• Title/Summary/Keyword: Carbon Absorption

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Nitrogen Incorporation of Nanostructured Amorphous Carbon Thin Films by Aerosol-Assisted Chemical Vapor Deposition

  • Fadzilah, A.N.;Dayana, K.;Rusop, M.
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.4
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    • pp.165-171
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    • 2013
  • Nanostructured pure a-C and nitrogen doped a-C: N thin films with small particle size of, ~50 nm were obtained by Aerosol-assisted CVD method from the natural precursor camphor oil. Five samples were prepared for the a-C and a-C: N respectively, with the deposition temperatures ranging from $400^{\circ}C$ to $600^{\circ}C$. At high temperature, the AFM clarifies an even smoother image, due to the increase of the energetic carbon ion bombardment at the surface of the thin film. An ohmic contact was acquired from the current-voltage solar simulator characterization. The higher conductivity of a-C: N, of ${\sim}{\times}10^{-2}Scm^{-1}$ is due to the decrease in defects since the spin density gap decrease with the nitrogen addition. Pure a-C exhibit absorption coefficient, ${\alpha}$ of $10^4cm^{-1}$, whereas for a-C:N, ${\alpha}$ is of $10^5cm^{-1}$. The high ${\sigma}$ value of a-C:N is due to the presence of more graphitic component ($sp^2$ carbon bonding) in the carbon films.

Development of Composite Sr Ferrite EM Wave Absorbers for GHz Frequency (GHz 대역용 복합형 Sr 페라이트 전파 흡수체의 개발)

  • Kim, Dong-Il;Moon, Sang-Hyun;Shin, Sung-Jae;Song, Jae-Man;Kim, Ki-Man
    • Journal of Navigation and Port Research
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    • v.28 no.6
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    • pp.503-507
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    • 2004
  • We prepared EM wave absorbers by using recycled Sr ferrite for GHz frequency, and investigated the effects of carbon additions and preparation temperatures on their EM wave absorption properties. A Sr ferrite EM wave absorber with the ratio of Sr ferrite: silicon rubber: carbon = 80 : 13.6: 6.4 wt% prepared at 7$0^{\circ}C$ showed -24 dB at 9.4 GHz and -23 dB at 5.5 GHz for 2 mm and 3 mm thickness, respectively.

Process Design and Cost Estimation of Carbon Dioxide Compression and Liquefaction for Transportation (이산화탄소 수송을 위한 압축 및 액화 공정 설계 및 비용 평가)

  • Yang, Seeyub;Lee, Ung;Lim, Youngsub;Jeong, Yeong Su;Kim, Jeongnam;Lee, Chiseob;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.988-993
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    • 2012
  • Energy and cost analysis of the preprocessing for carbon capture and storage transportation such as supercritical compression and liquefaction is done using chemical simulation model. Direct compression to supercritical phase (process 1-1), liquefaction and pumping (process 1-2), carbon dioxide compression and expansion as a refrigerant itself (process 2), usage of other refrigerant with compression and expansion (process 3-1), with absorption chiller (process 3-2), cascade refrigeration (process 3-2) have been simulated and evaluated. The specific cost is about 4 to 7 $/ton.

Change of End-tidal PCS During Cardiopulmonary Bypass (체외순환시 호기말 이산화탄소압의 변화)

  • 오중환
    • Journal of Chest Surgery
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    • v.25 no.12
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    • pp.1399-1403
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    • 1992
  • The evaluation of the effectivess of ongoing cardiopulmonary resucitation efforts is dependent on the commonly used methods, such as the presence of femoral or carotid artery pulsations, arterial blood gas determinations, peripheral arterial pressure and intracardiac pressure monitoring. But recent studies suggest that end-tidal carbon dioxide tension serves as a non-invasive measurement of pulmonary blood flow and therefore cardiac output under constant ventilation. A prospective clinical study was done to determine whether end-tidal carbon dioxide monitoring in open heart surgery under cardiopulmonary bypass could be used as a prognostic indicator of bypass weaning. We monitored end-tidal PCO2 values continuously during cardiopulmonary bypass in 30 patients. "Ohmeda 5210 CO-2 monitor" under infrared absorption method were incorperated into the ventilator circuit by means of a side point adaptor between endotracheal tube and ventilator tubing. 18 patients[Group I ] were res-ucitated from partial bypass followed by aorta cross clamp off and 12 patients[Group II ] from aorta cross clamp off followed by partial bypass. But there was no difference between two groups[p>0.05]. The value of end-tidal carbon dioxide tension during ventricular fibrillation or nearly arrest state was 6.6$\pm$2.9 mmHg, and at the time of spontaneous beating was 19.3$\pm$5.6 mmHg[Mean$\pm$Standard deviation], In conclusion end-tidal carbon dioxide tension monitoring provides clinically useful, continous, noninvasive and supplementary prognostic indicator during cardiopulmonary bypass weaning procedures.rocedures.

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Optical Limiting Properties of Multi-Walled Carbon Nanotube Suspensions (다중벽 탄소 나노튜브 현탁액의 광 리미팅 특성)

  • Yu Hyojung;Kim Sok Won
    • Korean Journal of Optics and Photonics
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    • v.15 no.5
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    • pp.449-454
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    • 2004
  • The optical limiter is an optical component which reduces laser beam intensity for the protection of eyes and light sensors. Carbon nanotube is now known as a highly efficient optical limiting material. Optical limiting effect of the multi-walled carbon nanotube suspensions, in several kinds of solvents such as distilled water, chloroform, ethanol and ethylene glycol, were measured in the range from room temperature to near to the boiling points of the solvents. The pulsed Nd:YAG laser whose wavelength is 1064 nm and pulse duration is 6 ns was used as a light source. The experimental result shows that the limiting efficiency was reduced as the temperature increased, and the suspension which has lower boiling point, viscosity and surface tension has highest efficiency.

A Study on the Regeneration Energy Reduction through the Process Improvement of the Carbon Dioxide Capture Process (상전이 현상을 이용한 이산화탄소 포집공정개선 및 재생에너지 절감에 대한 연구)

  • Kim, Yu-Mi;Kim, Dong-Sun;Cho, Jung-Ho
    • Clean Technology
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    • v.18 no.2
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    • pp.221-225
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    • 2012
  • In this study, simulation works for a carbon dioxide capture process using solvent absorption method have been performed for decrease of regeneration energy in applying phase transition of liquid solvent. When carbon dioxide is dissolved in 30 wt% MEA solvent, liquid mixture divided into two phase according to mole loading of dissolved carbon dioxide. Using this phenomenon, we can decrease regeneration energy about 61% than primary absorber column-stripper column process.

Synthesis and Characterization of Calcium Derivative Combined with High-Surface-Area Activated Carbon Composites for Fine Toxic Gas Removal

  • Areerob, Yonrapach;Nguyen, Dinh Cung Tien;Dowla, Biswas Md Rokon;Kim, Hyuk;Cha, Je-Woo;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.473-479
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    • 2018
  • Highly toxic gases such as hydrogen sulfide ($H_2S$), carbon dioxide ($CO_2$), and ammonia ($NH_3$) are generated by both nature and human activities and affect human health. In this research, activated carbon combined with $Ca(OH)_2$ and $CaCO_3$ (AC-CO and AC-CC, respectively) were fabricated and applied in absorbing toxic gases from air pollutants. Activated charcoal powder was compressed in the form of pellets and used in the designated conditions. The optimum operating conditions and material properties, such as adsorption capacity, effect of weight ratio of the mixture, and hardness, have been investigated after combining with the calcium derivative. The good performance exhibited in this study suggests that this material is expected to be an effective and economically viable adsorbent for $NH_3$, $CO_2$, and $H_2S$ removal from the air system.

Absorption Properties of $CO_2$ in Aqueous Solutions of Piperazine, Piperidine, Cyclohexylamine (Piperazine, Piperidine, Cyclohexylamine 수용액에 대한 이산화탄소의 흡수특성)

  • Song Ho-Jun;Lee Seoungmoon;Song Hocheol;Ahn Se-Woong;Park Jin-won
    • Journal of Energy Engineering
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    • v.14 no.4 s.44
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    • pp.219-225
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    • 2005
  • for the removal of carbon dioxide in flue gas, which is the main cause of the global warming, chemical absorption methods were widely used for years. Alkanolamines such as MEA, AMP, MDEA are mainly used as an absorbent. In this study, cyclic amines - Piperazine, Piperidine and Cyclohelylamine are investigated to compare the chemical solubilities, absorption capacities and rate ot reaction. In conclusion, Piperazine is the most effective absorbent of $CO_2$ and ran be the excellent alternative to the former absorbents. Experiments were performed at 5, 10, 15 weight percent, 30, 40, $50^{\circ}C$, and the gas solubilities are determined by back-titration method, and using Gas Chromatography the absorption rate was compared.

Microstructure and Mechanical Properties of the Sintered Kaolin Block with Fly Ashes (Fly Ash를 이용한 고령토벽돌의 소결 특성)

  • Lee, Jin-Uk;Lee, Sung-Min;Kim, Hyung-Tae;Choi, Eui-Seok;Lee, Yong-Seok
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1164-1170
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    • 2002
  • The effect of fly ash addition to the kaolin block has been investigated. The addition affected the firing temperature and physical properties such as water absorption and compressive strength. The starting materials were from korea natural resources and the fly ash were from the power plant using coal as fuel, containing free carbon of 8∼9 wt%. The starting natural materials were mixed with 5 different proportions of fly ash, pressed and then sintered at 1050, 1100, 1150 and 1200${\circ}C$. With sintering temperature, water absorption decreased and compressive strength increased. When specimens were sintered at the temperature lower than 1100${\circ}C$, water absorption increased and strength decreased with fly ash content. In contrast, when sintering was done at the temperature higher than 1150${\circ}C$, water absorption increased with fly ash content similarly but strength was improved.

Corrosion on Steel Surfaces with Sea-Salt Deposition and Artificial Seawater Film

  • Katayama, Hideki;Yamamoto, Masahiro;Kodama, Toshiaki;Nagasawa, Makoto;Itagaki, Masayuki;Watanabe, Kunihiro
    • Corrosion Science and Technology
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    • v.3 no.2
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    • pp.47-53
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    • 2004
  • The conditions to simulate the atmospheric corrosion behavior in the laboratory were investigated to clarify atmospheric corrosion mechanism of steel material in coastal area, For airborne sea salt and artificial seawater droplet, the various behaviors were observed by optical microscope, The particle size of the dried airborne sea salt was about $20{\mu}m$, and was about 1/10 compared with the artificial seawater droplet. Though the airborne sea salt represented the same behavior as the thermodynamic water absorption, the behavior of the artificial seawater droplet deviated from the results of the thermodynamic calculation, It is concluded that the water absorption behavior is influenced by the particle size of the dried sea salt. The corrosion behaviors of carbon steels were observed under the deposited condition of airborne sea salt and artificial seawater droplet. The corrosion behaviors showed a different trend, indicating that the corrosion behavior depended on the particle size of the dried sea salt. The corrosion in the actual environrnent progressed greater than that in the chamber. Furthermore, the summer showed the greater corrosion than the spring. It is found that the corrosion behaviors are attributed to the influence of the environmental factors.