• 대한기계학회논문집B
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• 제33권5호
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• pp.365-372
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• 2009

The influence of combustor pressure on the local reaction characteristics of $CH_4$/air flames was investigated by measurements of local chemiluminescence intensity. Induced flow flames are often applied to the industrial boiler systems and incinerator in order to improve heat transfer and prevent exhaust gas leakage. In order to investigate combustion characteristics in the induced flow pattern, the combustor pressure index($P^*$) was controlled in the range of $0.7{\sim}1.3$ for each equivalence ratio in the present combustion system, where $P^*$ is defined as the ratio of absolute pressure to atmospheric one. Relationship between local reaction intensity and pressure index have been investigated by simultaneous $CH^*$, $C^*_2$ and $OH^*$ intensity measurements. It could be observed that flame length became longer with decreasing $P^*$ from $CH^*$ chemiluminescence intensity of axial direction. The mean value of $C^*_2$ and $CH^*$ chemiluminescence intensities, which indicates reaction intensity in the $CH_4$/air flames, decreased with decreasing pressure index for ${\Phi}{\leq}1$, but increased with decreasing pressure index for ${\Phi}$>1. $C^*_2/CH^*$ intensity ratio, which can be a good marker to demonstrate local equivalence ratio, was almost same for ${\Phi}{\leq}1$ regardless of pressure index change, while they showed high level for lower pressure index for ${\Phi}$>1 conditions.

• 한국추진공학회지
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• 제18권1호
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• pp.73-84
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• 2014

본 논문에서는 화학발광 계측을 통한 연소화염의 당량비, 열방출율과 같은 물리량 판단에 대한 최신 연구결과를 정리 분석하였다. 현대의 연소장치는 연소의 동적 안정성 증대 및 공해물질 배출억제를 위해 세밀한 제어가 필요하다. 화학발광 세기 계측을 통한 물리량 파악은 그 적용에 있어서 많은 상대적 장점을 지니고 있다. 그러나 본 방법은 당량비, 연소압력, 입구온도, 난류세기, 연료 종류 등에 의해 많은 영향을 받는다. 연구결과를 종합하면, 메탄/공기 예혼합 화염에서 $CH^*/OH^*$가 연료 과농 조건을 제외하고 당량비와 밀접한 관계가 있다. 또한 넓은 공간에서 측정된 $OH^*$, $CH^*$ 신호는 전체 열방출율과 비례관계를 갖는 것으로 판단된다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.91-94
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• 2014

In this study, the laminar burning velocities of SNG fuel were studied using both experimental measurements and kinetic simulations. They were measured using the angle method of Bunsen flame configuration and the annular diverging channel combustor. And they were also numerically calculated by CHEMKIN Package with GRI 3.0 mechanisms. Spectrometer was used for characteristics of flame chemiluminescence of SNG fuels. From results of this work, first, we found that according to adding $H_2$ contents in the fuels the laminar burning velocities of SNG fuels were increased. And second, we also discovered existence of OH*, CH*, $C_2*$, HCO*, $CH_2*$ radicals and their correlation.

• Bulletin of the Korean Chemical Society
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• 제23권2호
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• pp.291-294
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• 2002

The reactions of triplet oxygen atom with halomethanes as a potential fire extinguisher were studied by a discharge flow-chemiluminescence imaging method. The experiments were carried out under second order conditions. The bimolecular atom-molecule reaction rate constants were determined in terms of the initial rate method. The initial concentration of oxygen atom was also determined under second order rate law instead of the pseudo-first order conditions with $[O(^3P)]_0{\ll}[sample]_0$. The second order conditions were more reliable than pseudo-first order conditions for the determinations of rate constants. The rate constants of the reactions $CF_3I\;+\;O(^3P)$, $CH_3PI\;+\'O(^3P)$, and $CHBrCl_2\;+\;O(^3P)$ were determined to be $5.0\;{\times}\;10^{-12}$ , $1.1\;×\;0^{-11}$ , and $1.9\;{\times}\;10^{-14}cm^3molecule^{-1}s^{-1}$, respectively.

• 한국연소학회:학술대회논문집
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• 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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• pp.75-81
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• 2003

In this paper, the study of effects of flow variables on flame structure and NOx emission concentration was performed in co-axial laminar partially premixed methane/air flames. the objectives are to reveal its effect as parameters were varied and to understand the correlation between flame structure and NOx emission characteristics in the reaction zone. equivalence ratio(${\Phi}$), fuel split degree(${\sigma}$), and mixing distance(x/D) were defined as a premixing degree and varied within $1.36{\sim}3.17$(equivalence ratio), $50{\sim}100$(fuel split degree), and $5{\sim}20$(mixing distance). the image of $OH{\ast}$ and $CH{\ast}$, and NOx concentration were obtained with an ICCD camera and a NOx analyzer. additionally the maximum intensity location of $OH{\ast}$ chemiluminescence and $CH{\ast}$ chemiluminescence were measured to compare each flame structures. In conclusion flame structure and NOx emission characteristics were changed from diffused to premixed flame when mixing degree was on the increase. the main effect on flame structure and NOx production was at first equivalence ratio(${\Phi}$), and next fuel split degree(${\sigma}$), and finally mixing distance(x/D).

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.258-262
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• 2011

실험용 분젠 연소기를 사용하여 예혼합된 메탄-산소 층류화염전파속도를 연구하였다. 이를 위해 $CH^*$ 자발광 측정기법과 슐리렌 사진술이 사용되었다. 실험결과는 CHEMKIN 3.7을 이용한 수치해석 결과와 비교하였다. 층류화염전파속도를 측정하기 위하여 층류여역 내에서 전체 당량비는 0.5에서 2.0까지 조절하였다. 동축 화염에서 화염전파속도는 각도측정법을 사용하였으며 슐리렌 사진에서는 3.1 m/s로 $CH^*$ 자발광 사진에서는 2.9 m/s로 측정되었다.

• 한국연소학회지
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• 제16권3호
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• pp.33-40
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• 2011

Combustion experiments were conducted at three different fuels ($CH_4$, $C_2H_4$ and $C_3H_8$) to investigate the effects of combustor pressure (30 ~ -30 kPa) on combustion charateristics and reaction zone structure. Regardless of the fuels, emission index of CO (EICO) increased with decreasing combustor pressure, and EICO of $C_2H_4$ was mostly affected by changing combustor pressure at subatmospheric pressure. In order to observe reaction zone, $OH^*$, $CH^*$ and ${C_2}^*$ chemiluminescence intensity were measured. The sequence of the chemiluminescence intensity peak position was affected by chemical characteristics of fuels rather than changing combustor pressure. The emission zone thickness of $C_2H_4$ and $C_3H_8$, defined by the full width at half maximum (FWHM) of $CH^*$ intensity profile, were increased with decreasing combustor pressure. however, the thickness of $C_2H_4$ exhibited the opposite tendency due to the characteristics of the fuel as the bond structure.

• Bulletin of the Korean Chemical Society
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• 제11권6호
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• pp.505-508
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• 1990

The electrochemical reduction and electrogenerated chemiluminescence (ECL) of $Ru(bpy)_3^{2+}-S_2O_8^{2-}\;in\;CH_3CN-H_2O$ solution were studied in the presence of sodium dodecyl sulfate (SDS) as an anionic surfactant. SDS enhanced the ECL and the fluorescence intensities and lengthened the duration of ECL due to the solubilization of reactants and possibly to the stabilization of ECL intermediates in the SDS micellar environment.

• 한국연소학회지
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• 제11권3호
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• pp.18-25
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• 2006

The present studying is aimed to establish the relationship between flame chemiluminescence$(OH^*,\;CH^*,\;C_2^*)$ intensities and combustion conditions such as $NO_x$ emission characteristics. Measurements are made for $OH^*,\;CH^*,\;C_2^*$ radicals in gas & light oil diffusion flames. At turbulent nonpremixed combustion mode, the equivalence ratio is varied. The optical emissions were measured by photomultiplier(PMT) using optical band pass filter and spectrometer system. The experimental results showed that the ratio of radicals and $NO_x$ emission characteristics have exponential correlations and equivalence ratio characteristics have linear correlations at this experimental conditions.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2000년도 제20회 KOSCO SYMPOSIUM 논문집
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• pp.142-151
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• 2000

Dump combustor is a combustor having a dump plane to make coherent structures. A non-premixed flame dump combustor of simple geometry was constructed. We conducted basic experiments such as frequency response on the combustor to confirm the characteristics of the phenomena as a typical dump combustion and unsteady combustion. Furthermore we visualized the flame front behavior by CH chemiluminescence and high speed motion analysis. In spite of the lack of another data such as velocity, species concentration and temperature, the results showed not only the periodic motion of flame front but the ignition process of vortex ring flame. Also we could check out Rayleigh criterion by combining the visualization data with the pressure data.