• Title/Summary/Keyword: Carbon/carbon-based materials

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Low temperature deposition of carbon nanofilaments using vacuum-sublimated $Fe(CO)_5$ catalyst with thermal chemical vapor deposition

  • Kim, Nam-Seok;Kim, Kwang-Duk;Kim, Sung-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.1
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    • pp.18-22
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    • 2007
  • Carbon nanofilaments were deposited on silicon oxide substrate by thermal chemical vapor deposition method. We used $Fe(CO)_5$ as the catalyst for the carbon nanofilaments formation. Around $800^{\circ}C$ substrate temperature, the formation density of carbon nanofilaments could be enhanced by the vacuum sublimation technique of $Fe(CO)_5$, compared with the conventional spin coating technique. Finally, we could achieve the low temperature, as low as $350^{\circ}C$, formation of carbon nanofilaments using the sublimated Fe-complex nanograins with thermal chemical vapor deposition. Detailed morphologies and characteristics of the carbon nanofilaments were investigated. Based on these results, the role of the vacuum sublimation technique for the low temperature deposition of carbon nanofilaments was discussed.

A Review on Thermal Conductivity of Polymer Composites Using Carbon-Based Fillers : Carbon Nanotubes and Carbon Fibers

  • Hong, Jin-Ho;Park, Dong-Wha;Shim, Sang-Eun
    • Carbon letters
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    • v.11 no.4
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    • pp.347-356
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    • 2010
  • Recently, the use of thermal conductive polymeric composites is growing up, where the polymers filled with the thermally conductive fillers effectively dissipate heat generated from electronic components. Therefore, the management of heat is directly related to the lifetime of electronic devices. For the purpose of the improvement of thermal conductivity of composites, fillers with excellent thermally conductive behavior are commonly used. Thermally conductive particles filled polymer composites have advantages due to their easy processibility, low cost, and durability to the corrosion. Especially, carbon-based 1-dimensional nanomaterials such as carbon nanotube (CNT) and carbon nanofiber (CNF) have gained much attention for their excellent thermal conductivity, corrosion resistance and low thermal expansion coefficient than the metals. This paper aims to review the research trends in the improvement of thermal conductivity of the carbon-based materials filled polymer composites.

Mechanical properties of carbon fiber sheet and carbon fiber strand sheet based on carbon fibers for the reinforcement of highway bridge RC slabs (도로교 RC 상판 보강을 위한 탄소섬유 기초 carbon fiber sheet와 carbon fiber strand sheet의 역학특성)

  • Won, Chan Ho;Abe, Tadashi;Ahn, Tae-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.6
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    • pp.290-293
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    • 2015
  • Recently, a lot of interest has been shown in structural maintenance managements of civil infrastructures. Many researchers have been conducted on various maintenance techniques and repair materials. Among other fiber materials the carbon fiber materials are especially focused on maintenance management of Highway Bridges. Extensive work has been done on Carbon Fiber Sheet (CFS). Nevertheless, Carbon Fiber Strand Sheet (CFSS) is a newly developed material, on which limited work has been done until now. Therefore, in this study bonding the CFSS to RC slab specimen and fatigue resistance evaluation has been conducted. The results demonstrated an increase of 25.3 times more reinforcement of RC slab compared to non-reinforced RC slab. Moreover, compared to CFS-bonded RC slab, The CFSS-bonded RC slab showed 1.2 times greater reinforcement.

Finding Optimal Conditions for the Densification Process of Carbon Materials (탄소 소재 치밀화 공정의 밀도향상을 위한 최적 조건 설정)

  • Kwon, Choonghee;Yang, Jaekyung
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.40 no.3
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    • pp.76-82
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    • 2017
  • Recently, the material industry in the world has started appreciating the value of new materials that can overcome the limitation of steel material. In particular, new materials are expected to play a very important role in the future industry, demonstrating superior performance compared to steel in lightweight materials and ability to maintain in high temperature environments. Carbon materials have recently increased in value due to excellent physical properties such as high strength and ultra lightweight compared to steel. However, they have not overcome the limitation of productivity and price. The carbon materials are classified into various composites depending on the purpose of use and the performance required. Typical composites include carbon-glass, carbon-carbon, and carbon-plastic composites. Among them, carbon-carbon composite technology is a necessary technology in aviation and space, and can be manufactured with high investment cost and technology. In this paper, in order to find the optimal conditions to achieve productivity improvement and cost reduction of carbon material densification process, the correlation between each process parameters and results of densification is first analyzed. The main process parameters of the densification process are selected by analyzing the correlation results. And then a certain linear relationship between major process variables and density of carbon materials is derived by performing a regression analysis based on the historical production result data. Using the derived casualty, the optimal management range of major process variables is suggested. Effective process operation through optimal management of variables will have a great effect on productivity improvement and manufacturing cost reduction by shortening the lead time.

Using Coffee-Derived Hard Carbon as a Cost-Effective and Eco-Friendly Anode Material for Li-Ion Batteries

  • Hong, Sung Joo;Kim, Seong Su;Nam, Seunghoon
    • Corrosion Science and Technology
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    • v.20 no.1
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    • pp.15-21
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    • 2021
  • Through a simple filtration process, followed by carbonization within a reductive environment, coffee waste grounds can be transformed into a non-porous hard carbon for use in multiple contexts. This resulting coffee-waste carbon has been evaluated as an eco-friendly and cost-effective replacement for conventional graphite. When compared with different types of carbon, our study found that the coffee-waste carbon fell into the category of hard carbon, as verified from the galvanostatic charge/discharge profiles. The coffee-waste carbon showed a superior rate capability when compared to that of graphite, while compromising smaller capacity at low C rates. During electrochemical reactions, it was also found that the coffee-waste carbon is well exposed to electrolytes, and its disordered characteristic is advantageous for ionic transport which leads to the low tortuosity of Li ions. Finally, the high irreversible capacity (low initial Coulombic efficiency) of the coffee-waste carbon, which if also often observed in amorphous carbon, can be adequately resolved through a solution-based prelithiation process, thereby proving that the coffee-waste carbon material is quite suitable for commercial use as an anode material for quickly-chargeable electrodes.

Ammonia-fueled Solid Oxide Fuel Cell Recirculation Systems for Power Generation (암모니아 활용 고체산화물 연료전지 재순환 발전 시스템)

  • JIN YOUNG PARK;THAI-QUYEN QUACH;JINSUN KIM;YONGGYUN BAE;DONGKEUN LEE;YOUNGSANG KIM;SUNYOUP LEE;YOUNG KIM
    • Journal of Hydrogen and New Energy
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    • v.35 no.1
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    • pp.40-47
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    • 2024
  • Ammonia is drawing attention as carbon free fuel due to its ease of storage and transportation compared to hydrogen. This study suggests ammonia fueled solid oxide fuel cell (SOFC) system with electrochemical hydrogen compressor (EHC)-based recirculation. Performance of electrochemical hydrogen pump is based on the experimental data under varying hydrogen and nitrogen concentration. As a result, the suggested system shows 62.04% net electrical efficiency. The efficiency is 10.33% point higher compared to simple standalone SOFC system (51.71%), but 0.02% point lower compared to blower-based recirculation system (62.06%). Further improvement in the EHC-based SOFC recirculation system can be achieved with EHC performance improvement.

Photocatalytic Oxidation for Organic Dye using Phenol Resin-based Carbon-titania Composites

  • Oh, Won-Chun;Na, Yu-Ri
    • Journal of the Korean Ceramic Society
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    • v.45 no.1
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    • pp.36-42
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    • 2008
  • Carbon/$TiO_2$ composite photocatalysts were thermally synthesized with different mixing ratios of anatase to phenol resin through an ethanol solvent dissolving method. The XRD patterns revealed that only anatase phase can be identified for Carbon/$TiO_2$ composites. The diffraction peaks of carbon were not observed, however, due to the low carbon content on the $TiO_2$ surfaces and the low crystallinity of amorphous carbon. The results of chemical elemental analyses of the Carbon/$TiO_2$ composites showed that most of the spectra for these samples gave stronger peaks for carbon and Ti metal than that of any other elements. The BET surface area increases to the maximum value of $488\;m^2/g$ with the area depending on the amount of phenol resin. From the SEM images, small $TiO_2$ particles were homogeneously distributed to a composite cluster with the porosity of phenol resin-based carbon. From the photocatalytic results, the MB degradation should be attributed to the three kinds of synergetic effects, such as photocatalysis, adsorptivity, and electron transfer by light absorption between supporter $TiO_2$ and carbon.

Mechanical and Thermal Properties of Phenolic Composite reinforced with Hybrid of Carbon Fabrics (하이브리드화에 의한 탄소 직물 복합재료의 역학적 특성 및 열적 특성)

  • Kim, Jae-Hong;Park, Jong-Kyu;Jung, Kyung-Ho;Kang, Tae-Jin
    • Composites Research
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    • v.20 no.4
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    • pp.18-24
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    • 2007
  • The mechanical and thermal properties of PAN-based/rayon-based carbon fabrics interply hybrid composite materials have been studied. Mechanical properties including tensile and interlaminar shear strengths were improved with increasing amount of continuous PAN-based carbon fabrics. The erosion rate and insulation index were determined through the torch test. Continuous rayon-based carbon fabrics composite indicated relatively low ablation resistant property. The thermal conductivity of hybrid composite of spun PAN-based/continuous rayon-based carbon fabrics is lower than that of the continuous PAN-based carbon fabrics composite.

Microwave Absorption Study of Carbon Nano Materials Synthesized from Natural Oils

  • Kshirsagar, Dattatray E.;Puri, Vijaya;Sharon, Maheshwar;Sharon, Madhuri
    • Carbon letters
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    • v.7 no.4
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    • pp.245-248
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    • 2006
  • Thin films of carbon-nano materials (CNMs) of different morphology have been successfully deposited on ceramic substrate by CVD at temperatures $800^{\circ}C$, $850^{\circ}C$ and $900^{\circ}C$ using plant based oils in the presence of transition metal catalysts (Ni, Co and Ni/Co alloys). Based on the return and insertion loss, microwave absorption properties of thin film of nanocarbon material are measured using passive micro-Strip line components. The result indicates that amongst CNMs synthesized from oil of natural precursors (mustered oil - Brassica napus, Karanja oil - Pongamia glabra, Cotton oil - Gossipium hirsuta and Neem oil - Azadirachta indica) carbon nano fibers obtained from neem's seed oil showed better microwave absorption (~20dB) in the range of 8.0 GHz to 17.90 GHz.

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