• Title/Summary/Keyword: Calcium Nitrate

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Characterization of Individual Atmospheric Particles, Collected in Susan, Korea, Using Low-Z Electron Probe X-ray Microanalysis (Low-Z Electron Probe X-ray Microanalysis 분석법을 이용한 해안인근 지역의 대기입자 분석)

  • 김혜경;노철언
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.5
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    • pp.503-513
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    • 2003
  • A single particle analytical technique, called low-Z electron probe X-ray microanalysis (low-Z EPMA) was applied to characterize atmospheric particles collected in Busan, Korea, over a daytime period in Dec. 2001. The ability to quantitatively analyze the low-Z elements, such as C, N, and 0, in microscopic volume enables the low-Z EPMA to specify the chemical composition of individual atmospheric particle. Various types of atmospheric particles such as organics, carbon-rich, aluminosilicates, silicon oxide, calcium carbonate, iron oxide, sodium chloride, sodium nitrate, ammonium sulfate, and titanium oxide were identified. In the sample collected in Busan, sodium nitrate particles produced as a result of the reaction between sea salt and nitrogen oxides in the atmosphere were most abundantly encountered both in the coarse and fine fractions. On the contrary, original sea salt particles were rarely observed. The fact that most of the carbonaceous particles were distributed in the fine fraction implies that their origin is anthropogenic.

Cell Wall Micropore Loading of Pulp Fibers (펄프 섬유의 세포벽 미세공극 충전)

  • Lee, Jong-Man;Jo, Byoung-Muk
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.4
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    • pp.57-64
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    • 1992
  • The unique cell wall micropores of pulp fiber can be utilized as loading site in variety of important practical application which could be the basis of new papermaking technologies. One of these includes the manufature of paper containing higher levels of in situ filler precipitated. Hardwood pulp fiber were first impregnated with the solution of sodium carbonate($Na_2CO_3$). The micropores in cell wall of pulp fibers were filled with the liquid salt solution. The second calcium nitrate($Ca(NO_3)_2$) solution formed an insoluble calcium carbonate($CaCO_3$) precipitate within the cell wall micropores by interacting with the first sodium carbonate solution. The effects of chemical concentration and dryness of pulp fibers on the retention of cell wall micropore loaded filler were investigated. The paper properties of cell wall micropore loaded pulp fibers were compared with those of conventionally loaded and lumen loaded pulp fibers. Also the presense of the fillers within the cell wall micropore was observed by SEM. Increasing the chemical concentration to generate the calcium carbonate increased the retention of filler in cell wall micropore loaded pulp fibers. The particle size distribution of precipitated calcium carbonate ranged from $0.1{\mu}m$ to $80{\mu}m$. But, the average particle size of cell wall micropore loaded calcium carbonate was $4{\mu}m$. The paper made from never dried pulp fibers, the cell wall micropores which were filled with calcium carbonate, had better mechanical and optical properties than those of conventionally loaded or lumen loaded pulp fibers.

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Single Particle Analysis of Atmospheric Aerosol Particles Collected in Seoul, 2001, Using Low-Z Particle Electron Probe X-ray Microanalysis (Low-Z Particle Electron Probe X-ray Microanalysis를 이용한 2001년 서울시 대기 중 입자상 물질 분석)

  • Koo Hee Joon;Kim HyeKyeong;Ro Chul-Un
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.823-832
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    • 2004
  • Atmospheric aerosol particles collected in Seoul on four single days, each in every seasons of 2001, were characterized and classified on the basis of their chemical species using low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA). Low-Z particle EPMA technique can analyze both the size and the chemical species of individual aerosol particles of micrometer size and provide detailed information on the size distribution of each chemical species. The major chemical species observed in Seoul aerosol were aluminosilicate, silicon dioxide, calcium carbonate, organic, carbon-rich, marine originated, and ammonium sulfate particles, etc. The soil originated species, such as aluminosilicate, silicon dioxide, and calcium carbonate were the most popular in the coarse fraction, meanwhile, carbonaceous and ammonium sulfate were the dominant species found in the fine fraction. Marine originated species such as sodium nitrate was frequently encountered, up to 30% of the analyzed aerosol particles.

Measurement Study at Kosan, Cheju Island during March-April, 1994: (I) Transport of Ambient Aerosol (고산에서의 1994년 3월 - 4월 측정연구: (I) 입자상 오염물질의 이동)

  • 김용표;박세옥;김진영;심상규;문길주;이호근;장광미;박경윤;강창희
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.1
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    • pp.79-90
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    • 1996
  • Total suspended particles were measured at Kosan, Cheju Island, Korea during the period of March 11 .sim. April 19, 1994. Concentrations of non-sea salt(nss) ions were higher than those measured at clean marine areas in Japan and other background marine areas in the world. Especially, nss sulfate concentration is compatable to thoes measured at Seoul. It is suggested that most nss sulfate concentration is originated from anthropogenic sources. Nss sulfate concentration shows strong correlation with ammonium and nss potassium concentrations while shows no a pparent correlation with nitrate and nss calcium concentrations. Nss calcium concentrations shows strong correlation with nss potassium and mss magnesium concentrations. It is deduced that nss potassium has two origins, one anthropogenic, the other crustal. Backward trajectory analysis results show the trajectories of air parcel during the measurement period were mostly originated from China. It is shown that cases of high nss sulfate with high nss calcium can occur when an air parcel originated from arid and semi-arid regions of morthwestern China or Mongolia passes through northeastern China.

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Electrochemical behavior of Calcium Titanate Coated Ti-6Al-4V Substrate in Artificial Saliva

  • Lee, Byoung-Cheon;Balakrishnan, A.;Ko, Myung-Won;Choi, Je-Woo;Park, Joong-Keun;Kim, Taik-Nam
    • Korean Journal of Materials Research
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    • v.18 no.1
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    • pp.22-25
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    • 2008
  • In this study, calcium titanate $(CaTiO_3)$ gel was prepared by mixing calcium nitrate and titanium isopropoxide in 2-methoxy-ethanol. $CaTiO_3$ gel was single-layer coated on Ti-6Al-4V using a sol-gel dip-coating technique. The coating was calcined at $750^{\circ}C$ in air by utilizing a very slow heating rate of $2^{\circ}C/min$. The crystalline phases of the coating were characterized by x-ray diffraction using a slow scan rate of $1^{\circ}/min$. The morphology of the coating was analyzed by scanning electron microscopy. The corrosion behavior of Ti-6Al-4V samples coated with $CaTiO_3$ films were tested in an artificial saliva solution by potentiodynamic polarization and were quantified by the Tafel extrapolation method. The electrochemical parameters showed a considerable increase in the corrosion resistance for the $CaTiO_3$-coated Ti-6Al-4V samples compared to bare substrates.

Effect of calcium hydroxide on inflammatory root resorption and ankylosis in replanted teeth compared with other intracanal materials: a review

  • Jahromi, Maryam Zare;Kalantar Motamedi, Mahmood Reza
    • Restorative Dentistry and Endodontics
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    • v.44 no.3
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    • pp.32.1-32.13
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    • 2019
  • Calcium hydroxide (CH) is the gold-standard intracanal dressing for teeth subjected to traumatic avulsion. A common complication after the replantation of avulsed teeth is root resorption (RR). The current review was conducted to compare the effect of CH with that of other intracanal medications and filling materials on inflammatory RR and replacement RR (ankylosis) in replanted teeth. The PubMed and Scopus databases were searched through June 2018 using specific keywords related to the title of the present article. The materials that were compared to CH were in 2 categories: 1) mineral trioxide aggregate (MTA) and endodontic sealers as permanent filling materials for single-visit treatment, and 2) Ledermix, bisphosphonates, acetazolamide, indomethacin, gallium nitrate, and enamel matrix-derived protein (Emdogain) as intracanal medicaments for multiple-visit management of avulsed teeth prior to the final obturation. MTA can be used as a single-visit root filling material; however, there are limited data on its efficacy due to a lack of clinical trials. Ledermix and acetazolamide were comparable to CH in reducing RR. Emdogain seems to be an interesting material, but the data supporting its use as an intracanal medication remain very limited. The conclusions drawn in this study were limited by the insufficiency of clinical trials.

A survey on the fluctuation of dissolved solids into the groundwater in Chejudo (제주도 지하수의 증분변화에 대한 고제)

  • 금성홍;신승종;오상실;송가기;오순미
    • Journal of environmental and Sanitary engineering
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    • v.8 no.1
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    • pp.67-80
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    • 1993
  • This survey was carried out to take the status of seawater intrusion into groundwater wells located in the eastern area of Chejudo, to get the elementary data which may evaluate the level of would-be groundwater contamination, and to perform effective the effort that will supply the clear water for the residents. The sampling sites were northeastern districts of Haengwon, Handong, and Sangdo, southeastern districts of Susan, Nansan, and Samdal, and northwestern districts, as reference, of Aewol, Keumnung, Panpo, Kosan, Shindo, and Bosung. We collected the samples from the public tap water by month, and analysed electrical conductivity, sodium(Na), potassium(K), magnesium(Mg), calcium(Ca), bicarbonate($HC0_{3^-}$), and items of the criteria as drinking water. In the northeastern districts we also added the sampling sites to survey the fluctuations of dissolved solids according to distance from seashore, including two private boreholes and one public tap water of Dukchun. The result is as follows 1) In the northeastern district, the concentration of chloride ion showed large fluctations from 40mg/l to 100mg/l, but suitable for the criteria of drinking water. It was thought that the drought influenced. 2) In the Sangdo of the northeastern districts, similar tendancy to Hangwon and Handong was showed only in the concentration of chloride ion, but different tendancy was showed in chloride-bicarbonate ratio, calcium-magnesium ratio, and sodium adsorption ratio(SAR). Considering these facts, it was not thought that seawater intruded. 3) The components of Na and Cl showed rapid slope in the northeastern districts above 3km from seashore. 4) In the northwestern districts as reference, the concentration of chloride ion fluctuated slightly according to the sampling sites and dates, and the concentration of nitrate-nitrogen in some sites exceeded the criteria of drinking water. These were thought that the surface contaminants rather than the intrusion of seawater influenced mainly the groundwater, considering the correlation(r=0.732) of chloride ion and nitrate-nitrogen. 5) Then we must consider the regional characteristies of soil profile in order to prevent the contamination of groundwater, and moniter also the movement of main components within the sol1 profile, not only the research of the intrusion of seawater.

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Influence on Platycodon grandiflorum Absorption of Nitrogen and Phosphorous Acid and Growth during Seedling Stage by Liquid Fertilizers Treatment (도라지 유묘기 액비처리가 질소와 인산의 식물체 흡수 및 생육에 미치는 영향)

  • Lee, Cheol-Ho;Lee, Shin-Woo;Ahn, Mi-Jeong;Cho, Kwang-Bok;Lee, Hyub
    • Korean Journal of Medicinal Crop Science
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    • v.19 no.4
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    • pp.227-232
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    • 2011
  • The roots of Platycodon grandiflorum has been widely used as a crude drug or a food stuff. Unfortunately, the output and the quality is not regular and highly dependent on the cultivation area and cultivation method. Therefore, seedling cultivation study of this plant under structure with various fertilizer supply was performed. As a result, significant big difference between ammonia nitrogen and nitrate nitrogen content was shown in the root at seedling stage while the difference was not significant in the aerial parts. Fresh weight of the root (7.73 g plant$^{-1}$) was higher in the group treated with three major nutrients (N, P and K) than in those treated with three major nutrients and calcium or magnesium or both calcium and magnesium, and non-treated group (2.69 g plant$^{-1}$). Total nitrogen content was recognized to be significantly correlated with root weight, plant height, number of leaves and weight of aerial parts. Ammonium nitrogen content was more correlated the growth of P. grandiflorum than nitrate nitrogen. For phosphoric acid, significant correlation was also shown with the four growth factors.

Optimized Culture Condition and Enzyme Activity of the Mycelia of Clavicorona pyxidata (좀나무싸리버섯(Clavicorona pyxidata)의 균사체 최적 배양조건 및 세포효소활성 특성)

  • Lee Tae-Hee;Kim Jin-Man;Han Yeong-Hwan
    • Korean Journal of Microbiology
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    • v.42 no.2
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    • pp.131-134
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    • 2006
  • The culture conditions for the enhanced mycelial of Clavicorona pyxidata DGUM 29005 were investigated. The optimal temperature and pH for the mycelial growth were $24^{\circ}C$ and 5.0, respectively. It was shown that trehalose was the best supplement of carbon sources in Czapek-Dox medium as a minimal medium for enhanced mycelial growth. In general, inorganic nitrogen sources were better than organic ones for mycelial growth. Calcium nitrate was the best out of the inorganic nitrogen test. The appropriate phosphorous and vitamin were $Na_2HPO_4$ and p-aminobenzoic acid, respectively. After the mycelial of C. pyxidata DGUM 29005 was cultivated at $24^{\circ}C$ for 20 days in MEM broth(pH 5.0), the specific activities of both exomycelial and endomycelial enzymes were determined. Among the exomycelial enzyme assayed, the specific activity of laccase was much higher than those of other enzymes. However, little or no enzyme activities of ${\alpha}$-amylase, chitinase, lipase and pretense were found.

Transesterification of Soybean Oil Using KOH/KL Zeolite and Ca/Undaria pinnatifida Char (KOH/KL제올라이트 및 Ca/미역촤를 이용한 대두유의 전이에스테르화 반응)

  • Jo, Yong Beom;Park, Sung Hoon;Jeon, Jong-Ki;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.23 no.6
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    • pp.604-607
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    • 2012
  • Solid base catalysts for biodiesel production were synthesized by impregnating basic metal species on two support materials with large specific surface area : zeolite and pyrolysis char. KL zeolite and Undaria pinnatifida char were impregnated with KOH aqueous solution and calcium nitrate solution, respectively, to enhance the basic strength. The catalysts synthesized were characterized using Hammett indicators and $CO_2$-TPD analysis. Biodiesel was produced using soybean oil and methanol over the catalysts synthesized. The content of fatty acid methyl esters was measured to evaluate the catalytic activity. Generally, the catalytic activity increased with increasing quantity of basic metal impregnated but impregnation of excessive amount of metal could cause reduction in the activity.