• Title/Summary/Keyword: Ca/S ratio

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Synthesis and Characterization of Calcium Derivative Combined with High-Surface-Area Activated Carbon Composites for Fine Toxic Gas Removal

  • Areerob, Yonrapach;Nguyen, Dinh Cung Tien;Dowla, Biswas Md Rokon;Kim, Hyuk;Cha, Je-Woo;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.473-479
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    • 2018
  • Highly toxic gases such as hydrogen sulfide ($H_2S$), carbon dioxide ($CO_2$), and ammonia ($NH_3$) are generated by both nature and human activities and affect human health. In this research, activated carbon combined with $Ca(OH)_2$ and $CaCO_3$ (AC-CO and AC-CC, respectively) were fabricated and applied in absorbing toxic gases from air pollutants. Activated charcoal powder was compressed in the form of pellets and used in the designated conditions. The optimum operating conditions and material properties, such as adsorption capacity, effect of weight ratio of the mixture, and hardness, have been investigated after combining with the calcium derivative. The good performance exhibited in this study suggests that this material is expected to be an effective and economically viable adsorbent for $NH_3$, $CO_2$, and $H_2S$ removal from the air system.

Error Analysis for Microwave Permittivity Measurement using Post Resonator Method (Post Resonator 방법에 의한 마이크로파 유전율 측정에서의 오차 분석)

  • Cho, Mun-Seong;Lim, Donggun;Park, Jae-Hwan;Park, Jae-Gwan
    • Journal of the Microelectronics and Packaging Society
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    • v.19 no.3
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    • pp.43-48
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    • 2012
  • Errors of relative permittivity calculation caused by the variation of sample aspect ratio (diameter/height) and measuring geometry were analyzed by computer simulation and measurement. Firstly, the $S_{21}$ spectrum of the sample (permittivity 38) was simulated in the post resonator measuring apparatus by HFSS simulation. Then, the relative permittivity was calculated from the $TE_{011}$ mode resonant frequency. The relative permittivity varied by ca. 0.3% with sample aspect ratio variation (D/H=0.8~1.6). The relative permittivity varied by ca. 1~10% when the 1~10% of air-gap was introduced in between the dielectric disk and upper conductor. All the simulation results showed consistent tendency with real measurement.

The Quality of Yakju be brewed from many kind of Nuruk (누룩에 따른 약주의 품질 평가)

  • 이미경;이성우;배상면
    • Journal of the East Asian Society of Dietary Life
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    • v.1 no.1
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    • pp.99-111
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    • 1991
  • In each nuruk using today, effect of pH on glucoamylase activity and viable cell count of yeast and bacteria was measured. Common components during fermentation, alcohol, acetaldehyde and acetone, amino acid composition, and total sugars and mineral content were determined in yakju(korean wine) brewed from different ingredients and by different methods. Results are summarized as follows ; 1. The lower the pH, the lower the glucoamylase activity in JK, BK, JK-S BK-S and JN. But the higher the glucoamylase activity ratio in Koji and KN. 2. Yeast and bacteria cell count could not determined in nuruk inoculated of seed. In JK, BK and JN, yeast cell count was 50${\times}$104∼80${\times}$104, bacteria cell count was 5${\times}$106∼24${\times}$106. 3. In yakju during fermentation, pH was higher in RU, total acidity content was higher in ST-N, ST-K, RU and ST-RUPO and alcohol content was lower in RUPO and ST-RUPO. 4. Ethanol and acetaldehyde content were highest in dukyunju. Trace amount of acetone was determined only in ST-K, RUPO and ST-RUPO . n-Propyl alcohol content was higher in ST-K, ST-RUPO and ST-N, iso-butyl alcohol content was higher in L-RUPO, Dukyunju and Songyupju and iso-amyl alcohol content was higher in Songyupju, RU, L-RUPO and Dukyunju. 5. In amino acids composition of each yakju, Pro, Ala and Val content was higher than other amino acids. Total amino acids content was the highest in Dukyunju and second highest in ST-N, NH3 was higher in ST-N, Dukyunju, RUPO than other samples. 6. Total sugars content was the highest in ST-N and second highest in RU. 7. P, K and Mg content were higher in Dukyunju and ST-N than in other samples. In Dukyunju, Ca and P ratio was 0.075 because of low Ca content and high P content.

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Precipitation of $CaCO_3$ Crystals from Variously Supersaturated Solutions (다양한 과포화 조건하에서의 탄산염광물의 합성에 대한 연구)

  • Hyeon Yoon;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.1
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    • pp.11-21
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    • 2004
  • Crystallization of CaC $O_3$ from the solutions of various degrees of supersaturation was carried out by a spontaneous precipitation method. The solution was kept at $25^{\circ}C$ and pH 6.9∼8.8. The solution compositions were varied in two ways: (1) The total carbonate, [C $O_3$]$_{Τ}$, to total calcium. [Ca]$_{Τ}$, ratios vary as ; [C $O_3$]$_{Τ}$/[Ca]$_{Τ}$ >1. [C $O_3$]$_{Τ}$/[Ca]$_{Τ}$=1, and [C $O_3$]$_{Τ}$/[Ca]$_{Τ}$<1. (2) The total calcium concentration, [Ca]$_{Τ}$, held at 0.02 mo1/d $m^3$, 0.2 mo1/d $m^3$, and 0.4 mo1/d $m^3$. We found that the CaC $O_3$ phase crystallized from the solutions of [C $O_3$]$_{Τ}$/[Ca]$_{Τ}$ $\geq$ 1 was mostly calcite with less than 1% of vaterite, while the CaC $O_3$ crystals precipitated from low carbonate concentration toward calcium concentration, [C $O_3$]$_{Τ}$/[Ca]$_{Τ}$ < 1, were dominated by vaterite crystals. It appears that the polymorph of CaC $O_3$ precipitate was mainly controlled not by the calcium concentration but by the carbonate concentration during the spontaneous precipitation. Also, we found that the surface roughness of vaterite increased with decreasing carbonate concentration from 0.8 or 0.5 of [C $O_3$]$_{Τ}$/[Ca]$_{Τ}$ ratios and the surface area of vaterite increased from 5.64∼7.34 $\mu\textrm{m}$ to 8.39∼10.3 $\mu\textrm{m}$.

Engineering Properties of Permeable Polymer Concrete for Pavement using Powdered Waste Glass and Recycled Coarse Aggregate (폐유리분말과 재생골재를 사용한 포장용 투수성 폴리머 콘크리트의 공학적 성질)

  • Sung, Chan-Yong;Kim, Tae-Ho
    • Journal of The Korean Society of Agricultural Engineers
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    • v.53 no.6
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    • pp.59-65
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    • 2011
  • This study was performed to evaluate the compressive and flexural strength, void ratio and permeability coefficient used powdered waste glass, $CaCO_3$, recycled coarse aggregate and unsaturated polyester resin to find optimum mix design of permeable polymer concrete for pavement. The compressive and flexural strength of permeable polymer concrete for pavement using powdered waste glass were in the range of 16.8~19.7 MPa and 4.7~6.1 MPa, respectively. it was satisfied the regulation of permeable concrete for pavement (18 MPa and 4.5 MPa). The void ratio and permeability coefficient were decreased with increasing the powdered waste glass, respectively. The void ratio and permeability coefficient were satisfied national regulation of permeable concrete for pavement (8 % and $1{\times}10^{-2}$ cm/s). In addition, this study found out that required amount of binder was decreased with increasing the powdered waste glass. This fact is expected to have economical effects during the use of powdered waste glass in the manufacture of permeable polymer concrete for pavement. Accodingly, the powdered waste glass can be used for permeable concrete material.

Quality and Sensory Evaluation of Whole Soybean Flour Tofu Prepared from various Processing Conditons (가공조건에 따른 전지대두분 두부의 품질 및 관능평가)

  • 김주영;김준하;김종국;문광덕
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.3
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    • pp.455-459
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    • 2001
  • Tofu (soybean curd) was made with whole soybean flour (WSF, 420 mesh) by various processing conditions of water addition ratio, heating time, coagulation temperature, molding pressure and 0.3% of mixed coagulant (CaSO₄:GDL=50:50(w/w)). Yield content of WSF-tofu was the highest in processing condition of 85℃ coagulation temperature, 10 times water addition, 5min. heating time and 25.00 g/㎠ molding pressure. As the increase of the water addition ratio from 8 to 14 times (water:WSF, v/w), Hunter's L and a values were increased. Raising of heating time (100℃, 1, 5, 10 and 15 min), a and b value were increased. Textural properties of WSF-tofu were significantly affected by coagulation temperature (75, 80, 85 and 90℃). Hardness was increased, but adhesiveness and cohesiveness were decreased. heating time was influenced on harness of WSF-tofu, but water addition ratio was not affected on hardness of WSF-tofu. Increasing of molding pressure (16.83, 25.00, 33.22 and 41.67 g/㎠, 1 hr) was resulted from a increased hardness, gumminess and chewingss of tofu, but adhesiveness was addition ratio, 5 min heating time and 25.00 g/㎠ molding pressure recorded the highest score in sensory evaluation test.

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Accumulation of Poly-$\beta$-Hydroxybutyrie Acid by Alcaligenes sp. (Alcaligenes sp.에 의한 Poly-$\beta$-Hydroxybutyric Acid의 축적)

  • 임명순;손홍주;박수민;이종근;이상준
    • Microbiology and Biotechnology Letters
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    • v.20 no.4
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    • pp.363-370
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    • 1992
  • Microorganisms capable of accumulating poly-p-hydroxybutyric acid(PHB) were isolated from soil by enrichment culture technique. Among them, the strain designated as FL-027 had high PHB productivity and was identified as Alcaligenes. The optimal medium composition for cell growth was 8.0 $g/\ell$ of fructose and 3.0 $g/\ell$ of $(NH_4)_2S0_4$, equivalent to C/N ratio 5.04 at pH 7.0 and $30^{\circ}C$. To investigate the optimal conditions for the PHB accumulation, we divided the process into two stages; the first stage for the growth of the cell in nutrient-rich medium and the second stage for the PHB accumulation in nutrient-deficiency medium. The optimal conditions for PHB accumulation were 8.0 $g/\ell$ of fructose and 0.25 $g/\ell$ of $(NH_4)_2S0_4$, equivalent to C/N ratio 60 at pH 6.5 and $30^{\circ}C$. PHB accumulation was stimulated by deficiency of nutrients such as $NH_4^+$, $Ca^{2+}$, $SO_4^{2+}$ in medium. Among them. $NH_4^+$ deficiency was chosen because of its effectiveness. We found the inhibition of cell growth by fructose in batch culture. In order to keep the fructose concentration at an optimal level, intermittent feeding fed-batch culture was employed, and the cell concentration as high as 10.83 $g/\ell$ whose PHB content was responsible for 43% of the dry cell weight. The purified PHB was identified as homopolymer of 3-hydroxybutyric acid by using IR and $^1H-NMR$.

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Mineral Contents and Fatty Acid Composition of Jemsosojoo (흑염소 소주의 무기질 함량과 지방산 조성)

  • 김종수;김관필;이만종
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.2
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    • pp.220-226
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    • 1998
  • This study was undertaken to analyze proximate comosition, mineral contents and fatty acid composition of pure jemsosojoo(PJ) and jemsosojoo added medicinal herb(JMH). Mositure, ash, crude protein and crude fat of pure jemsosojoo were higher than those of the JMH, but carbohydrate content was higher in the JMH. Among minerals, Ca, Mg, Fe, Zn content of the JMH were higher than those of the PJ, while P and Na were higher in the PJ and those difference were significant between the PJ and the JMH(p<0.05). U/S (unsaturaed fatty acid/saturated fatty acid) ratio was higher in the JMH than those of the PJ, the ratio o fglycolipid was 1.75 in the PJ and that of neutral lipid was 3.07 in the JMH. Octadecenoic acid, hexadecanoic acid, octadecenoic acid and hexadecenoic acid were major fatty acids in the total lipids, neutral lipids glycolipids and phospolipids of the PJ and the JMH. Especially, octadecadienoic acid and octadecatrienoic acid were higher in the JMH than those of the PJ.

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Study on the contents of nutrients and gelation substances in the Korean persimmons (감(枾)의 영양적성분(營養的成分) 및 gel화(化) 요소함량(要素含量) 조사연구(調査硏究))

  • Kim, Youn-Soon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.4 no.1
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    • pp.19-23
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    • 1975
  • From a study of the nutrient and gelation substances in Korean persimmon such as Jangdongsi, Pasi, Teabongsi, Kurigam, Nabjackgam, Gamsi and Hucks: The results obtained are summerized as follows: 1. According as persimmon changes into mellowed persimmon in the same kind the ammounts of sugar was increased, while the ammounts of fiber was decreased, but there was little difference in the other nutrient contents. 2. The ratio of 'Ca' and 'P' in persimmons in generally balanced at 1 : 2.5 3. Compared to the standard combination ratio of gelation substance, pectin in the persimmons was over but acid and sugars were very low.

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Geochemical Analysis and Fates of Pathogenic Indicating Bacteria on Seawater Intrusion in a Sand Box Model (인공 대수층내에서 발생하는 해수침투의 지화학적 분석 및 병원성 지표 미생물의 사멸 특성)

  • Lee, So-Jung;Park, Hun-Ju;Sung, Eun-Hae;So, Myung-Ho;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.4
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    • pp.385-392
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    • 2008
  • In this study, seawater intrusion was assessed employing a kind of biological parameters such as Escherichia coli and Enterococcus faecalis while lab-prepared reclaimed water was recharged to prevent seawater intrusion. Chemical factors indicating seawater intrusion such as Cl$^-$, Ca$^{2+}$, Mg$^{2+}$ and specific conductivity were also simultaneously investigated where an ion exchange between a matrix in artificial aquifer and cations in solution was estimated. Both Escherichia coli and Enterococcus faecalis were shown to be very sensitive against degree of salinity during saline water intrusion. Enterococcus faecalis more strongly resisted against salinity than that of Escherichia coli. The ratio of Enterococcus faecalis divided by E. coli in the process of seawater intrusion increased up to more than 50$\sim$100 times in 18 hours whereas E. coli was died off more than 90% during pumping and recharge rate kept at 10 mL/min. However, when the rates of both recharge and pumping was kept at 5 mL/min, Enterococcus faecalis / Escherichia coli was sustained in the range of 2.5$\sim$5.0, while Escherichia coli showed dimished death rate. Chemical factors such as Cl$^-$, Ca$^{2+}$, Mg$^{2+}$ and specific conductivity showed more than 0.9 of high correlation each other well explaining the degree of seawater intrusion. The degree of ion exchange between artificial aquifer and saline water can be efficiently interpreted by both minus $\Delta$Na, $\Delta$Mg variation and positive $\Delta$Ca variation.