• Composites Research
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• v.33 no.6
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• pp.329-335
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• 2020

In this study, the thermo-rheological behaivors of petroleum pitches with different softening points were studied, and a B-stage phenolic resins/petroleum pitches blends were prepared by adding petroleum pitches to the phenolic resins. As a result, the petroleum pitch with different softening points decreased the fluidity of the petroleum pitch as the Quinoline insoluble (QI) content increased and showed the viscous properties of the solid. In addition, the effect of adding petroleum pitches having different softening points on the thermo-rheological properties of phenolic resins was investigated. When petroleum pitch with a high softening point was added, the fluidity of the phenolic resin was reduced, and the hardening behavior was fast. It was possible to control the curing rate and curing behavior of the phenolic resin by adding petroleum pitches of different softening points. Among them, the phenolic resin mixture to which P-Pitch 2 was added has a higher fluidity than other blends under the same curing temperature condition.

• Applied Chemistry for Engineering
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• v.26 no.4
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• pp.406-412
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• 2015

Unidirectional carbon/carbon (C/C) composites were manufactured using phenolic resins as a precursor of the carbonized matrix throughout a one-step manufacturing process. Also, molybdenum oxide ($MoO_3$) and binder pitches were impregnated with phenolic resins to improve the bulk density and mechanical property of the C/C composites. In this study, the influence of $MoO_3$ and binder pitches on mechanical properties of the C/C composites were investigated by measuring flexural strength (${\sigma}_f$) and interlaminar shear strength (ILSS). The results show that the enhancement of interfacial adhesions between the fibers and matrix resins of the C/C composites with $MoO_3$ and binder pitches which led to the improvement of mechanical properties of the C/C composites. This indicates that the presence of $MoO_3$ and binder pitches in C/C composites can develop the graphite structure and increase the bulk density.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.04a
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• pp.215-217
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• 2000

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.192-197
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• 2004

The anisotropy in coefficient of thermal expansion (CTE) between the in-plane and out-of-plane of 3-dimensional thick composite structures induces residual stresses and the large void content due to insufficient compaction of fabric composites, which results in low interlaminar strengths. In order to reduce the through thickness CTE and the void content, in this work, carbon fabric phenolic laminates were compacted by pressure generated by autoclave and a compressive jig, from which the through-thickness CTEs and the void contents were measured. From the measurement, it was found that the through-thickness CTE and the void content had different characteristics from ordinary composites due to gas produced during the cure reaction of phenolic resin.

• Carbon letters
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• v.7 no.1
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• pp.27-33
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• 2006

Carbon-ceramic composites were fabricated by using fly ash and PANOX fibers as reinforcement. Fly ash, because of its small size particles e.g. submicron to micron level can be effectively dispersed along with fibrous reinforcements. Phenolic resin was used as carbon precursor. Both dry as well as wet methods were used for forming composites. The resulting composites were characterized for their microstructure, thermal and mechanical properties. The microstructure and mechanical properties of composites are found to be dependent on type of the fly ash, fibrous reinforcements as well as processing parameters. The addition of fly ash improves hardness and the fibers, which get co-carbonized on heat treatment, increase the flexural strength of the carbon-ceramic composites. Composites with dual reinforcement exhibit about 30-40% higher strength as compared to the composites made with single reinforcement, either with fly ash as filler or with chopped fibers.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.10a
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• pp.133-136
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• 2001

The effect of pre-carbonization condition on the mechanical properties of nonwoven needle-punched carbon/phenolic composite was studied. The nonwoven Oxi-PAN felt was pre-carbonized at different temperature. The pre-carbonized Oxi-PAN felt was needle-punched and then carbonized. Needle-punched nonwoven carbon preforms were formed into composites with phenol resin. The tensile and flexural strengths showed maximum value with pre-carbonization temperature of $500^{\circ}C$. Compared with the non-pre-carbonized composite, the mechanical properties were slightly improved.

• Carbon letters
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• v.3 no.3
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• pp.127-132
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• 2002

Unidirectional polymer composites were prepared using high-strength carbon fibers as reinforcement and phenolic resin as matrix precursor with keeping fiber volume fraction at 30, 40, 50 and 60% respectively. These composites were carbonized at $1000^{\circ}C$ and graphitised at $2600^{\circ}C$ in the inert atmosphere. The carbonized and graphitised composites were characterized for mechanical properties as well as microstructure. Microscopic studies were carried out of the polished surface of carbonized and graphitised composites after etching by chromic acid, to understand the effect of fiber volume fraction on oxidation at fiber-matrix interface. It is found that the flexural strength in polymer composites increases with fiber volume fraction and so does for the carbonised composites. However, the trend was found to be reversed in graphitised composites. In all the carbonized composites anisotropic region has been observed at fiber-matrix interface which transforms into columnar type microstructure upon graphitisation. The extension of strong and weak columnar type microstructure is function of fiber volume fraction. SEM microscopy of the etched surface of the sample reveal that composites containing 40% fiber volume has minimum oxidation at the interface, revealing a strong interfacial bonding.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.47 no.9
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• pp.642-648
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• 2019

In this study, Image-based computational analysis using the developed models was performed to predict the degradation of effective properties by ablation. The ablation tests of carbon/phenolic composites were performed using a 0.4 MW arc-heated wind tunnel. The carbon/phenolic composite samples were scanned using the micro-computed tomography (Micro-CT) to analyze the ablation characteristics according to a duration time of the ablation test. By calibrating the scanned images, computational models were developed that reflect the actual microstructure of the ablation composites. Also, nine computational models that reflect the actual pore shape were developed using the created cross-sectional images. Image-based computational analysis using the developed models was performed to predict the degradation of effective properties by ablation and the decrease of effective properties was confirmed with increase of porosity.

• Carbon letters
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• v.4 no.3
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• pp.111-116
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• 2003

Carbon/carbon composites were developed using PAN based carbon fibres and phenolic resin as matrix in different volume fractions and heat treated to temperatures between $1000^{\circ}C$ to $2500^{\circ}C$. Although both the starting precursors are nongraphitizing hard carbons individually, their composites lead to very interesting properties e.g. x-ray diffractograms show the development of graphitic phase for composites having fibre volume fractions of 30~40%. Consequently the electrical resistivity of such composites reaches a value of $0.8\;m{\Omega}cm$, very close to highly graphitic material. However, it was found that by increasing the fibre volume fraction to 50~60%, the trend is reversed. Optical microscopy of the composites also reveals the development of strong columnar type microstructure at the fibre (matrix interface due to stress graphitization of the matrix. The study forcasts a unique possibility of producing high thermal conductivity carbon/carbon composites starting with carbon fibres in the chopped form only.

• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.472-477
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• 2016

We studied the effects of anodic oxidation treatments of carbon fibers on interfacial adhesion of the carbon fibers-reinforced epoxy matrix composites with various current densities. The surface of treated carbon fibers was characterized by atomic force microscope (AFM), field emission-scanning electron microscope (FE-SEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS). The interlaminar shear strength (ILSS) of the composites was determined by a short beam shear test. This result showed that both the roughness and oxygen group of the carbon fibers surface increased in proportion to the current density. After anodic-oxidation-treated, the ILSS also increased as a function of the current density. In addition, the proportional relationship between ILSS and phenolic hydroxyl group was confirmed. The ILSS of the CF-2.0 sample increased by 4% compared to that of the CF-AS sample, because the anodic oxidation treatment increased the oxygen group and roughness on the carbon fibers surface, which leading to the improvement of the interfacial adhesion of the carbon fibers-reinforced epoxy matrix composites. Among these, the phenolic hydroxyl group which has the proportional relationship with ILSS is found to be the most important factor for improving the interfacial adhesion of the carbon fibers-reinforced epoxy matrix composites.