• Title/Summary/Keyword: CL-data

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Effects of Some Physico-Chemical Conditions of Sioil on Growth and Ionic Balance of the Tobacco Plant (Nicotiana Tabacum L.) I. Effect of Acidity(pH), Moisture(pF) and Anions (Cl-, SO4-) in Soil on Grwth and Ionic Balance of Tobacco (토양(土壤)의 몇가지 이화학적조건(理化學的條件)이 연초(煙草)의 생육(生育) 및 이온평형(平衡)에 미치는 영향(影響) I. 토양(土壤)의 pH, pF와 음(陰)이온(Cl-, SO4-)이 연초(煙草)의 생육(生育) 및 이온평형(平衡)에 미치는 영향(影響))

  • Kim, Jai-Jong;Cho, Seong-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.14 no.3
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    • pp.117-129
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    • 1981
  • An experiment with the tobacco plant was conducted in the pots. A sandy humic soil was used with 2 levels of pH, 3.5 and 5.8 with 2 kinds of anions, Cl as $NH_4Cl$ and $SO_4$ as $(NH_4)_2SO_4$, and with 4 levels of pF, 1.5, 2.0, 2.5, and 3.5. The pH-treatment created different N-forms; $NH_4$ at low pH(3.5) and $NO_3$ at high pH (5.8). The results are summarized as follows: 1. At low pH (3.5) with high concentration of $NH_4$ given as $NH_4Cl$, the high content of $NH_4$ and Cl in tobacco resulted in plants suffering from $NH_4$ and Cl toxicity as well as Mn toxicity. As a result of these toxicity, an extremly abnormal growth of tobacco was clearly appeared. In the tobacco grown at low pH with $NH_4$ given as $(NH_4)_2SO_4$, a large amount of the $NH_4$ uptake developed Mg and Ca deficiencies. $NH_4-N$, which had been applied to the soil of high pH (5.8), was almost completely transformed into $NO_3-N$ by nitrification and, on this low acidic soil, the plants were all healthy regardless of Cl or $SO_4$ added together with $NH_4-N$. However, dry matter production was higher and maturity faster when $SO_4$ was used as anion than when Cl was used. 2. High moisture content in soil, to some extent, is necessary for a good development and growth of the tobacco plant. Phosphate uptake seemed to be limited at higher moisture stress. The dry matter yield of tops and roots of tobacco were in the order of pF 1.8 > 2.1 > 2.6 > 3.6, respectively. 3. Data of chemical analysis and dry matter yields of tops and roots showed that the tobacco plant followed the normal (C-A) concept. In the normal growth of plants, the carboxylate content of tops was quite comparable to the estimated (C-A) values. If $NH_4$ content of plants remains in quite high quantities, it must be analysed and taken into consideration for the (C-A) calculation. Al is not transported toward tops in toxic amounts due to its high immobility, it mostly stay in or on the roots, probably due to precipitation as a aolt. When Al is present in high quantities, it has to be considered into the (C-A) calculation.

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Kinetics for Reduction of trans-[Co(en)$_2$(NO$_2$)Cl]$^+$ and [Fe(H$_2$O)$_6$]$^{2+}$ in Acidic Solution (산성용액내에서 trans-[Co(en)$_2$(NO$_2$)Cl]$^+$ 와 [Fe(H$_2$O)$_6$]$^{2+}$ 와의 산화환원반응에 대한 속도론적 연구)

  • Park Byung-Kak;Woo Tae-Ha;Lim Joo-Sang;Song Yeung-Dae
    • Journal of the Korean Chemical Society
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    • v.34 no.5
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    • pp.460-464
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    • 1990
  • Proton behavior was investgated for the redox reaction of trans-[$Co(en)_2(NO_2)Cl]^+$ with aqueous Fe(II) in acidic solution by UV/vis-spectrophotometric method. The reaction order of proton is first one and the rate constant(k$_H^+$) is 6.7 ${\times}\;10^{-1}L^2/mol^2{\cdot}min$. The values of $E_a$, ${\{Delta}H^{\neq}$, ${\{Delta}S^{\neq}$ are 14.5 Kcal/mol, 13.8 Kcal/mol and -18.3e.u., respectively. As the result of analysis of kinetic data, it has been found that this reaction proceeds through inner-sphere mechanism.

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Efficient Workload Distribution of Photomosaic Using OpenCL into a Heterogeneous Computing Environment (이기종 컴퓨팅 환경에서 OpenCL을 사용한 포토모자이크 응용의 효율적인 작업부하 분배)

  • Kim, Heegon;Sa, Jaewon;Choi, Dongwhee;Kim, Haelyeon;Lee, Sungju;Chung, Yongwha;Park, Daihee
    • KIPS Transactions on Computer and Communication Systems
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    • v.4 no.8
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    • pp.245-252
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    • 2015
  • Recently, parallel processing methods with accelerator have been introduced into a high performance computing and a mobile computing. The photomosaic application can be parallelized by using inherent data parallelism and accelerator. In this paper, we propose a way to distribute the workload of the photomosaic application into a CPU and GPU heterogeneous computing environment. That is, the photomosaic application is parallelized using both CPU and GPU resource with the asynchronous mode of OpenCL, and then the optimal workload distribution rate is estimated by measuring the execution time with CPU-only and GPU-only distribution rates. The proposed approach is simple but very effective, and can be applied to parallelize other applications on a CPU and GPU heterogeneous computing environment. Based on the experimental results, we confirm that the performance is improved by 141% into a heterogeneous computing environment with the optimal workload distribution compared with using GPU-only method.

Equilibrium Structure for CClF3 Using Real-Time and Time-Resolved Gas Electron Diffraction (시간 분해능 전자회절 분광법을 이용한 CClF3분자의 평형 구조 연구)

  • Seo, Seong S.;Ewbank, John D.
    • Journal of the Korean Chemical Society
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    • v.48 no.4
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    • pp.339-350
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    • 2004
  • The simplified cumulant method was applied to diffraction data of $CClF_3$ to study the equilibrium molecular parameters over a range of temperatures. The molecular parameters of $CClF_3$ by the simplified cumulant method were compared with those from the traditional method. Also the instrumentation of picosecond time resolved electron diffraction (TRED) and the experimental details are described. The total experimental temporal resolution was discussed in terms of the electron pulse width. The TRED system was applied to study the molecular structures for $CClF_3$ at room temperature. The molecular structural parameters $CClF_3$ from TRED are compared with those from GED/RT. The molecular parameters ($r_e$)of bonded C-F and C-Cl for $CClF_3$ by simplified CA are 132.00(2) pm and 175.20(3) pm, respectively, by using GED/RT. From the results of TRED experiments $r_a$ for bonded C-F and C-Cl are 132.23(13) pm and 177.23(19) pm.

Anti-apoptotic effect of fermented Citrus sunki peel extract on chemical hypoxia-induced neuronal injury (화학적 저산소증이 유도하는 뇌신경세포 손상에 있어서 미성숙 진귤 과피 발효 추출물의 보호 효과)

  • Ko, Woon Chul;Lee, Sun Ryung
    • Journal of Nutrition and Health
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    • v.48 no.5
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    • pp.451-456
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    • 2015
  • Purpose: Neuronal apoptotic events induced by aging and hypoxic/ischemic conditions is an important risk factor in neurodegenerative diseases such as ischemia stroke and Alzheimer's disease. The peel of Citrus sunki Hort. ex Tanaka has long been used as a traditional medicine, based on multiple biological activities including anti-oxidant, anti-inflammation, and anti-obesity. In the current study, we examined the actions of fermented C. sunki peel extract against cobalt chloride ($CoCl_2$)-mediated hypoxic death in human neuroblastoma SH-SY5Y cells. Methods: Cell viability was measured by trypan blue exclusion. Expression of apoptosis related proteins and release of cytochrome c were detected by western blot. Production of intracellular reactive oxygen species (ROS) and apoptotic morphology were examined using 2',7'-dichlorofluorescin diacetate (DCF-DA) and 4',6-diamidino-2-phenylindole (DAPI) staining. Results: Exposure to $CoCl_2$, a well-known mimetic agent of hypoxic/ischemic condition, resulted in neuronal cell death via caspase-3 dependent pathway. Extract of fermented C. sunki peel significantly rescued the $CoCl_2$-induced neuronal toxicity with the cell viability and appearance of apoptotic morphology. Cytoprotection with fermented C. sunki peel extract was associated with a decrease in activities of caspase-3 and cleavage of poly (ADP ribose) polymerase (PARP). In addition, increase in the intracellular ROS and release of cytochrome c from mitochondria to the cytosol were inhibited by treatment with extract of fermented C. sunki peel. Conclusion: Based on these data, fermented C. sunki peel extract might have a protective effect against $CoCl_2$-induced neuronal injury partly through generation of ROS and effectors involved in mitochondrial mediated apoptosis.

Effect of Tongue Scraping, ZnCl2 Mouth Rinse, and Periodontal Treatment on the Reduction of Oral Malodor (수종의 구취처치법의 구치감소효과에 관한 연구)

  • Park, Jong-Hoon;Han, Kyung-Soo;Kim, Moon-Gyu
    • Journal of Oral Medicine and Pain
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    • v.25 no.1
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    • pp.41-51
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    • 2000
  • This study was performed to investigate the effect of three modalities commonly used for reduction of oral malodor and to review the contributing factors for halitosis. For this study, 45 subjects of good general health in their third decades were selected, and they were divided into three groups by each modality, that is, tongue scraping, $ZnCl_2$ mouth rinse, and periodontal treatment. Subjective sense of halitosis, diets, Oral hygiene index based on tooth brushing and tongue brushing habit, resting salivary flow rate, gingival index, degree of tongue coating were recored in the Halito-Chart designed by the author. Oral malodor converted from volatile sulfur compound was measured by the Halimeter$^{(R)}$(Interscan Co., USA), and the correlation between the oral factors and pre-treatment halimeter score were analysed. Data obtained were analysed by the SPSS windows program and the results of this study were as follows : 1. There were no significant correlation between oral factors such as oral hygiene index, salivary flow rate, gingival index, degree of tongue coating and pre-treatment halimeter score. 2. Difference between pre- and post-treatment halimeter score by the three modalities were significant, but correlation between pre- and post-treatment score within group was most significant in the periodontal treatment group followed by the tongue scraping group and lowest in the $ZnCl_2$ mouth rinse group. 3. Reduction of halimeter score was significant only in subjects with relatively more tongue coating in the tongue scraping group, but in the $ZnCl_2$ mouth rinse group and in the periodontal treatment group, the modality applied to each group had same significant effects without regard to the degree of oral hygiene index or gingival index. 4. Men had more tongue coating than women, and reduction of halimeter score was significant in men, but not in women.

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Application of stoichiometric method in the assessment of groundwater chemistry in a coastal region having complex contaminant sources

  • Rajmohan Natarajan;Kim, Kang-Joo;Hwang, Gab-Soo;Kim, Hyun-Jung;Cho, Min-Joe
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.499-502
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    • 2004
  • Groundwater chemistry in a coastal region having complex contaminant sources was investigated. Water analysis data for 197 groundwater samples collected from the uniformly distributed sixty-six wells were used. Chemical analysis rand results indicate that groundwaters show wide concentration ranges in major inorganic ions, reflecting complex hydrochemical processes of pollutants. Due to the complexity of groundwater chemistry, Results illustrate that thirty five percent of the wells do not fit for drinking based on nitrate and chloride concentration in the study area. the samples were classified into four groups based on Cl and NO$_3$ concentrations and the processes controlling water chemistry were evaluated based on the reaction stoichiometry. The results explained the importance of mineral weathering, anthropogenic activities (nitrification and oxidation of organic matters), and Cl-salt inputs (seawater, deicer, NaCl, etc.) on groundwater chemistry. It was revealed that mineral dissolution is the major process controlling the water chemistry of the low Cl and NO$_3$ group (Group 1). Groundwaters high in NO$_3$ (Groups 2 and 4) are acidic in nature, and their chemistry is largely influenced by nitrification, oxidation of organic matters and mineral dissolution. In the case of chloride rich waters (Group 3), groundwater chemistry is highly influenced by mineral weathering and seawater intrusion associated with cation-exchange reactions.

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Efficient Task Distribution for Pig Monitoring Applications Using OpenCL (OpenCL을 이용한 돈사 감시 응용의 효율적인 태스크 분배)

  • Kim, Jinseong;Choi, Younchang;Kim, Jaehak;Chung, Yeonwoo;Chung, Yongwha;Park, Daihee;Kim, Hakjae
    • KIPS Transactions on Computer and Communication Systems
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    • v.6 no.10
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    • pp.407-414
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    • 2017
  • Pig monitoring applications consisting of many tasks can take advantage of inherent data parallelism and enable parallel processing using performance accelerators. In this paper, we propose a task distribution method for pig monitoring applications into a heterogenous computing platform consisting of a multicore-CPU and a manycore-GPU. That is, a parallel program written in OpenCL is developed, and then the most suitable processor is determined based on the measured execution time of each task. The proposed method is simple but very effective, and can be applied to parallelize other applications consisting of many tasks on a heterogeneous computing platform consisting of a CPU and a GPU. Experimental results show that the performance of the proposed task distribution method on three different heterogeneous computing platforms can improve the performance of the typical GPU-only method where every tasks are executed on a deviceGPU by a factor of 1.5, 8.7 and 2.7, respectively.

Adsorption Characteristics of Acetone, Benzene, and Metylmercaptan by Activated Carbon Prepared from Waste Citrus Peel (폐감귤박으로 제조한 활성탄에 의한 아세톤, 벤젠 및 메틸메르캅탄의 흡착특성)

  • Kam, Sang-Kyu;Kang, Kyung-Ho;Lee, Min-Gyu
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.663-669
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    • 2017
  • Activated carbons were prepared from waste citrus peels using KOH, NaOH, and $ZnCl_2$ as activating chemicals. They were prepared at optimal conditions including the chemical ratio of 300%, activation time of 1.5h, and activation temperature of $900^{\circ}C$ for KOH, $700^{\circ}C$ for NaOH, and $600^{\circ}C$ for $ZnCl_2$, which were named as ACK, ACN, and ACZ, respectively. Using the activated carbons, their adsorption characteristics for three target gases such as acetone, benzene, and methylmercaptan (MM) were carried out in a batch reactor. The adsorption behavior of activated carbons for three target gases followed the Freundlich model better than the Langmuir. And the experimental kinetic data followed a pseudo-second-order kinetic model more than pseudo-first-order one. Following the intraparticle diffusion model suggested that the external mass transfer and particle diffusion were occurred simultaneously during the adsorption process.

Kinetics of Oxidative Coupling of Methane over NaCl/ZnO/α-Al2O3 Catalyst (NaCl/ZnO/α-Al2O3 촉매상에서 메탄의 Oxidative Coupling의 속도론적 고찰)

  • Kim, Sang-Chai;Seo, Ho-Joon;Sunwoo, Chang-Shin;Yu, Eui-Yeon
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.256-265
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    • 1992
  • The kinetics for the oxidative coupling of methane over NaCl(30wt%)/ZnO(60wt%)/${\alpha}-Al_2O_3$ catalyst was investigated, and then the active oxygen species were discussed. The conversion rate of methane was measured at the atmospheric pressure with various combinations of partial pressure of methane and oxygen at temperature range of $650^{\circ}C{\sim}750^{\circ}C$, at conversions less than with 10%. These rate data were then used to verify the proposed Langmuir-Hinshelwood kinetic equation. The rate limiting step appeared to be the formation of the methyl radicals by the reactin of the adsorbed methane and the adsorbed oxygen, which were adsorbed on the different active sites of the catalyst. The activation energy of the methyl radical formation was estimated to be ca. 39 kcal/mol. From the kinetic studies, the oxygen species respolsible for the formation of methyl radicals was proposed to be diatomic oxygen such as $O{_2}{^{2-}}$ or $O_2{^-}$ on the surface.

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