• Title/Summary/Keyword: CP potential

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Reaction Condition for Biodiesel Production from Animal Fats (동물성 유지를 이용한 바이오디젤 생산의 반응조건)

  • Yang, Hee-Seung;Jeong, Gwi-Taek;Park, Suk-Hwan;Park, Jae-Hee;Park, Don-Hee
    • KSBB Journal
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    • v.22 no.4
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    • pp.228-233
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    • 2007
  • The high cost and lack of vegetable oil are limiting the expansion of biodiesel production. The purpose of research was to investigate the potential of animal fats as biodiesel feedstock. In this paper, transesterification using alkali catalyst and methanol was performed to reaction, we carried out experiments that it was changed variables as reaction temperature, methanol molar ratio, catalyst types, amount of catalyst and reaction time. The optimum reaction condition for biodiesel production was reaction temperature 65$^{\circ}C$, potassium hydroxide 1.0% (w/w), oil to methanol molar ratio 1:15 and reaction time 20 min. In this reaction condition, the contents of fatty acid methyl ester was reached to about 98.7%. Also, properties of biodiesel were measured to correspond to domestic quality standard of acid values, density and viscosity.

Semiconductor CdTe-Doped CdO Thin Films: Impact of Hydrogenation on the Optoelectronic Properties

  • Dakhel, Aqeel Aziz;Jaafar, Adnan
    • Korean Journal of Materials Research
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    • v.30 no.1
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    • pp.1-7
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    • 2020
  • Doping or incorporation with exotic elements are two manners to regulate the optoelectronic properties of transparent conducting (TCO) cadmium oxide (CdO). Nevertheless, the method of doping host CdO by CdTe semiconductor is of high importance. The structural, optical, and electrical properties of CdTe-doped CdO films are studied for the sake of promoting their conducting parameters (CPs), including their conductivity, carrier concentration, and carrier mobility, along with transparency in the NIR spectral region; these are then compared with the influence of doping the host CdO by pure Te ions. X-ray fluorescence (XRF), X-ray diffraction (XRD), optical absorption spectroscopy, and electrical measurements are used to characterise the deposited films prepared by thermal evaporation. Numerous results are presented and discussed in this work; among these results, the optical properties are studied through a merging of concurrent BGN (redshift) and BGW (blue shift) effects as a consequence of doping processes. The impact of hydrogenation on the characterisations of the prepared films is investigated; it has no qualitative effect on the crystalline structure. However, it is found that TCO-CPs are improved by the process of CdTe doping followed by hydrogenation. The utmost TCO-CP improvements are found with host CdO film including ~ 1 %Te, in which the resistivity decreases by ~ 750 %, carrier concentration increases by 355 %, and mobility increases by ~ 90 % due to the increase of Ncarr. The improvement of TCO-CPs by hydrogenation is attributed to the creation of O-vacancies because of H2 molecule dissociation in the presence of Te ions. These results reflect the potential of using semiconductor CdTe -doped CdO thin films in TCO applications. Nevertheless, improvements of the host CdO CPs with CdTe dopant are of a lesser degree compared with the case of doping the host CdO with pure Te ions.

CH4/N2 Separation on Flexible Metal-Organic Frameworks(MOFs) (플렉서블한 금속-유기 골격체(MOFs)를 활용한 메탄/질소 분리)

  • Jung, Minji;Park, Jawoo;Oh, Hyunchul
    • Korean Journal of Materials Research
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    • v.28 no.9
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    • pp.506-510
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    • 2018
  • Nitrogen is a serious contaminant in natural gas because it decreases the energy density. The natural gas specification in South Korea requires a $N_2$ content of less than 1 mol%. Thus, cost-effective $N_2$ removal technology from natural gas is necessary, but until now the only option has been energy-intensive processes, e.g., cryogenic distillation. Using porous materials for the removal process would be beneficial for an efficient separation of $CH_4/N_2$ mixtures, but this still remains one of the challenges in modern separation technology due to the very similar size of the components. Among various porous materials, metal-organic frameworks (MOFs) present a promising candidate for the potential $CH_4/N_2$ separation material due to their unique structural flexibility. A MIL-53(Al), the most well-known flexible metal-organic framework, creates dynamic changes with closed pore (cp) transitions to open pores (ops), also called the 'breathing' phenomenon. We demonstrate the separation performance of $CH_4/N_2$ mixtures of MIL-53(Al) and its derivative $MIL-53-NH_2$. The $CH_4/N_2$ selectivity of $MIL-53-NH_2$ is higher than pristine MIL-53(Al), suggesting a stronger $CH_4$ interaction with $NH_2$.

Surface Observation of Mg-HA Coated Ti-6Al-4V Alloy by Plasma Electrolytic Oxidation

  • Yu, Ji-Min;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.198-198
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    • 2016
  • An ideal orthopedic implant should provide an excellent bone-implant connection, less implant loosening and minimum adverse reactions. Commercial pure titanium (CP-Ti) and Ti alloys have been widely utilized for biomedical applications such as orthopedic and dental implants. However, being bioinert, the integration of such implant in bone was not in good condition to achieve improved osseointegraiton, there have been many efforts to modify the composition and topography of implant surface. These processes are generally classified as physical, chemical, and electrochemical methods. Plasma electrolytic oxidation (PEO) as an electrochemical route has been recently utilized to produce this kind of composite coatings. Mg ion plays a key role in bone metabolism, since it influences osteoblast and osteoclast activity. From previous studies, it has been found that Mg ions improve the bone formation on Ti alloys. PEO is a promising technology to produce porous and firmly adherent inorganic Mg containing $TiO_2$($Mg-TiO_2$ ) coatings on Ti surface, and the amount of Mg introduced into the coatings can be optimized by altering the electrolyte composition. In this study, a series of $Mg-TiO_2$ coatings are produced on Ti-6Al-4V ELI dental implant using PEO, with the substitution degree, respectively, at 0, 5, 10 and 20%. Based on the preliminary analysis of the coating structure, composition and morphology, a bone like apatite formation model is used to evaluate the in vitro biological responses at the bone-implant interface. The enhancement of the bone like apatite forming ability arises from $Mg-TiO_2$ surface, which has formed the reduction of the Mg ions. The promising results successfully demonstrate the immense potential of $Mg-TiO_2$ coatings in dental and biomaterials applications.

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A Practical Hull Form Optimization Method Using the Parametric Modification Function (파라메트릭 변환함수를 이용한 선형최적화의 실용화에 관한 연구)

  • Kim, Hee-Jung;Choi, Hee-Jong;Chun, Ho-Hwan
    • Journal of the Society of Naval Architects of Korea
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    • v.44 no.5
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    • pp.542-550
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    • 2007
  • A geometry modification is one of main keys in achieving a successful optimization. The optimized hull form generated from the geometry modification should be a realistic, faired form from the ship manufacturing point of view. This paper presents a practical hull optimization procedure using a parametric modification function. In the parametric modification function method, the initial ship geometry was easily deformed according to the variations of design parameters. For example, bulbous bow can be modified with several parameters such as bulb area, bulb length, bulb height etc. Design parameters are considered as design variables to modify hull form, which can reduce the number of design variables in optimization process and hence reduce its time cost. To verify the use of the parametric modification function, optimization for KCS was performed at its design speed (FN=0.26) and the wave making resistance is calculated using a well proven potential code with fully nonlinear free surface conditions. The design variables used are key design parameters such as Cp curve, section shape and bulb shape. This study shows that the hull form optimized by the parametric modification function brings 7.6% reduction in wave making resistance. In addition, for verification and comparison purpose, a direct geometry variation method using a bell-shape modification function is used. It is shown that the optimal hull form generated by the bell-shaped modification function is very similar to that produced by the parametric modification function. However, the total running time of the parametric optimization is six times shorter than that of the bell shape modification method, showing the effectiveness and practicalness from a designer point of view in ship yards.

The carryover effects of high forage diet in bred heifers on feed intake, feed efficiency and milk production of primiparous lactating Holstein cows

  • Chemere, Befekadu;Lee, Bae Hun;Nejad, Jalil Ghassemi;Kim, Byong Wan;Sung, Kyung Il
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.37 no.3
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    • pp.208-215
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    • 2017
  • This study was designed to investigate the carryover effects of high-forage to concentrate (F: C) diet in bred heifers on feed intake, feed efficiency (FE) and milk production of primiparous lactating Holstein cows. The experiment was conducted for 589 days (d) from onset of pregnancy through to the end of first lactation. Twenty-four bred heifers (Body weight: $BW=345.8{\pm}45.4kg$ and $15{\pm}1.2mon$ of age) randomly assigned to two groups of 3 pens containing 4 heifers each and fed high forage (HF) diet with F: C ratio of 91.7: 8.3% and low forage (LF) diet with F: C ratio of 77.8: 22.2% throughout the pregnancy period. After calving, lactating cows were fed total mixed ration (TMR) based diet. No differences (p > 0.05) were observed in dry matter intake (DMI) of bred heifers and primiparous lactating cows in both HF and LF groups. The FE of mid-to-late lactation period was higher (p< 0.05) in HF than LF group. However, the HF group showed higher (p < 0.05) milk yield, 4 % fat corrected milk (FCM) and energy corrected milk (ECM) than LF group during the 305 d lactation. The LF group showed higher (p < 0.05) milk fat, crude protein (CP), milk urea nitrogen (MUN), solid not fat (SNF) and somatic cell count (SCC) than HF group. It is concluded that restriction of F: C ratio to 91.7: 8.3% to bred heifers has the potential carryover effects to maintain higher milk yield and FE with no adverse effect on feed intake and milk composition of primiparous lactating Holstein cows.

Effects of harvest intervals and seeding rates on dry matter yield and nutritive value of alfalfa cultivars

  • Xu, Xuan;Min, Doohong;McDonald, Iryna
    • Journal of Animal Science and Technology
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    • v.63 no.5
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    • pp.1098-1113
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    • 2021
  • Maturation process of alfalfa (Medicago sativa L.) could be prevented by the reduction of lignin content in terms of conventional breeding or transgenic technology. Alfalfa could exhibit higher leaf/stem ratio, with a concern of yield loss. The objective of this study was to compare forage yield and nutritive value of low lignin alfalfa and two reference varieties subjecting to two harvest intervals and three seeding rates. The experimental design was a randomized complete block in a split-split plot arrangement with four replicates, where harvest intervals (28-day and 35-day) were assigned to whole plots, seeding rates were subplots, and varieties were sub-subplots. The weighted mean nutritive value was applied to two production years of 2016 and 2017. Hi-Gest 360 (low lignin alfalfa) provided similar yield potential and increased nutritive value compared to two reference varieties. Over a two-year production period, alfalfa harvested at every 28-day interval provided more economic returns than those at 35-day interval. For the seeding year and first production year, five cuts made by the 28-day interval produced more yield than four cuts by the 35-day interval. Due to limited rainfall in May 2017, a sharp drop of the first cutting overturned the advantage of the five-cut system. Shorter intervals between harvests generally increased crude protein (CP) concentrations. The differences of relative feed value (RFV) between two harvest intervals tended to be great during the first and second cuttings. Overall, harvest interval had a large effect on nutritive value and a more significant effect on alfalfa dry matter yield than variety selection. Seeding rate did not affect alfalfa yield and nutritive value.

Comparison of Regeneration Effects of Direct and Alternating Microcurrent Therapy on Atrophied Calf Muscle in a Rabbit (비복근 위축 토끼 모델에서 직류 및 교류 미세전류의 근육 재생 효과 비교)

  • Kim, Dong Han;Kwon, Dong Rak;Moon, Yong Suk
    • Clinical Pain
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    • v.19 no.2
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    • pp.80-89
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    • 2020
  • Objective: We compared the regenerative effects of microcurrent therapy (MT) according to the type of electric current, which were direct current microcurrent therapy (DCMT) and alternating current microcurrent therapy (ACMT) on atrophied calf muscle in cast-immobilized rabbit. Method: Rabbits were allocated into control group (sham MT), ACMT group, and DCMT group. Before starting treatment, right gastrocnemius (GCM) muscle was immobilized by cast for 2 weeks. Compound muscle action potential of tibial nerve in nerve conduction study, circumference of calf muscle using a ruler, and thickness of medial and lateral GCM muscle measured by ultrasound, cross sectional area (CSA), and proliferating cell nuclear antigen (PCNA) ratios (%) of muscle fibers were measured on the immunohistochemical analysis. Results: The mean atrophic changes (%) in right medial and lateral GCM muscle thickness, right calf circumference, and amplitude of CMAP of the right tibial nerve in ACMT group and DCMT group were significantly lower than those in control group, respectively (p<0.05). The mean CSA (μm2) of type I and type II and PCNA ratios (%) of medial and lateral GCM muscle fibers in ACMT group and DCMT group were significantly greater than those in control group, respectively (p<0.05). There were no significant differences between the ACMT group and DCMT group at all parameters. Conclusion: This study demonstrated that ACMT and DCMT showed better regeneration effect than sham MT. Microcurrent may be effective in regeneration of atrophied muscle regardless of the type of current.

A Study on Cathodic Protection Rectifier Control of City Gas Pipes using Deep Learning (딥러닝을 활용한 도시가스배관의 전기방식(Cathodic Protection) 정류기 제어에 관한 연구)

  • Hyung-Min Lee;Gun-Tek Lim;Guy-Sun Cho
    • Journal of the Korean Institute of Gas
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    • v.27 no.2
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    • pp.49-56
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    • 2023
  • As AI (Artificial Intelligence)-related technologies are highly developed due to the 4th industrial revolution, cases of applying AI in various fields are increasing. The main reason is that there are practical limits to direct processing and analysis of exponentially increasing data as information and communication technology develops, and the risk of human error can be reduced by applying new technologies. In this study, after collecting the data received from the 'remote potential measurement terminal (T/B, Test Box)' and the output of the 'remote rectifier' at that time, AI was trained. AI learning data was obtained through data augmentation through regression analysis of the initially collected data, and the learning model applied the value-based Q-Learning model among deep reinforcement learning (DRL) algorithms. did The AI that has completed data learning is put into the actual city gas supply area, and based on the received remote T/B data, it is verified that the AI responds appropriately, and through this, AI can be used as a suitable means for electricity management in the future. want to verify.

Ginsenoside Rg5 promotes wound healing in diabetes by reducing the negative regulation of SLC7A11 on the efferocytosis of dendritic cells

  • Wei Xia;Zongdong Zhu;Song Xiang;Yi Yang
    • Journal of Ginseng Research
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    • v.47 no.6
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    • pp.784-794
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    • 2023
  • Background: ginsenoside Rg5 is a rare ginsenoside with known hypoglycemic effects in diabetic mice. This study aimed to explore the effects of ginsenoside Rg5 on skin wound-healing in the Leprdb/db mutant (db/db) mice (C57BL/KsJ background) model and the underlying mechanisms. Methods: Seven-week-old male C57BL/6J, SLC7A11-knockout (KO), the littermate wild-type (WT), and db/db mice were used for in vivo and ex vivo studies. Results: Ginsenoside Rg5 provided through oral gavage in db/db mice significantly alleviated the abundance of apoptotic cells in the wound areas and facilitated skin wound healing. 50 μM ginsenoside Rg5 treatment nearly doubled the efferocytotic capability of bone marrow-derived dendritic cells (BMDCs) from db/db mice. It also reduced NF-κB p65 and SLC7A11 expression in the wounded areas of db/db mice dose-dependently. Ginsenoside Rg5 physically interacted with SLC7A11 and suppressed the cystine uptake and glutamate secretion of BMDCs from db/db and SLC7A11-WT mice but not in BMDCs from SLC7A11-KO mice. In BMDCs and conventional type 1 dendritic cells (cDC1s), ginsenoside Rg5 reduced their glycose storage and enhanced anaerobic glycolysis. Glycogen phosphorylase inhibitor CP-91149 almost abolished the effect of ginsenoside Rg5 on promoting efferocytosis. Conclusion: ginsenoside Rg5 can suppress the expression of SLC7A11 and inhibit its activity via physical binding. These effects collectively alleviate the negative regulations of SLC7A11 on anaerobic glycolysis, which fuels the efferocytosis of dendritic cells. Therefore, ginsenoside Rg5 has a potential adjuvant therapeutic reagent to support patients with wound-healing problems, such as diabetic foot ulcers.