• Title/Summary/Keyword: COD(chemical oxygen demand)

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Anaerobic Digestion of Pig Manure and Night Soil Mixed Waste in a Normal Temperature (I) (常溫에서 豚 . 人糞混合廢棄物의 嫌氣性處理(I))

  • Kim, Nam-Cheon;Min, Dal-Ki
    • Journal of Environmental Health Sciences
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    • v.14 no.1
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    • pp.63-71
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    • 1988
  • This study is an experimental research on the anaerobic digestion of pig manure and night soil mixed waste at room temperature (25$\circ$C), and the results are shown below: 1. The steady-state condition based on gas production as digestion temperature dropped to 25$\circ$C from 35$\circ$C was achieved at around 28, 47, 56, 64 days respectively when its hydraulic retention time(HRT) are 10, 20, 30, 40 days. 2, Alkalinity and volatile acid(VA) was increased as increasing the organic loading. 3. Removal efficiency of chemical oxygen demand(COD) and biochemical oxygen demand (BOD) was improved as longer HRT, and generally COD value is lower and BOD value is higher relatively. 4. Overall treatment efficiencies of mixed waste are higher than of pig manure and of night soft. 5. Organic removal efficiency at room temperature (25$\circ$C) is 20-25% lower at medium temperature (35$\circ$C) in a same VS loading condition. 6. Refractory fraction of the infiuent VS and organic removal rate constant(K) estimated at around 37% and 0.107/day respectively.

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Influence of River Discharge Fluctuation and Tributary Mixing on Water Quality of Geum River, Korea (유량변화와 지류유입에 따른 금강의 수질 변화)

  • Shim, Moo Joon;Lee, Soo Hyung
    • Journal of Korean Society on Water Environment
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    • v.31 no.3
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    • pp.313-318
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    • 2015
  • To study the influence of changes in river discharge on water quality of the main stem of the Geum River, we investigated variation of inflow load from tributaries with river discharge. We also studied the mixing behavior of pollutants during mixing of waters of the main stem and Gap Stream. For this study, we collected water quality data such as suspended solids (SS), biochemical oxygen demand (BOD), chemical oxygen demand (COD), total organic carbon (TOC), total nitrogen (TN) and total phosphorus (TP) representing pre-monsoon, monsoon, and post-monsoon events of 2013 from a website of Water Information System. Based on inflow load, the Gap and Miho streams may be ones of tributaries which may largely influence water quality of main stem in upper river region. The Suksung and Nonsan Streams seemed to further affect water quality downstream. Results of modified EMMA indicated SS and TP may have another source(besides Gap Stream) at pre-monsoon, monsoon, and post-monsoon period. In contrast, TN and organic matter (BOD, COD, TOC) were conservative at pre-monsoon and post-monsoon. However, when river discharge increased, these pollutants may also came from unspecified non-point sources. Therefore, we need to attempt to find non-point sources for the pollutants in the main channel of upper Geum River region.

Efficiency of Nutrient Removal and Biomass Productivity in The Wastewater by Microalgae Membrane Bioreactor Process (Microalgae Membrane Bioreactor (MMBR) 공정에서 하수의 영양염류 제거와 바이오매스 생산성 효율)

  • Choi, Hee-Jeong
    • Journal of Korean Society on Water Environment
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    • v.30 no.4
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    • pp.386-393
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    • 2014
  • The aim of this study was to investigate the nutrient removal and biomass productivity in the wastewater using MMBR (Microalgae Membrane Bioreactor). MMBR process was combined OPPBR (Optical Panel Photobioreactor) and MBR (Membrane bioreactor). The OPPBR and MBR were operated 3 days and 9h HRT (Hydraulic retention time), respectively, using microalgae as Chlorella vulgaris. The obtained result indicated that the biomass productivity of 0.498 g/L/d with light transmittance of 92% at a 305 mm depth in the OPPBR was achieved. The total consumption of BOD (Biochemical Oxygen Demand) and COD (Chemical Oxygen Demand) in the MMBR were found to be 97.56% and 96.06%, respectively. Additionally, the removal of TN, $NO_3-N$, TP and $PO_4-P$ were 94.94%, 91.04%, 99.54% and 93.06% in MMBR, respectively. These results indicated that the MMBR process was highly effective for COD, BOD and nutrient removal when compared to the separate OPPBR or MBR process. The MMBR process was effective for nutrient removal and biomass productivity and can be applied to treat wastewater in sewage treatment plant.

Analysis of Microbial Community Structure in Biological Wastewater Treatment Process of Mixed Wastewater Treatment Facility using Environmental·Ecological Technique (환경·생태학적 기법을 이용한 혼합폐수 처리장의 생물학적 처리공정 내의 미생물 군집 특성 분석)

  • Son, Hyeng-Sik;Lee, Sang-Joon;Son, Hee-Jong
    • KSBB Journal
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    • v.28 no.2
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    • pp.80-85
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    • 2013
  • The bacterial community structure in a biological reactor fed influent from a wastewater treatment system was investigated by denaturing gradient gel electrophoresis (DGGE) and in situ hybridization. Sludges were collected from three biological reactors (aerobic, oxic, and anoxic tanks) at the M wastewater treatment facility (WTF). The influent of the MWTF consisted of mixed tannery wastewater (40~65%) and seafood wastewater (35~60%). The treatment processes resulted in a removal efficiency for BOD (biochemical oxygen demand) and COD (chemical oxygen demand) of 83.6~98.2% and 72.8~84.6%, respectively for tannery wastewater than for seafood wastewater resulted in greater survival of biomass in the biological reactors and a higher removal of BOD, COD, and T-N of about 8~18%. In contrast, addition of greater amounts of seafood wastewater decreased the amount of biomass in the bioreactors due to the increasing concentration of chromium from that wastewater and it also. The dominant bacterial species during the high seafood wastewater input period were Burkholderia cepacia (JX901049) and an uncultured bacterium (JF247555), while Pseudomonas geniculata (HQ256559) was dominant during the high tannery wastewater input period. Flavobacteriumsp. BF.107 (FM173271) and Hyphomicrobium zavarzinii (Y14306) were dominant under anoxic conditions.

Influence of mixed liquor suspended solids on the removal efficiency of a hybrid membrane bioreactor

  • Palmarin, Matthew J.;Young, Stephanie
    • Membrane and Water Treatment
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    • v.7 no.1
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    • pp.11-22
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    • 2016
  • The characterization of treatment performance with respect to mixed liquor suspended solids (MLSS) concentration enables greater control over system performance and contaminant removal efficiency. Hybrid membrane bioreactors (HMBRs) have yet to be well characterized in this regard, particularly in the context of greywater treatment. The aim of this study, therefore, was to determine the optimal MLSS concentration for a decentralized HMBR greywater reclamation system under typical loading conditions. Treatment performance was measured at MLSS concentrations ranging from 1000 to 4000 mg/L. The treated effluent was characterized in terms of biochemical oxygen demand ($BOD_5$), chemical oxygen demand (COD), turbidity, ammonia ($NH_3$), total phosphorus (TP), total kjeldahl nitrogen (TKN), and total nitrogen (TN). An MLSS concentration ranging from 3000 to 4000 mg/L yielded optimal results, with $BOD_5$, COD, turbidity, $NH_3$, TP, TKN, and TN removals reaching 99.2%, 97.8%, 99.8%, 99.9%, 97.9%, 95.1%, and 44.8%, respectively. The corresponding food-to-microorganism ratio during these trials was approximately 0.23 to 0.28. Operation at an MLSS concentration of 1000 mg/L resulted in an irrecoverable loss of floc, and contaminant residuals exceeded typical guideline values for reuse in non-potable water applications. Therefore, it is suggested that operation at or below this threshold be avoided.

Kinetics of nitrification and acrylamide biodegradation by Enterobacter aerogenes and mixed culture bacteria in sequencing batch reactor wastewater treatment systems

  • Madmanang, Romsan;Jangkorn, Siriprapha;Charoenpanich, Jittima;Sriwiriyarat, Tongchai
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.309-317
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    • 2019
  • This study evaluated the kinetics of acrylamide (AM) biodegradation by mixed culture bacteria and Enterobacter aerogenes (E. aerogenes) in sequencing batch reactor (SBR) systems with AQUASIM and linear regression. The zero-order, first-order, and Monod kinetic models were used to evaluate the kinetic parameters of both autotrophic and heterotrophic nitrifications and both AM and chemical oxygen demand (COD) removals at different AM concentrations of 100, 200, 300, and 400 mg AM/L. The results revealed that both autotrophic and heterotrophic nitrifications and both AM and COD removals followed the Monod kinetics. High AM loadings resulted in the transformation of Monod kinetics to the first-order reaction for AM and COD removals as the results of the compositions of mixed substrates and the inhibition of the free ammonia nitrogen (FAN). The kinetic parameters indicated that E. aerogenes degraded AM and COD at higher rates than mixed culture bacteria. The FAN from the AM biodegradation increased both heterotrophic and autotrophic nitrification rates at the AM concentrations of 100-300 mg AM/L. At higher AM concentrations, the FAN accumulated in the SBR system inhibited the autotrophic nitrification of mixed culture bacteria. The accumulation of intracellular polyphosphate caused the heterotrophic nitrification of E. aerogenes to follow the first-order approximation.

Evaluation of Drainage by Near Infrared Spectroscopy

  • Takamura, Hitoshi;Miyamoto, Hiroko;Mori, Yoshikuni;Matoba, Teruyoshi
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1271-1271
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    • 2001
  • Water pollutants in drainage mainly consist of organic compounds. Hence, total organic carbon (TOC), chemical oxygen demand (COD), and biochemical oxygen demand (BOD) were generally used as the indices of pollution. However, these values are determined by special analyzer (TOC), titration method (COD), or microbe culture (BOD). Therefore, the development of simple and easy methods for the determination of water pollution is required. The authors reported the evaluation of water pollution by near infrared (NIR) spectroscopy in a model system with food components (Takamura et al. (200) Near Infrared Spectroscopy: Proceedings of 9th International Conference, pp. 503-507). In this study, the relationship between NIR spectra and drainage was investigated in order to develop a method for evaluation of drainage by NIR. Drainage was obtained in Nara Purification Center. The ranges of TOC, COD, and BOD were 0-130, 0-100 and 0-200, respectively. NIR transmittance spectra were recorded on NIR Systems Model 6250 Research Composition Analyzer in the wavelength range of 680-1235 and 1100-2500 nm with a quartz cell (light path: 0.5, 1, 2, 4 and 10mm) at 10-40. Statistical analysis was performed using NSAS program. A partial least squares (PLS) regression analysis was used for calibration. As the result, a good correlation between the raw NIR spectra and OC was obtained in the calibration. The best light path was 10 and 0.5mm in the wavelength range of 680-1235 and 110-2500nm, respectively. In the calibration, correlation coefficients(R) were 096-0.97 in the both range. In the prediction, however, a good correlation (R=0.89-0.96) was obtained only in the range of 6801235 nm, Similar results were obtained in the cases of COD and BOD. These results suggest the possibility that NIR spectroscopy can be used to evaluate drainage.

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Characteristics of Non-point Pollutants from the Road Runoff (1): Water Quality (도로노면 유출수의 비점오염원 배출 특성(1): 기본 수질 항목)

  • Park, Sangwoo;Oh, Jeill;Choi, Younghwa;Seo, Jeongwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.2
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    • pp.225-233
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    • 2007
  • Road runoff water is one of the non-point sources (NPSs) of pollution negatively influencing drinking water source. Numerous road runoff NPS waters have been studied for over the last decade. However, the sources of pollution can be conditional, seasonal, or accidental. Therefore, measurement of pollutant loadings in different site is necessary to estimate the effect of road runoff water. The objective of this study was to examine the quality of road runoff water from a city bridge in Seoul, Korea. This study was conducted for two years to assess annual discharge pollution loads. In this study, key water quality parameters including chemical oxygen demand ($COD_{Cr}$), biochemcial oxygen demand ($BOD_5$), total nitrogen (T-N), total phosphorus (T-P), and suspended solid (SS) were measured at 18 different events. The results showed that typically the pollutant concentrations are higher at the beginning of each event and decrease afterwards. The first 20% of the volume of the runoff from each event is transporting 46% ($COD_{Cr}$), 48% ($BOD_5$), 50% (T-N), 34% (T-P), 30% (SS), respectively. The event mean concentrations (EMCs) were $COD_{Cr}$ (199 mg/L), $BOD_5$ (41.2 mg/L), T-N (7.97 mg/L), T-P (0.42 mg/L) and SS (113 mg/L). Although the results were consistent with the previous study (Barbosa and Hvitved-Jacobsen, 1999), $COD_{Cr}$, $BOD_5$, T-N exhibit a stronger first flush effect compared to the other contaminants.

Simple Material Budget Modeling for the Paldang Reservoir in the Spring Season (팔당호의 춘계 단순물질수지 모델링)

  • Kong, Dongsoo
    • Journal of Korean Society on Water Environment
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    • v.33 no.6
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    • pp.696-714
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    • 2017
  • Simple material budget models were developed to predict the spring season (March ~ May) water quality for a river-type reservoir Paldang, in the Republic of Korea. These models are available at mixed water bodies whose light intensity is negligible at the bottom. The calculated data from the models fit quite well with field data collected for 30 years, from 1988 to 2017. The apparent settling velocity of total phosphorus was estimated to be $110m\;d^{-1}$. The critical hydraulic load that determines the usability of phosphorus for algal production appeared to be about $2.0m\;d^{-1}$. When a hydraulic load was larger than the critical value, the concentrations of chlorophyll ${\alpha}$ ($Chl.{\alpha}$), chemical oxygen demand (COD), and 5-day biochemical oxygen demand BOD in the reservoir water became insensitive to internal algal reactions. The model analysis showed that the allochthonous COD continued to increase while the allochthonous BOD slightly decreased after 1999. The decrease of allochthonous BOD is due to the expansion of sewage and wastewater treatment plants in the watershed. The increase of allochthonous COD seems to result from the increase in anthropogenic non-point sources as well as the increase in the discharge of natural organic matters due to climate change. Organic matter of algal origin continued to increase until the mid-2000s, but recently it has decreased as the phosphorus concentration has decreased. The COD and BOD of algal origin increased from 35 % and 27 % during 1988 ~ 1994 to 43 % and 40 % during 2000 ~ 2010, respectively, and then decreased to 25 % and 28 % during 2011 ~ 2017.

Operational conditions of electrochemical oxidation process for removal of cyanide (CN-) in real plating wastewater

  • Zhao, Xin;Jang, Minsik;Cho, Jin Woo;Lee, Jae Woo
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.217-222
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    • 2020
  • An electrochemical oxidation process was applied to remove cyanide (CN-) from real plating wastewater. CN- removal efficiencies were investigated under various operating factors: current density and electrolyte concentration. Electrolyte concentration positively affected the removal of both CN- and Chemical Oxygen Demand (COD). As the electrolyte concentration increased from 302 to 2,077 mg Cl-/L, removal efficiency of CN- and COD increased from 49.07% to 98.30% and from 23.53% to 49.50%, respectively, at 10 mA/㎠. Current density affected the removal efficiency in a different way. As current density increased at a fixed electrolyte concentration, CN- removal efficiency increased while COD removal efficiency decreased, this is probably due to lowered current efficiency caused by water electrolysis.