• Restorative Dentistry and Endodontics
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• 제48권4호
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• pp.41.1-41.17
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• 2023

Objectives: This scientometric and bibliometric analysis explored scientific publications related to hydraulic calcium silicate-based (HCSB) sealers used in endodontology, aiming to describe basic bibliometric indicators and analyze current research trends. Materials and Methods: A comprehensive search was conducted in Web of Science and Scopus using specific HCSB sealer and general endodontic-related terms. Basic research parameters were collected, including publication year, authorship, countries, institutions, journals, level of evidence, study design and topic of interest, title terms, author keywords, citation counts, and density. Results: In total, 498 articles published in 136 journals were retrieved for the period 2008-2023. Brazil was the leading country, and the universities of Bologna in Italy and Sao Paolo in Brazil were represented equally as leading institutions. The most frequently occurring keywords were "calcium silicate," "root canal sealer MTA-Fillapex," and "biocompatibility," while title terms such as "calcium," "sealers," "root," "canal," "silicate based," and "endodontic" occurred most often. According to the thematic map analysis, "solubility" appeared as a basic theme of concentrated research interest, and "single-cone technique" was identified as an emerging, inadequately developed theme. The co-occurrence analysis revealed 4 major clusters centered on sealers' biological and physicochemical properties, obturation techniques, retreatability, and adhesion. Conclusions: This analysis presents bibliographic features and outlines changing trends in HCSB sealer research. The research output is dominated by basic science articles scrutinizing the biological and specific physicochemical properties of commonly used HCSB sealers. Future research needs to be guided by studies with a high level of evidence that utilize innovative, sophisticated technologies.

• Restorative Dentistry and Endodontics
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• 제49권2호
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• pp.20.1-20.13
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• 2024

Objectives: This study investigated the nanoleakage of root canal obturations using calcium silicate-based sealer according to different drying methods. Materials and Methods: Fifty-two extracted mandibular premolars with a single root canal and straight root were selected for this study. After canal preparation with a nickel-titanium rotary file system, the specimens were randomly divided into 4 groups according to canal drying methods (1: complete drying, 2: blot drying/distilled water, 3: blot drying/NaOCl, 4: aspiration only). The root canals were obturated using a single-cone filling technique with a calcium silicate-based sealer. Nanoleakage was evaluated using a nanoflow device after 24 hours, 1 week, and 1 month. Data were collected twice per second at the nanoscale and measured in nanoliters per second. Data were statistically analyzed using the Kruskal-Wallis and Mann-Whitney U-tests (p < 0.05). Results: The mean flow rate measured after 24 hours showed the highest value among the time periods in all groups. However, the difference in the flow rate between 1 week and 1 month was not significant. The mean flow rate of the complete drying group was the highest at all time points. After 1 month, the mean flow rate in the blot drying group and the aspiration group was not significantly different. Conclusions: Within the limitations of this study, the canal drying method had a significant effect on leakage and sealing ability in root canal obturations using a calcium silicate-based sealer. Thus, a proper drying procedure is critical in endodontic treatment.

• 자원리싸이클링
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• 제32권6호
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• pp.10-17
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• 2023

칼슘실리케이트 시멘트(Calcium silicate cement, CSC)는 친환경 저탄소 시멘트로써 최근에 많은 연구가 진행되고 있다. 하지만 이산화탄소 반응 활성화와 시료 handling을 위하여 사전경화 단계를 진행하여야하는 어려움이 있다. 본 연구에서는 CSC에 칼슘설포아루미네이트(Calcium sulfoaluminate, CSA) 속경시멘트를 혼합하여 초기강도 발현으로 사전경화 없이 사용할 수 있는 CSC의 확대적용 가능성을 살펴보고자 하였다. 이를 위하여 이산화탄소 분위기에서 CSC 와 CSA 속경성 시멘트 혼합비율 변화에 따른 압축강도와 Q-XRD 광물특성 함량 변화를 측정하였다. 압축강도 측정결과, CSC 50% 조건에서 3일과 7일 압축강도가 각 각 14.18MPa과 22.98MPa로 1종시멘트 KS규격을 만족하였다. 광물특성 분석을 통하여 이산화탄소 반응생성물인 calcite 광물이 증가하여 강도발현에 기여했음을 알 수 있었다. 7일 경과 후에도 수화광물인 dicalcium silicate 및 yeelimite광물뿐 아니라, 이산화탄소와 반응하지 않은 rankiniten 및 pseudowollastonite 광물이 다량 관찰되어 7일이후의 강도발현 가능성을 확인하였다.

• 한국전기전자재료학회논문지
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• 제13권2호
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• pp.131-136
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• 2000

We have investigated the slurry induced metallic contaminations of undoped and doped silicate oxides surface on CMP cleaning process. The metallic contaminations by CMP slurry were evaluated in four different oxide films, such as plasma enhanced tetra-ethyl-orthyo-silicate glass(PE-TEOS), O3 boro-phos-pho-silicate glass(O3-BPSG), PE-BPSG, and phospho-silicate glass(PSG). All films were polished with KOH-based slurry prior to entering the post-CMP cleaner. The Total X-Ray fluorescence(TXRF) measurements showed that all oxide surfaces are heavily contaminated by potassium and calcium during polishing which is due to a CMP slurry. The polished O3-BPSG films presented higher potassium and calcium contaminations compared to PE-TEOS because of a mobile ions gettering ability of phosphorus. For PSG oxides, the slurry induced mobile ion contamination increased with an increase of phosphorus contents. In addition, the polishing removal rate of PSG oxides had a linear relationship as a function of phosphorus contents.

• 한국구조물진단유지관리공학회 논문집
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• 제18권5호
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• pp.51-58
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• 2014

본 연구에서는 철근콘크리트 구조의 FRP를 이용한 보강에서 낮은 내화성능을 개선하기 위한 방안을 찾기 위하여, 보강된 FRP의 외부를 내화보강하는 방법에 대한 내화실험을 실시하였다. 특히 철근콘크리트 부재의 피복에 홈을 형성하여 FRP를 매입하는 보강 즉, NSM 보강을 대상으로 하였다. 실험에서의 주요 변수는 보강방법과 사용 내화재료로서, Perlite계 재료를 표면에 분사하여 보강하는 방법, Calcium silicate계 보드로 표면에 부착하는 방법, 그리고 추가로 홈내부에 Polymer mortar 또는 Calcium silicate조각을 삽입하여 보강하는 방법으로 보강한 뒤 가열로 내부의 온도변화에 따른 열전달을 관찰하였다. 실험결과, Perlite계 내화뿜칠로 표면을 보강하는 경우보다 Calcium Silicate계 내화보드로 표면을 보강하는 방법이 효과적인 것으로 나타났다. 홈 내부의 에폭시가 유리전이온도에 도달할 때의 외부 표면온도 $820^{\circ}C$까지 내화단열성능을 확보할 수 있는 것으로 나타났다.

• Journal of Yeungnam Medical Science
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• 제37권3호
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• pp.217-225
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• 2020

Background: This study was performed to provide a long-term bacterial seal through the formation of reparative dentin bridge, calcium silicate-based pulp capping materials have been used at sites of pulpal exposure. The aim of this study was to evaluate the mineralization-inducing potentials of calcium silicate-based pulp capping materials (ProRoot MTA [PR], Biodentine [BD], and TheraCal LC [TC]) in human dental pulp cells (HDPCs). Methods: Specimens of test materials were placed in deionized water for various incubation times to measure the pH variation and the concentration of calcium released. The morphology of HDPCs cultured on the specimens was examined using a confocal laser scanning microscope (CLSM). Alizarin red S staining and alkaline phosphatase assays were used to evaluate mineralization-inducing potentials of the capping materials. Results: BD showed the highest calcium release in all test periods, followed by PR and TC. (p<0.05). All experimental groups showed high alkalinity after 1 day, except at 14 days. BD showed the highest cell viability compared with PR and TC after 1 and 3 days, while TC showed the lowest value (p<0.05). The CLSM analysis showed that cells were well adhered and expressed actin filaments for all pulp capping materials. Mineralization by PR and BD groups was higher than that by TC group based on alizarin red S staining. BD showed significantly higher alkaline phosphatase activity than PR and TC, while TC showed the lowest value (p<0.05). Conclusion: Within the limitations of the in vitro study, BD had higher mineralization-inducing potential than PR and TC.

• International Journal of Concrete Structures and Materials
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• 제9권4호
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• pp.453-462
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• 2015

A critical review on existing creep theories in calcium-silicate-hydrate (C-S-H) is presented with an emphasis on several fundamental questions (e.g. the roles of water, relative humidity, temperature, atomic ordering of C-S-H). A consensus on the rearrangement of nanostructures of C-S-H as a main consequence of creep, has almost been achieved. However, main disagreement still exists on two basic aspects regarding creep mechanisms: (1) at which site the creep occurs, like at interlayer, intergranular, or regions where C-S-H has a relatively higher solubility; (2) how the structural rearrangement evolutes, like in a manner of interlayer sliding, intra-transfer of water at various scales, recrystallization of gelled-like particles, or dissolution-diffusion-reprecipitation at inter-particle boundary. The further understanding of creep behavior of C-S-H relies heavily on the appropriate characterization of its nanostructure.

• 한국세라믹학회지
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• 제21권2호
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• pp.143-148
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• 1984

In this study we mainly dealt with the effects of organic retarder(calcium lignosulfate) on the early hydration process of clinker minerals. From a consideration of the hydration process of tricalcium silicate $(C_3S)$ tricalcium silicate $(C_3S)$-tricalcium aluminate $(C_3A)$ tricalcium silicate $(C_3S)$-tetracalcium aluminof-errite $(C_4AF)$ systems with calcium lignosulfate the following results were obtained. 1. when 0.25wt% of CLS was added to $C_3S$ the hydration process was progressed normally but adding of 0.5wt% its hydration was greatly retarded. 2. The hydration of $C_3S$-$C_3A$ system was progressed normally up to 0.5wt% but by adding gypsum its hydration was retarded slightly. 3. The hydration of $C_3S$-$C_4AF$ system was greatly retarded even with 0.25wt% of CLS but by adding gypsum its hydration process was recovered normally.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 봄 학술논문 발표대회
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• pp.144-145
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• 2021

Calcium silicate hydrate(C-S-H) is the principal binding phase that controls the strength and thermal stability of concrete. However, the effects of high temperature on the lattice structure and interatomic structure of C-S-H remains poorly understood due to its nanocrystallinity. This study aims to elucidate the change in interatomic distance of synthetic C-S-H with different Ca/Si molar ratios after exposure to high temperature via high energy X-ray scattering experiment which is a powerful analytical tool for amorphous materials.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.141-142
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• 2023

In this study, the strength development characteristics of calcium silicate cement mixed mortar according to carbonation hardening conditions were evaluated. As a result of measuring the compressive strength, the strength increased according to the carbonation hardening time, and the strength increase rate was higher for the specimen with a CO₂ concentration of 20%.