• Title/Summary/Keyword: CYCLING

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A Study on the Characteristics of Material in the Korean Up-cycling Fashion Brands (Part I) (업사이클링 패션브랜드에 나타난 소재특성 연구 (제1보))

  • Lee, Dahye;Jung, Kyunghee;Bae, Soojeong
    • Journal of the Korean Society of Clothing and Textiles
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    • v.42 no.3
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    • pp.486-502
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    • 2018
  • Mass-production caused by industrialization has led to environmental pollution; however, a potential solution to this problem is the Up-cycling fashion design belonging to the sustainable design category. This study analyzed the material characteristics of each brand fashion product by selecting 21 domestic Up-cycling fashion brands. The product types manufactured by domestic Up-cycling fashion brands could be divided into fashion clothing, bag, and fashion accessories. The materials used for each item included special material, waste fiber, waste leather, waste paper, and others. In the results of analyzing the material characteristics into the external characteristics and internal characteristics, the external characteristics included the durability with less abrasiveness and deformation as well as a mixture with other different materials, while the internal characteristics included a story arousing consumers' empathy, and scarcity without the same design due to the limitation of material.

Cycling Characteristics of MgH2 madeby Hydriding Chemical Vapor Deposition Method (HCVD 방법으로 제조된 MgH2의 Cycling 특성)

  • Park, Kyung-Duck;Han, Jeong-Seb
    • Korean Journal of Metals and Materials
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    • v.49 no.12
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    • pp.945-949
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    • 2011
  • The cycling characteristics of $MgH_2$ made by hydriding chemical vapor deposition method have been investigated. The particle size of $MgH_2$ made by HCVD was about $1{\mu}m$. The cycling experiment was performed by measuring hydrogen quantity absorbed at 673 K and under 35 atm of hydrogen pressure for 30 min. Up to 3 cycles the hydrogen storage capacity increased, but from 4 to 6 cycles the hydrogen storage capacity decreased rapidly. During this cycling test the particle size increased gradually from $1{\mu}m$ to $6{\mu}m$. This increase was due to sintering by the high reaction temperature and the heat of reaction during hydrogen absorption. From 7 to 30 cycles, the hydrogen storage capacity was maintained at 5.8 wt%. Even after 30 cycles, the plateau pressure was constant.

Contact Resistance and Thermal Cycling Reliability of the Flip-Chip Joints Processed with Cu-Sn Mushroom Bumps (Cu-Sn 머쉬룸 범프를 이용한 플립칩 접속부의 접속저항과 열 싸이클링 신뢰성)

  • Lim, Su-Kyum;Choi, Jin-Won;Kim, Young-Ho;Oh, Tae-Sung
    • Korean Journal of Metals and Materials
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    • v.46 no.9
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    • pp.585-592
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    • 2008
  • Flip-chip bonding using Cu-Sn mushroom bumps composed of Cu pillar and Sn cap was accomplished, and the contact resistance and the thermal cycling reliability of the Cu-Sn mushroom bump joints were compared with those of the Sn planar bump joints. With flip-chip process at a same bonding stress, both the Cu-Sn mushroom bump joints and the Sn planar bump joints exhibited an almost identical average contact resistance. With increasing a bonding stress from 32 MPa to 44MPa, the average contact resistances of the Cu-Sn mushroom bump joints and the Sn planar bump joints became reduced from $30m{\Omega}/bump$ to $25m{\Omega}/bump$ due to heavier plastic deformation of the bumps. The Cu-Sn mushroom bump joints exhibited a superior thermal cycling reliability to that of the Sn planar bump joints at a bonding stress of 32 MPa. While the contact resistance characteristics of the Cu-Sn mushroom bump joints were not deteriorated even after 1000 thermal cycles ranging between $-40^{\circ}C$ and $80^{\circ}C$, the contact resistance of the Sn planar bump joints substantially increased with thermal cycling.

Composited Conductive Materials for Enhancing the Ultrafast Performance for Anode in Lithium-Ion Battery (리튬이온전지 음극의 고속 성능 향상을 위한 도전재 복합화)

  • Ki-Wook, Sung;Hyo-Jin, Ahn
    • Korean Journal of Materials Research
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    • v.32 no.11
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    • pp.474-480
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    • 2022
  • Lithium-ion batteries (LIBs) are powerful energy storage devices with several advantages, including high energy density, large voltage window, high cycling stability, and eco-friendliness. However, demand for ultrafast charge/discharge performance is increasing, and many improvements are needed in the electrode which contains the carbon-based active material. Among LIB electrode components, the conductive additive plays an important role, connecting the active materials and enhancing charge transfer within the electrode. This impacts electrical and ionic conductivity, electrical resistance, and the density of the electrode. Therefore, to increase ultrafast cycling performance by enhancing the electrical conductivity and density of the electrode, we complexed Ketjen black and graphene and applied conductive agents. This electrode, with the composite conductive additives, exhibited high electrical conductivity (12.11 S/cm), excellent high-rate performance (28.6 mAh/g at current density of 3,000 mA/g), and great long-term cycling stability at high current density (88.7 % after 500 cycles at current density of 3,000 mA/g). This excellent high-rate performance with cycling stability is attributed to the increased electrical conductivity, due to the increased amount of graphene, which has high intrinsic electrical conductivity, and the high density of the electrode.

Effect of Temperature on the Deterioration of Graphite-Based Negative Electrodes during the Prolonged Cycling of Li-ion Batteries

  • Yang, Jin Hyeok;Hwang, Seong Ju;Chun, Seung Kyu;Kim, Ki Jae
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.208-212
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    • 2022
  • In this paper, we report the effects of temperature on the deterioration of graphite-based negative electrodes during the longterm cycling of lithium-ion batteries (LIBs). After cycling 75 Ah pouch-type LIB full cells at temperatures of 45℃ (45-Cell) and 25℃ (25-Cell) until their end of life, we expected to observe changes in the negative electrode according to the temperature. The thickness of the negative electrode of the cell was greater after cycling; that of the electrode of 45-Cell (144 ㎛) was greater than that of the electrode of 25-Cell (109 ㎛). Cross-sectional scanning electron microscopy analysis confirmed that by-products caused this increase in the thickness of the negative electrode. The by-products that formed on the surface of the negative electrode during cycling increased the surface resistance and decreased the electrical conductivity. Voltage profiles showed that the negative electrode of 25-Cell exhibited an 84.7% retention of the initial capacity, whereas that of 45-Cell showed only a 70.3% retention. The results of this study are expected to be relevant to future analyses of the deterioration characteristics of the negative electrode and battery deterioration mechanisms, and are also expected to provide basic data for advanced battery design.

Swelling and hydraulic characteristics of two grade bentonites under varying conditions for low-level radioactive waste repository design

  • Chih-Chung Chung;Guo-Liang Ren;I-Ting Chen;Che-Ju, Cuo;Hao-Chun Chang
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1385-1397
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    • 2024
  • Bentonite is a recommended material for the multiple barriers in the final disposal of low-level radioactive waste (LLW) to prevent groundwater intrusion and nuclear species migration. However, after drying-wetting cycling during the repository construction stage and ion exchange with the concrete barrier in the long-term repository, the bentonite mechanical behaviors, including swelling capacity and hydraulic conductivity, would be further influenced by the groundwater intrusion, resulting in radioactive leakage. To comprehensively examine the factors on the mechanical characteristics of bentonite, this study presented scenarios involving MX-80 and KV-1 bentonites subjected to drying-wetting cycling and accelerated ion migration. The experiments subsequently measured free swelling, swelling pressure, and hydraulic conductivity of bentonites with intrusions of seawater, high pH, and low pH solutions. The results indicated that the solutions caused a reduction in swelling volume and pressure, and an increase in hydraulic conductivity. Specifically, the swelling capability of bentonite with drying-wetting cycling in the seawater decreased significantly by 60%, while hydraulic conductivity increased by more than three times. Therefore, the study suggested minimizing drying-wetting cycling and preventing seawater intrusion, ensuring a long service life of the multiple barriers in the LLW repository.

Synthesis and Electrochemical Characterization of Polypyrrole/Multi-walled Carbon Nanotube Composite Electrodes for Supercapacitor Applications

  • Paul, Santhosh;Lee, Yoon-Sung;Choi, Ji-Ae;Kang, Yun-Chan;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1228-1232
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    • 2010
  • The nanocomposites of polypyrrole (PPy) and multi-walled carbon nanotube (MWCNT) with different composition are synthesized by the chemical oxidative polymerization method. In these composites, the MWCNTs are uniformly coated by PPy with different thickness. The electrochemical properties of the composite electrodes are investigated by cyclic voltammetry, galvanostatic charge-discharge cycling and electrochemical impedance spectroscopy. The full cells assembled with the PPy/MWCNT composite electrodes deliver initial specific capacitances ranging from 146.3 to 167.2 F/g at 0.5 mA/$cm^2$ and exhibit stable cycling characteristics. The effect of content of MWCNT in the composite on cycling performance of the cells is also investigated.

Cycling Performance of Li4Ti5O12 Electrodes in Ionic Liquid-Based Gel Polymer Electrolytes

  • Kim, Jin-Hee;Kang, Yong-Ku;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.608-612
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    • 2012
  • We investigated the cycling behavior of $Li_4Ti_5O_{12}$ electrode in a cross-linked gel polymer electrolyte based on non-flammable ionic liquid consisting of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and vinylene carbonate. The $Li_4Ti_5O_{12}$ electrodes in ionic liquid-based gel polymer electrolytes exhibited reversible cycling behavior with good capacity retention. Cycling data and electrochemical impedance spectroscopy analyses revealed that the optimum content of the cross-linking agent necessary to ensure both acceptable initial discharge capacity and good capacity retention was about 8 wt %.

Effect of Localized Recrystallization Distribution on Edgebond and Underfilm Applied Wafer-level Chip-scale Package Thermal Cycling Performance

  • Lee, Tae-Kyu
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.1
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    • pp.27-34
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    • 2015
  • The correlation between crack propagation and localized recrystallization are compared in a series of cross section analyses on thermal cycled edgebond and underfilm material applied wafer level chip scale package (WLCSP) components with a baseline of no-material applied WLCSP components. The results show that the crack propagation distribution and recrystallization region correlation can explain potential degradation mechanisms and support the damage accumulation history in a more efficient way. Edgebond material applied components show a shift of damage accumulation to a more localized region, thus potentially accelerated the degradation during thermal cycling. Underfilm material applied components triggered more solder joints for a more wider distribution of damage accumulation resulting in a slightly improved thermal cycling performance compared to no-material applied components. Using an analysis on localized distribution of recrystallized areas inside the solder joint showed potential value as a new analytical approach.