• Title/Summary/Keyword: CF$_4$

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The Study of Character of Electron Drift Velocity in CF4 Molecular Gas by the Boltzmann Equation (볼츠만 방정식에 의한 CF4 분자가스의 전자이동속도 특성에 관한 연구)

  • Song, Byoung-Doo;Ha, Sung-Chul
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1252-1257
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    • 2004
  • This paper describes the information for quantitative simulation of weakly ionized plasma. In previous paper, we calculated the electron transport coefficients by using two-term approximation of Boltzmann equation. But there is difference between the result of the two-term approximation of the Boltzmann equation and experiments in pure CF$_4$ molecular gas and in CF$_4$+Ar gas mixture. Therefore, In this paper, we calculated the electron drift velocity (W) in pure CF$_4$ molecular gas and CF$_4$+Ar gas mixture (1 %, 5 %, 10 %) for range of E/N values from 0.17~300 Td at the temperature was 300 K and pressure was 1 Torr by multi-term approximation of the Boltzmann equation by Robson and Ness. The results of two-term and multi-term approximation of the Boltzmann equation have been compared with each other for a range of E/N.

The Effects of Temperature Change on the Bending Strength of CF/PEEK Laminates after Impact (온도변화가 CF/PEEK 적층재의 충격 후 굽힘강도에 미치는 영향)

  • 양인영;정종안;나승우
    • Journal of the Korean Society of Safety
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    • v.18 no.2
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    • pp.34-39
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    • 2003
  • In this paper, when CF/PEEK laminates for high efficiency space structure are subjected to FOD(Foreign Object Damage), the effects of temperature change on the impact damages(interlaminar separation and transverse crack) of CF/PEEK laminates and the relationship between residual lift and impact damages are experimentally investigated. Composite laminates used in this experiment are CF/PEEK orthotropic laminated plates, which have two-interlaces [$0^{\circ}_4/90^{\circ}_8/0^{\circ}_4$]. A steel ball launched by the air gun collides against CF/PEEK laminates to generate impact damages. And then CF/PEEK specimens with impact damages are observed by a scanning acoustic microscope under room and high temperatures. In this experimental results, various relations are experimentally observed including the delamination area vs. temperature change, the bending strength vs. impact energy and the residual bending strength vs. impact damage of CF/PEEK laminates.

Evaluating The Water Resistance of Wood Adhesives Formulated with Chicken Feather Produced from Poultry Industry (도계부산물인 닭털을 이용한 목재접착제의 내수성 평가)

  • Park, Dae-Hak;Yang, In;Choi, Won-Sil;Oh, Sei Chang;Ahn, Dong-uk;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.1
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    • pp.126-138
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    • 2017
  • This study was conducted to investigate the potential of chicken feather (CF), which is a by-product in poultry industry, as a raw material of wood adhesives. For the purpose, adhesive resins were formulated with NaOH- and $H_2SO_4$-hydrolyzed CF as well as crosslinkers, and then the properties and water resistance of the adhesive resins against hot water were measured. CF was made of mainly keratin-type protein, and no or very low content of heavy metals was detected. Hydrolysis rate of CF increased as NaOH concentration in hydrolysis solutions increased. However, in order to minimize the loss of adhesive property of protein itself by the severe hydrolysis of CF and to seek its proper hydrolysis conditions, NaOH concentrations in hydrolysis solution determined to adjust to 5%, 7.5% and 10%. In the NaOH-hydrolyzed CF, $H_2SO_4$-hydrolyzed CF as a hardener and crosslinker were added to formulate CF-based adhesive resins. Solid content of the resins ranged from 28.3% to 44.8% depending on hydrolysis conditions and type of crosslinker. Viscosity of the resins at $25^{\circ}C$ was very high. However, when the temperature of the resins was increased to $50^{\circ}C$, the viscosity decreased greatly and thus the resins could be applied as a sprayable resin. Retention rate measured to evaluate the water resistance of adhesive resins was the highest in the cured resin formulated with 5% NaOH-hydrolyzed CF and 5% $H_2SO_4$-hydrolyzed CF of 10% based on the solid weight as a hardener. Retention rate depending on crosslinkers added into adhesive resins was the highest phenol-formaldehyde (PF) followed by melamine-urea-formaldehyde (MUF) and formalin. The retention rate of CF-based adhesives formulated with 5% NaOH-hydrolyzed CF, PF and $H_2SO_4$-hydrolyzed CF of 10% and over did not differ statistically from that of commercial MUF resins. All of CF-based adhesives formulated with PF as a crosslinker and one with 5% NaOH-hydrolyzed CF of 55%, 5% $H_2SO_4$-hydrolyzed CF of 15%, and MUF of 30% on the basis of solid weight could be substituted for commercial urea-formaldehyde resins, From the results, CF can be used as a raw material of wood adhesives if hydrolyzed in proper conditions.

CF4/O2 Gas를 사용한 디스플레이용 ICP 장비의 플라즈마 시뮬레이션

  • Lee, Yeong-Jun;O, Seon-Geun;Kim, Byeong-Jun;Jeon, Jae-Hong;Seo, Jong-Hyeon;Choe, Hui-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.267-267
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    • 2014
  • 디스플레이용 유도결합 플라즈마 시스템에서 CF4/O2 혼합가스를 이용하여 SiO2 식각공정에 대한 연구를 하기 위해 플라즈마 변수들에 대한 공간 분포를 살펴 보았다. 장비의 규격은 8세대 급, 안테나는 4turn을 기본으로 하며 동일한 크기의 안테나 9개를 배치하였다. 시뮬레이션 결과에 따른 플라즈마 주요변수들(전자밀도, 전자온도, 전위차)의 공간분포와 CF3+, CF2+, CF+, O2+, O-, F+, F- 이온들에 대한 공간분포를 확인 할 수 있었다.

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Electron Mean Energy in CF4, CH4, Ar mixtures (CF4, CH4, Ar 혼합기체의 전자 평균에너지)

  • Kim, Sang-Nam
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.64 no.4
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    • pp.241-245
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    • 2015
  • Energy Distribution Function in pure $CH_4$, $CF_4$ and mixtures of $CF_4$ and Ar, have been analyzed over a range of the reduced electric field strength between 0.1 and 350[Td] by the two-term approximation of the Boltzmann equation (BEq.) method and the Monte Carlo simulation (MCS). The calculations of electron swarm parameters require the knowledge of several collision cross-sections of electron beam. Thus, published momentum transfer, ionization, vibration, attachment, electronic excitation, and dissociation cross-sections of electrons for $CH_4$, $CF_4$ and Ar, were used. The differences of the transport coefficients of electrons in $CH_4$, mixtures of $CH_4$ and Ar, have been explained by the deduced energy distribution functions for electrons and the complete collision cross-sections for electrons. The results of the Boltzmann equation and the Monte Carlo simulation have been compared with the data presented by several workers. The deduced transport coefficients for electrons agree reasonably well with the experimental and simulation data obtained by Nakamura and Hayashi. The energy distribution function of electrons in $CF_4$-Ar mixtures shows the Maxwellian distribution for energy. That is, $f({\varepsilon})$ has the symmetrical shape whose axis of symmetry is a most probably energy.

A Study on the Interlaminar Fracture Toughness of Hybrid Composites (하이브리드 복합재료의 층간파괴인성치에 관한 연구)

  • Kim, Hyung-Jin;Gwark, Dae-Won;Lee, Hern-Sik;Kim, Jae-Dong;Koh, Sung-Wi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.40 no.4
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    • pp.328-336
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    • 2004
  • This paper describes the effect of loading rate, specimen geometries and material properties for ModeⅠ and Mode Ⅱ interlaminar fracture toughness of hybrid composite by using double cantilever beam (DCB) and end notched flexure (ENF) specimen. In the range of loading rate 0.2~20mm/min, there is found to be no significant effect of loading rate with the value of critical energy release rate (Gc).The value of Gc for variation of initial crack length are nearly similar values when material properties are CF/CF and GF/GF, however, the value of Gc are highest with the increasing intial crack length at CF/GF. The SEM photographs show good fiber distribution and interfacial bonding of hybrid composites when the moulding is the CF/GF.

A Study on Mode I Interlaminar Fracture Toughness of Hybrid Composites (하이브리드 복합재료의 모드 I 층간파괴인성치에 관한 연구)

  • 김형진;곽대원;김재동;고성위
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.39 no.4
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    • pp.262-268
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    • 2003
  • This paper describes the effect of loading rate, specimen geometries and material properties for Mode I interlaminar fracture toughness of hybrid composite by using double cantilever beam (DCB) specimen. In the range of loading rate 0.2-20mm/min, there is found to be no significant effect of loading rate with the value of critical energy release rate (G_IC). The value of $G_IC$ for variation of initial crack length are nearly similar values when material properties are CF/CF and GF/GF, however, the value of $G_IC/$ are highest with the increasing initial crack length at CF/GF. The SEM photographs show good fiber distribution and interfacial bonding of hybrid composites when the moulding is the CF/GF

Improvement of Weiss Model on the Conversion Factor of Fixed- to True-Interval Rainfall (임의시간 환산계수에 대한 Weiss 모형의 개선)

  • Yoo, Chulsang;Jun, Chang Hyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.4B
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    • pp.315-322
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    • 2011
  • This study reviewed the Weiss model, probably the only theoretical study available on the fixed- to true-interval rainfall conversion factor (CF), and implemented to propose a modified Weiss model. Also, the characteristics of the temporal distribution of rainfall were considered in the estimation of CF to overcome the problem of these two models, whose results were compared with those estimated empirically. As results, the CF was found to be differently estimated depending on the temporal distribution of rainfall. Especially, the theoretical CF estimate for the center-concentrated rainfall distribution was found to be very similar to that of empirical results of domestic and foreign studies.

The Effects of CF4 Partial Pressure on the Hydrophobic Thin Film Formation on Carbon Steel by Surface Treatment and Coating Method with Linear Microwave Ar/CH4/CF4 Plasma

  • Han, Moon-Ki;Cha, Ju-Hong;Lee, Ho-Jun;Chang, Cheol Jong;Jeon, Chang Yeop
    • Journal of Electrical Engineering and Technology
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    • v.12 no.5
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    • pp.2007-2013
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    • 2017
  • In order to give hydrophobic surface properties on carbon steel, the fluorinated amorphous carbon films were prepared by using linear 2.45GHz microwave PECVD device. Two different process approaches have been tested. One is direct deposition of a-C:H:F films using admixture of $Ar/CH_4/CF_4$ working gases and the other is surface treatment using $CF_4$ plasma after deposition of a-C:H film with $Ar/CH_4$ binary gas system. $Ar/CF_4$ plasma treated surface with high $CF_4$ gas ratio shows best hydrophobicity and durability of hydrophobicity. Nanometer scale surface roughness seems one of the most important factors for hydrophobicity within our experimental conditions. The properties of a-C:H:F films and $CF_4$ plasma treated a-C:H films were investigated in terms of surface roughness, hardness, microstructure, chemical bonding, atomic bonding structure between carbon and fluorine, adhesion and water contact angle by using atomic force microscopy (AFM), nano-indentation, Raman analysis and X-ray photoelectron spectroscopy (XPS).

Surface Reactions on the Bi4-xLaxTiO3O12 Thin Films Etched in Inductively Coupled CF4/Ar Plasma (유도결합 CF4/Ar 플라즈마에 의한 Bi4-xLaxTiO3O12 박막의 식각 표면 반응)

  • 김동표;김경태;김창일
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.5
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    • pp.378-384
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    • 2003
  • Etching species in CF$_4$/Ar plasma and the behavior of etching rate of Bi$_4$-$_{x}$L$_{x}$rTi$_3$O$_2$ (BLT) films were investigated in inductively coupled plasma (ICP) reactor in terms of etch parameters. The etching rate as functions of CF$_4$ contents showed the maximum 803 $\AA$/min at 20% CF$_4$ addition in CF$_4$/Ar plasma. The increase of RF power and DC bias voltage caused to an increase of etch rate. The variation of relative volume densities for F and he atoms were measured with the optical emission spectroscopy (OES). The chemical states of BLT were investigated with using X-ray photoelectron spectroscopy (XPS). XPS narrow scan analysis shows that La-fluorides remained on the etched surface. The presence of maximum etch rate at CF$_4$(20%)/Ar(80%) may be explained by the concurrence of two etching mechanisms such as physical sputtering and chemical reaction. The roles of he ion bombardment include destruction of metal (Bi, La, Ti)-O bonds as well as assistant for chemical reaction of metals with fluorine atoms.oms.