• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2008년도 학술발표회 논문집
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• pp.495-499
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• 2008

본 연구는 빗물 저장조 시스템의 유출량 변화모의를 통해 지붕면 유출제어의 가능성을 확인하고, 설계조건에 적절한 저장조(retention tank)-펌프 용량 조합의 결정방안을 제시하였다. 저장조의 운전조건을 고려한 물수지 방정식을 이용해 서울지역의 강우특성에 따른 저류량 및 첨두유출유량 변화를 모의하고, 그 결과를 강우재현기간별 저장조 용량-첨두 유출량-펌프 배수량 관계곡선 (TPP 곡선) 으로 작성하였다. 100년 빈도 첨두 유출을 지선 하수관로의 설계기준인 5년 빈도 첨두유출까지 제어할 경우, 지붕면적 $100m^2$ 당 펌프배수 용량은 $0{\sim}25{\ell}$/분, 저장조 용량은 $8.5{\sim}10m^3$으로 결정되었다. 즉, 서울지역의 지붕면적 $100m^2$ 당 적절한 저장조+펌프 용량조합은 $10m^3+0{\ell}$/분${\sim}8.5m^3+25{\ell}$/분이라고 할 수 있다. TPP 곡선을 이용하여 설계조건에 적절한 빗물 저장조-펌프의 용량조합 방안을 알 수 있었으며, 이를 이용해 현장여건에 고려한 구체적인 용량을 결정할 수 있을 것이다.

• 자연과학논문집
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• 제11권1호
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• pp.131-135
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• 1999

본 연구는 소나무 수피를 상토로 이용하기 위한 연구의 일환으로 보수성을 증진하기 위하여 수행하였다. 연구목적을 달성하기 위하여 건조된 수피를 Wiley mill 또는 hammer mill로 분쇄하여 입도분포를 조절하거나, 분쇄된 물질에 폐암면을 일정 비율로 혼합한 후 토양물리적 특성의 변화를 조사하였다. 분쇄전 수피는 5.6 mm 이상의 직경를 가진 입자의 점유 비율이 86.5%였으나, Wiley mill 또는 hammer mill로 분쇄하므로써 1 mm 이상의 직경을 가진 입자의 점유비율이 감소하고, 1 mm 이하의 입자 비율이 증가하였으며, Wiley mill이 hammer mill 보다 분쇄효과가 높았다. 분쇄에 의해 공극율 및 기상율이 감소하고 용기용수량 및 잔존수분량이 증가하여 보수성이 증가함을 나타내고 있다. Wiley mill로 분쇄된 물질에 50%의 폐암면을 혼합한 경우 공극율 81.1%, 용기용수량 67.7%, 기상율 13.4%, 잔존수분량이 235ml를 갖는 것으로 측정되었는데, 이것은 분쇄와 폐암면의 혼합에 의해 보수성이 증가하였으며, 상업적 생산에 가장 많이 이용되는 피트모쓰+질석 대조구에 비해 보수성이 증가함에도 불구하고 더 좋은 통기성을 보유함을 의미하고 있다.

• Bulletin of the Korean Chemical Society
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• 제30권7호
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• pp.1598-1602
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• 2009

The particle size of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode powder was controlled effectively by dispersion using lauric acid as a surfactant. The samples treated by lauric acid showed smaller particles of approximately half the original size compared to the particles of a pristine sample. A structural change due to the dispersion of Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ powder was not detected. The rate performance of the Li[$Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode was improved by dispersion using lauric acid, which was likely due to the decrease of the particle size. In particular, a sample dispersed pristine powder using lauric acid (L2) presented a greatly enhanced discharge capacity and capacity retention at a high C rate. The discharge capacity of a pristine sample was only 133 m$Ahg^{-1}$ (3C rate) and 96 m$Ahg^{-1}$ (12C rate) at the tenth cycle. In contrast, the L2 electrode delivered higher discharge capacities of 160 m$Ahg^{-1}$ (3C rate) and 129 m$Ahg^{-1}$ (12C rate) at the tenth cycle. The capacity retention at a rate of 12C/2C was also enhanced from ~ 45% (pristine sample) to 57% (L2) by treatment with lauric acid.

• Bulletin of the Korean Chemical Society
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• 제14권6호
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• pp.692-696
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• 1993

Prediction of retention times in transition metal-mandelate and transition metal-tartrate complex systems were studied on the cation exchanger. Plots of k' vs [mandelate] and k' vs [tartrate] were obtained under the condition of a constant competing cation concentration. The equation to predict the retention time of transition metal ion was derived from the ion exchange equilibria. Individual capacity factors (${k_1}',\;{k_2}'$) and stability constants ($K_1,\;K_2$) of the complexes were calculated from the non-linear least square method. Good resolution of the transition metals was predicted by the stepwise equation in the gradient method. The values of retention times from the calculation and the experiment agreed well each other.

• 대한토목학회논문집
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• 제30권1C호
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• pp.53-63
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• 2010

함수특성곡선은 불포화지반의 거동을 분석하는데 있어서 매우 중요한 물성으로 활용되고 있으나 많은 경우 상재하중과 세립분의 영향을 고려하지 않은 상태에서 측정되어 적용해 왔다. 따라서 본 논문에서는 국내의 대표적인 풍화토를 대상으로 상재하중과 점토의 함유량에 따른 함수특성 영향을 살펴보았다. 상재하중, 세립분, 그리고 이력 조건을 고려하여 함수특성과 불포화 투수계수를 SWCC 시험결과를 토대로 평가하였다. 또한 불포화시 습윤용적과 확산능력에 대하여도 살펴보았다.

• Journal of Microbiology and Biotechnology
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• 제21권2호
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• pp.147-153
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• 2011

Bacillus species have been involved in metal association as biosorbents, but there is not a clear understanding of this chelating property. In order to evaluate this metal chelating capacity, cultures and spores from Grampositive bacteria of species either able or unable to produce surface layer proteins (S-layers) were analyzed for their capacity of copper biosorption. Only those endowed of S-layers, like Bacillus sphaericus and B. thuringiensis, showed a significant biosorption capacity. This capacity (nearly 50%) was retained after heating of cultures, thus supporting that structural elements of the envelopes are responsible for such activity. Purified S-layers from two Bacillus sphaericus strains had the ability to biosorb copper. Copper biosorption parameters were determined for strain B. sphaericus 2362, and after analyses by means of the Langmuir model, the affinity and capacity were shown to be comparable to other bacterial biosorbents. A competitive effect of $Ca^{2+}$ and $Zn^{2+}$, but not of $Cd^{2+}$, was also observed, thus indicating that other cations may be biosorbed by this protein. Spores that have been shown to be proficient for copper biosorption were further analyzed for the presence of S-layer content. The retention of S-layers by these spores was clearly observed, and after extensive treatment to eliminate the S-layers, the biosorption capacity of these spores was significantly reduced. For the first time, a direct correlation between S-layer protein content and metal biosorption capacity is shown. This capacity is linked to the retention of S-layer proteins attached to Bacillus spores and cells.

• 한국습지학회지
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• 제18권4호
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• pp.424-431
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• 2016

생태저류지와 같은 LID 시설은 강우유출수를 관리하기 위하여 적용된다. LID 개념이 강우유출수 관리 계획의 중요한 부분이 되면서, LID 시설의 수문학적 성능과 LID 시설이 배수분구의 수문환경에 미치는 영향에 대한 명확한 이해가 필요한 상황이다. 본 연구는 설계 전략으로서 유황곡선의 활용에 관한 사항을 다루고 있다. 많은 LID 시설들과 마찬가지로 생태저류지는 자연 상태의 수문현상을 재현하고자 설치된다. 본 연구에서는 유황곡선 기준을 만족하는 생태저류지의 크기를 결정하려는 시도가 수행된다. 연구 결과, 현재 비점오염저감시설의 용량기준인 "5mm * 처리대상구역의면적"은 불투수율 20-30%인 지역에 유효함을 살펴볼 수 있다. LID 시설이 전형적으로 설치되는 100% 불투수 지역의 경우 자연상태 유황곡선의 재현을 기준으로 보면 47mm 정도의 유출고를 차집할 수 있는 용량이 요구되며, 이는 처리대상구역 면적의 11% 정도가 생태저류지로 활용되어야함을 의미한다. 하지만, 시설의 용량과 시설 면적의 기준은현실적으로 구현 가능한 조건에서 설정되어야 할 것이며, 또한 처리대상구역의 개별적인 수문학적 특성을 반영하여 결정되어야 할 것이다.

• 한국전기전자재료학회논문지
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• 제29권4호
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• pp.255-262
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• 2016

Effects of $SiO_x$ or C shells on electrochemical properties of Si nanoparticles were investigated. $SiO_x$ shells with thickness of 10~15 nm were formed on homogeneously crystalline Si nanoparticles. Incase of Si-C nanoparticles, there were 30~40 layers of C with a number of defects. Li-ion batteries were fabricated with the above-mentioned nanoparticles, and their electrochemical properties were measured. Pristine Si shows a high IRC (initial reversible capacity) of 2,517 mAh/g and ICE (initial columbic efficiency) of 87%, but low capacity retention of 22%, respectively. $SiO_x$ shells decreased IRC (1,534 mAh/g) and ICE (54%), while the retention increased up to 65%, which can be explained by irreversible phases such as $LiO_2$ and $Li_2SiO_3$. C shells exhibited no differences in IRC and ICE compared to the pristine Si but an enhanced retention of 54%, which might be from proper defect structures.

• 전기화학회지
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• 제7권1호
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• pp.1-8
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• 2004

This paper deals with the recent development of high-voltage cathode materials of mono- and di- metal ions substituted spinel $LiMn_2O_4$ for lithium batteries. $LiCu_xMn_{2-x}O_4(0{\leq}x{\leq}0.5)$ shows reversible intercalation/deintercalation in two potential regions, $3.9\~43\;and\;4.8-5.0V$ and stable electrochemical cycling behavior but with low capacity. $LiNi_{0.5}Mn_{1.5}O_4$ obtained by a sol-gel process delivers a capacity of 127mAh $g^{-1}$ on the first cycle and sustains a value of 124 mAh $g^{-1}$ even after the 60th cycle. The $Li_xCr_yMn_{2-y}O_4(0{\leq}x{\leq}0.5)$ solid-solutions exhibit enhanced specific capacity, larger average voltage, and improved cycling behaviors for low Cr content. $LiCr_yMn_{2-y}O_4$ presents a reversible Li deintercalation process at 4.9V, whose capacity is proportional to the Cr content in the range of $0.25{\leq}x{\leq}0.5$ and delivers higher capacities. $LiM_yCr_{0.5-y}Mn_{1.5}O_4(M=Fe\;or\;Al)$ shows that the capacity retention is lowered compared with lithium manganate. The cumulative capacities obtainable with Al-substitutted materials are less than those with Fe-substituted materials. $LiCr_xNi_{0.5-x}Mn_{1.5}O_4(x=0.1)$ delivers a high initial capacity of 1$152mAh\;g^{-1}$ with excellent cycleability.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.277-277
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• 2010

The capacity of the carbonaceous materials reached ca. $350\;mAhg^{-1}$ which is close to theorestical value of the carbon intercalation composition $LiC_6$, resulting in a relatively low volumetric Li capacity. Notwithstanding the capacities of carbon, it will not adjust well to the need so future devices. Silicon shows the highest gravimetric capacities (up to $4000\;mAhg^{-1}$ for $Li_{21}Si_5$). Although Si is the most promising of the next generation anodes, it undergoes a large volume change during lithium insertion and extraction. It results in pulverization of the Si and loss of electrical contact between the Si and the current collector during the lithiation and delithiation. Thus, its capacity fades rapidly during cycling. We focused on electrode materials in the multiphase form which were composed of two metal compounds to reduce the volume change in material design. A combination of electrochemically amorphous active material in an inert matrix (Si-M) has been investigated for use as negative electrode materials in lithium ion batteries. The matrix composited of Si-M alloys system that; active material (Si)-inactive material (M) with Li; M is a transition metal that does not alloy with Li with Li such as Ti, V or Mo. We fabricated and tested a broad range of Si-M compositions. The electrodes were sputter-deposited on rough Cu foil. Electrochemical, structural, and compositional characterization was performed using various techniques. The structure of Si-M alloys was investigated using X-ray Diffractometer (XRD) and transmission electron microscopy (TEM). Surface morphologies of the electrodes are observed using a field emission scanning electron microscopy (FESEM). The electrochemical properties of the electrodes are studied using the cycling test and electrochemical impedance spectroscopy (EIS). It is found that the capacity is strongly dependent on Si content and cycle retention is also changed according to M contents. It may be beneficial to find materials with high capacity, low irreversible capacity and that do not pulverize, and that combine Si-M to improve capacity retention.