• Title/Summary/Keyword: COD 감소

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STUDIES ON THE MATHEMATICAL KINETICS FOR THE REMOVABLE MOVING SCREEN MEDIA-ACTIVATED SLUDGE PROCESS (회전형 반고정망 활성슬럿지 공법의 수학적 해법에 관한 연구 1. 유기물 제거속도에 대하여)

  • HAN Ung-Jun;HAN Yeong-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.12 no.3
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    • pp.167-173
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    • 1979
  • It is preented the removable moving screen media-activated sludge (REMSMAS) process by using the biological fixed-film systems. The substrate removal kinetic difference between the aeration-only completed mixing activated sludge (CMAS) process and REMSMAS process were observed. The substrate removal kinetics were developed based on the attached and suspended microbial growths. The units of the aeration-only CMAS process were continously operated with the normal detention time of 4.5, 6, 9.5 and 12 flours studies after steady-state condition and the operating of the REMSMAS units conducted with the normal detention time of 6 and 12 hours studies in nonsteady-state condition. The feed solution was diluted 18 times to the raw starch wastewater in of order to maintain the proper COD (950mg/l) and BOD (450mg/l) concentration. Design parameters related to the suspended microbial growths were caculated by the equations used in the aeration-only CMAS model and these parameters used to evalute the kinetic constants in the REMSMAS process. The kinetic constant values of $Y_2,\;K_d,(\mu_{max})_s\;and\;K_s$ from Monod equations were respectively 0.78, 0.027/hr, 1.1/hr and 95mg/l in the aeration-only CMAS process. The value of the aera capacity (F) appeared to be $9.1\;mg/cm^2-day$ and the mean value of the saturation constant $(K_g)$ appeared to be 53.5 mg/l in the REMSMAs process. Also, the substrate removal .ate of the REMSMAS process was higher than that of the normal activated sludge process when this system was operated in steady-state condition. However, the rate was reduced as the critical operating day was approached.

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Ferric Chloride Addition Enhances Performance of Bioelectrochemical Anaerobic Digestion of Sewage Sludge at Ambient Temperature (제2철 이온을 이용한 상온조건에서 하수슬러지의 생물전기화학 혐기성소화 성능향상)

  • Feng, Qing;Song, Young-Chae;Jang, Seong-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.11
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    • pp.618-626
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    • 2016
  • The influence of ferric ion ($Fe^{+3}$) on bioelectrochemical anaerobic digestion for sewage sludge was explored at ambient temperature ($25^{\circ}C$). Before the addition of ferric ion, the removal of volatile solids (VS) was 65.9% and the specific methane production rate was 370 mL/L/d. After the addition of ferric ion (200 ppm) to feed sludge, the bioelectrochemical anaerobic digester was more stable in the state variables including pH, alkalinity, COD and VFAs, and the VS removal and specific methane production rate were increased to 69.8% and 396 mL/L/d, respectively. However, the methane content in biogas was slightly reduced by the addition of ferric ion, indicating that the activity of planktonic anaerobic bacteria (PAB) was more improved after the addition of ferric ion. The dominances of syntrophic bacteria (Cloacamonas) and hyrolytic bacteria (Saprospiraceae, Ottowia pentelensis) in the PAB were increased by the addition of ferric ion. The addition of ferric ion improved the performance of bioelectrochemical anaerobic digestion for sewage sludge at ambient temperature.

Effect of H2O2 Injection and Temperature Changing on the Organic Carbon Fraction in Chromatogram Dissolved Organic Carbon (CDOC) from Thermal Pretreatment (H2O2 주입과 온도변화가 열적 전처리 후 발생 슬러리의 CDOC 유기탄소분율에 미치는 영향평가)

  • Kim, Hee-Joong;Kim, Tae-Kyoung;Kim, Youn-Kwon
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.3
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    • pp.110-116
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    • 2016
  • Biogas yields point of view, the possibility of reusing excess sludge treated by thermal pretreatment for the purpose of improving the efficiency of the anaerobic digestion process has been investigated in recent year. Thermal pretreatment technology was considered as a pretreatment technique to improve excess sludge properties because of the solubilization of particulate organics. As a view point of sludge reduction and recycle, however, many researchers focused on the ability of particulate hydrolysis and COD solubilization under a high temperature, and few reports have addressed on the physical/chemical characteristics changing. This research was performed to evaluate the effects of a various temperature and chemical additives on carbon formation and fractionation in treated slurry from thermal pretreatment. Based on the results, it was revealed that oxidants injection and temperature changing have significantly caused the change of carbon fractions in slurry from thermal pretreament. Especially, it was considered that the efficiencies of particle hydrolysis increased with the increase of the reaction temperature. Low molecular weight(Mw < 350 g/mol) organic carbon formation increased with the increase of oxidants injection. It was expected that results of this research will provide an overview of the characteristics of thermal pretreatement for excess sludge reduction and recycle.

Studies on Removal of Water Pollutants by Aquatic Plants - I. Removal of Organic Matter by Water Hyacinth and Factors Affecting It's Growth (수생식물(水生植物)을 이용(利用)한 수질오염원제거(水質汚染源除去)에 관(關한) 연구(硏究) - 제1보(第1報) 부레옥잠의 유기물(有機物) 제거효과(除去效果) 및 생장(生長)에 미치는 제요인(提要因))

  • Pyon, Jong-Yeong;Lee, Kyu-Seung;Lee, Jong-Sik
    • Korean Journal of Weed Science
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    • v.5 no.2
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    • pp.143-148
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    • 1985
  • Water hyacinth, unused and tropical plant was examined in order to know the feasibility of application for purification of municipal drainage and industrial wastewater. This plant was effective to remove the COD from wastewater, although its removal ability was dependent on the organic sources. The effects of pH, NaCl concentration, water temperature and shading condition on the growth of water hyacinth were investigated. The optimum ranges of pH were weak acid- neutral, of water temperature were 17-$21^{\circ}C$, and unshading condition was better. The rapid propagation of this plant was also observed during hot summer season.

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Pulp Bleaching Effect and Ionization Rate of Chlorine Dioxide by Additive and Various pH Conditions (II) (pH와 첨가제에 의한 이산화염소의 분해율 및 펄프 표백효과(2)-첨가제가 chlorate 생성량의 감소와 펄프 표백 효과에 미치는 영향)

  • 윤병호;왕립군
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.49-57
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    • 1999
  • In CLO2 delignification and bleaching process, formation of chlorate corresponds to a loss of 20-36% of the original CKO2 charge. Because chlorate is inactive and harmful to environmental, it will be of benefit to find methods that can reduce the formation of chlorate during chlorine dioxide bleaching. Chlorate is mainly formed by the reaction HCIO +ClO2 $\longrightarrow$H+ + Cl_ +ClO3-2 On the other hand, AOX in chlorine dioxide bleacing is formed also due to the in-situ produced hypochlorous acid. THus both AOX and chlorate could be reduced by addition of hypochlorous acid. Some paper son the reduction of AOX by additives appeared , but systematic data on chlorate reduction as well as pulp and effluent properties are not available. THus this paper of focused on the effects on the reduction of chlorate and chlorine dioxide bleachability. The additives, fulfamic a챵, AMSO, hydrogen peroxide, oxalic acid were found to eliminate chlorine selectively in chlorine and chlorine dioxide mixture.However, when they were added to bleaching process, sulfamic acid and DMSO showed significant reduction of chlorate formation but hydrogen peroxide and oxalic aicd did not, and significant amount ofhydrogen peroxide was found resided in the bleaching effluent , In addition, sulfamic acid and DMSO decreased the bleaching end ph values while hydrogen peroxide and oxalic acid did not, which also indicated that hydrogen peroxide and oxalic acid were ineffective. The difference might be ascribed to the competitives of hypochlorous acid with lignin, chlorite (CKO2) and additives. Sulfamic acid and DMSO showed better pulpbrightness development but less alkaline extraction efficiency than hydrogen peroxide , oxalic acid and control, which means that insitu hypochlorous acid contributes to the formation of new chromophore structures that can be easily eliminated by alkaline extraction. DMSO decreased the delignification ability of chlorine dioxide due to the elimination of hypochlorous acid, but sfulfamic acid did to because the chlroinated sulfamic acid had stable bleachability. In addition, sulfamic acid, and SMSO shwed decreased color and COD of bleaching effluents, hydrogen peroxide decreased effluent color but not COD content, and oxalic acid had no statistically significant effects. No significant decreases of pulp viocosity were found except for hydrogen peroxide. Based on our results , we suggest that the effectiveness of hydrogen peroxide on the reduction of AOX in literature might be explained by other mechanisms not due to the elimination of hypochlorous acid , but to the direct decomposition of AOX by hydrogen peroxide.

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A Study on the Environmental Factors Affecting the Population of the Wintering Waterbirds in Wonju-Stream (원주천의 월동수조류 군집에 영향을 미치는 환경요인 연구)

  • Park, Yung Wook;Lee, Hwang Goo;Won, Kyung Ho;Choi, Jun Kil
    • Journal of Wetlands Research
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    • v.19 no.4
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    • pp.409-422
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    • 2017
  • In order to understand the environmental factors affecting the waterbird community in winter, we divided the watershed into 6 sections and investigated the size of the stream, the water quality, benthic invertebrates, and fish including birds. The influences on the community of water birds in Wonju stream were river structure, temperature and water quality. Among the structure of the river, the factors affecting the waterbird community in winter were the width of the stream and the width of the flowing water. The wider the width, the more species and the number of the winter waterbirds were. As the width of river water was wide, the smaller the width and width of the waterway, the fewer the population. The temperature changes of the wintering season affected the community of water birds because it led to freezing of rivers. The sections that were not frozen showed a significant increase and decrease in the temperature drop and rise. The values of pH, water temperature, COD, BOD, TN, TP and total E. coli increased with the increase of the downstream waterbirds population in the water quality survey. The water quality of S6 was affected by the downstream sewage treatment plant The number of wintering waterbirds was also highest. The effluent from the sewage treatment plant seems to have a considerable influence on the water quality. The increase of several items such as TN promotes the nutrition of the river, which leads to the accumulation of organic matter and the proliferation of aquatic organisms. This may be the cause of the increase in winter waterbirds as a food source. The benthic macroinvertebrate communities and fish communities did not show any correlation with the wintering water-birds communities.

Environmental Factors Related to Mass Moralities of Young Red Seabream (Pagrus major) in the Artificial Seed Production (일본산 참돔, Pagrus major 종묘생산과정중 사육수 변화로 인한 대량폐사)

  • 최상덕;정관식;김호진;김성수
    • Journal of Aquaculture
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    • v.11 no.2
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    • pp.203-212
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    • 1998
  • As seed production program is growing prosperously in various fishes in southern Korea, disease problems in larval and juvenile stages have emerged as a new research object. The following results were obtained from investigation about environmental factors related to mass mortalities of young Kinki red seabream, Pagrus major in process of artificial seedling production. Total length of red seabream larvae hatched was 2.93mm, and became 18.83~20.12mm at day 40. The first noticeable mortality of red seabream larvae (7.98~9.37mm) occurred in 25~30 day-old fish with the survival rates of 59.8~60.3%. Thereafter the mortality of larvae decreased, survival rate was 20.5~25.45% in day 40. After 20~30 days, the quality of pond water was bellow II class. During the experimental period COD, $PO_4$-P, $NO_2$-N, $NO_3$-N and $NH_$-N increased up to 3, 7, 34, 6 and 8 times, respectively, compared to initial ones. The number of viable bacteria in pond water and seabream larvae were $6.3{\times}10^6$~$2.3{\times}10^7$ cfu/ml, 4.3~$7.4{\times}10^6$ cfu/g in day 25, respectively. Among the isolated bacteria from the diseased red seabream in day 25, Vibrio spp. was considered to be the causative organism. External symptoms of this disease were floated, spined near the surface and inflated abdomen. When the isolated strain of the Vibrio was bathed to seabream larvae, $LD_50$ of seabream larvae was over $10^6$ cfu/ml of Vibrio spp.

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Design Parameters of Sequencing Batch Reactor treating ship sewage (연속 회분식 공정(SBR)을 이용한 선박 오 ${\cdot}$ 폐수처리 설계인자 도출)

  • Park, Sang-Ho;Kim, In-Soo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.29 no.1
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    • pp.293-298
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    • 2005
  • Lab scale experimental study was carried out for SBR process, to investigate the effects of influent ship sewage organic compound removal and Bacillus sp. state on design parameters. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than 95% of chemical oxygen demand(COD) were removed. In addition, about 97% of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged 93%. The performance load of SBR process was shown to be 0.095kg ${\cdot}$ TOC/$m^{3}$ ${\cdot}$ day. The pH was decreased from 8.1 to 7.0 within 30 min and increased to 7.3 at the end of anoxic stage, and these phenomena were explained. The sluge produced in the SBR process is characterized by low generation rate (about 0.36kg ${\cdot}$ MLSS/kg ${\cdot}$ TOC) and excellent settleability. The number of Bacillus sp. in the SBR was 24.2%, indicating that Bacillus sp. was a predominant species in the reactor.

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A Study on the Development of a Treatment Process for Phenolic Wastewaters (Phenol 폐수(廢水)의 처리공법(處理工法) 개발(開發)에 관한 연구(硏究))

  • Cho, Kwang Myung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.2 no.1
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    • pp.19-31
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    • 1982
  • The purpose of the research is to investigate the applicability of the filter activated sludge process for the treatment of toxic phenolic wastewaters. The experiment for the research was carried out by continuously feeding synthetic phenol wastewater for four periods, and the results show that a synthetic fiber filter is an adequate material for filter activated sludge process when taking consideration of durability, SS removal efficiency and wastewater permeability. The permeability of the filter sharply decreases when the temperature of the reactor is below $10{\sim}15^{\circ}C$ for a long period. In filter activated sludge process, even under high volumetric loading conditions, high phenol removal efficiencies can be attained due to the high microbial sludge concentration in the reactor and consequently low F/M ratio. In this research, the effluent phenol concentration were checked to be below $0.1mg/{\ell}$ at the influent phenol concentrations of $63{\sim}468mg/{\ell}$. During the research very low microbial yield coefficients, 0.035~0.160 kg SS/kg COD removed, were observed and the temperature coefficient for aerobic sludge digestion was measured to be 1.021.

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Assessing Effects of Farming Activities on the Water Quality in a Small Agricultural Watershed (충남 고성천 유역의 하천 수질 평가를 이용한 유역단위 질소와 인 수지 분석)

  • Kim, Min-Kyeong;Roh, Kee-An;Park, Seong-Jin;Choi, Chul-Mann;Ko, Byong-Gu;Yun, Sun-Gang;Lee, Jong-Sik
    • Korean Journal of Environmental Agriculture
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    • v.28 no.1
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    • pp.32-37
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    • 2009
  • This study was conducted to assess the impact of agricultural land use on the water quality in mountain village farmlands. Two soil types, paddy and upland soil were analysed for their chemical properties. Although, pH and organic matter contents were not significantly different to each other, concentrations of available P and exchangeable K and Ca were much higher in upland soil compared with those in paddy soil. The results of water quality analysis indicated that, in Goseong-cheon watershed, the nutrients contents were much higher in downstream area than in upstream area. Particularly, the elevation of $COD_{Mn}$ and T-P were significant during rainy season. When paddy fields coexist with upland fields, SS, T-N, and T-P concentrations in paddy fields were lower than those of upland fields. This may indicate that paddy fields possess an water-purifying ability by absorbing nutrients. This effect may reduce excessive nutrients discharged into the neighboring streams which may cause eutrophication problem. The difference between inflow and outflow of nitrogen and phosphorus during the cultivation period were measured as -98.9 kg $ha^{-1}$ and -29.7 kg $ha^{-1}$, which means that nutrient outflow was higher than inflow. This may suggest that much nutrient was discharged during the crop harvest period.