• Title/Summary/Keyword: Carbon/V

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Fabrication of Carbon Nanotube Field Emitters

  • Yoon, Hyeun-Joong;Jeong, Dae-Jung;Jun, Do-Han;Yang, Sang-Sik
    • Journal of Electrical Engineering and Technology
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    • v.3 no.1
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    • pp.121-124
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    • 2008
  • This paper presents the fabrication and field emission of carbon nanotube field emitters for a micro mass spectrometer. The carbon nanotube is an adequate material as a field emitter since it has good characteristics. We have successfully fabricated a diode field emitter and a triode field emitter. Each field emitter has been constructed using several micromachining processes and a thermal CVD process. In the case of the diode field emitter, to increase the electric field, the carbon nanotubes are selectively grown on the patterned nickel catalyst layer. The electron current of the diode field emitter is 73.2 ${\mu}A$ when the anode voltage is 1100V. That of the triode field emitter is 3.4 pA when the anode voltage is 1000V.

Reinforcement of Polyethylene Pipes with Modified Carbon Microfibers

  • Petukhova, E.S.;Savvinova, M.E.;Krasnikova, I.V.;Mishakov, I.V.;Okhlopkova, A.A.;Jeong, Dae-Yong;Cho, Jin-Ho
    • Journal of the Korean Chemical Society
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    • v.60 no.3
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    • pp.177-180
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    • 2016
  • The surface properties of carbon microfibers (CMFs) are modified by chemical deposition of carbon nanofibers via the so-called ethylene processing. CMFs and the modified CMFs (MCMFs) are investigated as reinforcement additives to fabricate polyethylene (PE) composites with enhanced mechanical characteristics. The mechanical properties of the PE-MCMF composites are found to be better and favorable for applications under harsh climatic conditions such as those in Siberia. Improved adhesive interaction between MCMFs and PE is responsible for these enhanced mechanical properties.

The Electronic Structure of Carbon Nanotubes with Finite Length : Tight Binding Theory

  • Moon, Won-Ha;Kim, Won-Woo;Hwang, Ho-Jung
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.1
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    • pp.23-29
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    • 2002
  • The electronic properties of Carbon Nanotube(CNT) are currently the focus of considerable interest. In this paper, the electronic properties of finite length effect in CNT for the carbon nano-scale device is presented. To Calculate the electronic properties of CNT, Empirical potential method (the extended Brenner potential for C-Si-H) for carbon and Tight Binding molecular dynamic (TBMD) simulation are used. As a result of study, we have known that the value of the band gap decreases with increasing the length of the tube. The energy band gap of (6,6) armchair CNT have the ranges between 0.3 eV and 2.5 eV. Also, our results are in agreements with the result of the other computational techniques.

Charge/Discharge Properties of $V_{2}O_{5}$-Flyash Composite electrode for Supercapacitor (Supercapcitor용 $V_{2}O_{5}$-Flyash Composite 전극의 충방전 특성)

  • 김명산;김종욱;구할본;박복기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.335-338
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    • 2000
  • Carbon is an attractive candidate for use in eletrochemical supercapacitors that depend on charge storage in the electrode/electrolyte international double layer. Property of an electrical double layer capacitor depend both on the technique used to prepare the electrode and on the current collector structure. The study is to research that V$_2$O$_{5}$-flyash-AC composite electrode for supercapacitor. The discharge capacitance of V$_2$O$_{5}$-flyash-AC(70wt%) in 1st and 50th cycle was 18.6F/g and 15.13F/g at current density of 0.5mA/cm$^2$. The discharge process of V$_2$O$_{5}$-flyash (3 : 97)-AC composite electrode is larger than that others.thers.

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The Growth of Diamond-Like-Carbon (DLC) Film by PECVD and the Characterization (PECVD에 의한 DLC 박막의 성장과 그 특성 조사)

  • 조재원;김태환;김대욱;최성수
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.248-254
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    • 1998
  • DLC(Diamond-Like-Carbon) thin film, one of the solid state amorphous carbon films, has been deposited by the method of PECVD (Plasma Enhanced Chemical Vapor Deposition). The structural features have been characterized using both FT-IR Spectroscopy and Raman Scattering. The film is considered to consist of microcrystalline diamond domains and graphitelike carbon domains, which are interconnected by hydrogenated $sp^3$ tetrahedral carbons. This shows a good agreement with the results by I-Vmeasurements. In I-Vstudy, the sudden increase of current has been observed and this phenomenon is understood to be due to the tunneling effect between graphitelike domains. A characteristic feature related to the $\beta$-SiC has been identified in the study of Raman Scattering for the very thin film, which suggests that a buffer layer forms at the interface of the Si substrate and the carbon film.

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Determination of Fluoroquinolone Antibacterial Agents by Square Wave Adsorptive Stripping Voltammetry (네모파 흡착 벗김 전압전류법에 의한 플루오로퀴놀론 계 항생제의 검출)

  • Boo, Han-Kil;Song, Youn-Joo;Park, Se-Jin;Chung, Taek-Dong
    • Journal of the Korean Electrochemical Society
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    • v.13 no.1
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    • pp.63-69
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    • 2010
  • Electrochemical behavior of fluoroquinolone antibacterial agents on carbon paste electrode (CPE) were investigated by cyclic voltammetry and square wave adsorptive stripping voltammetry. The fluoroquinolone antibacterial agents tested in this study were Enrofloxacin (ENR), Norfloxacin (NOR), Ciprofloxacin (CIP), Ofloxacin (OFL) and Levofloxacin (LEV). In acetate buffer at pH 4.5, the oxidation peak potentials of the fluoroquinolone antibacterial agents of ENR, NOR, CIP, OFL, and LEV were 0.952 V, 1.052 V, 1.055 V, 0.983 V, and 0.990 V (vs. Ag/AgCl), respectively. And their oxidation peak currents from square wave adsorptive stripping voltammograms are proportional to the concentration of each antibacterial agent over the range from $0.2\;{\mu}M$ to $1\;{\mu}M$.

Adsorption Characteristics of As(V) onto Cationic Surfactant-Modified Activated Carbon

  • Choi, Hyun-Doc;Park, Sung-Woo;Ryu, Byung-Gon;Cho, Jung-Min;Kim, Kyung-Jo;Baek, Ki-Tae
    • Environmental Engineering Research
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    • v.14 no.3
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    • pp.153-157
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    • 2009
  • Arsenic at abandoned mine sites has adversely affected human health in Korea. In this study, the feasibility of using cationic surfactant-modified activated carbon (MAC) to remove As(V) was evaluated in terms of adsorption kinetics, adsorption isotherms, and column experiments. The adsorption of As(V) onto MAC was satisfactorily simulated by the pseudo-second-order kinetics model and Langmuir isotherm model. In column experiments, the breakthrough point of AC was 28 bed volumes (BV), while that of MAC increased to 300 BV. The modification of AC using cationic surfactant increased the sorption rate and sorption capacity with regard to As(V). As a result, MAC is a promising adsorbent for treating As(V) in aqueous streams.

Carbon Monoxide as a Novel Central Pyrogenic Mediator

  • Jang, Choon-Gon;Lee, Seung-Jin;Yang, Sang-In;Kim, Jin-Hak;Sohn, Uy-Dong;Lee, Seok-Yong
    • Archives of Pharmacal Research
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    • v.25 no.3
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    • pp.343-348
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    • 2002
  • Carbon monoxide (CO) are produced by heme oxygenase (HO), and HO was detected in hypothalamus. However, the roles of CO produced in hypothalamus was not fully elucidated. So, we tested the effects of CO on body temperature because preoptic-anterior hypothalamus was known as the presumptive primary fever-producing site. CO-saturated aCSF ($4{\;}{\mu}l$, i.c.v.) and hemin ($10{\;}{\mu}g$, i.c.v.) elicited marked febrile response. Pretreatment with indomethacin completely inhibited CO- and hemin-induced fever. Zinc protoporphyrin-IX ($10{\;}{\mu}g$, i.c.v.) or ODQ ($50{\;}{\mu}g$, i.c.v.) partially reduced hemin-induced febrile response. Dibutyryl-cGMP ($100{\;}{\mu}g$, i.c.v.) produced profound febrile response and this febrile response was attenuated by indomethacin. These results indicate that endogenous CO may have a role as a pyrogenic mediator in CNS and CO-mediated pyresis is dependent on prostaglandin production and partially on activation of soluble guanylate cyclase.

Trace Mercury Determination by Differential Pulse Anodic Stripping Voltammetry Using Polythiophene-Quinoline/Glassy Carbon Modified Electrode

  • Yoo, Kwang-Sik;Woo, Sang-Beom;Jyoung, Jy-Young
    • Bulletin of the Korean Chemical Society
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    • v.24 no.1
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    • pp.27-31
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    • 2003
  • A Polythiophene-quinoline/glassy carbon (PTQ/GC) modified electrode was developed for the determination of trace mercury in industrial waste water, natural water, soil, and other media. The electrode was prepared by the cyclic voltammetric polymerization of thiophene and quinoline on glassy carbon (GC) electrode by the potential application from -0.6 V to +2.0 V (50 mV/sec) in a solution of 0.1 M thiophene, quinoline and tetrabutyl ammonium perchlorate (TBAP) in acetonitrile. Optimum thickness of the polymer membrane on the GC electrode was obtained with 20 repeated potential cyclings. The redox behavior of Cu(Ⅱ) and Hg(Ⅱ) were almost identical on this electrode. The addition of 4-(2-pyridylazo)resorcinol (PAR) to the solution containing Cu(Ⅱ) and Hg(Ⅱ) allowed the separation of the components due to the formation of the Cu(Ⅱ)-PAR complex reduced at -0.8V, which was different from the Hg(Ⅱ) reduced at -0.5 V on a saturated calomel electrode (SCE). The calibration graph of Hg(Ⅱ) shows good linear relationship with the correlation factor of 0.9995 and the concentration gradient of 0.33 ㎂/㎠/ppb down to 0.4 ppb Hg. The method developed was successfully applied to the determination of mercury in samples such as river, waste water, and sea water.

The Study of Low Carbon Microalloyed Forging Steels by Direct Quenching Method with Mo Additions (몰리브덴을 첨가한 직접 소입 저탄소 비조질강에 관한 연구)

  • Wee, Kyoum-Bok;Lee, Kyung-Sub
    • Korean Journal of Materials Research
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    • v.2 no.6
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    • pp.452-460
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    • 1992
  • Effects of the microalloyed elements, temperatures and cooling rates on the strength and toughness of the medium carbon microalloyed hot forging steels obtained by air cooling(A.C.) method and the low carbon microalloyed forging steels by direct quenching(D.Q.) method were investigated. Combined additions of V+Nb produced the optimum combination of strength and toughness with ferrite-pearlite structure of the medium carbon steel by the A.C. method. 831MPa in UTS and 52.1J in toughness were obtained for 0.40c+0.12V+0.07Nb. It was martensite structure for the low carbon steel by the D.Q. method. The highest UTS and toughness obtained by Mo additions were 855MPa and 108j by 0.12C+0.10V+0.03Nb+1.13Mo respectively. Especially, the toughness of the low carbon steel was twice better than that of the medium carbon steel. 110$0^{\circ}C$was more appropriate than 120$0^{\circ}C$ for the reheating and forging temperature and 1.$2^{\circ}C$ /s was the best cooling rate from the viewpoint of the strength and toughness. Multiple regression analysis was used to quantify the influence of the microalloyed elements, temperatures and cooling rates on the strength, toughness, austenite grain size, and the pearlite interlamellar spacing.

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