• Title/Summary/Keyword: CNF

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Feature-based Korean Phrase Structure Grammar adjusting X-bar Theory (X-바 이론을 변형한 자질기반의 한국어 구구조 문법)

  • Park, So-Young;Hwang, Young-Sook;Chung, Hoo-Jung;Kwak, Yong-Jae;Rim, Hae-Chabg
    • Annual Conference on Human and Language Technology
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    • 1998.10c
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    • pp.222-229
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    • 1998
  • 본 논문에서는 X-바 이론을 한국어에 적용하여 서로 다른 범주들간의 구조적 일반성을 파악하고, 한국어에 가능한 규칙만을 허용하여 불가능한 규칙을 배제시킬 수 있는 틀을 제시하고자 한다. 한국어가 비중심어간 어순이 자유롭고 기능어가 발달했다는 점을 고려하여, 중심어와 보충어 관계 중심의 기존 X-바 이론을 통사적 파생과 의미적 파생, 수식 및 하위범주의 관계를 중심으로 변형한다. 또한, 한국어의 빈번한 생략현상과 부분 자유 어순에 효과적으로 대응할 수 있도록 이진결합 중심의 CNF(Chomsky Normal Form)를 따른다. 제안하는 자질기반의 한국어 구구조 문법은 직관적이고 간단하면서도 대부분의 문장을 처리할 수 있을 만큼 표현력이 뛰어나다는 장점이 있다. 신문기사에서 454문장을 추출하여 실험한 결과, 약 97%의 문장에 대해 올바른 구문 분석 결과를 생성할 수 있음을 보였다.

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Fabrication and Cell Culturing on Carbon Nanofibers/Nanoparticles Reinforced Membranes for Bone-Tissue Regeneration

  • Deng, Xu Liang;Yang, Xiao Ping
    • Carbon letters
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    • v.13 no.3
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    • pp.139-150
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    • 2012
  • Poly-L-lactic acid (PLLA), PLLA/hydroxyapatite (HA), PLLA/multiwalled carbon nanotubes (MWNTs)/HA, PLLA/trifluoroethanol (TFE), PLLA/gelatin, and carbon nanofibers (CNFs)/${\beta}$-tricalcium phosphate (${\beta}$-TCP) composite membranes (scaffolds) were fabricated by electrospinning and their morphologies, and mechanical properties were characterized for use in bone tissue regeneration/guided tissue regeneration. MWNTs and HA nanoparticles were well distributed in the membranes and the degradation characteristics were improved. PLLA/MWNTs/HA membranes enhanced the adhesion and proliferation of periodontal ligament cells (PDLCs) by 30% and inhibited the adhesion of gingival epithelial cells by 30%. Osteoblast-like MG-63 cells on the randomly fiber oriented PLLA/TEF membrane showed irregular forms, while the cells exhibited shuttle-like shapes on the parallel fiber oriented membrane. Classical supersaturated simulated body fluids were modified by $CO_2$ bubbling and applied to promote the biomineralization of the PLLA/gelatin membrane; this resulted in predictions of bone bonding bioactivity of the substrates. The ${\beta}$-TCP membranes exhibit good biocompatibility, have an effect on PDLC growth comparable to that of pure CNF membrane, and can be applied as scaffolds for bone tissue regeneration.

Structural evolution and kinetic study of high isotacticity poly(acrylonitrile) during isothermal pre-oxidation

  • Zhang, Li;Dai, Yongqiang;Kai, Yi;Jin, Ri-Guang
    • Carbon letters
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    • v.12 no.4
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    • pp.229-235
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    • 2011
  • Isotactic polyacrylonitrile (PAN) with triad isotacticity of 0.53, which was determined by $^{13}C$ NMR, using dialkylmagnesium as an initiator, was successfully synthesized. Isothermal treatment of iso-PAN was conducted in air at 200, 220, 250 and $280^{\circ}C$. Structural evolutions and chemical changes were studied with Fourier transformation infrared and wide-angle X-ray diffraction during stabilization. A new parameter $CNF={I_{2240cm}}^{-1}/ ({I_{1595cm}}^{-1}+f^*{I_{1595cm}}^{-1})$ was defined to evaluate residual nitrile groups. Crystallinity and crystal size were calculated with X-ray diffraction dates. The results indicated that the nitrile groups had partly converted into a ladder structure as stabilization proceeded. The rate of reaction increased with treatment temperature; crystallinity and crystal size decreased proportionally to pyrolysis temperature. The iso-conversional method coupled with the Kissinger and Flynn-Wall-Ozawa methods were used to determine kinetic parameters via differential scanning calorimetry analysis with different heating rates. The active energy of the reaction was 171.1 and 169.1 kJ/mol, calculated with the two methods respectively and implied the sensitivity of the reaction with temperature.

Nondestructive Sensing Evaluation of Thermal Treated Carbon Nanotube and Nanofiber/Epoxy Composites Using Electrical Resistance Measurement (전기저항 측정 방법을 이용한 표면 처리된 탄소 나노튜브와 나노 섬유 강화된 에폭시 복합재료의 비파괴적 감지능 평가)

  • Jung Jin-Kyu;Park Joung-Man;Kim Dae-Sik;Kim Tae-Wook
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.15-18
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    • 2004
  • Nondestructive damage sensing and mechanical properties for thermal treated carbon nanotube(CNT) and nanofiber(CNF)/epoxy composites were investigated using electro-micromechanical technique. Carbon black (CB) was used only for the comparison. Electro-micromechanical techniques were applied to obtain the fiber damage and stress transferring effect of carbon nanocomposites with their contents. Thermal treatment and temperature affected on apparent modulus and electrical properties on nanocomposites due to enhanced inherent properties of each CNMs. Coefficient of variation (COV) of volumetric electrical resistance can be used to obtain the dispersion degree indirectly for various CNMs. Dispersion and surface modification are very important parameters to obtain improved mechanical and electrical properties of CNMs for multifunctional applications. Further optimized functionalization and dispersion conditions will be investigated for the following work continuously.

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Nondestructive Sensing Evaluation of Electrospun PVDF Fiber and Carbon Nanotube/Epoxy Composites Using Electro-Micromechanical Technique (Electro-Micromechanical 시험법을 이용한 Electrospun PVDF Fiber 및 CNT 강화 Epoxy 복합재료의 비파괴 감지능 평가)

  • Jung, Jin-Gyu;Kim, Sung-Ju;Park, Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.153-156
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    • 2005
  • Nondestructive sensing of electrospun PYDF web and multi-wall carbon nanotube (MWCNT)/epoxy composites were investigated using electro-micromechanical technique. Electrospinning is a technique used to produce micron to submicron diameter polymeric fibers. Electrospun PVDF web was also evaluated for the sensing properties by micromechanical test and by measurement electrical resistance. CNT composite was especially prepared for high volume contents, 50 vol% of reinforcement. Electrical contact resistivity on humidity sensing was a good indicator for monitoring as for multifunctional applications. Work of adhesion using contact angle measurement was studied to correlate acid-base surface energy between carbon fiber and CNF composites, and will study furher for interfacial adhesion force by micromechanical test.

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Manipulation of Surface Carboxyl Content on TEMPO-Oxidized Cellulose Fibrils

  • Masruchin, Nanang;Park, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.5
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    • pp.613-627
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    • 2015
  • Simple methods of conductometric titration and infrared spectroscopy were used to quantify the surface carboxyl content of cellulose fibrils isolated by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation. The effects of different cellulose sources, post or assisted-sonication oxidation treatment, and the amount of sodium hypochlorite addition on the carboxyl content of cellulose were reported. This study showed that post sonication treatment had no influence on the improvement of surface carboxyl charge of cellulose macrofibrils (CMFs). However, the carboxyl content increased for the isolated cellulose nanofibrils (CNFs). Thus the carboxyl content of CNFs is different from those of their corresponding bulk oxidized cellulose and CMFs. Filter paper as a CNF source imparted a higher surface charge than did hardwood bleached kraft pulp (HWBKP) and microcrystalline cellulose (MCC). It was considered that the crystallinity and microstructure of the initial cellulose affected oxidation efficiency. In addition, the carboxyl content of cellulose was successfully controlled by applying sonication treatment during the oxidation reaction and adjusting the amount of sodium hypochlorite.

Improved conductivity of transparent single-wall carbon nanotube-based thin films on glass

  • Min, Hyeong-Seop;Choe, Won-Guk;Kim, Sang-Sik;Lee, Jeon-Guk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.55.1-55.1
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    • 2010
  • 차세대 디스플레이용 전극 재료는 투명하면서도 낮은 저항값을 가져야 하는 투명 전극 재료로 금속, 금속산화물, 전도성 고분자, 탄소재료 등을 들 수 있다. 금속재료는 전도도는 우수하지만, 낮은 투과도로 투명전극 재료로 적절하지 않고, 대표적인 금속산화물 재료인 indium tin oxide (ITO)의 경우, 우수한 투과성과 낮은 면저항을 기반으로 차세대 디스플레이용 전극으로 현재 사용되고 있다. 하지만 ITO 박막은 휘거나 접을 때 기계적 안정성이 취약한 문제점을 나타내고 있다. 이러한 문제점을 극복하기 위해 전도성과 탄성계수가 높고, 저온에서 대면적 공정이 가능한 CNT을 투명 박막 전극 연구가 활발히 진행되고 있다. 하지만 투명전극 제조시, 탄소 나노튜브 간의 van der waals 인력에 의한 응집 현상으로 인한 분산의 불안정성과 분산제 사용으로 인하여 탄소 나노튜브 박막전극의 전기적, 광학적 특성이 저하를 야기한다. 이에 본 실험에서는 아크 방전 공정으로 합성한 SWCNT 분산액을 사용하여 spray coating 방법으로 glass 위에 박막을 형성하였다. SWCNT 투명 박막 전극 위에 DC sputtering을 이용하여 얇은Ni를 도포한 후, $450{\sim}500^{\circ}C$, ethylene gas 분위기의 thermal CVD방법으로 Carbon NanoFibers (CNFs)를 생성시킴과 동시에 분산제를 burning out하였다. CNF 성장 전후의 투명 박막의 전기적 특성은 four point probe를 이용하여 면저항과 UV-vis 장비를 이용하여 가시광선 영역에서의 광학적 투과도를 측정 비교하였다.

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Evaluation of Material Properties about CFRP Composite Adapted for Wind Power Blade by using DIC Method (풍력발전기 블레이드 적용 CFRP 복합재료의 DIC 방법에 의한 재료특성치 평가)

  • Kang, J.W.;Kwon, O.H.;Kim, T.K.;Cho, S.J.
    • Journal of Power System Engineering
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    • v.14 no.5
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    • pp.17-23
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    • 2010
  • In recent, the capacity of a commercial wind power has reached the range of 6 MW, with large plants being built world-wide on land and offshore. The rotor blades and the nacelle are exposed to external loads. Wind power system concepts are reviewed, and loadings by wind and gravity as important factors for the mechanical performance of the materials are considered. So, the mechanical properties of fiber composite materials are discussed. Plain woven fabrics Carbon Fiber Reinforced Plastics (CFRP) are advanced materials which combine the characteristics of the light weight, high stiffness, strength and chemical stability. However, Plain woven CFRP composite have a lot of problems, especially delamination, compared with common materials. Therefore, the aim of this work is to estimate the mechanical properties using the tensile specimen and to evaluate strain using the CNF specimen on plain woven CFRP composites. For the strain, we tried to apply to plain woven CFRP using Digital Image Correlation (DIC) method and strain gauge. DIC method can evaluate a strain change so it can predict a location of fracture.

Transfer of Antimicrobial-Resistant Escherichia coli and Resistance Genes in a Child Care Center

  • Hong, Hyunjin;Lee, Yeonhee
    • Journal of Microbiology and Biotechnology
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    • v.29 no.3
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    • pp.465-472
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    • 2019
  • Several reports describe antimicrobial-resistance transfer among children and the community in outbreak situations, but transfer between a child and a caregiver has not been examined in child care facilities under normal circumstances. We investigated the transfer of antimicrobial-resistance genes, resistant bacteria, or both among healthy children and teachers. From 2007 to 2009, 104 Escherichia coli isolates were obtained from four teachers and 38 children in a child care center. Twenty-six cephem-resistant isolates were obtained from children in 2007 and 2008. In 2009, cephem-resistant isolates were detected in children as well as a teacher. Nalidixic acid-resistant isolates from the same teacher for 3 years showed low similarity (<50%) to each other. However, an isolate from a teacher in 2007 and another from a child in 2008 showed high similarity (87%). Pulsed-field gel electrophoresis revealed 100% similarity for four isolates in 2007 and one isolate in 2008, and also similarity among seven isolates carrying the virulence gene (CNF1). This study yielded the following findings: (1) a gene for extended-spectrum ${\beta}$-lactamase was transferred from a child to other children and a teacher; (2) a nalidixic acid-resistant isolate was transferred from a teacher to a child; and (3) a virulent bacterium was transferred between children.

Interfacial Properties and Sensing of Carbon Nanofiber/Tube and Electrospun Nanofiber/Epoxy Composites Using Electrical Resistance Measurement and Micromechanical Technique (전기저항측정 및 미세역학시험법을 이용한 탄소나노섬유/튜브 및 전기방사된 나노섬유/에폭시 복합재료의 계면특성 및 감지능 연구)

  • Jung Jin-Gyu;Kim Sung-Ju;Park Joung-Man
    • Composites Research
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    • v.18 no.4
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    • pp.21-26
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    • 2005
  • Nondestructive damage sensing and load transfer mechanisms of carbon nanotube (CNT) and nanofiber (CNF)/epoxy composites have been investigated by using electro-micromechanical technique. The electrospun PVDF nanofibers were also prepared as a piezoelectric sensor. The electro-micromechanical techniques were applied to evaluate sensing response of carbon nanocomposites by measuring electrical resistance under an uniform cyclic loading. Composites with higher volume content of CNT showed significantly higher tensile properties than neat and low volume$\%$ CNT composites. CNT composites showed humidity sensing within limited temperature range. CNT composites with smaller aspect ratio showed higher apparent modulus due to high volume content in case of shorter aspect ratio. Thermal treated electrospun PVDF nanofiber showed higher mechanical properties than the untreated case due to crystallinity increase, whereas load sensing decreased in heat treated case. Electrospun PVDF nanofiber web also showed sensing effect on humidity and temperature as well as stress transferring. Nanocomposites and electrospun PVDF nanofiber web can be applicable for sensing application.