• Title/Summary/Keyword: CO₂

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Comparison of Construction Costs of Masonry Wall Types, including CO2 Emission Costs (조적벽의 CO2 배출비용을 포함한 건설원가 비교에 관한 연구)

  • Lee, Byung-Yun;Kim, Bo-Ra;Kim, Gwang-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.3
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    • pp.83-90
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    • 2010
  • The carbon dioxide($CO_2$) emissions that result from construction are one of the main factors causing a global warming problem. It is therefore necessary to make efforts to reduce $CO_2$ emissions in the construction industry. Some researchers have studied $CO_2$ emissions in the industry ; however, there has been a lack of study on $CO_2$ emissions cost. Therefore, in this study, the construction costs, including the $CO_2$ emission cost, of masonry wall type, which is a common brick wall, concrete brick wall, and fired brick wall, were examined. The purpose of this study is to compare the construction costs of masonry wall types, including $CO_2$ emission costs. The study found that the $CO_2$ emission costs were highest for the fired brick wall, followed by the concrete brick wall. This research could provide basic information that can be used in other engineering methods to convert $CO_2$ emissions to $CO_2$ emission cost.

Formation of Co-silicides using Co Single Layer and Co/Ti Bilayer (Co 단일막과 Co/Ti 이중막을 이용한 Co-실리사이드의 형성 연구)

  • Jang, Ji-Geun;Eom, U-Yong;Jang, Ho-Jeong;Hong, Seong-Su;Song, Jin-Tae
    • Korean Journal of Materials Research
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    • v.6 no.7
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    • pp.692-699
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    • 1996
  • nptype Si(100)웨이퍼를 precleaning하고 HF 용액에 dip etching한 후 E-beam dvaporator에 장착하여 Co 단일막($170\AA$, $340\AA$)과 Co/Ti 이중막($200\AA$/ $(50-100)\AA$)을 성장시켰다. 시편의 RTA 과정에서는 N2분위기에서 direct annealing 방식으로 열처리 온도와 시간을 변화시켜가며 Co-silicidation 공정을 수행하였다. Co 단일막으로 형성된 Co-실리사이드의 면저항은 $500^{\circ}C\leq$T$\leq$$850^{\circ}C$범위에서 열처리 온도와 시간의 변화에 관계없이 거의 일정한 값을 나타내었다. Co/Ti 이중막의 경우 Co-실리사이드의 형성온도가 Co 단일막의 경우에 비해 높게 나타나고 낮은 비저항의 CoSi2를 얻기 위해서는 $800^{\circ}C$이상의 온도로 열처리해야 함을 알 수 있었다. XRD 분석결과, Co 단일막으로부터 얻어진 CoSi2는 (111) 및 (220) 결정상을 나타내었으나, Co/Ti 이중막에 의한 CoSi2는 (200)결정상만이 나타나서 Si(100)기판과 에피층을 이루고 있음을 알 수 있었다. 본 실험에서 CoSi2의 비저항은 약 $18\mu$$\Omega$.cm로 나타났으며, TEM 및 AES 분석으로부터 Co/Ti bilayer-실리사이드가 다량의 Si과 Ti 외에 소량의 Co가 섞여있는 표면 복합층과, Si과 Co만이 존재하는 내부 에피층으로 구성됨을 확인하였다.

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CoMFA and CoMSIA Analysis on the Selective Fungicidal Activity of N-phenyl-D-phenylthionocarbamate Analogues against Resistant and Sensitive Gray Mold (Botrytis cinerea) (저항성 및 감수성 잿빛곰팡이병균(Botrytis cinerea)에 대한 N-Phenyl-O-phenylthionocarbamate 유도체들의 선택적인 살균활성에 관한 CoMFA 및 CoMSIA 분석)

  • Soung, Min-Gyu;Sung, Nack-Do
    • The Korean Journal of Pesticide Science
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    • v.11 no.3
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    • pp.138-143
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    • 2007
  • The relationships between three dimensional quantitative structure and activity relationships (3D-QSARs) for the selective fungicidal function between N-phenyl substituents of N-phenyl-O-phenyl-thionocarbamate derivatives analogues and their the fungicidal activities against resistant (RBC) and sensitive (SBC) gray mold (Botrytis cinerea) were studied quantitatively using CoMFA and CoMSIA methods. The statistical values of optimized CoMSIA (M7) model were better ($r^2$ & $q^2=CoMSIA{\gg}CoMFA$) than that of CoMFA (M5) model. And the factor influencing of the selective between the fungicidal activity against RBC and SBC was dependent on electrostatic field of CoMFA (M5) model. Therefore, it is predicted that, from the CoMSIA contour maps of CoMSIA (M7) model, the selectivity will be improved by the H-bond donor that is with negatively charged favored group at meta-position on the N-phenyl ring.

Research on the Production of CO2 Absorbent Using Railway Tie Concrete Waste (콘크리트 철도 침목 폐기물을 활용한 CO2 포집제 제조 연구)

  • Gyubin Lee;Jae-Young Lee;Hyung-Jun Jang;Sangwon Ko;Hye-Jin Hong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.3
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    • pp.260-266
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    • 2023
  • In recent years, excessive emissions of carbon dioxide(CO2) have become the cause of global climate change. Consequently, there has been significant research activity aimed at both removing and utilizing CO2. This study assesses the potential utilization of railway tie concrete waste, generated from railway infrastructure, as a CO2 absorption material and investigates the physicochemical properties before and after CO2 absorption to understand the CO2 removal mechanisms. Railway tie concrete waste primarily consists of Si(26.60 %) and contains 9.82 % of Ca. Compared to samples of Cement and Normal concrete waste, it demonstrated superior potential for use as a CO2 absorption material, with approximately 98 % of the Ca content participating in CO2 absorption reactions. Through Thermogravimetric Analysis(TGA) and X-ray Diffraction(XRD) analysis, it was confirmed that the carbonate reaction, where the Ca in railway tie concrete waste converts into CaCO3 through reaction with CO2 gas, is the primary mechanism for CO2 removal. Furthermore, Scanning Electron Microscopy(SEM) analysis revealed the formation of numerous CaCO3 particles with sizes less than 0.1 ㎛ after the CO2 absorption reaction. This transformation of large internal voids in the CO2 absorption material into mesopores resulted in an increase in the specific surface area of the material.

A Review of Enhanced Oil Recovery Technology with CCS and Field Cases (CCS와 연계한 석유회수증진 기술 동향 및 현장사례 분석)

  • Park Hyeri;Hochang Jang
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.59-71
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    • 2023
  • Carbon capture, and storage (CCS) is important for the reduction of greenhouse gases and achieving carbon neutrality. CCS focuses on storing captured CO2 permanently in underground reservoirs. CO2-enhanced oil recovery (CO2-EOR) is one form of CCS, where CO2 is injected into the underground to enhance oil recovery. CO2-EOR not only aids in the extraction of residual oil but also contributes to carbon neutrality by storing CO2 underground continuously. CO2-EOR can be classified into miscible and immiscible methods, with the CO2-water alternating gas (CO2-WAG) technique being a representative approach within the miscible method. In CO2-WAG, water and CO2 are alternately injected into the reservoir, enabling oil production and CO2 storage. The WAG method allows for controlling the breakthrough of injection fluids, providing advantages in oil recovery. It also induces hysteresis in relative permeability during the injection and production process, expanding the amount of trapped CO2. In this study, the effects of enhancing oil recovery and storing CO2 underground during CO2-EOR were presented. Additionally, cases of CO2-EOR application in relation to CCS were introduced.

Effect of Phosphorus Stress on Photosynthesis and Nitrogen Fixation of Soybean Plant under $CO_2$ Enrichment (대기 $CO_2$ 상승시 인산공급이 식물체의 광합성 및 질소고정에 미치는 영향)

  • Sa, Tong-Min
    • Applied Biological Chemistry
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    • v.40 no.2
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    • pp.134-138
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    • 1997
  • The objective of this study was to examine the effect of phosphorus deficiency on nitrogen fixation and photosynthesis of nitrogen fixing soybean plant under $CO_2$ enrichment condition. The soybean plants(Glycine max [L.] Merr.) inoculated with Bradyrhizobium japonicum MN 110 were grown with P-stressed(0.05 mM-P) and control(1 mM-P) treatment under control$(400\;{\mu}l/L\;CO_2)$ and enrichment$(800\;{\mu}l/L\;CO_2)$ enviromental condition in the phytotron equipped with high density lamp$(1000\;{\mu}Em^{-2}S^{-1})$ and $28/22^{\circ}C$ temperature cycle for 35 days after transplanting(DAT). At 35 DAT, phosphorus deficiency decreased total dry mass by 64% in $CO_2$ enrichment condition, and 51% in control $CO_2$ condition. Total leaf area was reduced significantly by phosphorus deficiency in control and enriched $CO_2$ condition but specific leaf weight was increased by P deficiency. Phosphorus deficiency significantly reduced photosynthetic rate(carbon exchange rate) and internal $CO_2$ concentration in leaf in both $CO_2$ treatments, but the degree of stress was more severe under $CO_2$ enrichment condition than under control $CO_2$ environmental condition. In phosphorus sufficient plants, $CO_2$ enrichment increased nodule fresh weight and total nitrogenase activity(acetylene reduction) of nodule by 30% and 41% respectively, but specific nitrogenase activity of nodule and nodule fresh weight was not affected by $CO_2$ enrichment in phosphorus deficient plant at 35 DAT. Total nitrogen concentrations in stem, root and nodule tissue were significantly higher in phosphorus sufficient plant grown under $CO_2$ enrichment, but nitrogen concentration in leaf was reduced by 30% under $CO_2$ enrichment. These results indicate that increasing $CO_2$ concentration does not affect plant growth under phosphorus deficient condition and phosphorus stress might inhibit carbohydrate utilization in whole plant and that $CO_2$ enrichment could not increase nodule formation and functioning under phosphorus deficient conditions and phosphorus has more important roles in nodule growth and functioning under $CO_2$ enrichment environments than under ambient condition.

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Phase sequence in Codeposition and Solid State Reaction of Co-Si System and Low Temperature Epitaxial Growth of $CoSi_2$ Layer (Co-Si계의 동시증착과 고상반응시 상전이 및 $CoSi_2$ 층의 저온정합성장)

  • 박상욱;심재엽;지응준;최정동;곽준섭;백홍구
    • Journal of the Korean Vacuum Society
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    • v.2 no.4
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    • pp.439-454
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    • 1993
  • The phase sequence of codeposited Co-Si alloy and Co/si multilayer thin film was investigated by differential scanning calormetry(DSC) and X-ray diffraction (XRD) analysis, The phase sequence in codeposition and codeposited amorphous Co-Si alloy thin film were CoSilongrightarrow Co2Si and those in Co/Si multilayer thin film were CoSilongrightarrowCo2Silongrightarrow and CoSilongrightarrowCo2Si longrightarrowCoSilongrightarrowCoSi2 with the atomic concentration ration of Co to Si layer being 2:1 and 1:2 respectively. The observed phase sequence was analyzed by the effectvie heat of formatin . The phase determining factor (PDF) considering structural facotr in addition to the effectvie heat of formation was used to explain the difference in the first crystalline phase between codeposition, codeposited amorphous Co-Si alloy thin film and Co/Si multilayer thin film. The crystallinity of Co-silicide deposited by multitarget bias cosputter deposition (MBCD) wasinvestigated as a funcion of deposition temperature and substrate bias voltage by transmission electron microscopy (TEM) and epitaxial CoSi2 layer was grown at $200^{\circ}C$ . Parameters, Ear, $\alpha$(As), were calculate dto quantitatively explain the low temperature epitaxial grpwth of CoSi2 layer. The phase sequence and crystallinity had a stronger dependence on the substrate bias voltage than on the deposition temperature due to the collisional daxcade mixing, in-situ cleannin g, and increase in the number of nucleation sites by ion bombardment of growing surface.

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Effect of the CO Tube insert for Emission Characteristics in a Compact Combustion Chamber (컴팩트 연소실 내 CO튜브 삽입에 따른 오염물질 배출특성)

  • Lee, Jae-Park;Kim, Jong-Min;Lee, Seung-Ro;Jang, Gi-Hyun;Lee, Chang-Eon
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2010.04a
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    • pp.66-71
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    • 2010
  • This study was the effect of CO tube insert for NOx and CO emission characteristics in a compact combustion chamber. In detail, NOx and CO emission characteristics with changing of distance due to inserting the CO tube between the burner and the main heat exchanger were investigated. For this study, the commercial program, FLUENT, and the GRI 2.11 detail reaction mechanism were used for the numerical study and a simple model heat exchanger was tested for the experimental study. As results, when the CO tube was inserted between the burner and the main heat exchanger, it was verified the simultaneous NOx and CO reduction method because of increasing the residence time and decreasing the flame temperature.

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Magnetic Properties of Co-P and Co-P-Cr Thin Films for Longitudinal Magnetic Recording (수평자기기록용 Co-P, Co-P-Cr 박막의 자기적특성)

  • Pyun-Woo Jang;Hong-Kyun Sohn;Taek-Dong Lee
    • Journal of the Korean Magnetics Society
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    • v.4 no.2
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    • pp.160-167
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    • 1994
  • In order to develop new magnetic media with higher coercivity, we have investigated the magnetic properties of Co-P/Cr and Co-P-Cr/Cr films. The coercivity of Co-P binary films deposited at RT was around 835 Oe in the range of 9-12 at.% P. In the Co-P binary system coercivity decreased with increasing substrate temperature for P contents of 9-12 at.%, which may be due to the decomposition of Co-P single phase to Co and $Co_{2}P$ phase. However, the coercivity of the films containing more than 12 at.% P is very low due to the formation of amorphous phase. The coercivity of Co-P-Cr ternary films increased with increasing Cr contents and reached the maximum value of 1020 Oe in the water $Co_{84}P_{10}Cr_{6}$ Film.

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CO2 conversion technology for CO gas synthesis using coal (석탄을 사용한 CO가스 제조를 위한 CO2 전환기술)

  • Lee, Ho-Yong;Park, Ji-Yong;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.4
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    • pp.712-717
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    • 2015
  • In this study, the experiment of CO production was performed using carbon dioxide and coal. The synthesis characteristics of CO gas was investigated using the chemical activation method of KOH. The preparation process has been optimized through the analysis of experimental variables such as activating chemical agents to coal ratio, the flow rate of gas and reaction temperature during $CO_2$ conversion reaction. Without the catalyst of KOH, the 66.7% of $CO_2$ conversion was obtained at the conditions of $T=950^{\circ}C$ and $CO_2$ flow rate of 300 cc/min. On the other hand, the 98.1% of $CO_2$ conversion was obtained using catalyst of KOH at same conditions. It was found that the feed ratio(Coal : KOH = 4 : 1) had better $CO_2$ conversion and CO selectivity than other feed ratios.