• Korean Journal of Agricultural and Forest Meteorology
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• v.23 no.4
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• pp.198-221
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• 2021

After large-scale reforestation in the 1960s and 1970s, forests in Korea have gradually been aging. Net ecosystem CO₂ exchange of old-growth forests is theoretically near zero; however, it can be a CO₂ sink or source depending on the intervention of disturbance or management. In this study, we report the CO₂ budget dynamics of the Gwangneung deciduous old-growth forest (GDK) in Korea and examined the following two questions: (1) is the preserved GDK indeed CO₂ neutral as theoretically known? and (2) can we explain the dynamics of CO₂ budget by the common mechanisms reported in the literature? To answer, we analyzed the 15-year long CO₂ flux data measured by eddy covariance technique along with other biometeorological data at the KoFlux GDK site from 2006 to 2020. The results showed that (1) GDK switched back-and-forth between sink and source of CO₂ but averaged to be a week CO₂ source (and turning to a moderate CO₂ source for the recent five years) and (2) the interannual variability of solar radiation, growing season length, and leaf area index showed a positive correlation with that of gross primary production (GPP) (R²=0.32~0.45); whereas the interannual variability of both air and surface temperature was not significantly correlated with that of ecosystem respiration (RE). Furthermore, the machine learning-based model trained using the dataset of early monitoring period (first 10 years) failed to reproduce the observed interannual variations of GPP and RE for the recent five years. Biomass data analysis suggests that carbon emissions from coarse woody debris may have contributed partly to the conversion to a moderate CO₂ source. To properly understand and interpret the long-term CO₂ budget dynamics of GDK, new framework of analysis and modeling based on complex systems science is needed. Also, it is important to maintain the flux monitoring and data quality along with the monitoring of coarse woody debris and disturbances.

• Journal of Applied Biological Chemistry
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• v.64 no.4
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• pp.351-356
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• 2021

Changing environmental conditions can affect plant growth by influencing water and nutrient transport and photosynthesis. Plant physiological responses under changing environmental conditions can be non-destructively monitored using electrodes as plant induced electrical signal (PIES). Objective of the study was to monitor PIES in response to increased CO₂ and decreased photosynthetic photon flux density (PPFD). The PIES increased during day time when transpiration and photosynthesis occurs and monitored CO₂ concentration was negatively correlated to the PIES. Enhanced CO₂ concentration slightly reduced PIES, but the effect of increased CO₂ was limited by light intensity. The effect of reduced PPFD was not appeared immediately because water and nutrient transport was not promptly affected by the light. The study was conducted to evaluate short-term effect of increasing CO₂ and decreasing PPFD, hence proline content and chlorophyll fluorescence was not significantly affected by the conditions.

• Membrane Journal
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• v.30 no.4
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• pp.269-275
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• 2020

In this study, CO₂ separation experiment was performed on a CH₄/CO₂ mixed gas using a ceramic hollow fiber membrane contactor (HFMC). In order to fabricate high-performance HFMC, experiments were conducted to manufacture high-permeability hollow fiber membranes, and the prepared hollow fiber membranes were evaluated through N₂ gas permeation experiments. HFMC for CH₄/CO₂ mixed gas separation was manufactured using the manufactured high-permeability hollow fiber membrane. In the experiment, mixed gas of CH₄/CO₂ (34.5% CO₂, CH₄ balance) and monoetanolamine (MEA) was used, and the effect of CO₂ removal efficiency on the flow rate of the absorbent was evaluated. The CO₂ removal efficiency increased as the liquid flow rate increased, and the CO₂ absorption flux also increased with the liquid flow rate.

• Korean Journal of Materials Research
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• v.12 no.10
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• pp.771-775
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• 2002

$Gd_2$$O_3$:Eu phosphor particles with nano-sized and non-aggregation characteristics were prepared by spray pyrolysis using the spray solution containing polymeric precursor and $Li_2$$CO_3$ flux material. Nano-sized $Gd_2$$O_3$:Eu phosphor particles had higher brightness than the commercial $Y_2$$O_3$:Eu phosphor particles. The $Gd_2$$O_3$:Eu phosphor particles had nano-size and non-aggregation characteristics after heat-treatment at $1000^{\circ}C$ when the addition amount of $Li_2$$CO_3$ flux was 1 wt.% and 3 wt.%. The mean size of particles were 200 nm and 400 nm when the amount of flux was 1 wt.% and 3 wt.%, respectively. The prepared phosphor particles had higher photoluminescence intensity than that of the commercial product regardless of the content of$ Li_2$$CO_3$ flux and had the maximum brightness when the content of flux was 5 wt %. The photoluminescence intensity of the nano-sized $Gd_2$$O_3$:Eu phosphor particles containing 3 wt.% $Li_2$$CO_3$ flux was 125% in comparison with that of the micron-sized $Y_2$$O_3$:Eu commercial product.

• Journal of The Korean Society of Agricultural Engineers
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• v.57 no.3
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• pp.109-120
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• 2015

Spatial heterogeneous characteristics of solar radiation energy from Climate Change gives rise to energy imbalance in the general ecological system including water resources. This study is to estimate the $CO_2$ flux of South Korea using Terra MODIS image and to assess the reliability of MODIS data from the ground measured $CO_2$ flux by eddy covariance flux tower data at 3 locations (two at mixed forest area and one at rice paddy area). The MODIS Gross Primary Productivity (GPP) product (MOD17A2), 8-day composite at 1-km spatial resolution was adopted for the spatial $CO_2$ flux generation. The MOD17A2 data by noise like cloud and snow in a day were tried to fill by Inverse Distance Weighted (IDW) method from valid pixels and the damping effect of MOD17A2 data were corrected by Quality Control (QC) flag. The MODIS $CO_2$ flux was estimated as the sum of GPP and Re (ecosystem respiration) by Lloyd and Taylor method (1994). The determination coefficient ($R^2$) between MODIS $CO_2$ and flux tower $CO_2$ for 3 years (2011~2013) showed 0.55 and 0.60 in 2 mixed forests and 0.56 in rice paddy respectively. The $CO_2$ flux generally fluctuated showing minus values during summer rainy season (from July to August) and maintaining plus values for other periods. The MODIS $CO_2$ flux can be a useful information for extensive area, for example, as a reliable indicator on ecological circulation system.

• Nuclear Engineering and Technology
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• v.54 no.1
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• pp.220-225
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• 2022

Perlite is one of the major constituents of the radioactive thermal insulation waste (RTIW) originating from nuclear power plants and, for proper waste management, a significant reduction in its volume is required prior to disposal. In this work, the volume reduction of perlite is studied by high-temperature treatment method with using K₂CO₃ as a flux. The perlite is ground with 0-30 wt% K₂CO₃, and differential thermal analysis/thermogravimetric analysis is used to monitor the glass transition temperature (T_g) and weight loss. The Tg varied between ~772.2 and 837.1 ℃ with the minima at ~643.5 ℃ with the addition of ~10 wt% K₂CO₃. It is observed that compared to the pure perlite the volume reduction ratio (VRR) increases with the addition of K₂CO₃. The VRR of 11.20 is observed with 5 wt% K₂CO₃ at 700 ℃, as compared to VRR of 5.56 without K₂CO₃ at 700 ℃. The X-ray photoelectron spectroscopy and scanning electron microscopy are used to characterize perlite samples heat-treated without/with 5 wt% K₂CO₃ at 700 ℃. Moreover, the atomic absorption spectroscopy indicates that the proposed heat-treatment procedure is able to completely retain the radionuclides present in the perlite RTIW.

• Journal of Korea Water Resources Association
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• v.56 no.11
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• pp.721-728
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• 2023

Agricultural drought is triggered by a depletion of moisture content in the soil, which hinders photosynthesis and thus increases carbon dioxide (CO₂) concentrations in the atmosphere. The aim of this study is to analyze the relationship between soil moisture (SM) and vegetation activity toward quantifying CO₂ concentration in the atmosphere. To this end, the MODerate resolution imaging spectroradiometer (MODIS), an optical multispectral sensor, was used to evaluate two regions in South Korea for validation. Vegetation activity was analyzed through MOD13A1 vegetation indices products, and MODIS gross primary productivity (GPP) product was used to calculate the CO₂ flux based on its relationship with respiration. In the case of SM, it was calculated through the method of applying apparent thermal inertia (ATI) in combination with land surface temperature and albedo. To validate the SM and CO₂ flux, flux tower data was used which are the observed measurement values for the extreme drought period of 2014 and 2015 in South Korea. These two variables were analyzed for temporal variation on flux tower data as daily time scale, and the relationship with vegetation index (VI) was synthesized and analyzed on a monthly scale. The highest correlation between SM and VI (correlation coefficient (r) = 0.82) was observed at a time lag of one month, and that between VI and CO₂ (r = 0.81) at half month. This regional study suggests a potential capability of MODIS-based SM, VI, and CO₂ flux, which can be applied to an assessment of the global view of the agricultural drought by using available satellite remote sensing products.

• Journal of Electrochemical Science and Technology
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• v.9 no.3
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• pp.212-219
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• 2018

Perovskite type ceramic membranes which exhibit dual ion conduction (proton and oxygen ion conduction) can permeate water and can aid solving operational problems such as temperature gradient and carbon deposition associated with a working solid oxide fuel cell. From this point of view, it is crucial to reveal water transport mechanism and especially the nature of the surface sites that is necessary for water incorporation and evolution. $BaCe_{0.8}Y_{0.2}O_{3-{\alpha}}$ (BCY20) was used as a model proton and oxygen ion conducting membrane in this work. Four different catalytically modified membrane configurations were used for the investigations and water flux was measured as a function of temperature. In addition, CO was introduced to the permeate side in order to test the stability of membrane against water and $CO/CO_2$ and post operation analysis of used membranes were carried out. The results revealed that water incorporation occurs on any exposed electrolyte surface. However, the magnitude of water permeation changes depending on which membrane surface is catalytically modified. The platinum increases the water flux on the feed side whilst it decreases the flux on the permeate side. Water flux measurements suggest that platinum can block water permeation on the permeate side by reducing the access to the lattice oxygen in the surface layer.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.27 no.3
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• pp.67-74
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• 2024

In the context of rapid temperature rise in mid-to-high latitude regions, cold region wetlands have become a hotspot for current wetland carbon cycle research due to their high sensitivity to climate change. Strengthening the monitoring of CO₂ fluxes in wetland ecosystems is of great practical significance for clarifying the carbon balance of wetlands and maintaining the ecological balance of wetland ecosystems in China's high latitude regions. In this study, the carbon flux (NEE, Net ecosystem exchange; GPP, Gross Primary Production; RECO, Ecosystem response) of Jingxin Wetland was monitored by eddy correlation method from August 2021 to March 2024.2022-2023 shows CO₂ sinks, absorbing 349.4 g C·m^-2·yr^-1 annually. The correlation analysis showed that Ta, VPD and PPFD were the main environmental factors affecting CO₂ flux in Jingxin wetland.

• Membrane and Water Treatment
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• v.13 no.4
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• pp.191-199
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• 2022

In industrial production, the development of traditional polyamide nanofiltration (NF) membrane was limited due to its poor oxidation resistance, complex preparation process and high cost. In this study, a composite NF membrane with high flux, high separation performance, high oxidation resistance and simple process preparation was prepared by the method of dilute solution dip coating. And the sulfonated polysulfone was used for dip coating. The results indicated that the concentration of glycerin, the pore size of the based membrane, the composition of the coating solution, and the post-treatment process had important effects on the structure and performance of the composite NF membrane. The composite NF membrane prepared without glycerol protecting based membrane had a low flux, when the concentration of glycerin increased from 5% to 15%, the pure water flux of the composite NF membrane increased from 46.4 LMH to 108.2 LMH, and the salt rejection rate did not change much. By optimizing the coating system, the rejection rate of Na₂SO₄ and PEG1000 was higher than 90%, the pure water flux was higher than 40 LMH (60psi), and it can withstand 20,000 ppm.h NaClO solution cleaning. When the post treatment processes was adjusted, the salt rejection rate of NaCl solution (250 ppm) reached 45.5%, and the flux reached 62.2 LMH.