• Title/Summary/Keyword: CL Data

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Metal-Dinitrosyl Complexes(Ⅳ) : Synthesis and Characterization of Symmetric and Asymmetric Dinuclear Molybdenum and Tungsten Complexes (금속-디니트로실 착물 (제 4 보) : 몰리브덴과 텅스텐의 대칭 및 비대칭 이핵 착물의 합성과 특성)

  • O, Sang O;Mo, Seong Jong
    • Journal of the Korean Chemical Society
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    • v.38 no.7
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    • pp.485-495
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    • 1994
  • Several new symmetric and asymmetric homo and hetero dinuclear complexes of the type $[Cl(dppp)(NO)_2M({\mu}-pyz)M'(NO)_2(dppp)Cl][ClO_4]_2$ and $[Cl(phen)(NO)_2M({\mu}-pyz)M'(NO)_2(dppp)Cl][ClO_4]_2$(M,M'= Mo or W; phen = 1,10-phenanthroline; dppp = 1,3-bis(diphenylphosphino)propane; pyz = 1,4-pyrazine) were synthesized in three-steps starting from $[M(NO)_2Cl_2]_n(M = Mo, W)$. The final products were purified by eluting it through silica gel column ($2{\times}20$ cm) with acetone as the eluent. Characterization of these complexes and some related complexes was accomplished through UV-vis., $^1H$-NMR, $^{13}C$-NMR and IR spectroscopies as well as elemental analysis. The infrared spectra indicate that the NO groups occupy cis-positions of the octahedral. The $^1H$ and $^{13}C-NMR$ data for the new compounds revealed a dimeric structures with bridged pyz.

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Study on the Possibility of Seawater Intrusion in the Ulsan Area Using Br : Cl Weight Ratios of Groundwater (지하수의 Br : Cl 함량비를 이용한 울산지역 해수침입 연구)

  • Cho, Byung-Wook;Lee, Byung-Dae;Yoon, Wook;Im, Hyun-Chul
    • Economic and Environmental Geology
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    • v.36 no.5
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    • pp.339-347
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    • 2003
  • Using 171 groundwater chemistry data, seawater intrusion in the Ulsan area was studied. The area near the downstream area of the Taehwa River shows the higher Cl concentrations(11,300 mg/L in maximum), whereas the Cl concentrations are generally low in the eastern coastal area maybe due to the geology of the area. When Cl concentrations are very low, groundwater shows Br:Cl weight ratios significantly deviating from the Br:Cl ratio of seawater($34.7{\times}10^{-4}$). However, Br:Cl ratios are very close to the value of seawater when Cl concentrations are higher than 100 mg/L. Eleven groundwater samples having very high Cl concentrations(>500 mg/L) show that ionic ratios for Ca, Mg, $SO_4$, $HCO_3$ and $SiO_2$ are considerably different from those of seawater. This indicates that the origin of the high Cl groundwaters occurring along the Taehwa River are likely to be the residual salines from the salterns previously located on the alluviums rather than the seawaters intruded recently. These waters seem to be accumulated in the sediments before the drastic expansion of the city. Considering the characteristics of the urban groundwater system where the inflow exceeds the outflow, it is anticipated that the high Cl concentration in the groundwater show a decreasing trend in the future.

Geometric Modeling and Five-axis Machining of Tire Master Models

  • Lee, Cheol-Soo
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.3
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    • pp.75-78
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    • 2008
  • Tire molds are manufactured by aluminum casting, direct five-axis machining, and electric discharging machining. Master models made of chemical wood are necessary if aluminum casting is used. They are designed with a three-dimensional computer-aided design system and milled by a five-axis machine. In this paper, a method for generating and machining a tire surface model is proposed and demonstrated. The groove surfaces, which are the main feature of the tire model, are created using a parametric design concept. An automatically programmed tool-like descriptive language is presented to implement the parametric design. Various groove geometries can be created by changing variables. For convenience, groove surfaces and raw cutter location (CL) data are generated in two-dimensional drawing space. The CL data are mapped to the tread surface to obtain five-axis CL data to machine the master model. The proposed method was tested by actual milling using the five-axis control machine. The results demonstrate that the method is useful for manufacturing a tire mold.

자유곡면 5축 NC가공에 있어서의 최적 CL data산출

  • 최병규;박정환;김화영
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 1991.10a
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    • pp.124-130
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    • 1991
  • 5-axis NC machining of sculptured surface using non-ballendmill cutters (eg. facemilling cutters) is widely used in the machining of turbine blades and marine propellers. Since there are more degrees of freedom in 5-axis machining than in 3-axis machining, generating "optimum" cutter paths and finding desirable cutter positions become very important in order for an efficient use of 5-axis NC machines. Also critical in 5-axis NC machining are collision avoidance, gouging checking, and efficient kinematic solutions. In this paper we discuss the above issues in generating 5-axis CL data. They are : kinematics modeling of NC machine; inverse kinematics solution; interference between machine component and surface; cutter gouging. A unique search method for obtaining optimal CL data is proposed. The proposed method has been successfully implemented in the machining of marine propellers on a dual 5-axis (ie, 9-axis) NC machine.C machine.

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Solvent Extraction of Cobalt Chloride from Strong Hydrochloric Acid Solutions by Alamine336 (진한 염산용액에서 Alamine336에 의한 염화코발트의 용매추출)

  • Lee, Man-seung;Lee, Jin-Young
    • Korean Journal of Metals and Materials
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    • v.46 no.4
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    • pp.227-232
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    • 2008
  • Solvent extraction reaction of cobalt by Alamine336 from strong hydrochloric acid solution was identified by analyzing the solvent extraction data reported in the literature. Analysis of the data by graphical method revealed that Alamine336 took part in the solvent extraction reaction as a monomer in the concentration ranges, [Co(II)] : 0.0169 - 0.102 M, [Alamine336] ; 0.02- 1.75 M, and [HCl ] : 5 - 10 M. The following solvent extraction reaction and equilibrium constant was obtained from the experimental data by considering the activity coefficients of chemical species present in the aqueous phase. $Co^{2+}+2Cl^{-}+R_3NHCl_{org}=CoCl_3\;R_3NH_{org}$, $K_{ex}=2.21$ The distribution coefficients of cobalt predicted in this study agreed well with those reported in the literature.

Parallel LDPC Decoding on a Heterogeneous Platform using OpenCL

  • Hong, Jung-Hyun;Park, Joo-Yul;Chung, Ki-Seok
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.6
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    • pp.2648-2668
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    • 2016
  • Modern mobile devices are equipped with various accelerated processing units to handle computationally intensive applications; therefore, Open Computing Language (OpenCL) has been proposed to fully take advantage of the computational power in heterogeneous systems. This article introduces a parallel software decoder of Low Density Parity Check (LDPC) codes on an embedded heterogeneous platform using an OpenCL framework. The LDPC code is one of the most popular and strongest error correcting codes for mobile communication systems. Each step of LDPC decoding has different parallelization characteristics. In the proposed LDPC decoder, steps suitable for task-level parallelization are executed on the multi-core central processing unit (CPU), and steps suitable for data-level parallelization are processed by the graphics processing unit (GPU). To improve the performance of OpenCL kernels for LDPC decoding operations, explicit thread scheduling, vectorization, and effective data transfer techniques are applied. The proposed LDPC decoder achieves high performance and high power efficiency by using heterogeneous multi-core processors on a unified computing framework.

SENSITIZED PHOTOINITIATING SYSTEM USED IN PHOTOPOLYMER FILMS

  • Liu, A.D;Trifunac, A.D;Krongauz, V.V.
    • Journal of the Korean Vacuum Society
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    • v.7 no.s1
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    • pp.20-24
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    • 1998
  • Photploymer films are widely used in printing and electronic industries, and their usage is expanding to encompass holography, data storage and data processing, optical waveguides and compact disks, etc. One of widely used photoplymerization initiator, 20chloro-hexaarylbiimidazole (o-Cl-HABI), is studied by laser flash photolysis in dichloromethane solution in the absence and presence of the visible light photosensitizing dye, 2, 5-bis[(2, 3, 6, 7 -tetrahydro- 1H, 5H -benzo [i, j,] quinolizin -1-yl) methylene]-cyclopenta-none, (JAW). In the presence of JAW, an increase in triarylimidazolyl radicals L.formation is observed in relative to the absence of JAW. The mechanism of this photosensitizing dissociation is concluded as the dissociation of the o-Cl-HABI radical anion formed by the electron transfer from excited singlet state of JAW to o-Cl-HABI. The observed formation of L.radicals exhibits a linear dependence on o-Cl-HABI concentration. The rate constant of electron transfer obtained from this dependence is equal to (1.0$\pm$0.2) x $10^9 M^{-1}s^{-1}$. No reaction between the excited triplet state of JAW and o-Cl-HABI is found.

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Five-axis CL Data Generation by Considering Tool Swept Surface Model in Face Milling of Sculptured Surface (공구이동궤적 모델을 이용한 5축 페이스밀링 가공데이터 생성)

  • 이정근;박정환
    • Korean Journal of Computational Design and Engineering
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    • v.9 no.1
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    • pp.35-43
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    • 2004
  • It is well known that the five-axis machining has advantages of tool accessibility and machined surface quality when compared with conventional three-axis machining. Traditional researches on the five-axis tool-path generation have addressed interferences such as cutter gouging, collision, machine kinematics and optimization of a CL(cutter location) or a cutter position. In the paper it is presented that optimal CL data for a face-milling cutter moving on a tool-path are obtained by incorporating TSS(tool swept surface) model. The TSS model from current CL position to the next CL position is constructed based on machine kinematics as well as cutter geometry, with which the deviation from the design surface can be computed. Then the next CC(cutter-contact) point should be adjusted such that the deviation conforms to given machining tolerance value. The proposed algorithm was implemented and applied to a marine propeller machining, which proved effective from a quantitative point of view. In addition, the algorithm using the TSS can also be applied to avoid cutter convex interferences in general three-axis NC machining.

Viscosities of Ternary Mixtures of Sucrose-Sodium Chloride-Water (Sucrose-NaCl- 물의 3성분 혼합액체의 점도에 관한 연구)

  • Oh, Myung-Suk
    • Korean Journal of Food Science and Technology
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    • v.22 no.1
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    • pp.66-70
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    • 1990
  • Correlations have been developed for estimating the viscosities of ternary mixtures of sucrose-sodium chloride-water over a temperature range of $10-40^{\circ}C$ and a concentration range of 1.0064-5.7037 molality sodium chloride and 0.3436-2.5966 molality sucrose. The viscosity data of sodium chloride and sucrose solutions have been fitted very well utilizing proposed polynomial equation, respectively and the temperature dependence analysis for sodium chloride and sucrose solutions showed that 1/T dependence is accurate. The experimental viscosity data for surose-sodium chloride-water mixtures were fitted to a five parameter polynomial with a goodness of fit approximating experimental error and it seems that there is no significant Interaction between sodium chloride and surose solutions.

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The Relationship between Depression and Health Behavior in Adolescents (청소년의 우울성향과 건강관련행위간의 관계 연구)

  • Park, Nam-Hee;Kim, Mi-Oak
    • Child Health Nursing Research
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    • v.11 no.4
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    • pp.436-443
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    • 2005
  • Purpose: This study was done to explore the levels of depression experienced by adolescents, and to compare health behavior between depressed and non-depressed adolescents. Method: Participants were chosen by a stratified random sampling of adolescents in the second grade of a high school in P city. Levels of depression and health behavior of the students were measured using questionnaires. Data collection was done in May, 2002. Data were analyzed with descriptive statistics and logistic regression using the SPSS WIN 10.0 Program. Results: The prevalence of depression (CES-D) among the students was $53.5\%$. In multiple logistic regression analysis, sex (OR 1.80, $95\%$ Cl 1.35-2.41), school performance, mid (OR 1.68, $95\%$ Cl 1.48-1.97) and low (OR 1.42, $95\%$ Cl 1.29-1.61), drinking (OR 1.47, $95\%$ Cl 1.09-1.98), and not eating breakfast (OR 1.74, $95\%$ Cl 1.56-1.97) were significantly higher in students in the depressed group than those in the non-depressed group. Conclusions: Based on the findings, we concluded that many adolescent experience depression and depression in adolescents is significantly related to behaviors of smoking, alcohol, no exercise, and not eating breakfast. However this study did not address causality among these variables. There, further research, such as a longitudinal study, is needed to identify causality among the variables.

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