• Title/Summary/Keyword: Calcium aluminate cement

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High-velocity impact of large caliber tungsten projectiles on ordinary Portland and calcium aluminate cement based HPSFRC and SIFCON slabs -Part I: experimental investigations

  • Korucu, H.;Gulkan, P.
    • Structural Engineering and Mechanics
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    • v.40 no.5
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    • pp.595-616
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    • 2011
  • Impact experiments have been carried out on concrete slabs. The first group was traditionally manufactured, densely reinforced concrete targets, and the next were ordinary Portland and calcium aluminate cement based HPSFRC (High performance steel fiber reinforced concrete) and SIFCON (Slurry infiltrated concrete) targets. All specimens were hit by anti-armor tungsten projectiles at a muzzle velocity of over 4 Mach causing destructive perforation. In Part I of this article, production and experimental procedures are described. The first group of specimens were ordinary CEM I 42.5 R cement based targets including only dense reinforcement. In the second and third groups, specimens were produced using CEM I 42.5 R cement and Calcium Aluminate Cement (CAC40) with ordinary reinforcement and steel fibers 2 percent in volume. In the fourth group, SIFCON specimens including 12 percent of steel fibers without reinforcement were tested. A high-speed camera was used to capture impact and residual velocities of the projectile. Sample tests were performed to obtain mechanical properties of the materials. In the companion Part II of this study, numerical investigations and simulations performed will be presented. Few studies exist that examine high-velocity impact effects on CAC40 based HPSFRC targets, so this investigation gives an insight for comparison of their behavior with Portland cement based and SIFCON specimens.

Calcium Sulfo Aluminate (CSA) Cement from Coal Ash Utilized as Barriers for Radioactive Waste Disposal

  • Ramakrishna, Chilakala;Thriveni, Thenepalli;Whan, Ahn Ji
    • Journal of Energy Engineering
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    • v.27 no.1
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    • pp.33-39
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    • 2018
  • In this paper, we reviewed briefly about the barrier materials for the radioactive waste disposal. The primary concept of the radioactive waste disposal is safety. The goal of the radioactive waste management is to assure that the environment is not adversely affected and also public. There are a wide variety of materials are available for the radioactive waste disposal or storage. Among those coal fly ash is one of the significant materials are used as a barrier material. Here we reported, the Calcium sulfo aluminate (CSA) from coal fly ash is effectively suitable for the radioactive waste disposal. This is one of the ways of utilization of waste and manufactured the valuable materials for future indeeds.

An Experimental Study on Evaluation of Repair Mortars with CAC (Calcium Aluminate Cement) for Sewer Pipe (하수관거 보수용 CAC 모르타르 성능평가에 대한 실험적 연구)

  • Chung, Jee-Seung;Kang, Weon-Dae
    • Journal of the Korean Society of Safety
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    • v.27 no.4
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    • pp.68-75
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    • 2012
  • The biogenic corrosion of mortars adopted in sewage repair by sulfuric acid-producing bacteria was considered in this paper. Calcium aluminate cement (CAC) was known to resist microbiologically-induced corrosion significantly better than portland and blended portland cement.In this study, CAC as well portland cement mortars were tested as main binder to evaluate the corrosion resistance by the chemical immersion test. Replacement ratios of CAC were changed as 0, 20, 40, 50, 60% of OPC binder and 0, 2, 4, 6% of EVA(Ethylene Vinyl Acetate) were also adopted to increase properties of CAC repair mortars in sewage application. Setting time, compressive strength, acid resistance and adhesive strength were measured for various experiments. As a results of the experiments, the proper formulation of repair mortars was found at 40% of CAC and 4% of EVA. Finally, the CAC mortars adopted in field sewer pipe and were demonstrated to superior in adhesion and workability.

High-velocity impact of large caliber tungsten projectiles on ordinary Portland and calcium aluminate cement based HPSFRC and SIFCON slabs -Part II: numerical simulation and validation

  • Gulkan, P.;Korucu, H.
    • Structural Engineering and Mechanics
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    • v.40 no.5
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    • pp.617-636
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    • 2011
  • We present the numerical implementation, simulation, and validation of the high-velocity impact experiments that have been described in the companion article. In this part, numerical investigations and simulations performed to mimic the tests are presented. The experiments were analyzed by the explicit integration-based software ABAQUS for improved simulations. Targets were modeled with a damaged plasticity model for concrete. Computational results of residual velocity and crater dimensions yielded acceptable results.

Chloride Binding Properties of Portland Cement Binder Incorporating CaAl2O4-CaAl4O7 (CaAl2O4-CaAl4O7 혼입 포틀랜드 시멘트 결합재의 염소이온 고정 특성)

  • Han, Jae-Doh;Lee, Yun-Su;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.4
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    • pp.1-9
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    • 2020
  • This study conducted to understand effects of CA (CaAl2O4) and CA2 (CaAl4O7) ratio on chloride binding ability and compressive strength and pore structure of cement mortar incorporating mixture of CA and CA2. The Portland cement based specimens were mixed with the clinkers CA and CA2, and these calcium aluminate clinker mixture were replaced 0, 5, 10% by weight of cement. After all the test specimens were cured for 28 days under water curing, they were immersed in the distilled water and NaCl solution. As a result, 28 days compressive strength of all specimens was similar, and As the replacement ratio of calcium aluminate clinker in the specimen increased, Friedel's salt production tended to increase. However, it was dependent on the amount of Al2O3 in the level of 5% replacement and CA ratio in the level of 10% replacement. Through equilibrium isotherm result, it was also indicated that as replacement ratio of calcium aluminate clinker in cement matrix increased, chloride binding capacity was improved, and chloride penetration was suppressed. In this study, the specimen replaced with 10% of the calcium aluminate clinker mixture (CA 39%, CA2 60%) was remarkable to control chloride attack. We figured out necessity to understand optimal CA/CA2 ratio to effectively apply CA2 as a sustainable building material by improving the chloride binding ability in Portland cement based system.

The effects of calcium aluminate cement according to particle sizes on calvarial bone defects in rats (백서 두개골 결손부에서 입자 크기에 따른 Calcium aluminate cement의 효과)

  • Shin, Jung-A;Yun, Jeong-Ho;Oh, Seung-Han;Paik, Jeong-Won;Choi, Se-Young;Kim, Chong-Kwan;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • v.32 no.4
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    • pp.769-779
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    • 2002
  • This present study was carried out to find the effects of calcium aluminate cement($CaO\;{\cdot}\;Al_2O_3$, CAC), which has been developed with bio-compatibility and mechanical properties, in biological environments. Two different particle sizes of CAC - 3.5${\mu}m$ vs. 212${\sim}$250${\mu}m$ which is recommended in periodontal bone grafting procedures-were filled in 8mm calvarial defect in Sprague-Dawley rat. The specimens were examined histologically, especially the bone-cement interface and the response of surrounding tissues. The results are as follows; 1. In the control group, inflammatory cells were observed at 2 weeks. At 8 weeks, periosteum and dura mater were continuously joined together in the defect areas. But in the center of defect area were filled up with the loose connective tissues. 2. In the experimental group l($212{\mu}m{\sim}250{\mu}m$ particle), immature bone was formed and outermost layer was surrounded by osteoid layer at 2 weeks. Osteoblasts were arranged between immature bone and osteoid layer. And, osteoid layer was remained until 8 weeks after surgery. 3. In the experimental group 2, periosteum and dura mater lost its continuity at 2 weeks. Scattering of CAC particles and infiltration of inflammatory cells were observed, which this findings deepened at 8 weeks. The result of this study shows that when calvarial defects in white rats are filled with calcium aluminate cement of 212${\sim}$250${\mu}m$, the materials are to be bio-compatible in growth and healing on surrounding tissues. When further researches are fulfilled, such as direct bone adhesion and bone regeneration ability, it's possible that CAC could be applied to various periodontology fields in the future.

The Effect of Addition of Blast-furnace Slag Powder and Limestone powder on Shotcrete Binder with Calcium Aluminate Accelerator (고로슬래그 분말 및 석회석 분말이 시멘트 광물계 급결제를 사용한 숏크리트 결합재 물성에 미치는 영향)

  • Kang, ong-Hee;Kim, Gyu-Yong;Choi, Jae-Won;Koo, Kyung-Mo;Hwang, Bong-Choon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.2
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    • pp.86-93
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    • 2020
  • Shotcrete concrete is generally used in the form of ready-mixed concrete products using type I ordinary portland cement(hereinafter referred to as OPC) and about 5% of accelerator mixed separately in the field. In this study, we tested the effect of addition of slag powder(SP) and limestone powder(LSP) on a penetration resistance, compressive strength of binder for shotcrete using calcium aluminate type accerlerator. And we analysed hydrates and pore structure effects on mortar performance. In the future, it is expected to be useful for manufacturing optimized composite cement as a binder for shotcrete.

Properties and Environmental Effects Estimation of Grout Using Set Accelerating Agent Made From Calcium Aluminate and Viscosity Agent (칼슘알루미네이트계 급결재와 증점제를 사용한 그라우트의 특성 및 환경영향 평가)

  • Heo, Hyung Seok;Yi, Seong Tae;Noh, Jae Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.4
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    • pp.122-129
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    • 2012
  • In this study, environmental problems(i.e., pH elevation and $Cr^{6+}$ detection) occurred by using the cement grout made from CA(calcium aluminate) were evaluated using viscosity agents(MC, chelate polymer). Ordinary portland cement and blaste-furnace slag cement were used by main materials and ACC(blended mixture of calcium aluminate) were used by accelerator for hardening of grout. In addition, viscosity agents were used for preventing pH elevation and heavy metal detection from grouting materials. From the results, it was noted that when chelate polymer was used, pH elevation and $Cr^{6+}$ detection were minimized. However, other cases showed higher pH elevation and $Cr^{6+}$ detection. At test 1 day, $Cr^{6+}$ detection with age presented over 97% of total value and, after that, additional increase was not distinct. As a result of this study, it was acknowledged that, to control pH elevation and heavy-metal (like $Cr^{6+}$) detection, the usage of BSC and chelate polymer is a very useful fact.