• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.67-67
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• 2011

Compound semiconductor/CNTs composites have shown considerably improved efficiency improvement in photovoltaic devices, which is often attributed to two different factors. One is the formation of efficient electronic energy cascade structures. The other effect of CNTs on the performance of photovoltaic devices is the decrement of interfacial resistance. The interfacial resistances at n-type/ p-type materials and/or n-type materials/TCO electrode are reduced by an outstanding electrical property of CNTs. In addition to the effects of CNTs, we report the third reason for increment of efficiency in photovoltaic devices by CNT's well-known electrical field enhancement effects. The improved ${\beta}$ values in reverse-FE currents of CIGS electrode with SWNTs layers indicate the enhancement of electrical field in photovoltaic devices, which implies the acceleration of the electron transfer rate in the cell. Due to the formation of an efficient electronic energy cascade structure and the decrease of the interfacial resistance as well as the improvement of the electrical field in the photovoltaic devices, the power conversion efficiency of electrochemically deposited superstrate-type CIGS solar cells was increased 24.3% in the presence of SWNTs and showed 10.40% conversion efficiency.

• Carbon letters
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• v.7 no.4
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• pp.266-270
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• 2006

Multi-walled carbon nanotube-poly methyl methacrylate (MWNT/PMMA) nanocomposite has been prepared by in situ polymerization of MMA dispersed with MWNTs. The MWNTs were functionalized by nitric acid and sulfuric acid treatment, and this was confirmed by FTIR spectrometer. The solution mixture of MWNTs and MMA was partially polymerized at $80^{\circ}C$, followed by the addition of AIBN and polymerization at $50^{\circ}C$. The MWNT-PMMA composite was prepared by casting the pre-polymer on the glass plate, and the optical properties have been studied using UV-vis spectrometer. The acid treated MWNTs were well dispersed in MMA with fairly good dispersion stability, while flocculation and sedimentation was observed from raw MWNTs in MMA.

• Advances in concrete construction
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• v.3 no.1
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• pp.15-37
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• 2015

Ongoing efforts for improved fracture toughness of engineered cementitious materials address the inherent brittleness of the binding matrix at several different levels of the material's geometric scale through the addition of various types of reinforcing fibers. Crack control is required for crack widths that cover the entire range of the grain size spectrum of the material, and this dictates the requirement of hybrid mixes combining fibers of different size (nano, micro, macro). Use of Carbon Nano-Tubes (CNT) and Carbon Nano-Fibers (CNFs) as additives is meant to extend the crack-control function down to the nanoscale where cracking is believed to initiate. In this paper the implications of enhanced toughness thus attained at the material nanostructure are explored, with reference to the global smeared constitutive properties of the material, through consistent interpretation of the reported experimental evidence regarding the behavior of engineered cementitious products to direct and indirect tension.

• International Journal of Aeronautical and Space Sciences
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• v.12 no.2
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• pp.115-133
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• 2011

Fiber reinforced polymer composites (FRPs) are being increasingly used for a wide range of engineering applications owing to their high specific strength and stiffness. However, their through-the-thickness performance lacks some of the most demanding physical and mechanical property requirements for structural applications, such as aerospace vehicles and military components. Carbon nanotubes (CNTs) and carbon nanofibers (CNFs), due to their excellent mechanical, thermal and electrical properties, offer great promise to improve the weak properties in the thickness direction and impart multi-functionality without substantial weight addition to FRPs. This paper reviews the progress made to date on i) the techniques developed for integration of CNTs/ CNFs into FRPs, and ii) the effects of the addition of these nanofillers on the interlaminar properties, such as such interlaminar shear strength, interlaminar fracture toughness and impact damage resistance and tolerance, of FRPs. The key challenges and future prospects in the development of multiscale CNT-FRP composites for advanced applications are also highlighted.

• Steel and Composite Structures
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• v.47 no.1
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• pp.1-17
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• 2023

This paper deals with the free vibration behavior of rotating composite beams reinforced with carbon nanotubes (CNTs) under uniform thermal loads. The temperature-dependent beam material is assumed to be a mixture of single-walled carbon nanotubes (SWCNTs) in an isotropic matrix and five different functionally graded (FG) distributions of CNTs are considered according to the variation along the thickness, namely the UD-uniform, FG-O, FG-V, FG-Λ and FG-X distributions where FG-V and FG-Λ are unsymmetrical patterns. Considering the Timoshenko beam theory (TBT), a new finite element formulation of functionally graded carbon nanotube reinforced composite (FGCNTRC) beam is created for the first time. And the effects of several essential parameters including rotational speed, hub radius, effective material properties, slenderness ratio, boundary conditions, thermal force and moments due to temperature variation are considered in the formulation. By implementing different boundary conditions, some new results of both symmetric and non-symmetrical distribution patterns are presented in tables and figures to be used as benchmark for further validation. In addition, as an alternative advanced composite application for rotating systems exposed to thermal load, the positive effects of CNT addition in improving the dynamic performance of the system have been observed and the results are presented in several tables and figures.

• Journal of Environmental Science International
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• v.25 no.4
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• pp.505-516
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• 2016

With the development of nanotechnology, nanomaterials are used in various fields. Therefore, the interest regarding the safety of nanomaterial use is increasing and much effort is diverted toward establishment of exposure assessment and management methods. Occupational exposure limits (OELs) are effectively used to protect the health of workers in various industrial workplaces. This study aimed to propose an OEL for domestic multi-walled carbon nanotubes (MWCNTs) based on animal inhalation toxicity test. Basic procedure for development of OELs was examined. For OEL estimation, epidemiological study and quantitative risk assessment are generally performed based on toxicity data. In addition, inhalation toxicity data-based no observed adverse effect level (NOAEL) and benchmark dose (BMD) are estimated to obtain the OEL. Three different estimation processes (NEDO in Japan, NIOSH in USA, and Baytubes in Germany) of OELs for carbon nanotubes (CNTs) were intensively reviewed. From the rat inhalation toxicity test for MWCNTs manufactured in Korea, a NOAEL of $0.98mg/m^3$ was derived. Using the simple equation for estimation of OEL suggested by NEDO, the OEL of $142{\mu}g/m^3$ was estimated for the MWCNT manufacturing workplace. Here, we used test rat and Korean human data and adopted 36 as an uncertainty factor. The OEL for MWCNT estimated in this work is higher than those ($2-80{\mu}g/m^3$) suggested by previous investigators. It may be greatly caused by different physicochemical properties of MWCNT and their dispersion method and test rat data. For setting of regulatory OELs in CNT workplaces, further epidemiological studies in addition to animal studies are needed. More advanced technical methods such as CNT dispersion in air and liquid should be also developed.

• Science of Emotion and Sensibility
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• v.22 no.4
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• pp.97-106
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• 2019

The purpose of this study was to investigate the effect of the type and measurement location of a fabric strain gauge sensor on the detection performance for respiratory signals. We implemented two types of sensors to measure the respiratory signal and attached them to a band to detect the respiratory signal. Eight healthy males in their 20s were the subject of this study. They were asked to wear two respiratory bands in turns. While the subjects were measured for 30 seconds standing comfortably, the respiratory was given at 15 breaths per minute were synchronized, and then a 10-second break; subsequently, the entire measurement was repeated. Measurement locations were at the chest and abdomen. In addition, to verify the performance of respiratory measurement in the movement state, the subjects were asked to walk in place at a speed of 80 strides per minute(SPM), and the respiratory was measured using the same method mentioned earlier. Meanwhile, to acquire a reference signal, the SS5LB of BIOPAC Systems, Inc., was worn by the subjects simultaneously with the experimental sensor. The Kruskal-Wallis test and Bonferroni post hoc tests were performed using SPSS 24.0 to verify the difference in measurement performances among the group of eight combinations of sensor types, measurement locations, and movement states. In addition, the Wilcoxon test was conducted to examine whether there are differences according to sensor type, measurement location, and movement state. The results showed that the respiratory signal detection performance was the best when the respiratory was measured in the chest using the CNT-coated fabric sensor regardless of the movement state. Based on the results of this study, we will develop a chest belt-type wearable platform that can monitor the various vital signal in real time without disturbing the movements in an outdoor environment or in daily activities.

• Bulletin of the Korean Chemical Society
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• v.27 no.6
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• pp.841-846
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• 2006

$Y_2O_2S$:Eu phosphors were synthesized via solid-state reactions. $Y_2O_2S$:Eu phosphor particles of various sizes were obtained by varying the firing temperature and firing time. The photoluminescence properties of these $Y_2O_2S$:Eu phosphors were examined. In addition, the cathodoluminescence properties of the $Y_2O_2S$:Eu phosphors were examined for applied voltages of 3-8 kV. The relationship between the luminescence intensity and particle size of the$Y_2O_2S$:Eu phosphors was investigated. The photoluminescence and cathodoluminescence of the $Y_2O_2S$:Eu phosphors are affected differently by variations in particle size.

• Journal of the Korean Vacuum Society
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• v.16 no.1
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• pp.33-39
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• 2007

Electrical and mechanical modifications of devices based on carbon nanotubes(CNTs) using an atomic force microscope(AFM) in the forms of cutting and reconnection of CNTs are demonstrated. In addition to the modifications, electrostatic force microscopy is used to visualize the cutting and reconnection of CNTs. In this way, AFM is shown to be a useful tool in local modifications and manipulations of CNT-based devices.

• Polymer(Korea)
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• v.37 no.3
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• pp.342-346
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• 2013

In this study, it was attempted to disperse carbon nanotubes (CNTs) in a polymer matrix using a twin-screw extruder which was good for dispersing fillers of micron sizes but not suitable for dispersing nanometer-sized materials. Improved dispersion of CNTs could be achieved by the addition of inorganic fillers with different geometrical shapes. An increase in the matrix viscosity provided a high shear stress on aggregated CNTs, leading to a good dispersion of CNTs. The presence of the inorganic fillers was supposed to suppress the re-aggregation of CNTs in the regions where a lower shear stress was applied. As a result, the CNTs dispersion was well stabilized.