• Title/Summary/Keyword: Calcium powder

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Re-hydration of Heat-treated $CaO-SiO_2-H_2O$ System and Their Application under Hydrothermal Condition (열처리한 $CaO-SiO_2-H_2O$계의 수열반응과 이의 응용에 관한 연구)

  • 윤철현;송태웅
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1387-1395
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    • 1994
  • Re-hydration properties of heated and ground CaO-SiO2-H2O system were studied under hydrothermal condition in order to examine the possibility of recycling ALC waste as raw materials of ALC. Powder of calcium silicate hydrates and ALC waste without heat treatment did not show further hydration while those of heat-treated at proper temperature showed re-hydration properties under hydrothermal condition. The lath-like shape of initially synthesized tobermorite was gradually turned into small debris during heating and plate-like tobermorite was crystallized during re-hydration of the heated powders. Heated and ground ALC waste could be added to natural raw mix for ALC at the ammount up to 20% with increased compressive strength and up to 30% with slightly decreased compressive strength. The optimum heating temperature of ALC for recycling was about 50$0^{\circ}C$.

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Improvement of Concrete Durability under Deicier and Freez-Thaw Environment (제설제 및 동결융해 환경하에서 콘크리트의 내구성 증진 방안에 관한 연구)

  • Lee, Byung-Duck;Yun, Byung-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.523-526
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    • 2005
  • In order to traffic safety during winter season, snowfall and cold area has been spread the deicing chemicals, and the spraying amount is increasing every year. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, the source of substantial cost penalties due to their corrosive action and acceleration to deterioration concrete structures. Deterioration due to de-icer salt occurs in practice in concrete pavement, dike, barrier and similar structure. This paper reports the results of effect of de-icer salt on durability of concrete structure in winter. To protect concrete structure from damage by de-icer salt in winter, the exposure test was performed using three methods such as increase in design strength upto 32MPa application of granulated blast furnace slag powder, and concrete sealer. Of these, the method of increase in design strength upto 32MPa showed better durability for deterioration by de-icer salt.

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Thermal Decomposition and Sintering Characteristics of Cr-Deficient $(La,Ca)CrO_3$ (크롬부족 (란탄, 칼슘)크로마이트의 열분해과정 및 소결특성)

  • 이상기;조성걸
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1182-1186
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    • 1997
  • La0.8Ca0.2Cr0.98O3 powder was prepared using the modified Pechini process. Various crystalline phases formed during thermal decomposition were investigated. (La,Ca)CrO4 phase, first formed from the precursor, was transformed to (La,Ca)CrO3 and CaCrO4 above 80$0^{\circ}C$, which remained up to 110$0^{\circ}C$. However, only (La,Ca)CrO3 phase consisting of orthorhombic and intermediate rhombohedral polymorphs was observed after sintering at 125$0^{\circ}C$. The specimens sintered at 140$0^{\circ}C$ exhibited 98% of relative density and rather wide grain size distribution with average grain size of 3-4 ${\mu}{\textrm}{m}$. Densification and grain growth of the specimens observed above 125$0^{\circ}C$ were presumably attributed to liquid phase sintering resulted from melting of Ca3(CrO4)2 phase.

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Cholesterol-Lowering Effect and Anticancer Activity of Kimchi and Kimchi Ingredients (김치와 김치재료의 콜레스테롤 저하 및 항암효과)

  • 이재준;정영기
    • Journal of Life Science
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    • v.9 no.6
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    • pp.743-752
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    • 1999
  • The purpose of the paper is to explore the current knowledge on the nutritional evaluation, cholesterol-lowering effect and antitumor activity of kimchi and its ingredients(Korean cabbage, garlic, red pepper powder, ginger and onion). Kimchi contains high contents of nutrients such as vitamins(ascorbic acid, $\beta$-carotene and vitamin B complex), minerals(calcium, potassium, iron and phosphorous), essential amino acids and dietary fiber. Kimch also contains high levels of lactic acid bacteria, allicin, capsaicin, organic acid, phenol compounds, flavonoid and sulfur compounds. The dietary fiber and lactic acid bacteria isolated from kimchi are effective in improving intestinal microflora of human. Isoluble dietary fiber shows anticancer activity, but soluble dietary fiber shows hypocholesterolemic effect. Lactic acid bacteria isolated from kimchi acts as a hypocholesterolemic or anticancer agent. A major ingredient of kimchi is mainly cruciferous and allium family vegetables, which were also reported to prevent cancer and atherosclerosis. It is suggested that kimchi is important not only as one of the traditional fermented Korean food but also as therapeutic agent for carcinogenesis and hypercholesterolemic state.

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Effects of Limestone on the Dissolution of Phosphate from Sediments under Anaerobic Condition (혐기성 퇴적물에서 석회석이 인산염용해에 미치는 영향)

  • Kim, Hag Seong;Park, Juhyun
    • Journal of Korean Society on Water Environment
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    • v.23 no.1
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    • pp.81-86
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    • 2007
  • This paper describes a study on the role of limestone which might affect the dissolution of phosphates when phosphate containing sediments are put under anaerobic conditions. A small quantity of calcium hydroxy-apatite, alone or mixed with limestone powder, was put in contact with aqueous solution of acetic acid or carbonic acid, and variations of phosphate concentration were determined time dependantly. The results showed that the concentration was remarkably low in the presence of limestone, signifying that the coexistence of limestone suppresses the dissolution of phosphate by organic acid and/or carbonic acid. Separate experiments conducted by developing an anaerobic condition, after mixing lake sediments with dried leaves and limestone, showed that the existence of limestone suppressed the dissolution of phosphate. These results show that the application of limestone might be a useful measure to prevent deterioration of water quality originated from eutrophication by inhibiting the internal loading of P in eutrophic water-bodies.

A Study on the Absorptive Removal of Magnesium ion and Calcium ion for Corrosion Prevent (부식방지를 위한 마그네슘 및 칼슘 이온의 흡착 제거에 관한 연구)

  • Hong Sung-Uk;An Hyung-Hwan
    • Journal of the Korean Society of Safety
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    • v.19 no.3 s.67
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    • pp.40-44
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    • 2004
  • To the removal of hardness materials, we've test the absorptive capacity of main material $Mg^{2+},\;Ca^{2+}$ on the using the activated carbon powder saturated in 0.1M Nitrilotriacetic acid by experimental methods. The absorptive properties of $Ca^{2+}\;and\;Mg^{2+}$ were measured with absorbent quantity and contact time., and investigated the physical properties of overall rate constant and adsorption constant adsorption isotherm, and Langmuir and Freundlich constant. In case of k' adsorption rate constants of $Ca^{2+},\;Mg^{2+}$, was 0.00299, 0.00529 by Bhattahary and Venkobachar equation. $k_{aa}$ was 0.00373, 0.00640 according with adsorption rate constants of Lagergren.

An Experimental Study on the Properties of Drying Shrinkage for Alkali-Activated Slag Mortar (알칼리 자극제를 혼입한 고로슬래그 모르타르의 건조수축 특성에 관한 실험적 연구)

  • Chun Jung-Hwan;Kim Jae-Hun;Jee Nam-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.97-100
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    • 2006
  • This paper report the result of the investigation on the properties of drying shrinkage for alkali-activated slag mortar in different relative humidity Commonly we know that drying shrinkage means lost more moisture but the mechanism of drying shrinkage of alkali activated slag mortar is not entirely due to the quantity of weight loss of water from mortar. pore size distribution and the calcium silicate hydrate gel characteristics have a critical influence on the magnitude of drying shringkage to alkali activated slag mortar. For this investigation, Ca(OH)2, Na2SiO4 were as alkali activator with 5 dosages(6%, 9%, 12%, 15%, 20%) and curing condition were three different relative humidity(35%, 65%, 95%) at $20{\pm}3^{\circ}C$

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The Fabrication of 4 Poles Anisotropic Plastic Magnets (4극 이방성 플라스틱자석의 제조)

  • 정왕일;진성빈;문현욱;신용진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.125-127
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    • 1996
  • This paper deals with the fabrication of 4 poles anisotropic Sr·ferrite plastic magnets. After Polyamide6 and polyamlde12 are kneaded respectively with Sr·ferrite powder, silane coupling and calcium stearate of lwt% are added for coating and pelleting. The pelleted specimen are injection-moulded under the magnetic field using 4 poles mould. For 4 poles anisotropic Sr·ferrite plastic magnets with polyamide6 as a binder, the surface magnetic flux density distribution is +943.8∼-943.87kG and the deviation is 5.2%, where as with polyamide12, the distribution is +1040.9∼-1040.9kG and the deviation is 5.4%. It shows that both of the magnet distributions are stable. As the results of the experiments, we find 4 poles anisotropic Sr·ferrite magnets have good properties as the materials appropriate for manufacturing magnet type synchronous motors.

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Durable of Concrete in Snowfall and Cold Regions (적설한랭지역에서 콘크리트의 내구성)

  • Lee, Byung-Duck;Cheong, Hai-Moon;Yun, Byung-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.221-224
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    • 2005
  • In order to traffic safety during winter season, snowfall and cold area has been spread the deicing chemicals, and the spraying amount is increasing every year. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, the source of substantial cost penalties due to their corrosive action and acceleration to deterioration concrete structures. Deterioration due to de-icer salt occurs in practice in concrete pavement, dike, barrier and similar structure. This paper reports the results of effect of de-icer salt on durability of concrete structure in winter. To protect concrete structure from damage by de-icer salt in winter, the exposure test was performed using three methods such as increase in design strength upto 35MPa application of granulated blast furnace slag powder, and concrete sealer. Of these, the method of increase in design strength upto 35MPa showed better durability for deterioration by de-icer salt.

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Hydration Analysis of Fine Particle and Old Mortar Attached on the Surface of Recycled Aggregate

  • Ko, Dong-Woo;Choi, Hee-Bok
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.5
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    • pp.460-467
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    • 2012
  • When recycled aggregate with old mortar and particles is used in concrete mixing, such aggregates can affect hydration reaction by promoting or inhibiting it. In this study, the possibility of hydration reaction on old mortar and particle was analyzed. Hydration reaction was carried out in old mortar that is finely crushed by an impact machine in the production of recycled aggregates, and it was found that this did have an impact on the strength development of concrete. Unlike in old cement, the hydration reaction did not progress in the particles, and it had high amounts of silica powder and calcium carbonate. In conclusion, the old mortar can have the influence of improving compressive strength, but the particles can delay the setting time of recycled aggregate concrete.