• Title/Summary/Keyword: Ca/S ratio

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Effects of Caprylic Acid and Cyclodextrin Complex on In vitro Fermentation Characteristics and Methane Production (Caprylic Acid와 Cyclodextrin 복합물이 In vitro 반추위 발효성상 및 메탄 생성에 미치는 영향)

  • Kim, K.H.;Seol, Y.J.;Lee, S.S.;Oh, Y.G.;Nam, I.S.;Kim, D.H.;Choi, C.W.
    • Journal of Animal Science and Technology
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    • v.49 no.5
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    • pp.657-666
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    • 2007
  • This study was conducted to evaluate the effects of dietary addition of caprylic acid(CA)-cyclodextrin (CD) complex on in vitro fermentation characteristics, total gas and methane production. Experiment was done with six treatment groups; 1) no CA-CD complex(control), 2) CA 20 mg(T1), 3) CD 830 mg(T2), 4) CA-CD complex 425 mg(T3), CA-CD complex 850mg(T4), CA-CD complex 1,700 mg(T5). Ruminal pH, ammonia and total VFA concentrations of T2, T3, T4 and T5 were lower(P<0.05) than those of control and T1 for the 12h incubation. The increase in molar percentage of propionate was observed in T4 and T5 compared with control and T2 for the 8h incubation(P<0.05), however, the ratio of acetate to propionate was unchanged in all treatments. Total gas of T1 was lower than that of control, but T2, T3, T4 and T5 were higher compared with control for 12h incubation(P<0.05). If the methane ratio (as %) to total gas for all treatments was compared, T3, T4 and T5(CA-CD supplemented groups) averaged 2.7% whereas control, T1 and T2 showed 3.4, 2.8 and 5.1%, respectively. Therefore, according to these results, it might be concluded that supplementation of CA-CD complex could reduce methane production without disrupting ruminal fermentation.

Oxygen Sites in Quaternary Ca-Na Aluminosilicate Classes : O-17 Solid-State NMR Study (사성분계 비정질 Ca-Na 알루미노규산염의 산소주변의 원자구조 : O-17 고상핵자기 공명분광학분석)

  • Sung, So-Young;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.347-353
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    • 2006
  • The atomic-nano scale structures of multi-component aluminosilicate glasses have not been well understood in spite of its implications fur dynamics and generation of magma in the natural system due to lack of suitable spectroscopic and scattering experiments. Here, we report O-17 MAS and isotropic projection of 3QMAS NMR spectra for quaternary Na-Ca silicate glasses $[(CaO)_x(Na_2O)_{1-x}]\;(A1_2O_3)_{0.5}(SiO_2)_6,\;CNAS)$ at 14.1 Tesla where atomic configurations around bridging oxygen (Si-O-Si, Si-O-Al) and non bridging oxygen (Na-O-Si, Ca-O-Si, (Na, Ca)-O-Si) are partially resolved. With increasing Na content, the fraction of Na-O-Si increases while those for bridging oxygens remain constant. The Na/Ca ratio apparently affects the peak widths of bridging oxygen peaks (e.g., Si-O-Si)) and thus the topological entropy as well as chemical shifts of the bridging oxygen peaks, implying that both BOs and NBOs are strongly interacting with network modifying cations The effect of cation field strength on the degree of Al-avoidance was also discussed.

Dietary Intake of Calcium and It's Apparent Absorption Rate of School Children in Korea (학령기아동의 칼슘섭취 현황 및 그 흡수율에 관한 연구)

  • Lee, Lil-Ha;Chang, Kyung-Jung
    • Journal of Nutrition and Health
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    • v.12 no.1
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    • pp.17-22
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    • 1979
  • This study was designed to investigate calcium intake, the ratio of Ca intake versus R.D.A. (Recommended Dietary Allowance) for Ca, apparent Ca absorption rate, and Ca sources of food among school children in Korea. One hundred school children aged from 6 to 12 years were engaged in this study; 33 subjects were from farming village neal Seoul, and 67 children from big cities. Two days of food consumption records and feces collections of the subjects had been done from April 1978 to June 1978. The following observations were made in the present study; 1) Average Ca intake of total subjects was $457{\pm}214mg$ which is only 76% of R.D.A. for Ca. Calcium intakes for farming village children was higher than that of the subjects from big cities (p<0.05). 2) Survey on the food sources of Ca revealed that the amount of Ca taken from cereals averaged 120 mg (22.3% of total Ca intake), 111 mg (24.3%) from fruits and vegetables, 176 mg (38.5%) from meats, poultry, fishes and eggs, and only 68 mg (14.9%) was supplied by milk and milk products. From the data collected, following observations were made; a) No significant difference in Ca intake from cereals was found between village children and the ones from big cities. b) Average Ca intake from fruits and vegetables of city children was significantly higher than that of village children (p<0.005) with the values for 133 mg for the former and 64 mg for the latter. c) For the group of meats, poultry, fishes and eggs, significantly higher intake was found in village subjects than city children (p<0.0005) with the values of 340 mg and 95 mg, respectively. d) Contrarily, Ca intake from milk and milk products was significantly (p<0.0005) much higher in the city children (98 mg) than village ones (7 mg). 3) Apparent Ca absorption rate of total subjects was 51%; 44% for village children and 54% for city children. Ca absorption rate tends to be higher in the city subjects but no significant difference was noted.

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A kinetic study of pyrite in the lime roasting of a vertical cyclone (수직 싸이클론의 ${Ca(OH)}_{2}$ 배소에서 $FeS_{2}$의 열적반응에 관한 연구)

  • 조종상
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.119-125
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    • 1999
  • This research has been studied in terms of investigating the reaction behavior of pyrite with a cyclone reactor. The Mathematical model has developed pyrite oxidation and lime sulfation in this reactor. The model assumes a chemical control shrinking core behavior for the pyrite and a fluid film control shrinking core behavior for the lime. The model was solved and characterized numerically. Experiments have been performed to study the influence of reaction parameters such as reactor temperatures, pyrite particle sizes, air flow rates, feeding rates, and mixing ratio of pyrite and lime. The oxidation and sulfation products were characterized chemically and physically.

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Analysis of Changes in Ion Concentration with Time and Drainage Ratio under EC-based Nutrient Control in Closed-loop Soilless Culture for Sweet Pepper Plants (Capsicum annum L. 'Boogie') (EC 기준 순환식 파프리카 수경재배에서 시간 경과 및 배액율에 따른 이온농도 변화 분석)

  • Ahn, Tae-In;Shin, Jong-Wha;Son, Jung-Eek
    • Journal of Bio-Environment Control
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    • v.19 no.4
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    • pp.298-304
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    • 2010
  • Nutrient uptake by plants and drainage ratio in culture beds can affect ion balance and concentrations of nutrient solutions in electrical conductivity (EC)-based closed-loop soilless culture. This study was conducted to analyze ion concentration changes with time and drainage ratio under EC-based nutrient control in closed-loop soilless culture for sweet pepper plants (Capsicum annum L. 'Boogie'). At first experiment, ion concentrations of the nutrient solution were periodically analysed while collected drainage was being reused by mixing with fresh nutrient solution at a dilution rate of EC $2.2\;dSm^{-1}$. Changes in ion concentrations of $K^+$, $Ca^{2+}$, $Mg^{2+}$, $NO_3^-$, $SO_4^{2-}$, and $PO_4^{3-}$ were 1.13, 5.35, 0.92, 0.9, 1.10, $0.19\;meq{\cdot}L^{-1}$, respectively. Ion balance such as $K^+$ : $Ca^{2+}$ and $SO_4^{2-}$ : $NO_3^-$ were mainly affected during the recirculation of nutrient solution. At second experiment, ion concentrations and EC of drainage were compared before and after replenishment under different four drainage ratios of 7%, 16%, 39%, and 51%. Ion ratios of the recirculated nutrient solutions such as $K^+$ : $Ca^{2+}$ for cation and $SO_4^{2-}$ : $NO_3^-$ for anion were investigated. ECs of drainage decreased with increase of drainage ratio and each ion concentration showed the same trends as EC did. Ion balances in drainage with drainage ratio were a little different from each other, but each ratio could be corrected by replenishment process. The ion balance at 7% drainage ratio was closest to initial ratio and followed by 16%, 51%, and 39% in the order. Ion balance such as $K^+$ : $Ca^{2+}$ and $NO_3^-$ : $PO_4^{3-}$ were mainly affected the correction process.

Analysis of Future Land Use and Climate Change Impact on Stream Discharge (미래토지이용 및 기후변화에 따른 하천유역의 유출특성 분석)

  • Ahn, So Ra;Lee, Yong Jun;Park, Geun Ae;Kim, Seong Joon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.2B
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    • pp.215-224
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    • 2008
  • The effect of streamflow considering future land use change and vegetation index information by climate change scenario was assessed using SLURP (Semi-distributed Land-Use Runoff Process) model. The model was calibrated and verified using 4 years (1999-2002) daily observed streamflow data for the upstream watershed ($260.4km^2$) of Gyeongan water level gauging station. By applying CA-Markov technique, the future land uses (2030, 2060, 2090) were predicted after test the comparison of 2004 Landsat land use and 2004 CA-Markov land use by 1996 and 2000 land use data. The future land use showed a tendency that the forest and paddy decreased while urban, grassland and bareground increased. The future vegetation indices (2030, 2060, 2090) were estimated by the equation of linear regression between monthly NDVI of NOAA AVHRR images and monthly mean temperature of 5 years (1998-2002). Using CCCma CGCM2 simulation result based on SRES A2 and B2 scenario (2030s, 2060s, 2090s) of IPCC and data were downscaled by Stochastic Spatio-Temporal Random Cascade Model (SST-RCM) technique, the model showed that the future runoff ratio was predicted from 13% to 34% while the runoff ratio of 1999-2002 was 59%. On the other hand, the impact on runoff ratio by land use change showed about 0.1% to 1% increase.

Porous silica ceramics prepared by sol-gel process-Effect of $H_2O/TEOS$ molar ratio- (솔-젤법에 의한 다공성 실리카 세라믹스의 제조-$H_2O/TEOS$ 몰비의 영향-)

  • Lee, Jin-Hui;Kim, Wha-Jung;Lee, Joon
    • Journal of the Korean Ceramic Society
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    • v.34 no.2
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    • pp.216-224
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    • 1997
  • Porous silica ceramics were prepared(with HCI catalyst) using H2O/TEOS molar ratios of 2.6~59.0, with the EtOH/TEOS ratio fixed. After preparing 9 kinds of sol, the followings were investigated; measurement of the gelation time, thermal analyses by TG/DTA, property analyses of the intermediates by FT-IR and X-ray diffractometry with dried samples, analyses of SiO2 polymer by FT-IR, the investigation of specific sur-face area and pore size distribution by N2-adsorption isotherm, and structural change of SiO2 polymer and pore morphology by TEM observation, with samples heat-treated to 50$0^{\circ}C$. In the concentrations of in-vestigated compositions and catalyst, gelation time showed a minimum at ca. 11 moles of water per one mole of TEOS, the highest degree of polymerization at ca. 8-18 moles, and the largest specific surface area at ca. 11 moles, which means that the polymerization proceeded fastest at ca. 11 moles of water. In con-clusion, the more water used, the faster the polymerization reaction up to ca. 11 moles, but more than ca. 11 moles of water caused retardation of gelation and resultant reduction of specific surface area.

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Properties of $CaO-P_2O_5-SiO_2$ Glasses ($CaO-P_2O_5-SiO_2$계 유리의 물성)

  • 조정식;김철영
    • Journal of the Korean Ceramic Society
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    • v.30 no.4
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    • pp.289-298
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    • 1993
  • Properties in terms of the variation of the glass compositions, which were density (p), molar volume(Vm), atom/ion packing density (Dp), refractive index (nD), transformation temperature (Tg), dilatometric softening point (Td), thermal expansion coefficient (α), Young's modulus (E), and knoop hardness (KHN) were investigated in CaO-SiO2 glasses and CaO-P2O5-SiO2 glasses containing less than 10mole% of P2O5. Those properties were measured by density measurement kit, Abbe refractometer, dilatometer, ultrasonic pulse echo equipment, and micro hardness tester. When CaO content was increased in CaO-SiO2 glasses, p, Dp, nD, Tg, Td, α, E and KHN were increased, while Vm was decreased. When P2O5 was added to the CaO-SiO2 glasses with constant CaO/SiO2 ratio as 1.07, p, Dp, nD, Tg, Td, α, E and KHN were decreased, while Vm was increased. When the amount of P2O5 in glasses was kept constant, the changes of the properties with variation of CaO content in the CaO-P2O5-SiO2 glasses were very similar to those of CaO-SiO2 glasses. These phenomena could be explained by the structural role of P2O5 in the CaO-P2O5-SiO2 glasses, which was polymerization of siicate structures and resulted in [PO4] monomer structure in glasses. Due to this structural characteristics, the bond strength and packing density were changed with compositions. Proportional relationships between 1) np and Dp, 2) Tg, Td, α and CaO content, 3) E and Vm-1, and 4) KHN and P2O5 content were evaluated in this investigation.

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An Analysis on the Contents of Fraction in CA-CCSSM and its Textbook (미국 캘리포니아 주의 CA-CCSSM과 그에 따른 교과서에 제시된 분수 개념에 관한 내용 분석)

  • Lee, Dae Hyun
    • Journal of Elementary Mathematics Education in Korea
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    • v.21 no.4
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    • pp.547-574
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    • 2017
  • The purpose of analysis of foreign curriculums and textbooks is to aimed to get the implications for the revision of curriculum, publishment of textbooks and teaching mathematics. In this study, Common Core State Standards and its textbooks was analyzed. The U. S. doesn't have the national mathematics curriculum. So, it can be happen some problems: students' lower mathematical achievement, assessment policy, decision of teaching contents, etc. In 2010, Common Core State Standards was developed by states. Furthermore, The California Department of Education reshaped standards: CA-CCSSM. This study analyzed the contents of fraction in CA-CCSSM and its textbooks. Fraction has many concepts and methods and models in teaching process. This study analyzed the equal parts, introducing fraction concept, the types of fraction, equivalent fractions, comparison of fractions. The conclusions are as follows; The equal parts are the important concept of fraction and introduced in geometry area before teaching of fraction. CA-CCSSM aims to understand a fraction as a number on the number line and represent fractions on a number line diagram. There are some similarity and difference in mixed number, fractions as a division and ratio, equivalent fractions and comparison of fractions between Korean curriculum and textbooks and CA-CCSSM.

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Effects of Extrusion Ratio and Extrusion Temperature on Microstructure and Tensile Properties of SEN6 Magnesium Alloy (SEN6 마그네슘합금의 미세조직과 인장 특성에 미치는 압출비와 압출 온도의 영향)

  • H. J. Kim;J. Y. Lee;S. C. Jin;S. H. Park
    • Transactions of Materials Processing
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    • v.33 no.3
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    • pp.178-184
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    • 2024
  • In this study, we investigated the effects of extrusion ratio and extrusion temperature on the microstructure and tensile properties of extruded Mg-6Al-0.3Mn-0.3Ca-0.2Y (SEN6) alloy. As the extrusion ratio and temperature increase, dynamic recrystallization during extrusion is promoted, leading to the formation of a fully recrystallized microstructure with increased grain size. Additionally, the increases in extrusion ratio and temperature lead to texture strengthening, exhibiting a higher maximum texture intensity. The extruded materials contain three types of secondary phases, i.e., Al8Mn4Y, Al2Y, and Al2Ca, with irregular or polygonal shapes. The quantity, size, distribution, and area fraction of the second-phase particles are nearly identical between the two materials. Despite its larger grain size, the tensile yield strength of the material extruded at 450 ℃ and an extrusion ratio of 25 (450-25) is higher than that of the material extruded at 325 ℃ and an extrusion ratio of 10 (325-10), which is mainly attributed to the stronger texture hardening effect of the former. The ultimate tensile strength is similar in the two materials, owing to the higher work hardening rate in the 325-10 extrudate. Despite differences in grain size and recrystallization fraction, numerous twins are formed throughout the specimen during tensile deformation in both materials; consequently, the two materials exhibit nearly the same tensile elongation.