attributed to their high electrical conductivity, dispersion hardening and anchoring effects. The relationship among the properties and the interaction of the MWCNTs with the aluminum matrix is discussed.

Preperation of Silicon Carbide Oxidation Protection Film on Carbon Thermal Insulator Using Polycarbosilane and Its Characterization (폴리카보실란을 이용하여 탄소단열재에 코팅한 실리콘카바이드 코팅막의 내산화 특성)

  • Ahn, Su-Bin;Lee, Yoonjoo;Bang, Jung-Won;Shin, Dong-Geun;Kwon, Woo-Teck
    • Korean Journal of Materials Research
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    • v.27 no.9
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    • pp.471-476
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    • 2017
  • In order to improve the high temperature oxidation resistance and lifespan of mat type porous carbon insulation, SiC was coated on carbon insulation by solution coating using polycarbosilane solution, curing in an oxidizing atmosphere at $200^{\circ}C$, and pyrolysis at temperatures up to $1200^{\circ}C$. The SiOC phase formed during the pyrolysis process was converted into SiC crystals as the heat treatment temperature increased, and a SiC coating with a thickness of 10-15 nm was formed at $1600^{\circ}C$. The SiC coated specimen showed a weight reduction of 8.6 % when it was kept in an atmospheric environment of $700^{\circ}C$ for 1 hour. On the other hand, the thermal conductivity was 0.17 W/mK, and no difference between states before and after coating was observed at all.

Characterization of Transparent Electrodes using Carbon Nanotubes Coated by Conductive Polymers (전도성 고분자가 코팅된 탄소 나노튜브 투명전극의 특성 분석)

  • Kim, Bu-Jong;Han, Sang-Hoon;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.1
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    • pp.19-25
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    • 2014
  • This study demonstrates transparent electrodes with characteristics desirable for touch screen panels using carbon nanotubes (CNTs). This has been accomplished by depositing CNTs on glass substrates via spray coating and then depositing thin conductive polymer films on the CNTs via spin coating. For all of the samples, such as CNTs, conductive polymers, and polymer-coated CNTs, the surface morphologies, sheet resistances, visible transmittances, chromatic properties are characterized as functions of their preparation conditions, such as the spray times for CNTs and the spin speeds for conductive polymers. The experimental results confirm that only the polymer-coated CNTs can satisfy all of the requirements that are required for electrodes of touch screen panels, such as the sheet resistance lower than $100{\Omega}/sq$, the visible transmittance higher than 80 %, and the yellowness smaller than 1.

Effect of Potassium Promoter on the Adsorption of Carbon Monoxide on Silica Supported Ruthenium

  • Lee, Jo-Woong;Chang, Sei-Hun;Pak, Hyung-Suk;Shin, Kook-Joe;Kim, Myung-Kun;Chung, Won-Il
    • Bulletin of the Korean Chemical Society
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    • v.9 no.3
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    • pp.137-143
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    • 1988
  • We have investigated the infrared spectra for carbon monoxide chemisorbed on silica supported ruthenium with and without potassium coating within the frequency range of 1800-2200 $cm^{-1}$ at various ruthenium concentrations and CO pressures. For the system without potassium coating, three bands were observed in the infrared spectra when CO was adsorbed on both the reduced and oxidized form of supported ruthenium. However, the relative intensities of these three bands were found to have no interdependence. Therefore, we have assigned each of these bands as arising from the CO stretching vibration for carbon monoxide molecules adsorbed on the Ru sites of different nature. On coating with potassium, the 2030 $cm^{-1}$ band observed for the system without potassium coating was found to suffer red shift by 10-30 $cm^{-1}$ and we conclude that this bathochromic shift is caused by enhancement in the capability of back donation of electrons from the metal atom to the antibonding ${\pi}{\ast}$ orbitals of CO due to the presence of potassium.

Effect of DLC Coating-layer on Engine Wear Characteristics for Improving Fuel Consumption of Automotive Engine (차량연비 향상을 위한 DLC 코팅 층이 엔진 마모특성에 미치는 영향)

  • Kim, Kee-Joo;Yoo, Seok-Jong;Choi, Byung-Ik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.1
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    • pp.112-119
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    • 2010
  • Recently, as the matters of environmental pollution, the energy exhaustion and alternative energy source have become more important issues, around industrial countries and the effort to improve fuel consumption is progressed continuously for decrease of air pollution. In an effort to improve fuel consumption for passenger cars, the study of DLC (Diamond Like Carbon) coating which is widely known to good wear characteristics come to the forefront. Therefore, in present study, it was investigated to the influence of DLC coating layer for wear characteristics with the piston ring material and then suggested to the development process for advanced automotive engine parts that showed improved wear characteristics. From these results, Finally, it will be contributed to improve the fuel consumption for passenger vehicles.

Characteristics of Hybrid-type Transparent Electrodes Fabricated by Coating Carbon Nanotubes with Conductive Polymers (탄소나노튜브 위에 전도성 고분자가 코팅된 하이브리드형 투명전극의 특성)

  • Park, Jin-Seok;Park, Jong-Seol;Kim, Bu-Jong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.36-41
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    • 2019
  • Hybrid-type transparent electrodes were fabricated by depositing carbon nanotubes (CNTs) via spray coating on polyethylene terephthalate (PET) substrates and then coating the CNTs with [poly(3,4-ethylenedioxythiophene)] (PEDOT) films via electro-polymerization. For all of the fabricated electrodes, their surface morphologies, electric sheet resistances, visible transmittances, and color properties (e.g., yellowness) were characterized as functions of the applied voltages and process times used in electro-polymerization. The sheet resistance of the CNTs was significantly reduced by the coating of PEDOT, while their visible transmittances slightly decreased. The yellowness values of the PEDOT-coated CNTs were observed to have substantially decreased via electro-polymerization. The experimental results confirmed that the fabricated hybrid electrodes had desirable properties for the application of transparent electrode in terms of the electrical resistance, optical transmittance, and chromaticity.

Pyrolytic Carbon Coating on A Simulated Fuel by Fluidized Bed Type Chemical Vapour Deposition

  • Park, Y.;Kim, Bong G.;Lee, Young W.;Dong S. Sohn
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.159-164
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    • 1997
  • Pyrolytic carbon layer was coated on A1203 balls by fluidized bed type chemical vapour deposition unit to develop the coating technology for the preparation of coated nuclear fuel. The deposition was carried out at the temperature ranges between 110$0^{\circ}C$ and 130$0^{\circ}C$ with various gas contents and flow rates. Source and carrier gas were propane and argon, respectively. X-ray analysis shows that the deposition layer was typical carbon spectra. The growth rate of carbon layer depended on the amount of source gas and the deposition temperature. For the alumina balls with 2mm in diameter, the deposition rate was 11${\mu}{\textrm}{m}$/hr in the flow gases containing 30% source gas at 130$0^{\circ}C$ with a total flow rate of 2.0$\ell$/min. Microstructural observation of the deposits with scanning electron microscope revealed that the deposits had relatively dense and isotropic structure. Chemical analysis by energy dispersive spectroscopy showed that the layer was pure carbon.

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The noble method for superhydrophobic thin film coating

  • Seo, Hyeon-Uk;Kim, Gwang-Dae;Jeong, Myeong-Geun;Kim, Dong-Un;Kim, Myeong-Ju;;Kim, Yeong-Dok;Im, Dong-Chan;Lee, Gyu-Hwan;Eom, Seong-Hyeon;Lee, Jae-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.496-496
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    • 2011
  • A very simple and cost-effective method for fabrication of SiOx-incorporated diamond-like carbon (DLC) thin films at a preparation temperature of less than $200^{\circ}C$ was developed. Since DLC coating can be prepared not under vacuum but atmospheric conditions without any carrier gas flow, not only wafers but also powderic substrates can be used for DLC coating. Formation of DLC coating could result in appearance of superhydrophobic behaviors, which was sustained in a wide range of pH (1~14). DLC-coated surfaces selectively interacted with toluene in a toluene/water mixture. These results imply that our preparation method of the DLC coating can be useful in many application fields such as creating self-cleaning surfaces, and water and air purification filters.

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