• Bulletin of the Korean Chemical Society
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• 제12권5호
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• pp.574-582
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• 1991

The CO molecules adsorbed on Ni(111) surface is studied in the cluster approximation employing EH method with self-consistent charge iteration. The effect of CO coverage is simulated by allowing the variation of valence state ionization potentials of each Ni atom in model cluster according to the self-consistent charge iteration method. The CO coverage dependent C-O stretching frequency shift, adsorption site conversion, and metal work function change are attributed to the charge transfer between metal surface and adsorbate. For CO/Ni(111) system, net charge transfer from Ni surface to chemisorbed CO molecules makes surface Ni atoms be more positive with increasing coverage, and lowers Ni surface valence band. This leads to a weaker interaction between metal surface valence band and Co $2{\pi}^{\ast}$ MO, less charge transfer to a single CO molecule, and the bule shift of C-O stretching frequency. Further increase of coverage induces the conversion of 3-fold site CO to lower coordination site CO as well as the blue shift of C-O stretching frequency. This whole process is accompanied by the continuous increase of metal work function.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2442-2444
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• 2007

CO adsorbates on the surface of Pt supported on carbon catalysts (Pt/C) were investigated by CO stripping voltammetry. Three types of CO adsorbed samples were prepared: by methanol dehydrogenation only (COm), by CO gas bubbling only (COg), and by methanol dehydrogenation followed by CO gas bubbling (COm+g). Our coverage data show that CO gas can be adsorbed on Pt/C catalyst already saturated with CO adsorbates by methanol dehydrogenation. The COm+g sample showed the properties of both COm as well as COg samples in terms of the potential although the CO adsorbed by dehydrogenation was completely exchanged with CO in the electrolyte solution. Therefore, the oxidation pathways of CO on Pt/C were observed to depend on the initial adsorption conditions of CO more strongly than on the CO coverage. Our results imply that an initial CO poisoning condition in fuel cell operation is an important factor to determine the difficulty in removing the adsorbed CO and confirm that the properties of the adsorbed CO do not change even with chemical replacement with CO in different conditions. In addition, our results indicate a low CO surface mobility on the Pt in an electrolyte solution.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2018년도 공동국제학술발표회
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• pp.5-5
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• 2018

• 방송공학회논문지
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• 제18권1호
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• pp.59-65
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• 2013

최근 지상파 방송은 아날로그 TV방송에서 디지털 TV방송으로의 전환이 진행 중에 있다. 이러한 디지털 TV방송 전환 이후에 동일 채널 간섭으로 인한 TV White space (TVWS)의 재할당 및 배치가 필요하다. 본 논문에서는 방송서비스 전파모델로 가장 많이 사용되고 있는 Longley-Rice와 ITU-R P.1546 전파모델에서 동일채널간섭 (CCI; co-channel interference)으로 인해 발생되는 TVWS에 대해 연구한다. 또한 디지털 방송에서 송신 안테나 높이와 송신전력에 따른 서비스 커버리지 반경과 CCI 반경을 분석한다. 분석결과에 의하면, Longley-Rice와 ITU-R P.1546 전파모델의 평균적인 CCI 반경 대 서비스 커버리지 반경의 비는 각각 2.54, 2.07이었다.

• JSTS:Journal of Semiconductor Technology and Science
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• 제2권2호
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• pp.132-140
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• 2002

This paper presents an ARM-based SOC bus transaction verification IP and the usage experiences in SOC designs. The verification IP is an AMBA AHB protocol checker, which captures legal AHB transactions in FSM-style signal sequence checking routines. This checker can be considered as a reusable verification IP since it does not change unless the bus protocol changes. Our AHB protocol checker is designed to be scalable to any number of AHB masters and reusable for various AMBA-based SOC designs. The keys to the scalability and the reusability are Object-Oriented Programming (OOP), virtual port, and bind operation. This paper describes how OOP, virtual port, and bind features are used to implement AHB protocol checker. Using the AHB protocol checker, an AHB simulation monitor is constructed. The monitor checks the legal bus arbitration and detects the first cycle of an AHB transaction. Then it calls AHB protocol checker to check the expected AHB signal sequences. We integrate the AHB bus monitor into Verilog simulation environment to replace time-consuming visual waveform inspection, and it allows us to find design bugs quickly. This paper also discusses AMBA AHB bus transaction coverage metrics and AHB transaction coverage analysis. Test programs for five AHB masters of an SOC, four channel DMAs and a host interface unit are executed and transaction coverage for DMA verification is collected during simulation. These coverage results can be used to determine the weak point of test programs in terms of the number of bus transactions occurred and guide to improve the quality of the test programs. Also, the coverage results can be used to obtain bus utilization statistics since the bus cycles occupied by each AHB master can be obtained.

• Nuclear Engineering and Technology
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• 제56권9호
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• pp.3750-3757
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• 2024

Rapidly obtaining the coverage characteristics of leaching solution in In-situ Leaching Area of Sandstone Uranium Mines is a necessary condition for optimizing well locations reasonably. In the presented study, the improved algorithm of the Fast Marching Method (FMM) was studied for rapidly solving coverage characteristics to replace the groundwater numerical simulator. First, the effectiveness of the FMM was verified by simulating diffusion characteristics of the leaching solution in In-situ Leaching Area. Second, based on the radial flow pressure equation and the interaction mechanism of the front diffusion of production and injection well flow field, an improved FMM which is suitable for In-situ Leaching Mining, was developed to achieve the co-simulation of production and injection well. Finally, the improved algorithm was applied to engineering practice to guide the design and production. The results show that the improved algorithm can efficiently solve the coverage characteristics of leaching solution, which is consistent with those obtained from traditional numerical simulators. In engineering practice, the improved FMM can be used to rapidly analyze the leaching process, delineate Leaching Blind Spots, and evaluate the rationality of well pattern layout. Furthermore, it can help to achieve iterative optimization and rapid decision-making of production and injection well locations under largescale mining area models.

• 한국항공우주학회지
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• 제43권5호
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• pp.449-455
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• 2015

Built-In-Test(이하: BIT)는 항공기 비행안전을 위해 반드시 필요한 기능으로 항공전자 장비의 경우 95% 이상의 높은 고장 진단능력을 요구하고 있다. BIT가 요구도에 명시된 고장 진단능력을 만족시키는지 확인하기 위해 BIT 성능분석이 필요하다. BIT 성능분석을 위해 FMECA (Failure Mode Effect Critical Analysis)에 기술된 고장모드를 활용하는 방법이 많이 사용되고 있으나, 본 논문에서는 분석 오류를 최소화할 수 있는 전자부품 기반의 BIT 성능분석 방법론을 소개한다. 또한, BIT 성능분석에서 제외될 수 있는 비행안전에 영향을 미치지 않는 전자부품 및 전자부품의 고장모드를 실제 개발사례에 적용하여 불필요한 BIT 기능 구현을 방지하고 정확한 BIT 성능분석을 수행할 수 있도록 하였다. BIT Demo를 수행하여 BIT 성능분석 결과와 실제 BIT 성능이 일치함을 확인하였다.

• Nuclear Engineering and Technology
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• 제55권11호
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• pp.3940-3955
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• 2023

A new method of numerical simulating prediction and decontamination effect evaluation for abrasive jet decontamination to radioactively contaminated metal is proposed. Based on the Computational Fluid Dynamics and Discrete Element Model (CFD-DEM) coupled simulation model, the motion patterns and distribution of abrasives can be predicted, and the decontamination effect can be evaluated by image processing and recognition technology. The impact of three key parameters (impact distance, inlet pressure, abrasive mass flow rate) on the decontamination effect is revealed. Moreover, here are experiments of reliability verification to decontamination effect and numerical simulation methods that has been conducted. The results show that: ⁶⁰Co and other homogeneous solid solution radioactive pollutants can be removed by abrasive jet, and the average removal rate of Co exceeds 80%. It is reliable for the proposed numerical simulation and evaluation method because of the well goodness of fit between predicted value and actual values: The predicted values and actual values of the abrasive distribution diameter are Ф57 and Ф55; the total coverage rate is 26.42% and 23.50%; the average impact velocity is 81.73 m/s and 78.00 m/s. Further analysis shows that the impact distance has a significant impact on the distribution of abrasive particles on the target surface, the coverage rate of the core area increases at first, and then decreases with the increase of the impact distance of the nozzle, which reach a maximum of 14.44% at 300 mm. It is recommended to set the impact distance around 300 mm, because at this time the core area coverage of the abrasive is the largest and the impact velocity is stable at the highest speed of 81.94 m/s. The impact of the nozzle inlet pressure on the decontamination effect mainly affects the impact kinetic energy of the abrasive and has little impact on the distribution. The greater the inlet pressure, the greater the impact kinetic energy, and the stronger the decontamination ability of the abrasive. But in return, the energy consumption is higher, too. For the decontamination of radioactively contaminated metals, it is recommended to set the inlet pressure of the nozzle at around 0.6 MPa. Because most of the Co elements can be removed under this pressure. Increasing the mass and flow of abrasives appropriately can enhance the decontamination effectiveness. The total mass of abrasives per unit decontamination area is suggested to be 50 g because the core area coverage rate of the abrasive is relatively large under this condition; and the nozzle wear extent is acceptable.

• Weed & Turfgrass Science
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• 제4권3호
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• pp.268-277
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• 2015

유기질비료의 원료를 이용하여 한지형 잔디의 종자 파종후 피복율, 생육 및 질의 증진을 위한 유지질비료 제제를 개발하였다. 개발 제제는 한지형 잔디의 생육에 필수적인 무기영양소와 유기물을 함유하고 있다. 유기질비료로 개발한 제제는 4종류로 creeping bentgrass "Penn-A1" 품종과 Kentucky bluegrass 혼합품종(Midnight 33%, Moonlight 33%와 Prosperity 33%)의 종자를 파종 후 50일에 1회 토양 시비로 시험하였다. creeping bentgrass와 Kentucky bluegrass의 피복율, 생장(생장지수) 및 잔디의 질은 2013년 가을부터 2014년 봄철기간 동안 경시적으로 평가를 하였다. 개발제제의 파종 후 1회 토양살포로 잔디 피복율, 잔디 엽색, 엽록소 함량 및 생장에서 통계적인 유의성의 차이를 보였다. creeping bentgrass와 Kentucky bluegrass의 피복율, 엽록소 함량, 잔디 엽색 및 생장은 봄철 6회 조사까지 통계적으로 유의성 있게 증가하였다. 이 결과에 의하면 일부 개발 제제의 사용은 한자형 잔디의 뗏장잔디의 생산과 잔디관리에 도움의 줄 것으로 생각한다.

• Journal of Communications and Networks
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• 제18권5호
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• pp.773-783
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• 2016

Both coordinated multi-point transmission and frequency reuse are effective approaches to mitigate inter-cell interference and improve network coverage. The motivation of this work is to explore the manner to effectively utilize the spectrum resource by reasonably combining cooperation and frequency reuse. The $Mat{\acute{e}}rn$ cluster process, which is appropriate to model networks with hot spots, is used to model the spatial distribution of base stations. Two cooperative mechanisms, coherent and non-coherent joint transmission (JT), are analyzed and compared. We also evaluate the effect of multiple antennas and imperfect channel state information. The simulation reveals that the proposed approach to combine cooperation and frequency reuse is effective to improve the network coverage for users located at both the center and the boundary of the cooperative region.