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A Study on the Corrosion Monitoring of Multi-functional Sensors for Reinforced Concrete Structures: Part 1 (철근 콘크리트 구조물용 다기능 멀티센서의 부식 모니터링에 관한 연구: Part 1)

  • Jin, Chung-Kuk;Jeong, Jin-A;Kyoung, Eun-Jin
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.270-274
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    • 2012
  • This study represents the result of corrosion monitoring on reinforced concrete specimens by means of multi-functional corrosion monitoring sensors. To confirm the effectiveness of the sensors, eight different kinds of condition were adopted. Test factors were corrosion potential, current, corrosion rate, resistivity, and temperature, which were monitored with the sensors. Through this study, judging corrosion of steel in concrete with single corrosion factor such as corrosion potential was difficult, because many other factors can have an influence on the reaction of corrosion. By using three different kinds of sensors, it could enhance the accuracy of corrosion monitoring.

Chromate-free Hybrid Coating for Corrosion Protection of Electrogalvanized Steel Sheets

  • Jo, Du-Hwan;Kwon, Moonjae;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.15-19
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    • 2012
  • Both electrogalvanized and hot-dip galvanized steel sheets have been finally produced via organic-inorganic surface coating process on the zinc surface to enhance corrosion resistance and afford additional functional properties. Recently, POSCO has been developed a variety of chromate-free coated steels that are widely used in household, construction and automotive applications. New organic-inorganic hybrid coating solutions as chromate alternatives are comprised of surface modified silicate with silane coupling agent and inorganic corrosion inhibitors as an aqueous formulation. In this paper we have prepared new type of hybrid coatings and evaluated quality performances such as corrosion resistance, spot weldability, thermal tolerance, and paint adhesion property etc. The electrogalvanized steels with these coating solutions exhibit good anti-corrosion property compared to those of chromate coated steels. Detailed components composition of coating solutions and experimental results suggest that strong binding between organic-inorganic hybrid coating layer and zinc surface plays a key role in the advanced quality performances.

Effect of Aging Time on the Resistance to Localized Corrosion of the Hyper Duplex Stainless Steel

  • Jeon, Soon-Hyeok;Kim, Soon-Tae;Lee, In-Sung;Kim, Ji-Soo;Kim, Kwang-Tae;Park, Yong-Soo
    • Corrosion Science and Technology
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    • v.9 no.5
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    • pp.209-215
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    • 2010
  • To elucidate the effect of aging time on resistance to localized corrosion of hyper duplex stainless steel, a double-loop electrochemical potentiokinetic reactivation test a potentiodynamic anodic polarization test, a scanning electron microscope-energy dispersive spectroscope analysis, and a thermodynamic calculation were conducted. With an increase in aging time, sigma phases are precipitated much more than chi phases due to the meta-stable chi phase acting as a transition phase. As aging time at $850^{\circ}C$ increases, the corrosion resistance decreases owing to an increase in Cr, Mo and W depleted areas adjacent to the intermetallic phases such as sigma phases and chi phases.

Evaluation of Iron Nickel Oxide Nanopowder as Corrosion Inhibitor: Effect of Metallic Cations on Carbon Steel in Aqueous NaCl

  • Chaudhry, A.U.;Mittal, Vikas;Mishra, Brajendra
    • Corrosion Science and Technology
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    • v.15 no.1
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    • pp.13-17
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    • 2016
  • The aim of this study was to evaluate the use of iron-nickel oxide ($Fe_2O_3$.NiO) nanopowder (FeNi) as an anti-corrosion pigment for a different application. The corrosion protection ability and the mechanism involved was determined using aqueous solution of FeNi prepared in a corrosive solution containing 3.5 wt.% NaCl. Anti-corrosion abilities of aqueous solution were determined using electrochemical impedance spectroscopy (EIS) on line pipe steel (API 5L X-80). The protection mechanism involved the adsorption of metallic cations on the steel surface forming a protective film. Analysis of EIS spectra revealed that corrosion inhibition occurred at low concentration, whereas higher concentration of aqueous solution produced induction behavior.

A Numerical Study on Flow-Accelerated Corrosion in Two Adjacent Elbows

  • Yun, Hun;Hwang, Kyeongmo;Moon, Seung-Jae
    • Corrosion Science and Technology
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    • v.15 no.1
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    • pp.6-12
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    • 2016
  • Flow-Accelerated Corrosion (FAC) is a well-known degradation mechanism that attacks the secondary piping in nuclear power plants. Since the Surry Unit 2 event in 1986, most nuclear power plants have implemented management programs to deal with damages in carbon and low-alloy steel piping. Despite the utmost efforts, damage induced by FAC still occurs in power plants around the world. In order to predict FAC wear, some computer programs were developed such as CHECWORKS, CICERO, and COMSY. Various data need to be input to these programs; the chemical composition of secondary piping, flow operating conditions and piping geometries. CHECWORKS, developed by the Electric Power Research Institute (EPRI), uses a geometry code to calculate geometry effects. Such a relatively simple geometry code is limited in acquiring the accuracy of FAC prediction. Recently, EPRI revisited the geometry code with the intention of updating it. In this study, numerical simulations were performed for two adjacent $90^{\circ}$ elbows and the results were analysed in terms of the proximity effect between the two adjacent elbows.

Evaluation on the Properties of Modified-sulfur Concrete as a Basic Study for Development of Anti-corrosive Concrete (내부식성 콘크리트 개발을 위한 기초연구로서 개질유황 혼합 콘크리트의 물성 평가)

  • Park, Sang-Soon;Na, Ok-Jung
    • Corrosion Science and Technology
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    • v.15 no.1
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    • pp.28-37
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    • 2016
  • Due to the increased construction of offshore concrete structures and the use of de-icing salts for the purpose of snow removal, the needs for the development of anti-corrosive concrete are increasing. To solve these problems, an evaluation of the mechanical and durability properties for concrete were conducted by mixing modified-sulfur as 0 %, 5 %, 10 %, 15 % cement weight ratio. Both strengths and the properties affecting durability such as water absorption coefficient, chloride ion permeability, accelerated carbonation resistance, rapid freezing and thawing, and chemical resistance were evaluated. All evaluations performed were according to the test specifications associated KS. The results indicate that mixing of modified-sulfur lowed chloride ion permeability and improved chemical resistance.

Cut Edge Corrosion of Painted Zn and 55%Al-Zn Coated Steels under Alternate Wetting and Drying

  • Nishikata, A.;Tsuda, T.;Tsuru, T.
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.34-38
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    • 2010
  • Electrochemical study on cut edge corrosion of prepainted Zn coated (GI) and 55%Al-Zn coated (GL) steels has been performed in wet-dry cyclic conditions. Maximum width of delaminated polymer coating from the cut edge for GI and GL specimens was evaluated under wet-dry cyclic conditions. The cyclic tests were carried out for 1000 h by changing of relative humidity, where the salt of NaCl was deposited on the specimen every 48 h. The cut edge corrosion test under NaCl deposit indicated that the delamination of the GL specimen progresses at a higher rate than the GI. The electrochemical corrosion monitoring was also performed under condition of alternate exposure to immersion in NaCl solution and drying at 60%RH and $25^{\circ}C$. On the basis of the results of the delamination tests and electrochemical measurements, the mechanism of cut edge corrosion for GI and GL were discussed.

Corrosion Behavior of Ti-13Nb-13Zr and Ti-6Al-4V Alloys for Biomaterial Application

  • Saji, Viswanathan S.;Jeong, Yong-Hoon;Yu, Jin-Woo;Choe, Han-Cheol
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.12-15
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    • 2010
  • Ti-13Nb-13Zr (TNZ) alloy has attracted considerable research attention in the last decade as a suitable substitute for the commercially used Ti-6Al-4V (TAV) alloy for orthopedic and dental implant applications. Hence, in the present work, a comparative evaluation has been performed on the electrochemical corrosion behavior of TNZ and TAV alloys in 0.9 wt.% NaCl solution. The result of the study showed that both the alloys had similar electrochemical behavior. The corrosion resistance of TAV alloy is found to be marginally superior to that of TNZ alloy.

Development of Ultra-High Strength Galvannealed Steel Sheets

  • Fujita, Nobuhiro;Matsumura, Ken-Ichiro;Nonaka, Toshiki;Tomokiyo, Toshimasa
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.16-19
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    • 2010
  • Application of ultra-high strength steel sheets is one of the most important methods to satisfy weight reduction and crash safety of a vehicle. Recently, there has been a trend to apply ultra-high strength steel sheets widely to underbody parts in which corrosion resistance is required. In this work, ultra-high strength galvannealed steel sheets with a tensile strength of 1180 MPa were developed. Newly developed ultra-high strength galvannealed steel sheets have comparable properties, such as mechanical properties, spot weldability, crashworthiness and adhesion of coatings, to conventional steel sheets.

A Method for Real Time Monitoring of Oxide Thickness in Plasma Electrolytic Oxidation of Titanium

  • Yoo, Kwon-Jong;Lee, Yong-K.;Lee, Kang-Soo
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.8-11
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    • 2010
  • During PEO (plasma-electrolytic-oxidation) treatment of titanium, the relationship between the thickness of oxide film and the measured electrical information was investigated. A simple real time monitoring method based on the electrical information being gathered during PEO treatment is proposed. The proposed method utilizes the current flowing from a high frequency voltage source to calculate the resistance of an oxide film, which is converted into the thickness of an oxide film. This monitoring method can be implemented in PEO system in which an oxide film is grown by constant or pulsed voltage/current sources.