• Title/Summary/Keyword: CL-data

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Synthesis and Structural Characterization of Five- and Six-Coordinate Cobalt(Ⅱ) Complexes of Tripodal Liand. Tris-(2-benzimidazolylmethyl)amine

  • 라명수;문무신
    • Bulletin of the Korean Chemical Society
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    • v.18 no.4
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    • pp.406-409
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    • 1997
  • The various cobalt(Ⅱ) complexes were synthesized and characterized using tris-(2-benzimidazolylmethyl)amine (ntb) as a ligand where the ntb plays as a tripodal tetradentate ligand to form complexes with a trigonal pyramidal geometry. The complexes have 5 and 6 coordinate cobalt(Ⅱ) ions depending on the additional ligand used. In each complex the additional ligand, chloride anion, or acetate anion occupies the "open" site trans to the apical tertiary nitrogen atom of ntb ligand. Complex 1, [Co(Ⅱ)(ntb)Cl]Cl has a trigonal bipyramidal geometry. This geometry was easily constructed using ntb as a tetradentate ligand and chloride as a monodentate ligand. The complex is isostructural to the corresponding manganese(Ⅱ) complex. Crystal data are as follows: [Co(Ⅱ)(ntb)Cl]Cl·MeOH, 1. triclinic space group P1; a=13.524(2) Å, b=14.037(2) Å, c=17.275(1) Å; α=78.798(9), β=84.159(8)°, γ=65.504(9)°; V=2929.6(6) Å3; Z=4; R1=0.0715, wR2=0.1461 for reflections of I > 2σ(I). Six coordinate complex 2 [Co(ntb)(OAc)](OAc) was synthesized using ntb as a tetradentate ligand and acetate as a bidentate chelating ligand.

Comparison of Recovery Levels of Staphylococcus aureus Treated at Different NaCl Concentrations after Sublethal Heating (Staphylococcus aureus 의 sublethal heating 후 NaCl 농도에 따른 회복 정도 비교)

  • Park, Kyung-Shik;Kim, Min-Ju;Jung, Hye-Jin;Kim, Keun-Sung
    • Journal of Food Hygiene and Safety
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    • v.24 no.4
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    • pp.368-372
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    • 2009
  • The viability of Staphylococcus aureus, a significant cause of food poisoning in Korea, on TSA plates was determined after sublethal heating treatments and NaCl treatments. In addition, recovery levels of sublethally injured cells on TSA plates containing different concentrations of NaCl (TSAS) were investigated. The viability decreased significantly with increasing degree of sublethal heating treatments, but increases in NaCl treatment concentrations from 0 to 6% had little effect on the viability. After being sublethally treated at $55^{\circ}C$ for 30 min, bacterial populations were reduced by 7.91, 7.97 and 7.99 log CFU/mL on 2, 4 and 6% TSAS, respectively. After being sublethally treated at 60oC for 30 min, bacterial populations were reduced by 6.46, 6.47 and 6.48 log CFU/mL on 2, 4 and 6% TSAS, respectively. Decimal reduction times (D-value) decreased with increasing NaCl treatment concentrations after sublethal heating at 55 and $60^{\circ}C$. These data imply that the S. aureus cells sublethally injured by insufficient heating processes had a lower recovery rate with increasing NaCl concentrations in the recovery media.

Physicochemical Characteristics of Groundwater Salinization in the eastern aea of Cheju Island (제주도 동부지역 지하수의 염수화와 이화학적 특성)

  • Oh, Youn-Keun;Kim, Kyung-Hoo;Ryu, Seong-Pil
    • Journal of Environmental Science International
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    • v.9 no.3
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    • pp.253-259
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    • 2000
  • The purpose of this study is to investigate the physicochemical characteristics of salinization of groundwater at the estern area of Cheju island. For this purpose, the major ions of groundwater, spring water are analyzed. The concentration of $Cl^-$ and Na^++K^+$/ contained in the groundwater at near the coastline are higher than those at inland area away from the coastline. The water quality components of groundwater observed at this area can be classified into 4 types such as Na-Cl, $HCO_3, Na-Cl-HCO_3$ and Ca-HCO$_3$. The concentration ratio of $SO_4^1 to Cl^- is 0.1354(R^2=0.972)$ at this area. This value is very similar with Dittomer's ratio of 0.13. For Na^+, K^+, and Mg^{2+}/ versus Cl^-$, their ratios also show a significant relationship between sea water and groundwater in this area. From the chloride-bicarbonate ratio, it can be estimated that the intrusion distance of seawater from coastline to inland area is 2.8km at Onpyung-Nansan, Sangdo and Pyungdae areas, and 5.4km at Kosung-Susan area. The mixing ratio between seawater and fresh water by the intrusion of seawater is decreased with the distance toward inland from coastline. This ratio(fresh water : seawater) is 80:20 in spring water adjacent the coastlines, Onpyung area and 99.8:0.2 in the well at No.3 of Susan located at inland away from the coastline. The concentration of $Na^+$ observed at field is 25~45% lower than that theoretically calculated by this mixing ratio. Based on the data of EC, the equipotential line of 500$\mu$mhos/cm is located at 4~5km poing at Kosung-Susan area and 2.5km point at the other area. The equation of correlation between $Cl^-$ concentration and EC values is $Cl^-$=0.1927EC-16.683 for the area lower than 500 $\mu$mhos/cm and $Cl^-$=0.2773EC for the area beyond 500 $\mu$mhos/cm.

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Effects of N-acetylcysteine (NAC) on chemiluminescence response as a non-specific immune parameter in Far Eastern catfish Silurus asotus (항산화물질 N-acetylcysteine (NAC)이 메기에서 비특이적 면역지표인 화학발광 반응에 미치는 영향)

  • Park, Kwan Ha;Lee, Han-Na;An, Jae-Young;Bae, Jun Sung;Lee, Chae Won;Yang, Chan Young;Choi, Sang-Hoon
    • Journal of fish pathology
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    • v.32 no.1
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    • pp.21-28
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    • 2019
  • It has been reported that various anti-oxidant substances stimulate non-specific immune responses in fishes. In this study it was examined whether N-acetylcysteine (NAC), a precusor for anti-oxidant glutathione (GSH) synthesis, can modulate non-specific immune function in Far Eastern catfish Silurus asotus. Immune functions were assessed using the respiratory burst activity monitored by chemiluminescence (CL) responses in isolated leucocyte. NAC stimulated CL responses with doses of 10 or 100 mg/kg, but not with 1 mg/kg after 48 hr injection. It was observed with 10 mg/kg NAC that CL activity continued to elevate from 24 hr through 96 hr post-dosing, and returned to the near preinjection level by 10 days. To understand whether NAC can also activate CL activity in vitro, NAC was directly added to isolated catfish leucocytes. It was observed, however, that NAC can not stimulate CL at reasonable concentration ranges in vitro. As NAC is a precursor for the strong anti-oxidant glutathione (GSH), a putative immune stimulator, it was assessed whether GSH can also stimulate CL responses. Observed results show that GSH activated CL both in vivo and in vitro. The data obtained collectively support the proposition that NAC indirectly stimulates non-specific immune functions in catfish by enhancing GSH biosynthesis, but not by direct action of NAC. Such effects may have beneficial significance in aquaculture for practical utilization.

Toward Generic, Immersive, and Collaborative Solutions to the Data Interoperability Problem which Target End-Users

  • Sanchez-Ruiz, Arturo;Umapathy, Karthikeyan;Hayes, Pat
    • Journal of Computing Science and Engineering
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    • v.3 no.2
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    • pp.127-141
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    • 2009
  • In this paper, we describe our vision of a "Just-in-time" initiative to solve the Data Interoperability Problem (a.k.a. INTEROP.) We provide an architectural overview of our initiative which draws upon existing technologies to develop an immersive and collaborative approach which aims at empowering data stakeholders (e.g., data producers and data consumers) with integrated tools to interact and collaborate with each other while directly manipulating visual representations of their data in an immersive environment (e.g., implemented via Second Life.) The semantics of these visual representations and the operations associated with the data are supported by ontologies defined using the Common Logic Framework (CL). Data operations gestured by the stakeholders, through their avatars, are translated to a variety of generated resources such as multi-language source code, visualizations, web pages, and web services. The generality of the approach is supported by a plug-in architecture which allows expert users to customize tasks such as data admission, data manipulation in the immersive world, and automatic generation of resources. This approach is designed with a mindset aimed at enabling stakeholders from diverse domains to exchange data and generate new knowledge.

Epidemiological Aspects of Cutaneous Leishmaniasis during 2009-2016 in Kashan City, Central Iran

  • Moein, Doroodgar;Masoud, Doroodgar;Saeed, Mahboobi;Abbas, Doroodgar
    • Parasites, Hosts and Diseases
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    • v.56 no.1
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    • pp.21-24
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    • 2018
  • Cutaneous leishmaniasis (CL) can be seen in 2 forms, zoonotic and anthroponotic, in Iran. In this study, epidemiological aspects of CL were studied during an 8-year period (2009-2016) in city of Kashan, central Iran. The demographic and epidemiological data, including age, sex, occupation, number and site of the lesions, treatment regimen, past history of CL, and season of all patients were gathered from the health centers. Descriptive statistics were used to describe features of the study data. Total 2,676 people with CL were identified. The highest annual incidence was estimated to be 182 per 100,000 population in 2009 and the least was in 2016 (47 per 100,000 population). The highest frequency affected age groups were observed in 20-29 year-old patients (20.9%). More than 51% of the patients were under 30 years old. The maximum frequency of the disease, 1,134 (43.3%), was seen in autumn. The most common location of lesions was hands (61.4%). Most of the patients (81.6%) were treated by systemic glucantime regimen. In the city of Kashan, the incidence rate of the CL disease is significantly higher than many other regions of Iran. To reduce the risk of disease, control of reservoir hosts and vectors of disease, and education of individual protection are strongly recommended.

Characteristics of Long-term Water Quality Trend of Dongrae Hot Spring (동래온천의 장기적인 수질 변동 특성)

  • Jeon, Hang-Tak;Hamm, Se-Yeong;Lee, Cholwoo;Lee, Jong-Tae;Lee, Jeong Rak
    • The Journal of Engineering Geology
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    • v.30 no.3
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    • pp.379-397
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    • 2020
  • In this study, Long-term change of water quality in Donrae Hot Spring was characterized using water quality data from 1922 to 2019. According to Mann-Kendall analysis and Sen's slope using long-term water quality data of Dongnae Hot Spring from 1922 to 2019, temperature, Ca, SiO2, and HCO3 show an increasing trend whereas EC, Na, K, Mg, Cl, and SO4 show a decreasing trend or negligible trend. In addition, the water type of Dongnae Hot Spring stably belongs to Na-Cl type over time. The spatial distributions of water temperature and chemical constituents in 2004, 2009, 2014, and 2019 show variable patterns with showing some difference depending on sampling locations in different years. These results indicate that despite the long-term pumping of the hot spring water, the water quality is quite stable during the entire study period.

Design and Implementation of an Approximate Surface Lens Array System based on OpenCL (OpenCL 기반 근사곡면 렌즈어레이 시스템의 설계 및 구현)

  • Kim, Do-Hyeong;Song, Min-Ho;Jung, Ji-Sung;Kwon, Ki-Chul;Kim, Nam;Kim, Kyung-Ah;Yoo, Kwan-Hee
    • The Journal of the Korea Contents Association
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    • v.14 no.10
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    • pp.1-9
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    • 2014
  • Generally, integral image used for autostereoscopic 3d display is generated for flat lens array, but flat lens array cannot provide a wide range of view for generated integral image because of narrow range of view. To make up for this flat lens array's weak point, curved lens array has been proposed, and due to technical and cost problem, approximate surface lens array composed of several flat lens array is used instead of ideal curved lens array. In this paper, we constructed an approximate surface lens array arranged for $20{\times}8$ square flat lens in 100mm radius sphere, and we could get about twice angle of view compared to flat lens array. Specially, unlike existing researches which manually generate integral image, we propose an OpenCL GPU parallel process algorithm for generating real-time integral image. As a result, we could get 12-20 frame/sec speed about various 3D volume data from $15{\times}15$ approximate surface lens array.

Inactivation of Agrobacterium tumefaciens Inoculated on Fresh Radix Ginseng by Electron Beam Irradiation and Aqueous Chlorine Dioxide Treatment

  • Chun, Ho-Hyun;Kim, Ju-Yeon;Song, Kyung-Bin
    • Journal of Applied Biological Chemistry
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    • v.51 no.3
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    • pp.117-122
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    • 2008
  • Inactivation of Agrobacterium tumefaciens was evaluated on the inoculated fresh Radix Ginseng by electron beam irradiation or aqueous chlorine dioxide ($ClO_2$) treatment. Two groups of fresh ginsengs were prepared and inoculated with A. tumefaciens. One group was then irradiated at 0, 2, and 4 kGy using an electron beam accelerator, and the other group was treated with 0, 50, and 100 ppm of aqueous $ClO_2$. Microbiological data indicated that populations of A. tumefaciens significantly decreased with increasing irradiation dose or aqueous $ClO_2$ concentration. In particular, A. tumefaciens was eliminated by irradiation at 4 kGy, and 100 ppm $ClO_2$ treatment reduced the populations of A. tumefaciens by 1.44 log CFU/g. These results suggest that electron beam irradiation or aqueous $ClO_2$ treatment can be useful in improving the microbial safety of fresh ginsengs during storage.

Dry Etching Characteristics of Indium Zinc Oxide Thin Films in Adaptive Coupled Plasma

  • Woo, Jong-Chang;Choi, Chang-Auck;Kim, Chang-Il
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.4
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    • pp.216-220
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    • 2013
  • The etching characteristics of indium zinc oxide (IZO) in $Cl_2/Ar$ plasma were investigated, including the etch rate and selectivity of IZO. The IZO etch rate showed non-monotonic behavior with increasing $Cl_2$ fraction in the $Cl_2/Ar$ plasma, and with increasing source power, bias power, and process pressure. In the $Cl_2/Ar$ (75:25%) gas mixture, a maximum IZO etch rate of 87.6 nm/min and etch selectivity of 1.09 for IZO to $SiO_2$ were obtained. Owing to the relatively low volatility of the by-products formation, ion bombardment was required, in addition to physical sputtering, to obtain high IZO etch rates. The chemical state of the etched surfaces was investigated with X-ray photoelectron spectroscopy. These data suggested that the IZO etch mechanism was ion-enhanced chemical etching.