• Title/Summary/Keyword: CARBON

Search Result 26,544, Processing Time 0.046 seconds

Characterization of Nanostructure and Electronic Properties of Catalytically Grown Carbon Nanofiber (촉매법으로 제조한 나노탄소섬유의 미세구조 및 전기적 특성 제어 연구)

  • 김명수;우원준;송희석;임연수;이재춘
    • Journal of the Korean Ceramic Society
    • /
    • v.37 no.4
    • /
    • pp.345-353
    • /
    • 2000
  • Carbon nanofibers were prepared from the decomposition of various carbon-containing gases over pure Ni, pure Fe and their alloys with Cu. They yields, properties, and structure of carbon nanofibers obtained from the various reaction conditions were analyzed. Type of reacting gas, reaction temperature and catalyst composition were changed as the reaction variable. With Ni-Cu catalysts, the maximum yields of carbon nanofibers were obtained at temperatures between 550 and 650$^{\circ}C$ according to the reacting gas mixtures of C2H2-H2, C2H4-H2 and C3H8-H2, and the surface areas of the carbon nanofibers produced were 20∼350㎡/g. In the case of CO-H2 mixture, the rapid deposition of carbon nanofibers occurred with Fe-Cu catalyst and the maximum yield were obtained around 550$^{\circ}C$ with the range of surface areas of 140∼170㎡/g. The electrical resistivity of carbon nanofiber regarded as the key property of filler for the application of electromagnetic interference shielding was very sensitive to the type of reactant gas and the catalyst composition ranging 0.07∼1.5Ωcm at a pressure of 10000 psi, and the resistivity of carbon nanofibers produced over pure nickel catalyst were lower than those over alloy catalysts. SEM observation showed that the carbon nanofibers produced had the diameters ranging 20∼300 nm and the straight structure of carbon nanofibers changed into the twisted or helical conformation by the variation of reacting gas and catalyst composition.

  • PDF

A Study of Mechanical Interfacial Properties of Carbon Nanotube on Carbon Fiber/Epoxy Resin Composites (탄소나노튜브로 표면처리 된 탄소섬유/에폭시 수지 복합재료의 기계적 특성 연구)

  • Hong, Eunmi;Lee, Kyuhwan;Kim, Yangdo;Lim, Dongchan
    • Journal of the Korean institute of surface engineering
    • /
    • v.46 no.5
    • /
    • pp.223-228
    • /
    • 2013
  • In this work, the grow of carbon nanotube (CNT) on carbon fiber was introduced on PAN-based carbon fibers for the enhancement of mechanical interfacial strength of carbon fibers-reinforced composites. The surface properties of carbon fibers were determined by scanning electron microscopy (SEM) and mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS). From the results, it was found that the mechanical interfacial properties of CNT-carbon fibers-reinforced composites (CNT-CFRPs) enhanced with decreasing the CNT content. The excessive CNT content can lead the failure due to the interfacial separation between fibers and matrices in this system. In conclusion, the optimum CNT content on carbon fiber surfaces can be a key factor to determine the mechanical interfacial properties of the CNT-CFRPs.

Gamma-Radiolysis of Carbon Dioxide (IV). Effect of the Addition of Alcohols on the Gamma-Radiolysis of Gaseous Carbon Dioxide$^+$

  • Jin Joon Ha;Choi Jae Ho;Pyun Hyung Chick;Choi Sang Up
    • Bulletin of the Korean Chemical Society
    • /
    • v.9 no.1
    • /
    • pp.55-59
    • /
    • 1988
  • The gaseous carbon dioxide has been irradiated with Co-60 gamma-radiation in the presence and absence of various alcohols, and the radiolysis products analyzed by gas chromatography. Experimental results indicate that no detectable amount of carbon monoxide is formed when pure carbon dioxide is irradiated. By adding small quantities of alcohols to carbon dioxide, however, considerable amount of carbon monoxide, ketones, alcohols and other organic products have been detected. By adding 0.1% of methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-methyl-l-propanol, 2-butanol, and 2-methyl-2-propanol, G(CO) values obtained are 4.4, 4.5, 5.2, 4.4, 5.2, 5.0, 4.7 and 4.1, respectively. These high yields of carbon monoxide suggest that the oxidation reactions of carbon monoxide may be suppressed by scavenging oxygen atom with the alcohols. The main radiolytic decomposition reactions of the alcohols present in small quantity in carbon dioxide may be supposed to be the reactions with the oxygen atom produced by the radiolysis of carbon dioxide. The decomposition reactions seems to follow pseudo-first order kinetics with respect to the alcohols. The decomposition rate measured with 2-propanol is the fastest and that with 2-methyl-2-propanol the slowest. The mechanisms of the radiolytic decomposition reactions of the alcohols present in carbon dioxide are discussed on the basis of the experimental results of the present study.

Using Coffee-Derived Hard Carbon as a Cost-Effective and Eco-Friendly Anode Material for Li-Ion Batteries

  • Hong, Sung Joo;Kim, Seong Su;Nam, Seunghoon
    • Corrosion Science and Technology
    • /
    • v.20 no.1
    • /
    • pp.15-21
    • /
    • 2021
  • Through a simple filtration process, followed by carbonization within a reductive environment, coffee waste grounds can be transformed into a non-porous hard carbon for use in multiple contexts. This resulting coffee-waste carbon has been evaluated as an eco-friendly and cost-effective replacement for conventional graphite. When compared with different types of carbon, our study found that the coffee-waste carbon fell into the category of hard carbon, as verified from the galvanostatic charge/discharge profiles. The coffee-waste carbon showed a superior rate capability when compared to that of graphite, while compromising smaller capacity at low C rates. During electrochemical reactions, it was also found that the coffee-waste carbon is well exposed to electrolytes, and its disordered characteristic is advantageous for ionic transport which leads to the low tortuosity of Li ions. Finally, the high irreversible capacity (low initial Coulombic efficiency) of the coffee-waste carbon, which if also often observed in amorphous carbon, can be adequately resolved through a solution-based prelithiation process, thereby proving that the coffee-waste carbon material is quite suitable for commercial use as an anode material for quickly-chargeable electrodes.

Carbon Storage in an Age-Sequence of Temperate Quercus mongolica Stands in Central Korea

  • Kim, Sung-geun;Kwon, Boram;Son, Yowhan;Yi, Myong Jong
    • Journal of Forest and Environmental Science
    • /
    • v.34 no.6
    • /
    • pp.472-480
    • /
    • 2018
  • This study was conducted to estimate carbon storage in Quercus mongolica stands based on stand age class, and to provide basic data on the carbon balance of broad-leaved forests of Korea. The research was conducted at the experimental forest of Kangwon National University, Hongcheon-gun County, Gangwon-do Province, Korea. Three plots were set up in each of three Q. mongolica forest stands (III, V, and VII) to estimate the amount of carbon stored in Q. mongolica aboveground vegetation, coarse woody debris (CWD), organic layer, mineral soil, and litterfall. The carbon storage of the aboveground vegetation increased with an increase in stand age, while the carbon storage ratio of stems decreased. The carbon storage of the organic layer, CWD, and litterfall did not show any significant differences among age classes. In addition, the carbon concentration and storage in the forest soils decreased with depth, and there were no differences among age classes for any soil horizon. Finally, the total carbon storage in the III, V, and VII stands of Q. mongolica were 132.2, 241.1, and $374.4Mg\;C\;ha^{-1}$, respectively. In order to predict and effectively manage forest carbon dynamics in Korea, further study on deciduous forests with other tree species in different regions will be needed.

Exposure Assessment of Cashiers at Expressway Tollbooths (고속도로 톨게이트 요금수납원의 작업환경 유해인자 노출평가)

  • Park, Hae Dong;Kang, Joon Hyuk;Kim, Joonbeom
    • Journal of Korean Society of Occupational and Environmental Hygiene
    • /
    • v.31 no.1
    • /
    • pp.13-21
    • /
    • 2021
  • Objectives: The purpose of this study was to evaluate the exposures of cashiers who work at expressway tollbooths. Methods: We measured temperature(temp.), relative humidity(RH), and contaminants with direct reading instruments at ten expressway toll gate in September 2015. Elemental carbon was collected on the quartz filters and analyzed with an OCEC analyzer. Results: The average levels for temp., RH, carbon monoxide, carbon dioxide, dust(PM10), and black carbon were respectively 24.6~27.8℃, 32.3~65.3%, 0.5~1.2 ppm, 456~559 ppm, 12~111 ㎍/㎥, and 3.1~10.1 ㎍/㎥ at each tollbooth. The concentrations of elemental carbon within the tollbooth(1.8~7.2 ㎍/㎥) were lower than outdoors(2.5~10.0 ㎍/㎥), but exhibited a high correlation(r2=0.855). The exposure levels for carbon monoxide, black carbon, and elemental carbon in the tollbooths were significantly higher than the offices. The concentrations of black carbon and elemental carbon showed a high correlation(r2=0.756). Conclusions: The levels of contaminants were below the occupational exposure limits in the expressway tollbooth. There were ventilation and air conditioning systems in the booths, but it is necessary to maintain and use the systems properly.

An Analysis of Low-Carbon Certification Premium of Fresh Agricultural Products on Online (온라인 거래 신선 농산물의 저탄소 인증 프리미엄 분석)

  • Lee, Choon-Soo;Kim, Hyeon-Seo;Kim, Hyeon-Sik;Oh, Jin-A
    • Korean Journal of Organic Agriculture
    • /
    • v.30 no.3
    • /
    • pp.375-391
    • /
    • 2022
  • This study investigated the online transaction status of low-carbon certified fresh agricultural products and analyzed the low-carbon certified premium. For two months from March to April 2022, eight products (rice, apple, pear, sweet persimmons, paprika, tomatoes, cherry tomatoes, and lettuce) were surveyed at major online shopping malls. The low-carbon certification premium was analyzed using hedonic price analysis model. As a result of the online market survey, the low-carbon certified agricultural products were not traded in the case of rice, cherry tomatoes, and paprika. And the proportion of low-carbon certified agricultural products in the case of tomatoes and lettuce was low. As a result of the low-carbon premium analysis, of the five products that analyzed the low-carbon certification premium, four products excluding pear did not have a low-carbon certification premium. Thus, it is necessary to expand the sale of the low-carbon certified agricultural products by distributors, and various efforts to secure the premium of certified agricultural products are important.

Effects of activated carbon on the compressive strength of Portland cement concrete

  • Sungmin Youn;Andrew Ball;Claire Fulks;Sanghoon Lee;Sukjoon Na
    • Geomechanics and Engineering
    • /
    • v.33 no.1
    • /
    • pp.19-27
    • /
    • 2023
  • A series of experiments were performed to evaluate the effects of activated carbon on the compressive strength and air content of Portland Cement Concrete (PCC). Activated carbon/PCC composites were prepared by mixing concrete components with commercial activated carbon granules with weight fractions of 0, 0.5%, 1%, and 2% to cement. All PCC specimens were then tested for compressive strength on 7, 14, 21, and 28 days. The experimental results showed that adding 0.5% of activated carbon increased the compressive strength significantly over the curing periods compared to the normal PCC without activated carbon. For the specimens has 0.5% activated carbon, the 7, 14, 21, and 28-day compressive strengths increased by 28.7%, 22.2%, 26.8%, and 22.9%, respectively. However, adding excessive amounts of more than 1% activated carbon had a minimal effect on the compressive strength or even decreased it, which agrees with other studies. Regarding the air contents of the mixtures, adding activated carbon decreased the air content from 3.6% to around 1.5%. The surface morphologies of fine aggregates and activated carbon particles were compared using a novel image processing technique. The results indicated that the surface of activated carbon significantly differs from that of aggregates.

A new model and testing verification for evaluating the carbon efficiency of server

  • Liang Guo;Yue Wang;Yixing Zhang;Caihong Zhou;Kexin Xu;Shaopeng Wang
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • v.17 no.10
    • /
    • pp.2682-2700
    • /
    • 2023
  • To cope with the risks of climate change and promote the realization of carbon peaking and carbon neutrality, this paper first comprehensively considers the policy background, technical trends and carbon reduction paths of energy conservation and emission reduction in data center server industry. Second, we propose a computing power carbon efficiency of data center server, and constructs the carbon emission per performance of server (CEPS) model. According to the model, this paper selects the mainstream data center servers for testing. The result shows that with the improvement of server performance, the total carbon emissions are rising. However, the speed of performance improvement is faster than that of carbon emission, hence the relative carbon emission per unit computing power shows a continuous decreasing trend. Moreover, there are some differences between different products, and it is calculated that the carbon emission per unit performance is 20-60KG when the service life of the server is five years.