• Title/Summary/Keyword: COD(chemical oxygen demand)

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Long-term Variation and Characteristics of Water Quality in the Garolim Coastal Areas of Yellow Sea, Korea (가로림연안 수질환경의 특성과 장기변동)

  • Park, Soung-Yun;Kim, Hyung-Chul;Kim, Pyoung-Joong;Park, Gyung-Soo;Ko, Joen-Young;Jeon, Sang-Baek;Lee, Seung-Min;Park, Jong-Soo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.4
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    • pp.315-328
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    • 2009
  • Long-term trends and distribution patterns of water quality were investigated in the Garolim coastal areas of Yellow Sea, Korea from 1998 to 2007. Water samples were collected at 3 stations and physicochemical parameters were analyzed including water temperature, salinity, suspended solids(SS), chemical oxygen demand(COD), dissolved oxygen(DO) and nutrients. Spatial distribution patterns were not clear among stations but the seasonal variations were distinct except pH and ammonia. The trend analysis by principal component analysis(PCA) during twenty years revealed the significant variations in water quality in the study area. Annual water qualities were clearly classified into 4 clusters by PCA; year cluster 1997, 1998 and 2000-2002, 1999 and 2003-2006/2008. By this multi-variate analysis the annual trends were summarized as follows; In recent years, salinity increased, whereas dissolved inorganic nitrogen, nitrate nitrogen and COD decreased and water quality generally continued to be in good condition in Gsrolim coastal areas without inflow of freshwater from land. Garolim coastal areas are required to be conserved continuously as important coastal areas for fisheries.

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A Review on Emission and Mitigation of N2O in Biological Wastewater Treatment (생물학적 하폐수처리과정에서 N2O 배출 및 저감에 관한 고찰)

  • Cho, Kyung-Suk
    • Microbiology and Biotechnology Letters
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    • v.46 no.3
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    • pp.181-193
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    • 2018
  • Nitrous oxide ($N_2O$) is a potent greenhouse gas as well as an ozone-depleting substance. $N_2O$ is emitted during the biological nitrogen removal process in wastewater treatment systems (WTSs), and has significant environmental impacts. In this study, $N_2O$ emission in WTSs was comprehensively reviewed to better understand the effects of key parameters on $N_2O$ emission and obtain useful guidelines for $N_2O$ mitigation strategies in WTSs. Three biological pathways leading to $N_2O$ emission are hydroxylamine oxidation, nitrifier denitrification, and heterotrohic denitrification. Measurements at lab-, pilot- and full-scale WTSs have shown large variations in $N_2O$ emission (0-95% of N-loaded) during wastewater treatment. In the full-scale WTSs (0-14.6% $N_2O$ of N-loaded), the average and median values were 1.95% and 0.2% of N-loaded, respectively. Dissolved oxygen, nitrite concentrations, and chemical oxygen demand (COD)/N ratio are the most important parameters leading to $N_2O$ emission. A variety of operational strategies have been suggested to minimize $N_2O$ emission from WTSs. A new $N_2O$ mitigation strategy involving the introduction of microorganisms with high $N_2O$ reductase activity or oxygenic denitrification ability has been proposed as an alternative canonical denitrification.

Contents of Inorganic Elements in Shellfish and Geochemical Characteristics of Surface sediments on the West Coast of Korea (서해연안 패류의 성분원소 함량 및 퇴적물의 지화학적 특성)

  • Choi, Yoon Seok;Park, Kwang Jae;Song, Jae Hee;Yoon, Sang Pil;Chung, Sang Ok;An, Kyoung Ho
    • The Korean Journal of Malacology
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    • v.28 no.3
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    • pp.225-232
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    • 2012
  • In order to evaluate the relationship of between the contents of inorganic elements in shellfish and surface sediments, we measured the concentration of inorganic elements (As, Ca, Cd, Cr, Fe, Hg, Li, Mn, Ni, P, Pb, Zn) in various shellfish and surface sediments of research area. The enrichment factor (EF) and the index of accumulation rate (Igeo) of the metals showed that the research areas can be classified as moderately polluted, or unpolluted. And also we measured the geochemical characteristics of surface sediments(grain size, chemical oxygen demand (COD), ignition loss (IL) and acid volatile sulfide (AVS). The grain sizes for research areas of surface sediment were similar the ratio of silt and clay in comparison with other sites. The COD and IL in surface sediment ranged from 5.41 to 14.06 mg/g. d.w. (mean $8.78{\pm}3.16$ mg/g d.w.) and from 0.92 to 3.17% (mean $2.08{\pm}0.86%$), respectively. Siginificant differences in metal concentrations also were determinated in the shellfish tissue among the different sites. However, except for metals(Mn, Zn), which showed some elevation of concentrations, the variations in the shellfish tissue were not related to variations in the sediment.

Environmental Characteristics and Distributions of Marine Bacteria in the Surface Sediments of Kamak Bay in Winter and Summer (동 . 하계 가막만 표층 퇴적물의 환경특성과 해양미생물의 분포)

  • Lee, Dae-Sung;Kim, Yun-Sook;Jeong, Seong-Yun;Kang, Chang-Keun;Lee, Won-Jae
    • Journal of Environmental Science International
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    • v.17 no.7
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    • pp.755-765
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    • 2008
  • To investigate correlation between the distribution of marine bacteria and environmental characteristics in the surface sediments of Kamak Bay, chemical oxygen demand(COD), acid volatile sulfide(AVS), ignition loss(IL), total organic carbon(TOC), and total organic nitrogen(TON) were measured and analyzed at 7 stations in winter and summer. In winter, COD and AVS ranged from 13.45 mg/g to 30.06 mg/g(average: 23.58 mg/g) and from 0.03 mg/g to 1.04 mg/g(average: 0.63 mg/g), respectively. IL, TOC, and TON ranged from 8.03% to 11.41%(average: 9.41%), from 1.17% to 2.10%(average: 1.62%), and from 0.09% to 0.18%(average 0.15%), respectively. In summer, COD, AVS, IL, TOC, and TON ranged from 14.06 mg/g to 32.19 mg/g(average: 24.71 mg/g), from 0.03 mg/g to 1.11 mg/g(average: 0.66 mg/g), from 9.00% to 12.15%(average: 10.96%), from 1.27% to 2.12%(average 1.77%), and from 0.12% to 0.19%(average: 0.16%), respectively. These values were relatively higher than those in winter. Kamak Bay had high C/N ratio that might be resulted from the input of terrestrial sewage and industrial wastewater. The number of marine viable bacteria was $8.9{\times}10^4\;cfu/g$ in winter and $9.7{\times}10^5\;cfu/g$ in summer. The most abundant species were Pseudomonas spp., Flavobacterium spp., and Vibrio spp, in the surface sediments of Kamak Bay. It was found that the concentration of organic matters and viable bacterial cells in the inner part were relatively higher than those in the outer of Kamak Bay. The distribution of viable bacterial cells was closely influenced by environmental factors.

Comparison of the Methods to Analyze Freshwater Sediments (담수 퇴적물의 분석법간 비교 분석)

  • Yoon, Byeng-Seok;Kim, Eun-Mi;Kim, Hak-Chul;Lee, Jae-Hee;Jung, Sang-Gi;Lee, Sang-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1207-1212
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    • 2006
  • In this study, Chemical Oxygen Demand(COD) which is the measure of organic substances, Total nitrogen(T-N), Total phosphorous(T-P), Fe and Mn were analyzed in the sediments of dam reservoir. The purpose of this study were to understand the relevances among the analytical methods adopted and the applicabilities of those methods. For the determination of COD, Standard Method for the Examination of Marine Environment(SMEME) and Standard Method for the Examination of Sanitary(SMES) was used. Both method had wide dynamic range and the deviations of the values obtained by two methods were small because $KMnO_4$ method closely reflected BOD and organic substances. For the determination of T-N and T-P, Standard Method for the Examination of Food(SMEF) and Standard Method for the Examination of Sanitary(SMES) were used. Two methods for T-N were both the acid-base titration but SMES gave less T-N values than SMEF because of the differences in digestion and distillation steps. Two methods for T-P gave the comparable values after acid digestion of $HNO_3$ and $HClO_4$. The determination of heavy metals as a Fe, Mn was mainly divided to the leaching method and acid digestion method. The values obtained by leaching method were less than those by digestion method. It is thought that the condition of acid digestion was more severe than that of leaching method.

Flocculating Activity and Dehydration Efficiency of Biopolymer Flocculant Biopol32 in Industrial Wastewater Treatment (생물고분자응집제 Biopol32의 산업폐수에 대한 응집활성 및 탈수효과)

  • Lee, Myoung Eun;Oh, Nara;Suh, Hyun-Hyo
    • Journal of Life Science
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    • v.29 no.3
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    • pp.362-368
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    • 2019
  • For the practical application and development of biopolymer flocculant Biopol32 produced by Pseudomonas sp. GP32, its flocculation effect on wastewater from food processing, slaughter houses, and the dyeing industry was investigated. In the food processing wastewater, Biopol32 led to a chemical oxygen demand (COD) reduction rate of 70% and a suspended solid (SS) removal rate of 49% at pH 6.0. In the slaughter house wastewater at pH 4.0, a COD reduction rate of 61% and SS removal rate of 91% were observed, and in the dyeing wastewater, the rates were 72% and 92%, respectively, at pH 5.0. The size of floc formed during the flocculation process was 10 mm at a final concentration of 20 ppm, and the dehydration efficiency was 62%. In both the bioflocculant Biopol32 group and a PAA synthetic flocculant group, optimal flocculant concentration that yielded the best overall dehydration efficiency was 20 ppm, and, at this concentration, the shortest filtration time to reach the natural critical moisture content of 78.1% was attained.

Evaluation of Treatment Efficiencies of Pollutants under Different Pollutant Fractions in Activated Sludge-Constructed Wetland System for Treating Piggery Wastewater (활성슬러지-인공습지 공법에 의한 돈사폐수처리시스템에서 오염물질의 분획별 정화효율 평가)

  • Kim, Seong-Heon;Seo, Dong-Cheol;Park, Jong-Hwan;Lee, Choong-Heon;Choi, Jeong-Ho;Kim, Hong-Chul;Ha, Yeong-Rae;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.31 no.4
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    • pp.344-350
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    • 2012
  • BACKGROUND: To design and develop a constructed wetland for effective livestock wastewater treatment, it is necessary to understand the removal mechanisms of various types of pollutants in constructed wetlands. The objective of this study was to evaluate the treatment efficiency of pollutants under different types of fraction in constructed wetland system for treating piggery wastewater. METHODS AND RESULTS: The piggery wastewater treatment plant that consisted of activated sludge tank, aerobic and anaerobic beds was constructed. The concentration of COD(Chemical oxygen demand) in effluent by fraction was 71.5 mg/L for soluble COD, 142 mg/L insoluble COD. The concentration of SS(Suspended solid) in effluent by existing form was 102 mg/L for volatile SS, 15.5 mg/L for fixed SS. The concentration of T-N(Total nitrogen) and T-P(Total phosphorus) in effluent by existing form were 12.8 mg/L and 3.05 mg/L for dissolved form, 35.0 mg/L and 1.93 mg/L for suspended form. The removal efficiencies of COD, SS, T-N and T-P in hot season(summer and autumn) were higher than those in cold season(spring and winter). The removal efficiencies of COD, SS, T-N and T-P in effluent were 98.0, 99.0, 98.2 and 99.2% for all seasons, respectively. CONCLUSION(S): The results indicated that removal types of pollutants were insoluble COD(ICOD), volatile SS(VSS), dissolved T-N(DTN) and dissolved T-P(DTP) in constructed wetlands for treating piggery wastewater.

Analysis of Relationship Between Water Quality Parameters in Agricultural Irrigation Reservoirs and Land Uses of Associated Watersheds (농업용저수지 유역의 토지이용과 수질항목 간의 상관관계 분석)

  • Yoon, Chun-Gyeong;Lee, Sae-Bom;Jung, Kwang-Wook;Han, Jung-Yoon
    • Korean Journal of Ecology and Environment
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    • v.40 no.1
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    • pp.31-39
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    • 2007
  • Monitoring data of 48 agricultural irrigation reservoirs from 1999 to 2004 was analyzed for water quality characteristics including biochemical oxygen demand $(BOD_5)$, chemical oxygen demand (COD), total nitrogen (TN), total phosphorus (TP), and chl-${\alpha}$. Land uses of the watersheds associated with these reservoirs were determined for residential, forest, upland, paddy and miscellaneous, and regressed against water quality characteristics. Correlation analysis showed that forest land use was negatively correlated with all the water quality characteristics implying it's beneficial effects in water quality perspectives. Other land uses including residential, upland, and paddy generally illustrated positive correlation with water quality characteristics, which indicates most human activities of the watershed could degrade water quality of the receiving water bodies. Paddy land use partially contributed to the water quality degradation in contrast to the previous studies. It might be attributed to the relatively clean water quality of the study area, where even slight pollutant loading could degrade sensitively water quality. Further investigation is recommended for the effect of proximity as well as land use portions on the water quality of receiving water body.

Investigation of Microbiological and Physiochemical Quality for Irrigation Water used in Napa Cabbage Cultivation (배추 재배에 이용되는 농업용수의 미생물 오염도 조사 및 이화학성분 분석)

  • Yun, Bohyun;Kim, Min Kyung;Ryu, Jin Hee;Kim, Won-Il;Park, Byeong-Yong;Kim, Hyun-Ju;Lee, Seung-Don;Kim, Se-Ri
    • Journal of Food Hygiene and Safety
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    • v.32 no.5
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    • pp.396-403
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    • 2017
  • The purpose of this study was to investigate water quality for irrigation water used in Napa cabbage cultivation. The water samples were analyzed for physiochemical and microbiological quality for a total of 111 samples including surface water (n = 75) and groundwater (n = 36) collected from five different regions where Napa cabbage is massively grown. As a conclusion, the levels of fecal indicators for surface water were higher than those for groundwater. The numbers of coliform from surface water and groundwater were 1.96-4.96 and 0-3.98 log MPN/100 mL, respectively. Enterococci were detected in 95% (72/75) of surface water samples and 22% (8/36) of groundwater samples. Besides, 97% (73/75) of surface water samples were observed being contaminated with Escherichia coli, and 22% (8/36) of groundwater sample was positive for E. coli. In the case of surface water, E. coli and coliform correlate to T-P, and enterococci showed relevance to the suspended solid (SS) and biochemical oxygen demand (BOD). In groundwater, fecal indicator bacteria showed relevance to the SS and chemical oxygen demand (COD). These results could be provided as fundamental date for establishing microbial standard of water used in leafy vegetables cultivation.

A Study of Antimicrobial Resistance in Escherichia coli and the Distribution of Indicator Microorganisms in Asan City (아산시 지표미생물의 분포와 Escherichia coli의 항생제 내성에 관한 연구)

  • Lee, Geun-Yeol;Kim, Keun-Ha;Kwon, Mun-Ju;Kwon, Hyuk-Ku;Kim, Yeon-Hee;Lee, Jang-Hoon
    • Journal of Environmental Health Sciences
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    • v.36 no.3
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    • pp.229-235
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    • 2010
  • Efforts to evaluate water pollution using indicator microorganisms have been underway for decades, and driven by research on water purity control applications, water quality criteria are growing more and more strict. Furthermore, recent reports indicate that high concentrations of antibiotics are not absorbed, and are present in excrement from animals and humans dosed with unnecessarily high levels of antibiotics. This has emerged as very important issue from the standpoint of being an ecological and health hazard. In this study, water pollution was analyzed through physicochemical and microbiological means, and antibiotic resistance in indicator microorganisms was assessed. In physicochemical analysis, biochemical oxygen demand (BOD)$_5$ and chemical oxygen demand (COD)$_{Mn}$ evaluation showed that pollution by organisms was highest at the G1 location with a high human population, and the DP location which has many livestock-containing households. The indicator organism levels at the G1 location were: Total Coliforms (1205 colony forming units (CFU)/100 ml), Fecal Coliforms (270 CFU/100 ml), Escherichia coli (253 CFU/100 ml) and Fecal Streptococci (210 CFU/100 ml), while for the DP location levels were: Total Coliforms (1480 CFU/100 ml), Fecal Coliforms (438 CFU/100 ml), E. coli (560 CFU/100 ml), and Fecal Streptococci (348 CFU/100 ml). Levels of fecal indicator microorganisms such as Fecal Coliforms, E. coli and Fecal Streptococci were high at all locations in the fall (the period after the rainy season), and the yearly distribution was similar between these organisms. If the number of livestock-containing households was high, almost all strains of E. coli (as distinct from the other indicator organisms) showed resistance to antibiotics, with the degree of resistance varying between areas. E. coli strains from the OY area in particular, which has a high population density, showed strong resistance to AM10 and Va30. While strong antibiotic resistance was observed overall at the DP and OY locations, no resistance was observed at the EB location.