• Title/Summary/Keyword: CO poisoning

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The Sanitary Characteristics of Differenct Commercial Seasoned Shrimp Soy Sauce (시판 간장새우살장의 위생 특성)

  • Lee, Jong Soo;Lim, Jeong Wook;Kim, Hye Jin;Park, Sun Young;Kim, Ye Jin;Shon, Suk Kyung;Kim, Jin-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.53 no.6
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    • pp.851-860
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    • 2020
  • Shrimp in seasoned soy sauce (S-SS) is a popular seafood product in Korea, but it could be potentially hazardous; thus, this study was conducted to investigate its safety. Commercial S-SS were collected and analyzed for pH, volatile basic nitrogen (VBN), hygenic indicator microorganisms (viable cell count, coliforms, and Escherichia coli), food poisoning bacteria (Staphylococcus aureus, Vibrio parahaemolyticus, and Listeria monocytogenes), preservatives (dehydroacetic acid, sorbic acid, benzoic acid, and its salt, parahydroxybenzoate), tar colorants, and sensory properties. Domestic and foreign standards were also investigated for S-SS. Commercial S-SS ranged from to 6.2-7.3 for pH, 13.7-39.1 mg/100 g for VBN, and 4.6-6.9 log CFU/g for viable cells. The coliforms and E. coli of commercial S-SS were from ND to 3.4 log CFU/g and negative, respectively. Food poisoning bacteria, preservatives, and tar colorants were not detected in commercial S-SS. Only the coliform count and presence of E. coli in commercial S-SS exceeded the set standards of vietnam, while all items were within domestic and foreign standards.

Hydrogen Production for PEMFC Application in Plasma Reforming System (PEMFC용 플라즈마 개질 시스템의 수소 생산)

  • Yang, Yoon Cheol;Chun, Young Nam
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.1002-1007
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    • 2008
  • The purpose of this paper studied the optimal hydrogen production condition of plasma reforming system to operate the PEMFC. Plasma reforming reactor used with Ni catalyst reactor at the same time, So $H_2$ concentration increased. Also the WGS and PrOx reactor were designed to remove CO concentration under 10 ppm, because CO has effect on catalyst poisoning of PEMFC. The maximum $H_2$ production condition in plasma reforming system was S/C ratio 3.2, $CH_4$ flow rate 2.0 L/min, catalytic reactor temperature $700{\pm}5^{\circ}C$ and input power 900 W. At this time, the concentration of produced syngas was $H_2$ 70.2%, CO 7.5%, $CO_2$ 16.2%,$CH_4$ 1.8%. The hydrogen yield, hydrogen selectivity and $CH_4$ conversion rate were 56.8%, 38.1% and 92.2% respectively. The energy efficiency and specific energy requirement were 37.0%, 183.6 kJ/mol. In additional, The experiment of $CO_2/CH_4$ ratio proceeded. Also WGS reactor experiment was proceeding on optimum condition of plasma reactor and the exit concentration were $H_2$ 68%, CO 337 ppm, $CO_2$ 24.0%, $CH_4$ 2.2%, $C_2H_4$ 0.4%, $C_2H_6$ 4.1%. At this time, experiment result of PrOx reactor were $H_2$ 51.9%, CO 0%, $CO_2$ 17.3%.

Cultural Condition of the Production of Alkaline Pretense by f parahaemolyticus(1) (V. parahaemolyticus에 의한 Alkaline Pretense 생산조건(1))

  • 양지영;한종흔;강현록;황미경;차재호
    • Journal of Food Hygiene and Safety
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    • v.15 no.2
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    • pp.176-178
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    • 2000
  • V parahaemolyticus possessed an extracellular alkaline pretense activity during the stationary growth phase. Various factors such as nitrogen sources, the concentration of NaCl and metal ions were investigated for optimizing the production of alkaline pretense from V. parahaemolyticus ATCC 17802. Among the nitrogen sources tested skim milk showed the distinct increase of the activity and the activity was the highest at 2% in final concentration after 60 hours incubation. The addition of NaCl and metal ions did not increase the alkaline pretense activity. CoC$_2$, CuC1$_2$, and HgCl rather highly inhibited alkaline protease production.

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Assessment of Flame Retardancy for Acrylonitrile Butadiene Styrene Containing Metal Powder and Flame Retardant (금속분말-난연제 함유 ABS의 난연 특성 평가)

  • Song, Young-Ho;Chung, Kook-Sam
    • Fire Science and Engineering
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    • v.21 no.2 s.66
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    • pp.30-35
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    • 2007
  • The flame retardancies by the addition of metal powder and flame retardant were evaluated to present as the fundamental data to decrease the fire hazard of polymers and life losses by suffocation and poisoning. For this study, the experiments of flame retardancy were conducted as follows : weight loss rate using thermogravimetric analysis, the measurement of the limiting oxygen index(LOI) and char yield. And smoke mass concentration and CO yield were measured. Acrylonitrile butadiene styrene containing metal powder and flame retardant reduced weight loss rate and increased LOI and char yield with the decreased smoke mass concentration and CO yield. It was found that the most effective complex was tricresyl phosphate-Mo complex.

The Characteristic Analysis and Modeling of Aged PEMFC by Output Low Ripple Current (출력 저주파 리플전류에 따른 노화된 연료전지의 특성분석 및 모델링)

  • Kim, J.H;Jang, M.H.;Choi, J.S.;Tak, Y.S.;Cho, B.H.
    • Proceedings of the KIPE Conference
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    • 2010.11a
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    • pp.72-73
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    • 2010
  • 연료전지에 출력 저주파 리플전류가 유입될 때, 연료전지 내부에 화학적 특성변화인 Flooding, Drying 및 CO-poisoning이 발생하며 이는 연료전지 노화에 따른 특성변화를 야기한다. 이는 연료전지 노화에 따른 특성분석 및 노화되지 않은 기존 연료전지 시스템 모델의 수정이 불가피함을 나타낸다. 따라서, 본 논문은 연료전지에 연결되는 부하의 출력 저주파 리플전류에 따른 연료전지의 노화에 따른 특성분석 및 차후 진행될 연료전지의 모델링 방향을 간단히 제시하였다. 연료전지의 등가회로 모델 기반 시 저주파 리플전류에 따른 전압-전류 곡선 및 전기화학적 실험결과로 얻어진 노화된 모델 파라미터 값을 연료전지 시스템에 적용하여 노화된 연료전지의 특성분석을 실시하였다. 또한, 노화 전후의 연료전지 등가회로 모델 차이를 간단히 언급하고 차후 진행될 모델링 방향을 제시하였다.

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A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction II. Effect of Alkali Metal Salt on the Activity of CoMo Catalyst (황에 저항성을 가지는 수성가스 전환반응 촉매의 연구 II. CoMo 촉매의 활성에 미치는 알칼리 금속염의 영향)

  • Kim, Joon Hee;Lee, Ho In
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.696-702
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    • 1998
  • The effect of alkali metal salt on the activity of Co-Mo catalyst which has high resistance to sulfur poisoning for water gas shift reaction(WGSR) was studied. Two groups of catalysts were prepared to investigate the effects of anion and cation in alkali metal salts. For K-doped catalysts made with various potassium salts having different anion, the catalytic activity was explained to depend mainly on the BET surface area. Among the catalysts prepared by various nitrates of alkali metal as precursor, the Li-doped catalyst showed the best activity, and the others did not make significant differences giving relatively low activities. And the change of BET surface area by varying the loading of alkali metal showed a similar trend to that of activity. In this case, the activity was dependent on both BET surface area and the ratio of $Mo^{6+}$ with a tetrahedral coordination symmetry to $Mo^{6+}$ with an octahedral one, $Mo^6+[T]/Mo^{6+}[O]$ value.

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Effect of Carbon Dioxide in Fuel on the Performance of PEMFC (연료중의 이산화탄소 불순물에 의한 고분자전해질연료전지의 성능변화 연구)

  • Seo, Jung-Geun;Kwon, Jun-Taek;Kim, Jun-Bom
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.42-46
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    • 2008
  • Even though fuel cell have high efficiency when pure hydrogen from gas tank is used as a fuel source, it is more beneficial to generate hydrogen from city gas (mainly methane) in residential application such as domestic or office environments. Thus hydrogen is generated by reforming process using hydrocarbon. Unfortunately, the reforming process for hydrogen production is accompanied with unavoidable impurities. Impurities such as CO, $CO_2$, $H_2S$, $NH_3$, $CH_4$, and $CH_4$ in hydrogen could cause negative effects on fuel cell performance. Those effects are kinetic losses due to poisoning of the electrode catalysts, ohmic losses due to proton conductivity reduction including membrane and catalyst ionomer layers, and mass transport losses due to degrading catalyst layer structure and hydrophobic property. Hydrogen produced from reformer eventually contains around 73% of $H_2$, 20% or less of $CO_2$, 5.8% of less of $N_2$, or 2% less of $CH_4$, and 10ppm or less of CO. This study is aimed at investigating the effect of carbon dioxide on fuel cell performance. The performance of PEM fuel cell was investigated using current vs. potential experiment, long run(10 hr) test, and electrochemical impedance measurement when the concentrations of carbon dioxide were 10%, 20% and 30%. Also, the concentration of impurity supplied to the fuel cell was verified by gas chromatography(GC).

A Study on the Performance and Exhaust Emissions Characteristics of LPG Engine using LPG Fuel with New Sulfur Free Odorant (새로운 비황분계 부취제 혼합 LPG 연료의 엔진성능과 배출가스 특성에 관한 연구)

  • Kim, Jae-Kon;Yim, Eui Soon;Min, Kyong-Il;Jung, Choong-Sub
    • Journal of Energy Engineering
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    • v.23 no.3
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    • pp.88-95
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    • 2014
  • In general, odorants are added to fuel gases, such as LPG, LNG and city gas, to prevent gas poisoning, ignition, explosion, or other accident caused by fuel gases, and to enable immediate and easy detection of fuel-gas leakage by emitting an offensive smell. This study describes a study on the performance and exhaust emissions (CO, THC, $CO_2$, $NO_x$, $SO_2$) characteristics of liquefied petroleum gas (LPG) engine using LPG fuel with new sulfur free odorant (K-Petro S-Free). New sulfur free odorant (40 mg/kg) was added to 2 type LPG fuels for summer, and winter and it was used in performance and exhaust emissions, compare to LPG fuel with sulfur containing odorant (EM, ethyl mercaptan). Engine performance using LPG with sulfur free odorant was similar to LPG with sulfur-containing odorant. Exhaust emissions (CO, THC, $CO_2$, $NO_x$) of LPG with sulfur free odorant were also similar characteristics, compare with sulfur containing odorant. Especially, $SO_2$ emission using LPG with K-Petro S-Free odorant was more reduced 83 % than LPG with sulfur containing odorant(EM) at 2000 rpm.

A Study on the Mortality in Oxygen and Toxic Gas Concentration According using Experimental Animals (실험동물을 이용 산소 및 유해가스 농도에 따른 치사율 연구)

  • Kim, Hyeon-Yeong
    • Journal of the Korean Institute of Gas
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    • v.17 no.4
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    • pp.18-25
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    • 2013
  • It may occur health hazards or death by suffocation or acute poisoning in case of oxygen deficiency in ambient or exposure to harmful gas. As a part of accident prevention, we studied the change of activity and lethal dose by changing the concentration of several hazardous gas with inhalation exposure chamber and laboratory animals. We investigated the lethality and motility change during either the 4 hrs whole body exposure to oxygen, nitrogen, toluene, $H_2S$, CO and 48 recovery. As results, it is estimated that 5% oxygen concentration as lethal concentration and 5.5% as $LC_{50}$ (rat, 4 hrs) with statistics for dose-response. The results of lethality in oxygen deficient condition (approximately 6%), the lethalities were 40%, 20% with 20 ppm $H_2S$, 600 ppm CO respectively, and was not increased the lethality with 8% CO. Thus, it was confirmed that the $H_2S$, CO had influence to lethal dose, while toluene had low fluence.

Early Pulmonary Irradiation in Paraquat ($Gramoxone^{(R)}$) Poisoning (Paraquat 중독 환자에서 전폐 방사선치료의 효과)

  • Lee, Chang-Geol;Kim, Gwi-Eon;Suh, Chang-Ok
    • Radiation Oncology Journal
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    • v.13 no.4
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    • pp.321-330
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    • 1995
  • Purpose : To evaluate whether the early pulmonary irradiation can prevent or decrease the pulmonary damage and contribute to improve ultimate survival in paraquat lung. Materials and Methods : From Jun. 1987 to Aug. 1993, thirty patients with paraquat poisoning were evaluated. Fourteen of these patients were received pulmonary irradiation(RT). All of the patients were managed with aggressive supportive treatment such as gastric lavage, forced diuresis, antioxidant agents and antifibrosis agents. Ingested amounts of paraquat were estimated into three groups(A : minimal 50cc). Pulmonary irradiation was started within 24 hours after admission(from day 1 to day 11 after ingestion of paraquat). Both whole lungs were irradiated with AP/PA parallel opposing fields using Co-60 teletherapy machine. A total of 10Gy(2Gy/fr. x 5days) was delivered without correction of lung density. Results : In group A, all patients were alive regardless of pulmonary irradiation and in group C, all of the patients were died due to multi-organ failure, especially pulmonary fibrosis regardless of pulmonary irradiation. However, in group B, six of 7 patients($86{\%}$) with no RT were died due to respiratory failure, but 4 of 8 patients with RT were alive and 4 of 5 patients who were received pulmonary irradiation within 4 days after ingestion of paraquat were all alive though radiological pulmonary change. One patient who refused RT after 2Gy died due to pulmonary fibrosis. All 3 patients who were received pulmonary irradiation after 4 days after ingestion were died due to pulmonary fibrosis in spite of recovery from renal and hepatic toxicity Conclusion : It is difficult to find out the effect of pulmonary irradiation on the course of the paraquat lung because the precise plasma and urine paraquat concentration were not available between control and irradiation groups. But early pulmonary irradiation within 4 days after paraquat poisoning with aggresive supportive treatment appears to decrease Pulmonary toxicity and contribute survival in patients with mouthful ingestion of paraquat who are destined to have reversible renal and hepatic damage but irreversible pulmonary toxicity.

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