• Journal of the Korean Recycled Construction Resources Institute
• /
• v.12 no.1
• /
• pp.8-16
• /
• 2024

Limestone (CaCO₃, calcium carbonate), which is used as a raw material in the portland cement and steel industry, emits CO₂ through decarbonation by high temperatures in the manufacturing process. To reduce CO₂ emissions by the use of raw materials like limestone, it has been proposed to replace limestone with various industrial by-products that contain CaO but less or none of the carbonated minerals, that cause CO₂ emissions. Loss of Ignition (LOI), Thermogravimetric analysis (TG), and Infrared Spectroscopy (IR) are used to quantitative the amount of CO₂ emission by using these industrial by-products, but CO₂ emissions can be either over or underestimated depending on the characteristics of by-product materials. In this study, we estimated CO₂ contents by LOI, TG, IR and DTG(Differential Thermogravimetric analysis) of calcite(CaCO₃) and samples that contain CO₂ in the form of carbonate and whose weight increases by oxidation at high temperatures. The test results showed for CaCO₃ samples, all test methods have a sufficient level of reliability. On the other hand, for the CO₂ content of the sample whose weight increases at high temperature, LOI and TG did not properly estimate the CO₂ content of the sample, and IR tended to overestimate compared to the predicted value, but the estimated result by DTG was close to the predicted valu e. From these resu lts, in the case of samples that contain less than a few percent of CO₂ and whose weight increases during the temperature that carbonate minerals decompose, estimating the CO₂ content using DTG is a more reasonable way than LOI, TG, and IR.

• Journal of Environmental Policy
• /
• v.11 no.2
• /
• pp.55-71
• /
• 2012

This paper attempts to estimate the energy price elasticity of per capita $CO_2$ emissions, which helps to understand the influence of recent energy price increase on the natural reduction of $CO_2$ emissions. For this purpose, this study researched panel data of twenty-nine OECD countries from 1978 to 2009 and adopted estimation models for testing the environmental Kuznets hypothesis. Estimation results show that the 1% increase of energy price index will cause a statistically significant decrease of per capita $CO_2$ emissions by 0.26 ~ 0.31%, which is substantial enough for policy consideration. Also Kuznet curves in estimation models were identifed, the turning points of income lie between 22.2~48.5 thousand US dollars, depending on model specifications.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2012.05a
• /
• pp.49-51
• /
• 2012

This study was conducted as a part of database construction for development of CO₂ assessment system for concrete to assess CO₂ emissions and analyze characteristics of blast furnace slag manufactured in Korea through life cycle assessment method. For this, life cycle CO₂ emissions assessment technique for construction materials was examined. The entire manufacturing process for blast furnace slag was analyzed on blast furnace slag manufacturer in Korea for application of assessment technique. Life cycle CO₂ assessment was performed on blast furnace slag after classifying assessment process into raw material production step, raw material transportation step and construction material manufacture step.

• Proceedings of the KIEE Conference
• /
• 2007.07a
• /
• pp.816-817
• /
• 2007

As UNFCC(United Nations Framework Convention on Climate Change) is enhanced, Korea will perform a CO2 reduction duty. The CO2 reduction duty will effect Korea power system because coal and oil thermal generations emit large CO2 form about 46% of total CO2 emission. Moreover various alternatives should be designed to comply with CO2 reduction duty. In this paper, we analysis resource planning considering CO2 emission constraints and emission trading. And we analysis resource planning under using LP(Linear Programing) and MIP(Mixed Integer Programing).

• Environmental and Resource Economics Review
• /
• v.28 no.2
• /
• pp.231-276
• /
• 2019

This paper analyzed the impact of the penetration of EV(electric vehicle) and FCEV(fuel cell electric vehicle) into the automobile industry, using a static CGE approach. There are contrasting view on the economic impact of EV/FCEV penetration: negative economic impact due to shrunken intermediate inputs versus positive impact because of input saving technical progress. Regarding environment, there is no clear consensus whether EV or FCEV will contribute to the reduction of $CO_2$ emissions in Korea. This study attempts to provide an answer to these questions. By giving shocks to the input coefficients of automobile industries and automobile using sectors, as well as to the final demands for energies. we integrated the Bass diffusion model into the CGE framework, The result suggests that the EV penetration has adverse impact on the $CO_2$ emission while the FCEV penetration has positive impact. On the other hand, both EV and FCEV have positive impacts on GDP. When considering automobile manufacturing sectors only, adverse impacts on $CO_2$ are demonstrated both for EV and FCEV. However, since the size of $CO_2$ increase is small, these results does not alter the overall effects.

• Journal of the Korea Concrete Institute
• /
• v.24 no.5
• /
• pp.597-604
• /
• 2012

The present study assessed the $CO_2$ emissions of concrete according to the type and replacement ratio of supplementary cementitious materials (SCM) and concrete compressive strength using a comprehensive database including 2464 cement concrete specimens and 776 cement concrete mixes with different SCMs. The system studied in $CO_2$ assessment of concrete based on Korean lifecycle inventory was from cradle to pre-construction, which includes consistent materials, transportation and production phases. As the performance efficiency indicators, binder and $CO_2$ intensities were analyzed, and simple equations to evaluate the amount of $CO_2$ emission of concrete were then formulated as a function of concrete compressive strength and the replacement ratio of each SCM. Hence, the proposed equations are expected to be practical and useful as a guideline to determine the type and replacement ratio of SCM and unit content of binder in concrete mix design that can satisfy the target compressive strength and $CO_2$ reduction percentage relative to cement concrete.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.28 no.6
• /
• pp.1063-1069
• /
• 2022

According to domestic air pollutant emission statistics, a considerable amount of air pollutants is generated by ships. Therefore, various policies are being implemented to limit air pollutant emissions from ships and improve the air quality in ports. In addition, international conventions are carried out for the prevention of marine pollution by ships. However, because few studies and experiments have been conducted on the measurement of air pollutants emitted from actually operating ships, this study presented a method and possibility for evaluating air pollutant emissions from a 9,196GT ship actually operating using a portable emission measurement system (PEMS). A difference in emission occurred depending on the RPM and load, and the emission of NO_X was 497-2,060ppm, CO₂ was 1.55-6.9%, and CO was 0.002-0.14%. The emission specified in the shop test provided by the engine manufacturer differed from the actual emission measured. This study proved that the maximum emission of each air pollutant generated in the entire sailing section of the ship was included in the PEMS measurement range, and the possibility of using PEMS for ships within 10,000GT was verified.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.11a
• /
• pp.554-554
• /
• 2009

지구온난화는 범지구적 환경문제로 매우 빠른 속도로 진행되면서 그 심각성을 더해가고 있다. 특히 해수면 상승이나 대형 태풍, 홍수, 가뭄 등의 이상기후가 빈번하게 발생되며 생태계에도 심각한 타격을 주고 있다. 이러한 지구온난화를 유발하는 물질들에 대해 도쿄의정서(Annex A)에 6대 온실가스($CO_2$ (이산화탄소), 메탄($CH_4$), $N_2O$(아산화질소), PFC(불화탄소), HFC(수소화불화탄소), $SF_6$(육불화황))로 정의 하여 규제대상으로 분류하고 있다. $CO_2$를 제외한 Non-$CO_2$ 온실가스들은 배출량이 $CO_2$에 비해 매우 낮지만 GWP(지구온난화지수)가 매우 커 지구온난화에 미치는 영향이 상당하다. 최근 이산화탄소 이외에 지구온난화 문제를 일으키는 온실가스에 대한 많은 관심으로 대상가스의 처리 또는 재활용을 위한 신기술 및 신공정 개발에 박차를 가하고 있다. 온실가스 중 HFCs는 GWP가 1300으로 미량의 배출로도 심각한 기후변화를 일으킬 수 있는 물질로, 우리나라의 경우 1990년 이후 HFCs 배출량 증가율은 연 평균 4.9% ~ 13.8%이다. 국내외 온실가스 처리기술은 대부분 CO2에 대한 연구개발 및 실증화가 지배적이고, non-CO2에 대한 처리기술 개발수준은 미흡할 뿐만 아니라 본 연구 대상인 HFCs 의 경우에는 처리기술 연구개발이 전무하다. 특히 HFCs는 냉매 또는 발포제로 사용되는데 일반적으로 사용 후 특별한 처리과정 없이 대기중으로 배출된다. 본 연구에서는 non-CO2 가스인 HFC-134a 를 대상으로 혼합가스에서 분리 회수를 위해 하이드레이트 기술을 접목시켜 경제적, 친환경적인 기술개발을 목적으로 한다. kinetic 반응장치와 고압반응기 및 magnetic drive system 을 이용하여 stirring speed와 driving force에 따른 HFC-134a 하이드레이트 형성속도의 상관관계를 제시하고자 한다.

• Analytical Science and Technology
• /
• v.26 no.6
• /
• pp.401-406
• /
• 2013

Oxygen($O_2$) consumption and carbon dioxide($CO_2$) excretion of a fertile chicken egg during incubation were measured by a gas mass spectrometer. A closed sample chamber was developed to collect gas samples during the 20 days of artificial incubation of both a fertile and an infertile egg. After leaving an egg in the sample chamber for an hour, using a gas-tight syringe, samples of 2 mL of gas were collected from the closed sample chamber and analyzed using a gas mass spectrometer in 2~4 day intervals. The $O_2$ consumption and $CO_2$ excretion of chicken embryos increased rapidly after 10 days from the starting point of incubation. After 20 days, 23 mL of $O_2$ was consumed and 16 mL of $CO_2$ was excreted per hour. Throughout the whole period of incubation, concentration of $O_2$ decreased 4.3 mol% and $CO_2$ increased only 3.1 mole%, i.e., the mole of consumed $O_2$ and the mole of excreted $CO_2$ were not the same. On the other hand, during the same period, concentration of $N_2$ increased about 1.3 mol% and the increased mole fraction of $N_2$ was comparable with the difference (1.2 mol%) between the mole fraction of consumed $O_2$ and excreted $CO_2$. Therefore, we can attribute the increase of $N_2$ mole% to the difference of mole fraction between consumed $O_2$ and excreted $CO_2$. In this study, through the analysis of gas, we could explain the respiration of a fertile chicken egg during incubation.

• Journal of Climate Change Research
• /
• v.3 no.4
• /
• pp.259-270
• /
• 2012

Mobile air conditioning(MAC) systems of light-duty vehicles consume the most energy among auxiliary parts. Vehicle $CO_2$ reduction policies in Korea, US EPA and EU include the strategies to reduce additional $CO_2$ by MAC operation with providing incentive for the high-efficient MAC technologies. It is under development how to estimate MAC $CO_2$ and to differentiate advanced or high-efficient MAC system in US EPA and EU. The additional energy by MAC operation would beaffected by not only driving patterns but also environmental conditions such as temperature and humidity. In this study, we estimated MAC $CO_2$ of Korean light-duty vehicles with various driving cycles and environmental conditions. Test results were corrected to reference conditions for varied temperature and humidity during tests to get the comparable data for test vehicles. The test results showed that high-efficient MAC technologies have potential to reduce MAC $CO_2$ approximately by 50%. Considering the rate of MAC $CO_2$ to vehicle $CO_2$, it is expected that the introduction of high-efficient MAC technologies would considerably reduce vehicle $CO_2$ emission in MAC operation.