• Title/Summary/Keyword: COD removal

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Integrated Digestion of Thermal Solubilized Sewage Sludge to Improve Anaerobic Digestion Efficiency of Organic Waste (유기성 폐기물의 혐기성 소화효율 향상을 위한 열가용화 하수슬러지의 통합소화)

  • Oh, Kyung Su;Hwang, Jung Ki;Song, Young Ju;Kim, Min Ji;Park, Jun Gyu;Pak, Dae Won
    • Journal of Korean Society on Water Environment
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    • v.38 no.2
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    • pp.95-102
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    • 2022
  • Studies for improving the efficiency of the traditional anaerobic digestion process are being actively conducted. To improve anaerobic digestion efficiency, this study tried to derive the optimal pretreatment conditions and mixing conditions by integrating the heat solubilization pretreatment of sewage sludge, livestock manure, and food waste. The soluble chemical oxygen demand (SCOD) increase rate of sewage sludge before and after heat solubilization pretreatment showed an increased rate of 224.7% compared to the control group at 170℃ and 25 min and showed the most stable increase rate. As a result of the biomethane potential test of sewage sludge before and after heat solubilization pretreatment, the total chemical oxygen demand (TCOD) and SCOD removal rates increased as the heat solubilization temperature increased, but did not increase further at temperatures above 170℃. In the case of methane generation, there was no significant change in the cumulative methane generation from 0.134 to 0.203 Sm3-CH4/kg-COD at 170℃ for 15 min. As a result of the integrated digestion of organic waste, the experimental condition in which 25% of the sewage sludge, 50% of the food waste, and 25% of the livestock manure were mixed showed the highest methane production of 0.3015 m3-CH4/kg-COD, confirming that it was the optimal mixing ratio condition. In addition, under experimental conditions mixed with all three substrates, M4 conditions mixed with 25% sewage sludge, 50% food waste, and 25% livestock manure showed the highest methane generation at 0.2692 Sm3-CH4/kg-COD.

Effect of Alkaline Pretreatment on Sludge Aerobic Digestion and Fertilizer Value (알칼리 전처리에 의한 슬러지 호기성 소화 및 액비 특성 변화)

  • Hwang, Eung-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.1
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    • pp.90-96
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    • 2008
  • In order to meet the stringent requirement of sludge disposal and to find ecological alternative, aerobic digestion coupled with alkaline pretreatment was studied. The treated sludge was tested for the potential of liquid fertilizer. In the aerobic digestion, it was obvious that the performance of digester B(fed with the sludge pretreated by NaOH) was better than that of digester A(fed with raw sludge) in terms of COD and SS removal. SS and VSS removal rates in digester B were 66% and 69%, respectively. At 5 days, TSS removal rate reached 47% in the digester B, which was 71% of final TSS removal rate. It revealed that the pretreatment process can shorten the retention time of aerobic digestion. 94.1% of TCOD in the raw sludge was reduced by alkaline pretreatment and aerobic digestion. Final SCOD was in the range of 220$\sim$230 mg/L implying the sludge was stabilized. Nitrification and pH drop were observed in the aerobic digestion. Final nitrate concentrations in digester A and B were 445.4 and 223.1 mg/L and final pH in digester B was 3.0. Biological assays reported that leaf size of cucumber seedling increased with nitrate concentration and sludge to soil ratio. The sludge treated by alkaline and aerobic digestion promoted the growth of seedling leaf and stem remarkably compared to raw sludge. In contrast, the aerobically digested sludge without pretreatment improved leaf growth and inhibited stem growth.

Biofilm Processes for Volume Decrease in Recirculating Water Treatment Systems for Aquaculture

  • Kim Jeong-Sook;Yoon Gil-Ha;Ghim See-Jun;Kang Lim-Seok;Lee Byung-Hun
    • Fisheries and Aquatic Sciences
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    • v.1 no.2
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    • pp.242-249
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    • 1998
  • The engineering aspect of water treatment processes in the recirculating aquaculture system was studied. To recycle the water in the aquaculture system, a wastewater treatment process was required to maintain high water quality for the growth and health of the cultured fish. In this study, three different biofilm processes were used to reduce the concentration of organic matters and ammonia from the recirculating water - two phase fluidized bed, three phase fluidized bed, and trickling filter. The objectives of this research were to evaluate the optimum treatment conditions of the biofilm processes for the recirculating aquaculture system, and thereby reduce the volume of biofilm processes, which are commonly used for the recycle water treatment processes for aquaculture. The result of this study showed that the removal efficiency of organic matters by trickling filter was found to be lower than that of the fluidized bed. In the trickling filter system, anthracite showed better organic removal efficiency than crushed stone as a media. In the two phase fluidized bed, the maximum removal efficiency of either organics or ammonia was obtained when both the packing rate of media was maintained to $40\%$ of total reactor depth excepting sediment zone and the bed expansion rate was maintained to $100\%$. When 100 tilapia (Oreochromis niloticus) of each average 200g was reared, the pollutant production rate was 0.07g $NH_4\;^+-N/kg$ fish/day and 0.06g P04-3-P/kg fish/day, and sludge production rate was 0.39 g SS/kg fish/day. In the two phase and three phase fluidized bed, the volume of water treatment tank could be calculated from an empirical equation by using the relationship between the influent COD to $NH_4\;^+-N$ ratio (C/N, -), media concentration (Cm, g/L), influent ammonia nitrogen concentration (Ni, mg/L), effluent ammonia nitrogen concentration (Ne, mg/L), bed expansion rate $(E,\;\%)$, and influent flowrate $(Q,\;m^3/hr)$. The empirical equation from this study is $$V_2\;=\;10^{3.1279}\;C/N^{3.5461}\;C_m\;^{-3.7473}\;N_i\;^{4.6477}\;E^{0.0326}\;N_e\;^{-0..8849}\;Q\;(Two\;Phase\;FB) V_3\;=\;10^{11.7507}\;C/N^{-1.2330}\;C_m\;^{-6.5715}\;N_i\;^{1.5091}\;N_e\;^{-1.8489}\;Q (Three\;Phase\;FB)$$

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The Effect of the Reaction Time Increases of Microbubbles with Catalyst on the Nitrogen Reduction of Livestock Wastewater (가축분뇨의 마이크로버블과 촉매와의 반응 시간 증가에 따라 질소 제거에 미치는 영향)

  • Jang, Jae Kyung;Sung, Je Hoon;Kang, Youn Koo;Kim, Young Hwa
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.10
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    • pp.578-582
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    • 2015
  • It was investigated whether the removal of nitrogen ions included livestock wastewater were increased by increasing the reaction time of livestock wastewater and microbubbles with catalyst. For this study, the nitrogen reduction system using microbubbles with catalyst was used. The two reactors were consecutively arranged, and the second reactor (Step 2) was located to next the first reactor (Step 1). Each reactor was reacted for 2 hours and air or oxygen as oxidant was fed into the reactor during operation before microbubble device. When oxygen was used, ammonia nitrogen was removed each 18.3% and 52.8% during 2 (only step 1) and 4 (step 1 and step 2) hours reactions. This value was higher than that of when air was fed. When oxygen was used, the longer the reaction time, the ammonia nitrogen removal was higher. The longer the reaction time, the higher the nitrite and nitrate was also removed such as ammonia nitrogen. Also this system was examined whether organic matter removal is effective. The total chemical oxygen demand (TCOD) removal was higher than the soluble chemical oxygen demand (SCOD). Some materials among causing substances COD were difficult to decompose biologically. Therefore, it means that it will be easy to operate the biological processes following step and reduce the concentration of organic contaminants in effluent.

Optimal Trajectory Finding and re-optimization of SBR for Nitrogen Removal (연속 회분식 반응기에서 최적 질소 제거를 위한 최적 궤적 찾기와 재최적화)

  • Kim, Young-Whang;Yoo, ChangKyoo;Lee, In-Beum
    • Korean Chemical Engineering Research
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    • v.45 no.1
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    • pp.73-80
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    • 2007
  • This article aims to optimize the nitrogen removal of a sequencing batch reactor (SBR) through the use of the activated sludge model and iterative dynamic programming (IDP). Using a minimum batch time and a maximum nitrogen removal for minimum energy consumption, a performance index is developed on the basis of minimum area criteria for SBR optimization. Choosing area as the performance index makes the optimization problem simpler and a proper weighting in the performance index makes it possible to solve minimum time and energy problem of SBR simultaneously. The optimized results show that the optimal set-point of dissolved oxygen affects both the total batch time and total energy cost. For two different influent loadings, IDP-based SBR optimizations suggest each supervisory control of batch scheduling and set-point trajectory of dissolved oxygen (DO) concentration, and can save 20% of the total energy cost, while meeting the treatment requirements of COD and nitrogen. Moreover, it shows that the re-optimization of IDP within a batch can solve the modelling error problem due to the influent loading changes, or the process faults.

Research on improvement of water purification efficiency by porous concrete using bio-film (생물막을 이용한 다공성 콘크리트의 수질정화 효율 개선에 대한 연구)

  • Kim, Tae-Hoon;Li, Feng-Qi;Ahn, Tae-Woong;Choi, I-Song;Oh, Jong-Min
    • Journal of Environmental Impact Assessment
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    • v.20 no.6
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    • pp.815-821
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    • 2011
  • This study aims to estimate the biological decomposition capacity of MPC(Microorganism Porous-Concrete). MPC has specific surface area formed by inside pores, and bio compound was added to those pores to reduce pollutants loading. To evaluate the water purification capacity of MPC, we carried out the comparative studies using different media types [GPC(General Porous-concrete), CPC(Compound porous-concrete), LPC(Lightweight aggregate porous-concrete)] under the condition of CFSTR, and different retention times (30, 60 and 120 min). We also estimated the purification capacity of MPC under different concentrations of pollutant loadings. The MPC showed higher efficiency in water purification function than other conventional porous concretes with efficient decrease rates of SS, BOD, COD, and nutrient concentrations. In the comparison experiment for different retention times, MPC showed the highest removal efficiency for all tested pollutants in the longest retention time(120 min). In the long period test, the removal efficiencies of MPC concrete were high until 100 days after the set up of the operation, but began to decrease. Outflow flux was invariable compared with inflow flux so that extra detention time for media fouling such as back washing is not needed. But the results suggested that appropriate management is necessary for long-term operation of MPC. As the final outcome, MPC using bio organisms is considered to be efficient for stream water purification when they used as substrates for artificial river structure.

The Treatment of Animal Wastewater by the Combination of Trickling Filter System and Activated Sludge Process (살수여상 활성오니 연계방법에 의한 축산뇨요수 처리)

  • Ryoo J. W.
    • Journal of Animal Environmental Science
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    • v.10 no.2
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    • pp.81-86
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    • 2004
  • This experiment was conducted to evaluate combination system of wood chip trickling system and activated sludge process. The results obtained are summarized as tallows. The trickling filter system using wood chip was used as a biological pre-treatment system for treating piggery wastewater. At pre-treatment the removal efficiencies were BOD $91\%$ CODmn $65\%$, SS $75\%$ T-N $73\%$, T-P $69\%$. After pre-treatment the removal efficiencies in activated sludge process were BOD $99\%$ CODmn $94.6\%$, SS $97.8\%$ T-N $91.1\%$, T-P $91\%$. This study shows a very stable method with pre-treatment of trickling filter using wood chip. These combined treatment system was very useful for piggery wastewater.

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Microbe Adhesion and Organic Removal from Synthetic Wastewater Treatment using Polypropylene Media Modified by Ion-Assisted Reactions (이온 보조 반응에 의하여 활성화된 폴리프로필렌 담체를 이용만 합성폐수 처리시 미생물 부착 및 유기물의 제거)

  • Seon, Yong-Ho;Han, Sung;Koh, Seok-Keun
    • KSBB Journal
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    • v.17 no.3
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    • pp.235-240
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    • 2002
  • The surface of polypropylene was modified by 1 keV $Ar^+$ ion beam in an $O_2$ environment in order to enhance wettability. Contact angle of deionized water on modified polypropylene was reduced from $78^{\circ}$to $22^{\circ}$. The enhanced wettability is originated from newly formed functional groups such as ether, carbonyl, and carbonyl groups. During immersion in deionized water, the enhanced wettability has remained nearly same. After washing in water, the hydrophilic functional groups on the polymer surface have been very stable. The modified polypropylene was adopted as bio-film media to remove organics in synthetic wastewater. Microbe adhesion on the polypropylene surface was improved due to the newly formed hydrophilic groups.

A Study on the Development of Performance Evaluation Method for the Stormwater Treatment Wetland (비점오염관리를 위한 강우유출수 처리습지의 성능평가방법 개발)

  • Kim, Young Ryun;Kim, Sang Dan;Lee, Suk Mo;Sung, Kijun;Song, Kyo Ook;Son, Min Ho
    • Journal of Korean Society on Water Environment
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    • v.29 no.3
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    • pp.354-364
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    • 2013
  • The performance of the stormwater wetlands can be significantly influenced by antecedent stormwater in storage at the commencement of a stormevent. As inflows are intermittent and stochastic in nature, the evaluation of the treatment efficiency of a stormwater wetland should be considered by runoff capture and water treatment characteristics during interevent periods. In this study, analytical probabilistic model is applied to identity runoff capture rate and treatment efficiency of the stormwater wetland. To achieve this, continuous rainfall data recorded in Busan for 31 years has been analyzed to derive the runoff capture rate, and 1st order kinetic decay constants ($k_V$, 1/d) are calculated from regression analysis to identify pollutants removal during interevent periods. The results show that about 60.9% of annual average runoff is captured through the stormwater wetland. The annual average treatment efficiencies of SS, BOD, COD, TN and TP is about 11.4, 8.9, 9.8, 4.3 and 9.6%, respectively. The analytical model has been compared with the numerical model and it shows that analytical model is valid. Performance evaluation methods developed in this study has the advantages of considering characteristics of rainfall-runoff, facility type and pollutant removal.

Characteristics of Food Waste Leachate Treatment in Thermophilic two Stage Anaerobic Digestion Combined UF Membrane (막결합형 고온 이상 혐기성 소화공정에서 음폐수 처리 특성)

  • Kim, Young-O;Jun, Duk-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.3
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    • pp.21-24
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    • 2012
  • In this study, Anaerobic Membrane Bioreactor(AnMBR) treating food waste leachate was operated to investigate treatment efficiency of anaerobic process, operational parameters and production of biogas. AnMBR was operated under the condition of filtration type of inside-out mode. AnMBR was operated under the condition that range of permeate flux was from 15 to 20 LMH and range of transmembrane pressure was from 1 to $3 kgf/cm^2$. It was not good that AnMBR was performed under direct connection between anaerobic reactor and external UF module. so, this connection method changed to indirect connection using buffer tank was placed between anaerobic reactor and UF external module. TCOD and SCOD values were that influent were about 113 g/L, 62 g/L and effluent were 25 g/L, 12 g/L, respectively. also TCOD and SCOD removal efficiency were 77% and 81%, respectively. but after added UF process, COD and SCOD removal efficiency was increased to 93% and 86%, respectively.