• 제목/요약/키워드: CNT dispersion solution

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스트레치 센서를 이용한 스쿼트 시 발목 가동범위 체크 센서 양말에 관하여 -20대 후반 남성을 중심으로- (Using a Stretch Sensor About of Squat Ankle Range of Motion Check Socks -Focusing on Men in Their Late 20s-)

  • 송관우;박진희;김주용
    • 패션비즈니스
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    • 제26권2호
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    • pp.129-142
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    • 2022
  • The purpose of this study is to develop socks to check the range of ankle movement during squats for men in their late 20s. Sensors of 6, 8, and 12 mm were selected, and each sample was impregnated 1 to 3 times. It was prepared using a CNT dispersion, and the GF value was measured using UTM. Among them, the sample with 2 impregnation showed the best GF value. As a result of applying each sample to the socks, the 12 mm sensor was wider than the area of the Achilles tendon, resulting in noise, and the 8 mm sensor was higher than the tensile strength of the socks, resulting in a decrease in the graph. Therefore, testing was performed using a 6 mm sensor. In order to determine the effectiveness of the sensor, the normal operating range was checked through squats, and significant changes were confirmed when the operating range was checked again through squats by performing operations that can increase the operating range through Gastrocnemius, Soleus stretching, and low lunge. Using the results of this study, it is expected that the average value of the ankle movement range of the user is checked prevent injury, to be provided as basic data for the production of shoe products and the promotion of physical health.

다양한 계면활성제를 이용한 고순도 단일벽 탄소나노튜브의 수계 분산 (Dispersion of Highly Pure Single-Walled Carbon Nanotube in Aqueous Solution of Various Surfactants)

  • 곽정춘;김명수;이내성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.153-153
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    • 2008
  • Practical application of single-walled carbon nanotubes (SWCNTs) qualified as a promising material has been limited by either poor dispersion or their insolubility in aqueous or organic media due to formation of bundling by relatively high surface energy. Thus, major attention to overcome this issue has been paid at surface modification of CNTs by functionalization, but this introduces defects to the sidewall of CNTs, consequently perturbing the inherent electronic and optical properties. Therefore, using surfactants is a general approach to disperse SWCNTs with lower damages by which bundled nanotubes could be dispersed up to the level of individuals or small bundles. Here, we have investigated various surfactants for their efficiency in dissolving purified SWCNTs produced by arc discharge in deionized water. To compare the surfactants respectively, we have determined the least amount of each surfactant to suspend the nanotubes under optimized experimental conditions(CNT amount, sonication power, and centrifugation speed, etc.) set on the basis of the most common surfactant (sodium dodecyl sulfate, SDS) and discussed the qualitative and quantitative characterization of SWCNT dispersions by UV-Vis absorption spectroscopy. Quantitative aspect about nanotube dispersion was that in particular N-methyl-2-pyrrolidone (NMP) and sodium dodecylbenzene sulfonate (NaDDBS) were found to be effective in dispersing individual tubes.

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Transparent Conducting Film for Flat Panel Display using CNT by Electrospinning

  • Moon, Jin-San;Park, Jae-Hong;Han, Jae-Hee;Berdinsky, Alexander S.;Nam, Jae-Do;Lee, Dae-Hoi;Yoo, Ji-Beom
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.978-980
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    • 2004
  • We report the preparation and properties of polymer paste solutions with CNTs using conventional paste forming process. Electrospinning has been used for the fabrication of nano-fiber composite. In this process, dispersion of CNTs is very important matter. So, we emphasize the necessity of dispersion of CNTs in the solution and investigate effects of process parameters of electrospinning. The advantage of simple electrospinning process will be discussed..

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The Preparation of Multi-walled CNT-PMMA Nanocomposite

  • Seo, D.W.;Yoon, W.J.;Park, S.J.;Jo, M.C.;Kim, J.S.
    • Carbon letters
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    • 제7권4호
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    • pp.266-270
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    • 2006
  • Multi-walled carbon nanotube-poly methyl methacrylate (MWNT/PMMA) nanocomposite has been prepared by in situ polymerization of MMA dispersed with MWNTs. The MWNTs were functionalized by nitric acid and sulfuric acid treatment, and this was confirmed by FTIR spectrometer. The solution mixture of MWNTs and MMA was partially polymerized at $80^{\circ}C$, followed by the addition of AIBN and polymerization at $50^{\circ}C$. The MWNT-PMMA composite was prepared by casting the pre-polymer on the glass plate, and the optical properties have been studied using UV-vis spectrometer. The acid treated MWNTs were well dispersed in MMA with fairly good dispersion stability, while flocculation and sedimentation was observed from raw MWNTs in MMA.

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탄소계 나노소재를 적용한 시멘트 페이스트 복합체의 유변학적 특성에 대한 연구 (Experimental Study on the Reological Properties of Carbon Nano Materials as Cement Composites)

  • 김원우;문재흠;양근혁
    • 한국건설순환자원학회논문집
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    • 제10권3호
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    • pp.227-234
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    • 2022
  • 본 연구에서는 탄소계 나노소재를 적용한 시멘트 페이스트 복합체의 유변학적 특성을 실험적으로 분석하였다. 탄소계 나노소재인 산화그래핀과 탄소나노튜브의 사용성을 고려하여 수용액 상태로 혼입한 굳기전 시멘트 페이스트에서 흐름성 및 레올로지를 측정하였다. 그리고 굳은 시멘트 페이스트 복합체는 만능재료 실험기를 활용하여 압축강도 측정을 검토하였다. 산화그래핀은 수용액 상태로 혼입하였을 때 혼입율 상승 시 흐름성이 감소하고 소성 점도와 전단응력이 급격하게 증가하였다. 탄소나노튜브 수용액도 동일한 경향성을 가졌으나 시멘트 중량대비 0.2 % 미만을 혼입한 경우 산화그래핀과 비교하여 상대적으로 증가율이 낮게 측정되었다. 이는 판상형 형태인 그래핀의 비표면적이 커서 시멘트 페이스트의 흐름성을 감소시키고 소성 점도와 전단응력을 상승시키는 것으로 판단된다. 탄소나노튜브 수용액은 0.2 %이상 혼입 시 소성점도가 일반배합 대비 2.16배 수준으로 급격히 상승하며 전단응력도 상대적으로 높게 측정되었다. 이는 탄소나노튜브의 혼입량이 과혼입 되면서 시멘트 페이스트 내에서 분산이 제대로 되지 않아 탄소나노튜브 간의 뭉침으로 인한 응집효과로 판단된다. 압축강도는 그래핀 혼입시 강도 상승율이 미미하였으며, CNT는 최대 약 12 %의 상승효과가 있음을 확인하였다. 따라서 탄소계나노소재 적용 시 상대적으로 CNT를 사용할 경우가 사용 가능성이 높을 것으로 판단되나 최대 혼입량 및 분산에 사용될 계면활성제에 대한 추가적인 연구가 필요할 것으로 판단된다.

루어낚시 참여자의 손목 움직임 측정을 위한 스트레치 센서 개발 (The Development of Stretch Sensors for Measuring the Wrist Movements for People Using Fishing Lures)

  • 최윤성;박진희;김주용
    • 감성과학
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    • 제25권3호
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    • pp.77-90
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    • 2022
  • 본 연구의 목적은 루어낚시 참여자의 손목 움직임 측정을 위한 스트레치 센서를 개발하는 것이다. 손목움직임 측정을 위해 스트레치 센서를 손목에 부착하여 배굴, 저굴 그리고 랜딩동작을 게이지율, 인장강도 그리고 신장회복률을 척도로 실험을 진행하였다. CNT 분산액을 이용한 전도성 센서를 개발하고 E-band에 동일한 조건으로 적용하였다. 함침을 각각 한 번, 두 번, 그리고 세 번한 같은 크기의 5종, 15가지 센서를 만능재료시험기(Dacell dn-fga Universal testing machine, UTM)를 활용해 게이지율(Gauge Factor)을 측정하였다. 두 번 함침한 센서가 게이지율이 가장 우수했으며, 게이지율과 인장강도가 높은 세 가지 센서로 프로토 타입을 제작하였다. 아두이노에 연결하여 동작테스트를 한 결과, 인장강도와 게이지율이 가장 높은 시료 1이 세 가지 동작에서 일정한 파장이 유지되었다. 시료 2,3은 배굴과 저굴에서는 일정한 파장을 나타내었지만, 랜딩동작에서는 신호 노이즈가 나타났다. 이는, 랜딩동작에서는 인장강도와, 게이지율에 따라 파장의 패턴이 다르게 나타나는 것을 알 수 있었다. 이와 같은 결과로 손목의 움직임 측정을 위한 스트레치 센서 제작시에 필요한 조건들을 유추할 수 있었다. 본 연구의 결과를 활용하여 루어낚시용 스마트 웨어러블 제품 개발에 응용이 가능할 것으로 사료된다.

Butyl 및 Hexyl기가 도입된 다중벽 탄소나노튜브의 분산성 (Dispersibility of multi-walled carbon nanotubes functionalized with butyl and hexyl group)

  • 유정현;남병욱
    • 한국산학기술학회논문지
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    • 제11권7호
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    • pp.2713-2718
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    • 2010
  • 탄소나노튜브의 분산성을 개선하고자 다중벽 탄소나노튜브(multi-walled carbon nanotube, MWNT)를 초음파 반응기에서 butyllithium 및 hexyllithium solution을 이용하여 표면을 화학적으로 개질하였다. 개질된 MWNT는 적외선 분광분석 및 라만분광법을 이용하여 MWNT에 알킬기가 도입되었는지를 확인하였다. 또한, 열중량분석기를 이용하여 알킬기가 MWNT에 도입된 함량을 분석하였으며, MWNT 및 개질된 MWNT를 다양한 용매에 따른 분산성을 조사하였다. 그 결과 유기물의 함량은 5% 내외로 분석되었고 일정 범위내의 용해도 상수를 갖는 용매에 분산성이 개선됨을 확인하였다.

Multiwalled Carbon Nanotubes Functionalized with PS via Emulsion Polymerization

  • Park, In-Cheol;Park, Min;Kim, Jun-Kyung;Lee, Hyun-Jung;Lee, Moo-Sung
    • Macromolecular Research
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    • 제15권6호
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    • pp.498-505
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    • 2007
  • This study demonstrated the in-situ functionalization with polymers of multi-walled carbon nanotubes (MWNTs) via emulsion polymerization. Polystyrene-functionalized MWNTs were prepared in an aqueous solution containing styrene monomer, non-ionic surfactant and a cationic coupling agent ([2-(methacryloyloxy)ethyl]trime-thylammonium chloride (MATMAC)). This process produced an interesting morphology in which the MWNTs, consisting of bead-string shapes or MWNTs embedded in the beads, when polymer beads were sufficiently large, produced nanohybrid material. This morphology was attributed to the interaction between the cationic coupling agent and the nanotube surface which induced polymerization within the hemimicellar or hemicylindrical structures of surfactant micelles on the surface of the nanotubes. In a solution containing MATMAC alone without surfactant, carbon nanotubes (CNTs) were not well-dispersed, and in a solution containing only surfactant without MATMAC, polymeric beads were synthesized in isolation from CNTs and continued to exist separately. The incorporation of MATMAC and surfactant together enabled large amounts of CNTs (> 0.05 wt%) to be well-dispersed in water and very effectively encapsulated by polymer chains. This method could be applied to other well-dispersed CNT solutions containing amphiphilic molecules, regardless of the type (i.e., anionic, cationic or nonionic). In this way, the solubility and dispersion of nanotubes could be increased in a solvent or polymer matrix. By enhancing the interfacial adhesion, this method might also contribute to the improved dispersion of nanotubes in a polymer matrix and thus the creation of superior polymer nanocomposites.

초음파처리를 통한 탄소나노튜브 분산용액 제조 및 시멘트 페이스트의 적용성 평가 (Production of Carbon Nanotube Dispersion Solution Using the Ultrasonic Treatment and Applicability Evaluation on the Cement Paste)

  • 박성환;김지현;정철우
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 가을 학술논문 발표대회
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    • pp.174-175
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    • 2021
  • Currently, the construction structures become larger and more high-performance in modern society, demands for ultra-high strength and light weight construction materials are increasing rapidly. Therefore, this study aims to confirm the applicability of nanomixed cement supplemented with physical and mechanical properties using nanomaterials.Changes in compressive strength and properties were analyzed according to the ratio of cement paste and dispersant (PCE) made by ultrasonication of carbon nanotubes (CNT)

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Ultrasonic waves in a single walled armchair carbon nanotube resting on nonlinear foundation subjected to thermal and in plane magnetic fields

  • Selvamani, Rajendran;Jayan, M. Mahaveer Sree;Ebrahimi, Farzad
    • Coupled systems mechanics
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    • 제10권1호
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    • pp.39-60
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    • 2021
  • The present paper is concerned with the study of nonlinear ultrasonic waves in a magneto thermo (MT) elastic armchair single-walled carbon nanotube (ASWCNT) resting on polymer matrix. The analytical formulation is developed based on Eringen's nonlocal elasticity theory to account small scale effect. After developing the formal solution of the mathematical model consisting of partial differential equations, the frequency equations have been analyzed numerically by using the nonlinear foundations supported by Winkler-Pasternak model. The solution is obtained by ultrasonic wave dispersion relations. Parametric work is carried out to scrutinize the influence of the non local scaling, magneto-mechanical loadings, foundation parameters, various boundary condition and length on the dimensionless frequency of nanotube. It is noticed that the boundary conditions, nonlocal parameter, and tube geometrical parameters have significant effects on dimensionless frequency of nano tubes. The results presented in this study can provide mechanism for the study and design of the nano devices like component of nano oscillators, micro wave absorbing, nano-electron technology and nano-electro- magneto-mechanical systems (NEMMS) that make use of the wave propagation properties of armchair single-walled carbon nanotubes embedded on polymer matrix.