• Title/Summary/Keyword: COD Removal

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Characteristics of Food Waste Leachate Treatment in Thermophilic two Stage Anaerobic Digestion Combined UF Membrane (막결합형 고온 이상 혐기성 소화공정에서 음폐수 처리 특성)

  • Kim, Young-O;Jun, Duk-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.3
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    • pp.21-24
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    • 2012
  • In this study, Anaerobic Membrane Bioreactor(AnMBR) treating food waste leachate was operated to investigate treatment efficiency of anaerobic process, operational parameters and production of biogas. AnMBR was operated under the condition of filtration type of inside-out mode. AnMBR was operated under the condition that range of permeate flux was from 15 to 20 LMH and range of transmembrane pressure was from 1 to $3 kgf/cm^2$. It was not good that AnMBR was performed under direct connection between anaerobic reactor and external UF module. so, this connection method changed to indirect connection using buffer tank was placed between anaerobic reactor and UF external module. TCOD and SCOD values were that influent were about 113 g/L, 62 g/L and effluent were 25 g/L, 12 g/L, respectively. also TCOD and SCOD removal efficiency were 77% and 81%, respectively. but after added UF process, COD and SCOD removal efficiency was increased to 93% and 86%, respectively.

Influence of Reactive Media Composition and Chemical Oxygen Demand as Methanol on Autotrophic Sulfur Denitrification

  • Qambrani, Naveed Ahmed;Oh, Sang-Eun
    • Journal of Microbiology and Biotechnology
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    • v.22 no.8
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    • pp.1155-1160
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    • 2012
  • Sulfur-utilizing autotrophic denitrification relies on an inorganic carbon source to reduce the nitrate by producing sulfuric acid as an end product and can be used for the treatment of wastewaters containing high levels of nitrates. In this study, sulfur-denitrifying bacteria were used in anoxic batch tests with sulfur as the electron donor and nitrate as the electron acceptor. Various medium components were tested under different conditions. Sulfur denitrification can drop the medium pH by producing acid, thus stopping the process half way. To control this mechanism, a 2:1 ratio of sulfur to oyster shell powder was used. Oyster shell powder addition to a sulfur-denitrifying reactor completely removed the nitrate. Using 50, 100, and 200 g of sulfur particles, reaction rate constants of 5.33, 6.29, and $7.96mg^{1/2}/l^{1/2}{\cdot}h$ were obtained, respectively; and using 200 g of sulfur particles showed the highest nitrate removal rates. For different sulfur particle sizes ranging from small (0.85-2.0 mm), medium (2.0-4.0 mm), and large (4.0-4.75 mm), reaction rate constants of 31.56, 10.88, and $6.23mg^{1/2}/l^{1/2}{\cdot}h$ were calculated. The fastest nitrate removal rate was observed for the smallest particle size. Addition of chemical oxygen demand (COD), methanol as the external carbon source, with the autotrophic denitrification in sufficiently alkaline conditions, created a balance between heterotrophic denitrification (which raises the pH) and sulfur-utilizing autotrophic denitrification, which lowers the pH.

Efficient aerobic denitrification in the treatment of leather industry wastewater containing high nitrogen concentration

  • Kang, Kyeong Hwan;Lee, Geon;Kim, Joong Kyun
    • Environmental Engineering Research
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    • v.20 no.1
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    • pp.79-87
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    • 2015
  • To treat leather industry wastewater (LIW) containing high nitrogen concentration, eight aerobic denitrifiers were isolated from sludge existing in an LIW-treatment aeration tank. Among them, one strain named as KH8 had showed the great ability in denitrification under an aerobic condition, and it was identified as Pseudomonas aeruginosa R12. The aerobic denitrification ability of the strain KH8 was almost comparable to its anaerobic denitrification ability. In lab-scale aerobic denitrifications performed in 1-L five-neck flasks for 48 hr, denitrification efficiency was found to be much improved as the strain KH8 held a great majority in the seeded cells. From the nitrogen balance at the cell-combination ratio of 10:1 (the strain KH8 to the other seven isolates) within the seeded cells, the percentage of nitrogen loss during the aerobic denitrification process was estimated to be 58.4, which was presumed to be converted to $N_2$ gas. When these seeded cells with lactose were applied to plant-scale aeration tank for 56 day to treat high-strength nitrogen in LIW, the removal efficiencies of $COD_{Cr}$ and TN were achieved to be 97.0% and 89.8%, respectively. Under this treatment, the final water quality of the effluent leaving the treatment plant was good enough to meet the water-quality standards. Consequently, the isolated aerobic denitrifiers could be suitable for the additional requirement of nitrogen removal in a limited aeration-tank capacity. To the best of our knowledge, this is the first report of aerobic denitrifiers applied to plant-scale LIW treatment.

Removal of Nutrients from Domestic Wastewater Using Intermittently Aerated Activated Sludge Systems Supplemented with Fermented Settled Sludge (발효된 1차 침전슬러지를 공급하여 간헐폭기조를 이용한 도시하수의 영양염류 처리)

  • Weon, Seung-Yeon;Lee, Sang-Ill
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.18-23
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    • 2004
  • In this research, a 2-stage intermittently aerated activated sludge system(IA) and intermittently aerated dynamic flow activated sludge system(DF) were investigated for the removal of nutrients in domestic wastewater. Wastewater was characterized by low C/N( organics/nitrogen) ratio. $COD_{cr}$, $BOD_s$, TKN and TP concentrations of domestic wastewater were 235, 47, 32 and 5.4 mg/L, respectively. Three sets of IA and one set of DF were operated. Three of four systems were added with fermented settled sludge taken from primary settling tank as an external electron donor and the other(IA) for control reactor was operated without addition of electron donor. All systems were operated at same sludge retention time of 20 days and hydraulic retention time of 12hrs. The supplemental electron donor was supplied into the anoxic mode. A higher denitrification rate was observed from the reactors with fermented settled sludge as an electron donor for denitrification compared to that of without addition of organic source. The result of this study indicates that the settled primary sludge, if the fermented at the acid stage, was an excellent electron donor for denitrification. 81 % of TN and 80% of TP were removed from the systems with the supplemental organic source added. However, the control reactor without addition of electron donor showed only 39% of TN and 43% of TP.

Applicable Feasibility of Fenton Oxidation and Zeolite Ion Exchange Processes for Removal of Non-Biodegradable Matters and Ammonia in Livestock Wastewater (축산폐수 중의 난분해성 물질 및 암모니아 제거를 위한 Fenton 산화와 Zeolite 이온교환 공정의 적용 가능성)

  • Cho, Chang-Woo;Kim, Byoung-Young;Chae, Soo-Choen;Chung, Paul-Gene
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.600-606
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    • 2007
  • Livestock wastewater containing concentrated organic matters and nutrients has been known as one of the major pollutants. It is difficult to apply the conventional activated sludge process to treat livestock wastewater because of high Non-biodegradable (NBD) matter and ammonia. The objectives of this study are to remove NBD matters including aromatic compounds and ammonia in livestock wastewater using Coagulation-Fenton oxidation-Zeolite (CFZ) processes and ascertain applicable feasibility in the field through pilot plant experiment. NBD matters and color remained in the treated water were removed over 92% by Fenton oxidation as the second treatment process. Ammonia was removed by over 99.5% in the zeolite ion exchange process as the last treatment method. From $UV_{254}$, $E_2/E_3$ ratio and GC/MS analyses of treated water at each process, the aromatic compound was converted to aliphatic and aromaticity was decreased. In pilot scale test, organics and ammonia removal efficiencies were not much different from the result of lab-scale test at various operation conditions. Furthermore, reaction time and dosage of Fenton reagent in pilot scale experiment reduced by 40 min and 50% rather than in lab-scale test. $BOD_5$, $COD_{Mn}$, SS, T-N and T-P of treated water in the pilot-scale experiment also met the effluent standards.

A Study on Strengthening Option of T-N Effluent Water Quality Standards of Sewage Treatment Plants (하수처리시설의 T-N 방류수 수질기준 강화방안에 관한 연구)

  • Kim, Ji Tae
    • Journal of Korean Society on Water Environment
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    • v.34 no.2
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    • pp.216-225
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    • 2018
  • Over the past 40 years, the public sector has continued to invest in the sewage treatment plants (STPs) in Korea. Currently, the domestic sewage treatment rate is over 90% with the enhancement of operating efficiency of the STPs, and water quality of major rivers has been continuously improved. However, COD and T-N indicators are stagnating or slightly worsening, and though advanced treatment facilities are installed in most of the STPs, there is a limit to the removal of nutrients. Since there are a lot of water pollution sources in the vicinity of the watershed because of high population density in Korea, it is essential to reduce the inflow of the nutrients in order to prevent the eutrophication of the rivers and lakes. While the effluent T-P standard in STPs has greatly strengthened since 2012, which results in the considerable investment for the improvement of treatment process in STPs for the last few years, it is necessary to strengthen the T-N standards, as the effluent standard of T-N has been maintained at 20 mg/L since 2002. In this study, based on the analysis of the effluent T-N standard status of major industrialized countries, and the domestic nitrogen load in public waters, the option of appropriate T-N standard level is reviewed, and the required investment costs and the effect of strengthening the standard are estimated.

Practical Research on the Advanced Detention Pond for the Improvement of Water Quality of Agricultural Reservoir (농업용저수지의 수질개선을 위한 오염물질 침강지 조성 기법)

  • Pae, Yo Sop;Nam, Gui Sook
    • Journal of Wetlands Research
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    • v.10 no.3
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    • pp.79-86
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    • 2008
  • To improve water quality for agricultural use, it is needed to introduce the natural and low-cost self-purification system. It is also necessary to develop the water purification facilities for more efficient and convenient design, construction, operation and management. This study aims to develop the practical facilities to improve water quality for agricultural use. The practical detention pond system, which uses artificial floating island and shield skirts with bio-media, enhanced removal efficiencies of SS, TN and TP more particularly than the detention pond using an auxiliary dam. The removal efficiencies SS, TN and TP for the practical detention pond were 55.7%, 61.0% and 55.9%, respectively. The facilities of the practical detention pond has a lot of disadvantages such as the low-cost and high efficiency as well as uncountable impacts regarding ecology and landscape. However, an auxiliary dam is recommended to be installed in shallow depth due to low efficiency.

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Applicability of the SBR Process Using Aerobic Granular Sludge (AGS) in Municipal Wastewater Treatment (호기성 그래뉼 슬러지를 이용한 연속 회분식 공정의 도시하수처리에 대한 적용)

  • Yae, Jae-Bin;Ryu, Jae-Hoon;Hong, Seong-Wan;Kim, Hyun-Gu;Ahn, Dae-Hee
    • Journal of Environmental Science International
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    • v.27 no.4
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    • pp.233-240
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    • 2018
  • The purpose of this study was to confirm the applicability of aerobic granular sludge (AGS) in the advanced sewage treatment process. Simulated influent was used in the operation of a laboratory scale reactor. The operation time of one cycle was 4 h and the reactor was operated for six cycles per day. The volume exchange ratio was 50%. The influent was injected in divisions of 25% to increase the removal efficiency of nitrogen in every cycle. As a result, the removal efficiencies of $COD_{Cr}$ and TN in this reactor were 98.2% and 76.7% respectively. During the operation period, the AGS/MLVSS concentration ratio increased from 70.0% to 86.7%, and the average $SVI_{30}$ was 67 mL/g. The SNR and SDNR were 0.073-0.161 kg $NH_4{^+}$-N/kg MLVSS/day and 0.071-0.196 kg $NO_3{^-}$-N/kg MLVSS/day respectively. These values were higher or similar to those reported in other studies. The operation time of the process using AGS is shorter than that of the conventional activated sludge process. Hence, this process can replace the activated sludge process.

State Evaluation of Nutrient Removal in an Intermittent Aeration Process by Monitoring ORP & pH (ORP와 pH 측정에 의한 간헐폭기 고도처리 공정 제어의 평가)

  • Ko, Kwang Baik;Suh, Jun Suk
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.401-409
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    • 2002
  • In this study, to evaluate the applicability of ORP and pH as process control parameters for an intermittent aeration process, a 200L/d bench-scale plant was installed and operated for 90 days. It was fed with synthetic wastewater which contained $COD_{Cr}$ : 400mg/L, TN : 40mg/L and TP : 7mg/L. ORP & pH were measured on-line and compared with the variation of nutrient concentrations. As the results, both of the ORP and pH were able to monitor successfully nitrification and denitrification. Bending-points on the ORP curve and peak points on the pH curve corresponded to the termination of nitrification and denitrification. For P uptake and release, pH was the best indicator for performance evaluation. The aerobic pH apex was appeared when P uptake was accomplished and there was a relationship between the P release and pH variation. But the pH curve needed filtering because there were many noises on it. In this study, the shape of the ORP & pH curves were varied as the operating conditions such as aeration rates and organic loads were changed. It allowed the operating states of biological systems to be effectively evaluated. If it is properly managed to show the bending points and peak points clearly, the on-line monitoring of ORP & pH will be a reliable and effective technique for process control of intermittent aeration processes.

Treatment of Recycling Wastewater of Aquaculture Using DynaSand Filter( I ) (상향류식 연속역세여과를 이용한 양어장 순환수 재이용(I))

  • 박종호;김이오;황규덕;황금희;조규석;김동식
    • Journal of Aquaculture
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    • v.15 no.2
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    • pp.87-93
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    • 2002
  • To improve the efficiency of biological filters used for treating recycled wastewater of aquaculture, the conventional and advanced DynaSand Filters were tested. Applying the fluid mechanics and physical chemistry theories to wastewater treatment plant, the advanced filter focuses on detection of wastewater characteristics and automatic operation of DynaSand Filter to improve backwashing, oxygen transport, turbidity removal and continuous head loss. The Filter removes COD, ammonia, and suspended solids (SS), the major pollutants in aquaculture wastewater. The total volume of the DynaSand Filter is 70 L, while the working volume is 35 L per cycle. The removal efficiency of the advanced DynaSand Filter is 71 % for SS (as against 55 % for the conventional filter), 84 % for ammonia, 85 % for T-P, and 88 % for SRP.