• Title/Summary/Keyword: CS-coefficient

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Adsorptive Removal of Radionuclide Cs+ in Water using Acid Active Clay (산활성 점토를 이용한 수중의 방사성 핵종 Cs+ 흡착 제거)

  • Lee, Jae Sung;Kim, Su Jin;Kim, Ye Eun;Kim, Seong Yun;Kim, Eun;Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.66 no.2
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    • pp.78-85
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    • 2022
  • Natural white clay was treated with 6 M of H2SO4 and heated at 80℃ for 6 h under mechanical stirring and the resulting acid active clay was used as an adsorbent for the removal of Cs+ in water. The physicochemical changes of natural white clay and acid active clay were observed by X-ray Fluorescence Spectrometry (XRF), BET Surface Area Analyser and Energy Dispersive X-line Spectrometer (EDX). While activating natural white clay with acid, the part of Al2O3, CaO, MgO, SO3 and Fe2O3 was dissolved firstly from the crystal lattice, which bring about the increase in the specific surface area and the pore volume as well as active sites. The specific surface area and the pore volume of acid active clay were roughly twice as high compared with natural white clay. The adsorption of Cs+ on acid active clay was increased rapidly within 1 min and reached equilibrium at 60 min. At 25 mg L- of Cs+ concentration, 96.88% of adsorption capacity was accomplished by acid active clay. The adsorption data of Cs+ were fitted to the adsorption isotherm and kinetic models. It was found that Langmuir isotherm was described well to the adsorption behavior of Cs+ on acid active clay rather than Freundlich isotherm. For adsorption Cs+ on acid active clay, the Langmuir isotherm coefficients, Q, was found to be 10.52 mg g-1. In acid active clay/water system, the pseudo-second-order kinetic model was more suitable for adsorption of Cs+ than the pseudo-first-order kinetic model owing to the higher correlation coefficient R2 and the more proximity value of the experimental value qe,exp and the calculated value qe,cal. The overall results of study showed that acid active clay could be used as an efficient adsorbent for the removal of Cs+ from water.

Characteristics of Particles Size and Element Distribution in the Coastal Bottom Sediments in the Vicinity of Youngkwang Nuclear Power Plant (영광 원자력발전소 주변해역 표층퇴적물의 입도와 원소분포 특성)

  • 은고요나
    • Economic and Environmental Geology
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    • v.33 no.3
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    • pp.195-204
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    • 2000
  • order to investigate physical characteristics and element concentrations of sediments, coastal bottom sediments were collected at 20 stations in the vicinity of Youngkwang Nuclear Power Plant. After air drying of samples in the laboratory. article size distribution was examined by Master sizer (X-350F), radio-activity by HPGe ${\gamma}$-spectrphotometer, and element concentrations by ICP-AES and AAS. According to particle size analysis , sediments are mainly composed of silt fraction weith 23% of sand, 65% of silt and 12% of clay on average. Most sediments are derived from muddy environment that silt dominates with the characteristics of 5.3${\varsigma}$ mean particle size, poorly sorted, very fine skewed and lepto-kurtic. Only two sediments are well sorted with sandy silt owing to wind, winnowing action, tide and current andits complex reactions. Element concentrations in the coastal bottom sediments are relatively high at finer sediment and show significant relationship with grain size. Index of geoaccumulation by heavy metals at every sampling station is classified as practically unpolluted. The radioactivities of the sediments were measured for 15 isotope elements, and 2 elements of K-40 and Cs-137 were detected in most sediments. The K-40 is the natural nuclide and the artificial nuclide of Cs-137 was thought to be derived from the fallout of past nuclear weapon test. The results of correlation coefficient between grain size and radioactivity shows that the activity of Cs-137 significantly increases in finer grain.

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Price Realities and their Implications of Environment-friendly Agricultural Products for School Food Service - Focused on the Chungnam-Do Case - (학교급식 친환경농산물의 가격실태 분석과 시사점 -충남 친환경 학교급식을 중심으로-)

  • Kim, Ho
    • Korean Journal of Organic Agriculture
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    • v.28 no.4
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    • pp.491-504
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    • 2020
  • School food services using environment-friendly agricultural products (E.F.A.E) have been promoted by school food service center (S.F.S.C) of each county in Chungnam. Since Dangjin S.F.S.C was established for the first time in 2011, 13 S.F.S.Cs have been established in 13 counties of Chungnam. 9 S.F.S.Cs of them have been managed directly by each county and 4 S.F.S.Cs of them managed by contracted cooperatives. Price deviation of 8 foodstuffs (rice, radish, spinach, cabbage, scallion, onion, garlic and potato) which are consumed much relatively was showed differently by counties. And in the average price of 8 foodstuffs, that of foodstuffs produced within the county was lower than that of produced in Chungnam and domestic. Also, the coefficient of variation of school foodstuffs was lower than that of retail market because S.F.S.C has procured school foodstuffs by contract cultivation between each S.F.S.C and producers. Contract cultivation effected on E.F.A.E price stability and producers' farm income.

Prediction of compressive strength of concrete modified with fly ash: Applications of neuro-swarm and neuro-imperialism models

  • Mohammed, Ahmed;Kurda, Rawaz;Armaghani, Danial Jahed;Hasanipanah, Mahdi
    • Computers and Concrete
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    • v.27 no.5
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    • pp.489-512
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    • 2021
  • In this study, two powerful techniques, namely particle swarm optimization (PSO) and imperialist competitive algorithm (ICA) were selected and combined with a pre-developed ANN model aiming at improving its performance prediction of the compressive strength of concrete modified with fly ash. To achieve this study's aims, a comprehensive database with 379 data samples was collected from the available literature. The output of the database is the compressive strength (CS) of concrete samples, which are influenced by 9 parameters as model inputs, namely those related to mix composition. The modeling steps related to ICA-ANN (or neuro-imperialism) and PSO-ANN (or neuro-swarm) were conducted through the use of several parametric studies to design the most influential parameters on these hybrid models. A comparison of the CS values predicted by hybrid intelligence techniques with the experimental CS values confirmed that the neuro-swarm model could provide a higher degree of accuracy than another proposed hybrid model (i.e., neuro-imperialism). The train and test correlation coefficient values of (0.9042 and 0.9137) and (0.8383 and 0.8777) for neuro-swarm and neuro-imperialism models, respectively revealed that although both techniques are capable enough in prediction tasks, the developed neuro-swarm model can be considered as a better alternative technique in mapping the concrete strength behavior.

A Study on the Environmental Service Quality of Department Store by Total CS-coefficient (총체적 고객만족계수를 활용한 백화점의 환경 서비스품질에 관한 연구)

  • Shin, Ah-Reum;Lee, Sang-Bok
    • Proceedings of the Korean Society for Quality Management Conference
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    • 2006.11a
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    • pp.79-84
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    • 2006
  • Many Papers of Customer satisfaction are issued. Kana who have proposed 'Quality Dualism' for grasping of Customers' potential needs and Timko who have proposed 'Customer Satisfaction coefficient' that made up for the weak points of Kana' s model. But the model of Timko which have weak points as well that does not consider the indifferent Quality of the Kana's model. In this paper, I propose 'Total Customer Satisfaction coefficient' that made up for the weak points of Timko's Model also Kana's Model. And I have applied my method to the department store.

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A Study on Service Quality of Fashion Retail Stores, using the Kano Model & Potential Customer Satisfaction Improvement Index - Focused on Department Stores - (Kano 모델 및 PCSI 지수를 통한 의류점포의 서비스품질에 관한 연구 - 백화점을 중심으로 -)

  • Han, Sang-In;Hwang, Sun-Jin
    • Journal of the Korean Society of Costume
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    • v.61 no.1
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    • pp.34-46
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    • 2011
  • The purposes of this study are to classify apparel service quality elements using the Kano's model, and to identify how much service quality can increase the degree of customer satisfaction when the service quality is fully fulfilled. Women over 20 years-old from metropolitan areas participated in the study. Data from 254 questionnaires were used for the statistical analysis. The results were as follows: First, 17 service quality elements were categorized into one-dimensional quality which could lead to both satisfaction and dissatisfaction, and 3 services quality elements were categorized into indifferent quality which neither result in satisfaction nor dissatisfaction. Second, potential customer satisfaction improvement(PCSI) Index was developed using Kano model and CS coeffient. Findings of this study provide both industry and academic researchers with a guide to increase customer satisfaction in fashion retail store.

Electrogravimetric and Electrochemical Ac Response of Polypyrrole Films

  • Yang, Haesik;Lee, Hochun;Kwak, Juhyoun
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.663-668
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    • 1995
  • Ion transport of a polypyrrole/chloride (PPy/Cl) film and a polypyrrole/poly(styenesulfonate) (PPy/PSS) film as a function of applied dc potential was investigated by employing electrogravimetric impedance technique and electrochemical impedance technique. The cation and anion contribution to the whole charge capacitance and the diffusion coefficients of cation and anion in a PPy/PSS film were calculated by fitting the electrogravimetric impedance data with proposed model circuit. The diffusion coefficients of $Na^+$ in a 1 M $NaClO_4$ solution are over 1 order of magnitude larger than those of $ClO{_4}^-$, and $ClO{_4}^-$ contribution to charge compensation decreases as dc potential lowers. The charge compensation of a PPy/Cl film ir a 1 M CsCl solution is carried out largely by $Cl^-$ at 0.2 V vs. Ag/AgCl and by $Cs^+$ as well as $Cl^-$ at -0.4 V.

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N-gram Adaptation using Information Retrieval and Dynamic Interpolation Coefficient (정보검색 기법과 동적 보간 계수를 이용한 N-gram 적응)

  • Choi, Joon-Ki;Oh, Yung-Hwan
    • Proceedings of the KSPS conference
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    • 2005.11a
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    • pp.107-112
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    • 2005
  • 연속음성인식을 위한 언어모델 적응기법은 특정 영역의 정보만을 담고 있는 적응 코퍼스를 이용해 작성한 적응 언어모델과 기본 언어모델을 병합하는 방법이다. 본 논문에서는 추가되는 자료 없이 인식 시스템이보유하고 있는 코퍼스만을 사용하여 적응 코퍼스를 구축하기 위해 언어모델에 기반한 정보검색 기법을 사영하였다. 검색된 적응 코퍼스로 작성된 적응 언어모델과 기본 언어모델과의 병합을 위해 본 논문에서는 입력음성을 분할하여 각 구간에 최적인 동적 보간 계수를 구하는 방법을 제안하였다. 제안된 적응 코퍼스를 구하는 방법과 동적 보간 계수는 기본 언어모델 대비절대 3.6%의 한국어 방송뉴스 인식 성능 향상을 보여주었으며 기존의 검증자료를 이용한 정적 보간 계수에 비해 상대 13.6%의 한국어 방송뉴스 인식 성능 향상을 보여 주었다.

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Studies on the Behaviour of Radionuclides in the Soil-Plant System;1) On the Uptake of Cesium-137 by Soybean (토양(土壤)-식물계(植物界)에 대(對)한 방사성핵종(放射性核種)의 거동(擧動)에 관(關)한 연구(硏究);I. 대두작물(大豆作物)에 의(依)한 Cs-137의 흡수이행(吸收移行))

  • Ryu, Joon;Kim, Jae-Sung;Lee, Young-Il
    • Korean Journal of Environmental Agriculture
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    • v.2 no.1
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    • pp.30-34
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    • 1983
  • The present study was carried out to determine the effect of a radionuclide, cesium-137, in soybean, which is an element released usually from nuclear facilities. Soybean plants were grown on the pots treated with cesium-137 $0.5{\sim}60{\mu}Ci/1kg$ soil and the uptake, translocation and accumulation of the radiocesium in the plant parts were measured at different growth stage. The results are summarized as follows: 1) Visual toxic symptoms on the plants due to treatment of radioactive cesium were not observed up to $60{\mu}Ci/10Kg$ soil in a pot. 2) The uptake of cesium-137 in soybean plant was increased with increment of concentration applied, while the uptake of potassium was proportionally decreased, indicating to have an ion antagonistic relationship between them. 3) The absolute amounts of cesium-137 in the plants were gradually increased by the pod setting stage, but rather reduced at harvesting stage. The accumulation occurred more in the leaves and stems than the soybean seeds. 4) The rate of uptake was ranged from 0.069 to 0.005 with proportional decrease by increasing concentration applied and the rate of Cs-137 translocation from plants to seeds was averaged 38.6% in soybean plant. The concentration coefficient was 0.04 in the soybean seeds from the pots treated with $20{\mu}Ci$ of cesium-137 and decreased with increment of cesium-137 applied.

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Geochemical Data Analysis of the Granitic Rocks Potentially Related to Fluorite Mineralization in the Geumsan District (금산지역 형석광화작용과 관련된 화강암질암의 지구화학적 자료 해석)

  • Chin, Ho-Ill;Chon, Hyo-Taek;Min, Kyoung-Won
    • Economic and Environmental Geology
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    • v.28 no.4
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    • pp.369-379
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    • 1995
  • About forty ore deposits of $CaF_2{\pm}Au{\pm}Ag{\pm}Cu{\pm}Pb{\pm}Zn$ are widely distributed in the Geumsan district and are believed to be genetically related to the Mesozoic Geumsan granitic rocks. Based on their petrogeochemistry and isotopic dating data, the granitic rocks in this district can be classified into two groups ; the Jurassic granitic rocks(equigranular leucocratic granite, porphyritic biotite granite, porphyritic pink-feldspar granite, seriate leucocratic granite) and the Cretaceous granitic rocks(seriate pink-feldspar granite, equigranular alkali-feldspar granite, equigranular pink-feldspar granite, miarolitic pink-feldspar granite, equigranular biotite granite). Spatial distribution of fluorite ore deposits, fluorine contents of granitic rocks and fracture patterns in this district suggest that three granitic rocks(equigranular biotite granite, equigranular pink-feldspar granite, miarolitic pink-feldspar granite) of the Cretaceous period be genetically related to the fluorite mineralization. In these fluorite-related granitic rocks, fluorine is most highly correlated with Cs(correlation coefficient(r)>0.9), and also highly with MnO, U, Sm, Yb, Lu, Zn, Y, Li(r>0.7). Statistically the variation of fluorine in the fluorite-related granitic rocks can be explained in terros of only three elements, such as Lu, CaO and Cs, and the fluorite-related granitic rocks can be discriminated from the fluorite-nonrelated granitic rocks by a linear functional equation of La, Ce, Cs and F($Z_{Ust}=-1.38341-0.00231F-0.19878Ce+0.38169La+0.54720Cs$). Also, equigranular alkali-feldspar granite is classified into the fluorite-related granitic rocks by means of the linear functional equation($Z_{Ust}$).

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