• 제목/요약/키워드: CD73

검색결과 217건 처리시간 0.022초

비소와 중금속으로 오염된 광미의 토양세척 후 잔류 중금속의 안정화 처리 (Stabilization of Residual Heavy Metals after Soil Washing of Mine Tailings Contaminated with Arsenic and Heavy Metals)

  • 임미희;김명진
    • 대한환경공학회지
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    • 제36권1호
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    • pp.67-73
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    • 2014
  • 본 연구에서는 토양세척기법으로 1차 처리한 광미에 제거되지 않고 남아있는 중금속을 인산염을 이용해서 안정화하였다. 광미에 잔류하는 오염물질 농도는 As (1,861 mg/kg), Cd (20 mg/kg), Cu (56 mg/kg), Pb (2,149 mg/kg), Zn (633 mg/kg)이었다. 안정화제로는 $CaHPO_4$, $Ca(H_2PO_4)_2{\cdot}H_2O$, hydroxyapatite를 사용하였고, 안정화제의 첨가량은 0.1 wt%, 1 wt%, 10 wt%, 안정화 기간은 1, 3, 5, 7, 14일로 조절하였다. 세 가지 안정화제 모두 효율이 높았지만, 그 중에서 $Ca(H_2PO_4)_2{\cdot}H_2O$의 효율이 가장 높았고 첨가량은 1 wt%가 적당했다. 안정화 기간에 따른 효율차이는 크지 않았다. 1 wt% $Ca(H_2PO_4)_2{\cdot}H_2O$를 사용해서 1일 동안 안정화처리를 한 경우, TCLP 용출액의 비소와 중금속 농도는 As (0.328 mg/L), Cd (0.250 mg/L), Cu (0.143 mg/L), Pb (0.359 mg/L), Zn (2.622 mg/L)로 모두 각각의 RCRA-TCLP 기준치 이하로 나타나 안정성이 있는 것으로 평가되었다.

두 단계 중화적정에 의한 산성 광산 유출수 중의 중금속 제거 (Characterization and Two-Phase Neutralization of Acid Mine Drainage)

  • 정병룡;정종배
    • Applied Biological Chemistry
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    • 제42권1호
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    • pp.73-78
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    • 1999
  • Pyrite의 산화과정에서 생성되는 황산 때문에 발생하는 산성 광산 유출수는 다량의 중금속들을 함유하므로 적절한 처리 과정을 거친 후 배출되어야 한다. 산성 광산 유출수의 중화과정에서 발생하는 침전물은 주로 철과 알루미늄의 수산화물인대, 이 두 침전물은 2단계 중화과정을 거치면 분리될 수 있다. 본 연구에서는 대구시 달성군 가창면에 위치한 폐중석광산의 유출수를 이용하여 철과 알루미늄의 침전물에 의한 중금속의 제거 현상을 조사하였다. 유출수의 pH는 3.2였으며 As, Cd, Cu, Mn, Pb, Zn 등의 함량이 하천수질기준이나 폐수배출허용기준을 상회하였다. 1단계 중화에서는 $Ca(OH)_2$를 이용하여 철이 먼저 침전되도록 하였으며, 철을 100% 침전시켰을 때 납은 상당부분 침전으로 제거되었으나 대부분의 중금속은 제거되지 않았다. 2단계 중화에서는 1단계 중화 후의 상등액을 pH 7.5까지 적정하였는데, 이 때 As, Cd, Cu, Mi, Mn, Zn 등의 중금속들이 하천으로 방류가 가능한 수준으로 제거되었다. 1단계 중화에서 발생한 철 침전물은 특별한 처리 없이 폐기될 수 있을 것이며, 2단계 중화에서 생성된 침전물은 중금속을 함유하므로 특정폐기물로 취급하여 처리하여야 할 것이다. 이러한 두 단계 중화과정을 거치면 효과적인 중금속의 제거와 함께 산성 광산 유출수의 처리 후 발생하는 중금속 함유 침전물의 처리에 따른 비용의 절감이 가능할 것이다.

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GLOBAL CONVERGENCE OF AN EFFICIENT HYBRID CONJUGATE GRADIENT METHOD FOR UNCONSTRAINED OPTIMIZATION

  • Liu, Jinkui;Du, Xianglin
    • 대한수학회보
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    • 제50권1호
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    • pp.73-81
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    • 2013
  • In this paper, an efficient hybrid nonlinear conjugate gradient method is proposed to solve general unconstrained optimization problems on the basis of CD method [2] and DY method [5], which possess the following property: the sufficient descent property holds without any line search. Under the Wolfe line search conditions, we proved the global convergence of the hybrid method for general nonconvex functions. The numerical results show that the hybrid method is especially efficient for the given test problems, and it can be widely used in scientific and engineering computation.

통신기능이 부가된 LED Tile용 구동회로 개발 (Drive Circuit Development for LED Tile Which is Added the Communication)

  • 천우영;송상빈;김진홍;김기훈
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2007년도 춘계학술대회 논문집
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    • pp.70-73
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    • 2007
  • 생활수준의 향상으로 인하여 조명 및 디스플레이 제품을 이용하여 건물 및 건축물에 대하여 장식을 하는 것이 일반화 되어가고 있다. 본 연구에서는 옥외 및 옥내에 사인물로 사용되어지고 있으며 설치가 간편한 디스플레이 조명기기인 LED Tile을 개발하여 옥내 및 옥외용 디스플레이 조명 시장의 시장성 확보하기 위하여, 광학설계를 통한 고휘도 LED의 선정 및 배치, 케이스 설계를 실시하고 LED모듈에 AC 220V 전원을 직접 인가할 수 있으며 효율이 높고 최적화된 구동회로를 설계하였다. 또한 One Chip 마이크로컨트롤러를 사용하여 RGB LED의 광색가변 및 점멸 제어회로를 설계하고, LED 모듈간에 2개의 제어선만을 연결하여 다양하고 다이나믹한 패턴 동작(점멸, 광색가변)이 가능하도록 펌웨어를 설계하였다. 그 결과 설계된 LED Tile은 전체 크기가 $D130{\times}W130{\times}H50mm$로 매우 컴팩트하고 LED 배치 및 광학설계를 통하여 최대광도 60cd를 실현하였으며, LED Tile의 동작개수에 관계없이 설치가 간단하며 10개 이상의 디스플레이 패턴 제어가 가능하였다.

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OLED 소자의 가속수명 시험에 관한 연구 (A study on OLED device's accelerated lifetime test)

  • 최영태;조재립
    • 대한안전경영과학회지
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    • 제10권3호
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    • pp.73-79
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    • 2008
  • Display's life time is defined as the time of 50% luminance drop. It was used luminance and temperature as accelerated factor to accelerated lifetime at test. When it's working jule-heat is generated and device's temperature is growing as any temperature because OLED is self-luminance display device. So we decided temperature condition is 25, $70^{\circ}C$, and luminance condition is $60{\sim}300cd/m^2$ in test. It's assumed accelerated lifetime model by result of the test.

A Novel Polymer Membrane for Extraction Applications

  • Wang, Xungai;Xu, Jianying;Paimin, Rohani;Shen, Wei
    • Fibers and Polymers
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    • 제3권2호
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    • pp.68-73
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    • 2002
  • In this study, a new type of Aliquat 336/PVC membrane has been made for extraction experiments. This new membrane is capable of holding more Aliquat 336 than previously developed extraction membranes, hence overcoming a major problem that has confronted many researchers for a long time. The new membrane has been used try investigate the rate of extraction fur the Cd(II) ion in 2.0 M HCI solution and the effect of membrane thickness on the rate of extraction. The experimental results have shown this new membrane has a promising future in relevant industrial applications. A new method is also used in this study to qualitatively identify the oily substance on the surface of membrane after the extraction experiment was completed. This oily substance has been found to be Aliquat 336.

방사면역치료(I): 방사면역접합체 개발 (Radioimmunotherapy (I): Development of Radioimmunoconjugates)

  • 최태현;임상무
    • Nuclear Medicine and Molecular Imaging
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    • 제40권2호
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    • pp.66-73
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    • 2006
  • Monoclonal antibodies are designed to bind specifically to certain antigen, give therapeutic effect to the target and to be produced in large scale with homogeneity. The monoclonal antibodies conjugated with radionuclide can deliver therapeutic irradiation to the target, and showed successful results in certain malignancies, which is known as radioimmunotherapy. The target-to-background ratio depends on the antigen expression in the target and normal tissues, which is related to the therapeutic efficacy and toxicity in radioimmunotherapy. For the solid tumor beta-ray energy should be high, but lower beta energy is better for the hematological malignancies. I-l31 is widely used in thyroid cancer with low cost and high availability. Labeling monoclonal antibody with I-131 is relatively simple and reproducible. Some preclinical data for the I-131 labeled monoclonal antibodies including acute toxicity and efficacy are available from already published literatures in KIRAMS, physician sponsored clinical trial protocols using Rituximab, KFDA approved anti-CD20 chimeric monoclonal antibody and I-131 were approved by KFDA and currently are ongoing.

Analysis for the secondary gamma-ray emission for glasses irradiated with various doses of fast neutron: Case study borate and silicate glasses

  • O.L. Tashlykov;V. Yu. Litovchenko;N.M. Aristov;K.A. Mahmoud
    • Nuclear Engineering and Technology
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    • 제55권7호
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    • pp.2366-2372
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    • 2023
  • Are borate and silicate glasses suitable for working as shieling materials against fast neutrons? To correctly answer the above question, some silicate, and borate-based glasses were fabricated and irradiated with various doses of fast neutrons varied between 1.73 and 12.10 MGy. The color and hardness of the fabricated glasses were affected by the fast neutron fluence where the transparent glasses turned colored as well as the hardness of the fabricated glasses was decreased. The gamma-ray spectrometric analysis shows a high activity concentration produced in the barium borate glasses due to the formation of radioisotopes Ba-131 and Ba-133 reaches to 5.92E+05 Bq and 4.25E+03 Bq, respectively for sample Cd-5 Batch 3. Additionally, the gamma-ray spectrometric analysis for the sodium silicate glasses shows low activity concentrations emitted from isotopes formed due to the activation of Y2O3-associated impurities. These activities are low compared to that emitted by barium borate-based glasses.

Adsorption of Heavy Metal Ions onto Chemically Oxidized Ceiba pentandra (L.) Gaertn. (Kapok) Fibers

  • Chung, Byung-Yeoup;Cho, Jae-Young;Lee, Min-Hee;Wi, Seung-Gon;Kim, Jin-Hong;Kim, Jae-Sung;Kang, Phil-Hyun;Nho, Young-Chang
    • Journal of Applied Biological Chemistry
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    • 제51권1호
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    • pp.28-35
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    • 2008
  • The physico-chemical properties of kapok fibers were altered via the combination processes of chlorite-periodate oxidation, in order to assess their efficacy as a heavy metal adsorbent. The chemically-oxidized kapok fibers were found to harbor a certain amount of polysaccharides, together with lowered lignin content. This alteration in lignin characteristics was clearly confirmed via FTIR and NBO yield. Moreover, chemically oxidized kapok fibers retained their hollow tube shape, although some changes were noted. The chemically oxidized kapok fibers evidenced elevated ability to adsorb heavy metal ions with the best fit for the Langmuir adsorption isotherm model. Three cycles of adsorption-desorption were conducted with in-between regeneration steps. Our experimental results indicated that chemically oxidized kapok fibers possessed excellent adsorption characteristics, and the modified kapok fibers could be completely regenerated with almost equimolar diluted sodium hydroxide. Pb, Cu, Cd and Zn ions evidenced adsorption rates of 93.55%, 91.83%, 89.75%, and 92.85% on the chemically oxidized kapok fibers. The regeneration efficiency showed 73.58% of Pb, 71.55% of Cu, 66.87% of Cd, and 75.00% of Zn for 3rd cycle with 0.0125N NaOH.

조립재가 흙의 역학적 성질에 미치는 영향 (Effect of Coarse mateflal on the mechanical properties of Soil)

  • 윤충섭;김호일
    • 한국농공학회지
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    • 제31권3호
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    • pp.57-69
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    • 1989
  • The study was carried out for the strength parameter of coarse grained Soil and slope stability analysis of earth dam. The test samples were taken fifteen kinds of soil from cohesive soil to coarse gravel. The degree of compaction of test samples for shear test and permeability test was chosen 95 percentage of maximum dry density. The results of this study are as follows ; 1.The maximum dry density(Yd) of coarse grained soil increase in proportion to coarse particles(P) with the relation of Y d= 1.609+0.0043P. 2.The coefficients of permeability(k) decrease by the increase of fine particles(n) with the relation of k=0.0426e-0 185n. 3.The cohesions of soil decrease by the increase of coarse particles, but internal friction angles are more increased in same condition. 4.The internal friction angles(${\Phi}$) decrease in inverse proportion to void ratio(e) with the relation of ${\Phi}$ = 73.068 - 69.268e. 5.The strength parameters( Ct ${\Phi}$t) by triaxial compression test are clearly smaller than that (Cd, ${\Phi}$d) by direct shear test in fine grained soil, but the differences between both parameters are a little in coarse grained soil.The relations of both parameters are as follows; Ct = O.544Cd + 0.04 ${\Phi}$t= 1.282${\Phi}$d-2306 6.In cohesive soil, the strength parameters( Cl ${\Phi}$l) by large size shear test apparatus are similar to the strength parameters(Cs , ${\Phi}$s) by small size shear test appratus, but Cs and ${\Phi}$s values are larger than Cl and ${\Phi}$l values from 10 percentage to 20 percentage in coarse grained soil. 7.The fine grained soil is inappropriate to high dam more than 20 meters and it must be taken coarse grained soil with high internal friction angle for high dam.

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