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A Study on Soil Clay Minerals and the Distribution of Heavy Metals in Soils Derived from Black Shale and Black Slate in Dukpyoung Area (충북 괴산 덕평리 일대 흑색셰일 및 흑색점판암기원 토양의 점토광물 조성 및 중금속원소의 분산)

  • Chon, Chul-Min;Moon, Hi-Soo;Choi, Sun Kyung;Woo, Nam Chil
    • Economic and Environmental Geology
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    • v.30 no.6
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    • pp.567-586
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    • 1997
  • Concentrations of several heavy metals in soils derived from black shale and slate have been reported to be higher than the average concentrations in non-polluted soils. This study describes and characterizes soil minerals, and investigates the distribution of heavy metals in soils, and then examines their relationship. Soils in the study area are mainly consist of guartz and feldspars with minor amount of kaolin, illite, vermiculite, chlorite and illite-vermiculite interstratified minerals. Mineral compositions are similar in mountain-, farmland-, and paddy-soils. The residual soils derived from sandy phyllites contain less illites than those from black shale and black slate. Heavy metals appear to be more concentrated in soils than in rocks. The concentrate ratios in soils to rocks ranges 1.1 times for Cr, 2 for Cu, 1.4 for Ni. The contour maps of Cd, Zn, Pb, Cu contents using 0.43N $HNO_3$-extraction imply that these elements are highly concentrated in the soils near the past uranium exploration region, coal seams, black slate beds and tailings than other parts of the study area. The proportions of the day in most soils are less than 10%. In spite of small proportions of the clay, the concentrations of heavy metals from clay fractions to the total concentrations are high: 1~2.4 times for Co, 1.4~2.5 for Cu, 1.2~2.6 for Ni, 1~5 for Pb, 1~2.7 for Zn and 1.6~1.8 for Cr and V. The contents of organic carbons in clay fractions are also 1.5~3.9 times higher than in silt and sand fractions. Cu, Pb and organic carbons show positive relationship in all size fractions. In the size-fractionated soil profile samples, the contents of heavy metals and organic carbons show analogous trends with depth. For the clay fractions of soil profile samples, the contents of heavy metals with depth have analogous trends to abundances of vermiculites, which have the high CEC in main clay minerals.

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Study on Chemical Characterization of PM2.5 based on Long-term Database (1990 ~ 2012) and Development of Chemical Species Profiles During Haze Days and Asian Dust Days in Yongin-Suwon Area (장기간 (1990 ~ 2012) 측정자료를 이용한 용인-수원지역에서의 PM2.5의 화학적 특성연구 및 헤이즈와 황사 현상 시 화학성분별 질량분율표의 개발)

  • Lim, Hyoji;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.3
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    • pp.223-238
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    • 2015
  • The $PM_{2.1}$ was collected by LVCI (low volume cascade impactor) during Group-A Period (September 1990 to December 2012) and the $PM_{2.5}$ was collected by HVAS (high volume air sampler) during Group-B Period (September 2009 to April 2012) at Kyung Hee University, Global Campus located on the boarder of Yongin and Suwon. The 8 water-soluble ions ($Na^+$, $NH_4{^+}$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, $ NO_3{^-}$, and $SO_4{^{2-}}$) were analyzed by IC, and the 14 inorganic elements (Al, Mn, Si, Fe, Cu, Pb, Cr, Ni, V, Cd, Ba, Zn, Ti, Ag) were analyzed by XRF and ICP-AES after performing proper pre-treatments of each sample filter. The average total mass fractions of $SO_4{^{2-}}$, $NO_3{^-}$, and $NH_4{^+}$+ to $PM_{2.5}$ samples during Group-B Period were 0.39 in normal days, 0.44 in haze days, and 0.27 in Asian dust days, respectively; however, the average total mass fractions of Al, Fe, and Si to $PM_{2.5}$ mass were 0.043 in normal days, 0.021 in haze days, and 0.036 in Asian dust days, respectively. Especially the concentration of Pb was significantly decreased during Group-B Period rather than during Group-A Period, while Cr and Ni was increased during Group-B Period. In this study, we intensively compared the annual and seasonal patterns of major chemical species among normal days, haze days, and Asian dust days. Further we developed mass fraction profiles by collecting episode cases of haze days and Asian dust days, which were consisting of 22 chemical species. Those profiles are considered to be useful when applying various receptor models and establishing air quality management plans near future.

Combustion of a Female Body Due to an External Ignition Source (외부 점화원에 의한 여성 신체의 연소)

  • Cho, Young Jin;Ji, Hong Keun;Kim, Sun Jae;Lim, Kyu Young;Lee, Dong Kyu;Choi, Gyeong Won;Park, Jong Taek;Moon, Byung Sun;Goh, Jae Mo;Park, Nam Kyu
    • Fire Science and Engineering
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    • v.34 no.2
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    • pp.94-96
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    • 2020
  • In November 2013, a case of sustained combustion of a female body was encountered in a Korean farming village. The body was almost completely incinerated from the neck to the knees, and other parts of the body, such as the head, arms, lower legs, and feet, were slightly damaged. The most likely external ignition source was the flame from a matchstick. The elderly woman was found incinerated on the floor of the living room, while other objects in the house were largely undamaged except for having a brown oily or greasy coating. Flammable substances were not detected from the woman's intact pieces of clothing and socks, and her muscular tissues did not contain toxic chemicals. The concentration of carboxyhemoglobin in her peripheral blood was 11% and that of ethyl alcohol in her aqueous humor was below 0.010%. An autopsy failed to determine the exact cause of death because of excessive charring.

Meningeal Hemangiopericytomas and Meningomas: a Comparative Immunohistochemical and Genetic Study

  • Trabelsi, Saoussen;Mama, Nadia;Chourabi, Maroua;Mastouri, Maroua Haddaji;Ladib, Mohamed;Popov, Sergey;Burford, Anna;Mokni, Moncef;Tlili, Kalthoum;Krifa, Hedi;Jones, Chris;Yacoubi, Mohamed Tahar;Saad, Ali;Brahim, Dorra H'mida-Ben
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.16
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    • pp.6871-6876
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    • 2015
  • Background: The meningeal hemangiopericytoma (MHPC) is a vascular tumor arising from pericytes. Most intracranial MHPCs resemble meningiomas (MNGs) in their clinical presentation and histological features and may therefore be misdiagnosed, despite important differences in prognosis. Materials and Methods: We report 8 cases of MHPC and 5 cases of MNG collected from 2007 to 2011 from the Neuro-Surgery and Histopathology departments. All 13 samples were re reviewed by two independent pathologists and investigated by immunohistochemistry (IHC) using mesenchymal, epithelial and neuro-glial markers. Additionally, we screened all tumors for a large panel of chromosomal alterations using multiplex ligation probe amplification (MLPA). Presence of the NAB2-STAT6 fusion gene was inferred by immunohistochemical staining for STAT6. Results: Compared with MNG, MHPCs showed strong VIM (100% of cases), CD99 (62%), bcl-2 (87%), and p16 (75%) staining but only focal positivity with EMA (33%) and NSE (37%). The p21 antibody was positive in 62% of MHPC and less than 1% in all MNGs. MLPA data did not distinguish HPC from MNG, with PTEN loss and ERBB2 gain found in both. By contrast, STAT6 nuclear staining was observed in 3 MHPC cases and was absent from MNG. Conclusions: MNG and MHPC comprise a spectrum of tumors that cannot be easily differentiated based on histopathology. The presence of STAT6 nuclear positivity may however be a useful diagnostic marker.

In Vivo Angiogenic Capacity of Stem Cells from Human Exfoliated Deciduous Teeth with Human Umbilical Vein Endothelial Cells

  • Kim, Ji-Hye;Kim, Gee-Hye;Kim, Jae-Won;Pyeon, Hee Jang;Lee, Jae Cheoun;Lee, Gene;Nam, Hyun
    • Molecules and Cells
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    • v.39 no.11
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    • pp.790-796
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    • 2016
  • Dental pulp is a highly vascularized tissue requiring adequate blood supply for successful regeneration. In this study, we investigated the functional role of stem cells from human exfoliated deciduous teeth (SHEDs) as a perivascular source for in vivo formation of vessel-like structures. Primarily isolated SHEDs showed mesenchymal stem cell (MSC)-like characteristics including the expression of surface antigens and in vitro osteogenic and adipogenic differentiation potentials. Moreover, SHEDs were positive for NG2, ${\alpha}$-smooth muscle actin (SMA), platelet-derived growth factor receptor beta ($PDGFR{\beta}$), and CD146 as pericyte markers. To prove feasibility of SHEDs as perivascular source, SHEDs were transplanted into immunodeficient mouse using Matrigel with or without human umbilical vein endothelial cells (HUVECs). Transplantation of SHEDs alone or HUVECs alone resulted in no formation of vessel-like structures with enough red blood cells. However, when SHEDs and HUVECs were transplanted together, extensive vessel-like structures were formed. The presence of murine erythrocytes within lumens suggested the formation of anastomoses between newly formed vessel-like structures in Matrigel plug and the host circulatory system. To understand underlying mechanisms of in vivo angiogenesis, the expression of angiogenic cytokine and chemokine, their receptors, and MMPs was compared between SHEDs and HUVECs. SHEDs showed higher expression of1VEGF, SDF-$1{\alpha}$, and $PDGFR{\beta}$ than HUVECs. On the contrary, HUVECs showed higher expression of VEGF receptors, CXCR4, and PDGF-BB than SHEDs. This differential expression pattern suggested reciprocal interactions between SHEDs and HUVECs and their involvement during in vivo angiogenesis. In conclusion, SHEDs could be a feasible source of perivascular cells for in vivo angiogenesis.

Quality Characterization of Salmon Oil Microencapsulated with Various Wall Materials (다양한 피복물질을 이용한 연어 오일의 미세캡슐화 및 품질 특성)

  • LIM, Hyun-Jung;PARK, Seul-Ki;KIM, Min-Jeong;LEE, Won-Kyung;MIN, Jin-Ki;CHO, Young-Je
    • Journal of Fisheries and Marine Sciences Education
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    • v.27 no.5
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    • pp.1334-1342
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    • 2015
  • The aim of this study was to investigate the quality characterization of salmon oil microencapsulated with maltodextrin (MD), cyclodextrin (CD), sodium caseinate (SC), arabic gum (AG) and WPI. After spray drying to ambient temperature, the salmon oil powders were packed (single package) and placed at room temperature ($25^{\circ}C$) for 30 day. The quality characterization of salmon oil powder including total oil (%), extractable oil (%), encapsulation efficiency (%), fatty acid, SEM, pH, acid value (AV), peroxide value(POV) were investigated. Salmon oil was microencapsulated with a high power yield (> 80%); including the formulation MD/SC and MD/SC/WPI. The microencapsules of MD/SC/WPI presented spherical shapes, smooth texture and non-porous surfaces. The pH of MD/SC/WPI varied from 6.11 to 5.99 (p>0.05). The AV of MD/SC/WPI varied from 4.74 to 4.61 (p>0.05). The pH and AV were not significantly different. The POV of MD/SC/WPI increased with storage day (p<0.05). It was concluded that MD/SC/WPI could delay lipid oxidation and high yield (82.55%) of salmon oil powder.

Alteration in plasma chemokine profile in a high-fat diet-induced obesity mouse model (고지방식이로 비만을 유도한 생쥐에서 혈장 케모카인 발현 변화)

  • Kim, Dong-Hwan;Cho, Jeong Min;Seo, Min Joon;Lim, Ju Hyun;Bae, Hae-Rahn
    • Journal of Nutrition and Health
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    • v.51 no.5
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    • pp.369-378
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    • 2018
  • Purpose: Obesity is associated with a dysregulation of metabolic balance and is regarded as a low grade chronic inflammation. Western-style diet and physical inactivity are leading causes of obesity. This study examined the profiles of forty plasma cytokines and chemokines at the same time in the early stages of high-fat diet-induced obesity using a mouse model. Methods: A total of 30 male CD1 mice, 12 ~ 14 weeks of age, were enrolled. The mice were fed a high-fat diet for 6 weeks to induce obesity. The plasma glucose and triglyceride concentrations were measured using a hexokinase colorimetric assay kit and a serum triglyceride determination kit, respectively. The relative levels of multiple cytokines and chemokines in the plasma were determined using a mouse cytokine array kit. Results: The mice exhibited significant weight gain after 6 weeks of a high-fat diet. The genital fat depot was enlarged along with an increase in the number and the mean size of white adipocytes as early as 4 weeks after a high-fat diet. In addition, the plasma glucose and triglyceride levels increased significantly after 4 weeks of a high-fat diet. Cytokine array analysis revealed a remarkable increase in the expression of both CXCL12 and CXCL13, whereas the proinflammatory cytokines remained low after 4 weeks of a high-fat diet. Conclusion: A significant increase in plasma levels of CXCL12 and CXCL13 was observed after 4 weeks of a high-fat diet, which might induce the migration of B lymphocytes, T lymphocytes, and monocytes from the blood to expanding adipose tissue or fat associated lymphoid clusters, playing a key role in adipose tissue remodeling and local immunity during the early stages of high-fat diet-induced obesity.

A Study on the Moisture Evaporation and Property Change Depending on the Composting Temperature for the Escalator Reversing Composting System (기계교반 퇴비화시설에서의 구간별 발효온도에 따른 수분 증발량 및 특성 변화 연구)

  • Kwag J. H.;Choi D. Y.;Park C. H.;Jeong K. H.;Kim J. H.;Kang H. S.;Yang C. B.;La C. S.
    • Journal of Animal Environmental Science
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    • v.10 no.3
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    • pp.163-168
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    • 2004
  • This research was carried out to investigate the moisture evaporation and property change depenging on the composting temperature for the escalator reversing composting system. The system was supported by the Y livestock cooperative composting factory. According to the test, the composting remperature eas varied in the range of $65\~80^{\circ}C$. The water content was de-creased to $75\%$ and became about $60\%$ at the end of the phase. Total nitrogen became $0.58\%$, total phosphoric acid $1.47\%$ and potashium $0.49\%$ at the end of the phase.

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Chinese yam necrotic mosaic virus Isolated from Chinese Yam in Korea (한국산 장마(Dioscorea oppasita cv. Jang-Ma)에서 분리한 Chinese yam necrotic mosaic virus)

  • Kang, Dong-Kyoon;Kondo, Toru;Shin, Jong-Hee;Shin, Hye-Young;Sung, Jung-Hyun;Kang, Sang-Gu;Chang, Moo-Ung
    • Research in Plant Disease
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    • v.9 no.3
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    • pp.107-115
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    • 2003
  • Chinese yam (Dioscorea opposita cv. Jang-Ma) plants showing necrotic mosaic symptom were collected from their growing fields in Andong, Euisong, Gunwi and Daegu, Korea. Direct negative stainning method by electron microscope showed filamentous particles of about 660 nm in length. Immunosorbent electron microscopy (ISEM) revealed filamentous particles of 660nm decorated with antiserum of Chinese yam necrotic mosaic virus (ChYNMV). The virues purified partially were used to isolate viral RNA as template for RT-PCR to amplify about 1.2 kbp of 3'-terminal region (coat protein, 3'-UTR) with ChYNMV specific and oligo-dT primers. Amino acids sequences of amplified CP genes revealed that the viruses shared 97.9% similarity with ChYNMV (AB044386) wh ich was known as the member of Macluravirus. So the viruses from Chinese yam (D. opposita cv. Jang-Ma) plants were identified as ChYNMV. Comparing the CP amion acid sequences of ChYNMV strains with other macluraviruses such as Cardamon mosaic virus (CdMV), Narcissus latent virus (NLV) and Maclura mosaic virus (MacMV) revealed that N-terminal was the most varialbe region and conserved regions were present within the genus Macluravirus.

Optimization of Coho Salmon Hydrolysate Using Japanese Squid Liver and Its Properties (일본산 오징어 간을 이용한 은연어 가수분해물 제조의 최적화와 가수분해물의 특성)

  • Lee, Su-Seon;Park, Joo-Dong;Konno, Kunihiko;Choi, Yeung Joon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.11
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    • pp.1759-1766
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    • 2013
  • In this study, the optimal conditions for salmon hydrolysate using squid liver and compositional properties of hydrolysate were investigated. The optimal conditions were $55^{\circ}C$, pH 5.5 and 0.66~0.67% (w/w) in the ratio of squid liver to acidic and thermal treated salmon muscle. The free amino acid of hydrolysate from the acidic treated salmon muscle was higher than that of hydrolysate from the thermal treated salmon muscle, while the total amino acid and mineral were high in the acidic treated salmon muscle. Furthermore, cadmium of hydrolysate from the thermal denatured salmon muscle was below 2 ppm, and has an acceptable level as potential ingredient. The distribution of peptide molecular weight was 40.0% for 1.0~9.5 kDa, 6.7% for 0.5 kDa, and 47.4% of others in hydrolysate from the thermal treated salmon muscle. Both hydrolysates did not show any toxicity against the HepG2 cell line for up to $200{\mu}g/mL$.