Presently, for the cement industry, studies that seek to reduce $CO_2$, because of the development of the plastic industry and demand for reduction of energy use, have been actively conducted among them, studies attempting to use Gamma-$C_2S({\gamma}-C_2S)$ to fix $CO_2$ have been actively conducted. The ${\gamma}-C_2S$ compound has an important function in reacting to $CO_2$ and stiffening through carbonatization in the air. The ${\gamma}-C_2S$ compound, reacting to $CO_2$ in the air, generates $CaCO_2$ within the pore structure of cement materials and densifies the pore structure this leads to an improvement of the durability and to the characteristic of resistance against neutralization. Therefore, in this experiment, in order to synthesize ${\gamma}-C_2S$, limestone sludge and waste foundry sands are used these materials are plasticized for 30 or 60 minutes at $1450^{\circ}C$, and are prevented from being cooled in the temperature range of $30{\sim}1000^{\circ}C$ when they are about to be cooled. XRD analysis and XRF analysis are used to determine the effects of this process on ${\gamma}-C_2S$ synthesization, the temperature at which a thing is plasticized, and the conditions for cooling that obtain in the plasticized clinker also, in order to confirm the $CO_2$ capture function, analysis of the major hydration products is conducted through an analysis of carbonatization depth and compressive strength, and through MIP analysis and XRD Rietveld analysis. As a result of these analyses, it is found that when ${\gamma}-C_2S$ was synthesized, the clinker that was plasticized at $1450^{\circ}C$ for one hour demonstrated the highest yield rate the sample with which the ${\gamma}-C_2S$ was mixed generated $CaCO_3$ when it reacted with $CO_2$ therefore, carbonatization depth and porosity were reduced, and the compressive strength was increased.
Symptoms of potassium deficiency were studied with flue-cured tobacco (N.C 2326) which had been applied with several levels of nitrogen and potassium fertilizer at 7, 10, and 13 Kg N/10a, and 15, 20, and $25KgK_2O/10a$, respectively. The distributions of T-N, $NH_4-N, \;NO_3-N$, and K contents in 18 leaves from the bottom to the top stalk position were investigated at 63 days after transplanting. The T-N content in the different stalk positions was increased from the bottom to the top ; however, vice versa in K content. As increasing the application levels, the increasing rate of the T-N content in the different leaf fractions were similar to those of rib and laminae. On the contrary, the rates of K content in the rib were higher then that of laminae and in the bottom than the top stalk position. Those indicated that the unbalance of nitrogen and potassium contents in the leaves came to maximum in the laminae of the top stalk position and was possibly affected by the application level of nitrogen rather than potassium. The T-N content in the laminae was higher than that of the rib. However the K and $NO_3$-N contents in the laminae were significantly lower than those of the rib. Therefore the $K^+$ uptake by tobacco was thought to be accompanied with $NO_3$- and transported smoothly up to the rib, but not from the rib to the laminae where assimilation materials were accumulated. Distribution of inorganic components in the different positions of vegetative organ were also investigated at 60 days after transplanting. The T-N and $P_2O_5$ contents were in order as; top > middle> bottom of the stalk and the stalk position, and laminae > vein > midrib of leaf fraction, however vice versa in K content of the stalk position and leaf fraction. In addition distributions of CaO and MgO contents in the each leaf fraction were resemble to that of the T-N content. On the contrary, the distributions of the CaO and MgO contents in the different stalk positions were similar to that of the K content.
Seo, Hye-Ji;Choi, Young-Min;Hwang, In-Guk;Nam, Jin-Sik;Hwang, Jin-Bong;Lee, Ki-Teak;Lee, Jun-Soo;Lee, Jiyoon;Kim, Sena
The Korean Journal of Food And Nutrition
/
v.29
no.5
/
pp.663-669
/
2016
This study was conducted to analyze the nutrient compositions of stem and fruit of Opuntia ficus-indica var. saboten (OF) and Opuntia humifusa (OH). The results of the two-way analysis of variance test indicated that the parts, varieties and parts*varieties had influence on nutrient content except crude protein, soluble dietary fiber, Fe, Se, I, vitamin E, niacin and vitamin C. Moisture and crude ash content was higher in stem than in fruit, while crude lipid and insoluble dietary content was higher in fruit than in stem. Mineral content revealed that K (1,313.67 mg% in OF, 1,351.38 mg% in OH) was the highest in fruit and Ca (5,146.29 mg% in OF, 1,388.19 mg% in OH) was the highest in stem. Vitamin C was the most abundant vitamin in the fruit of OF (199.98 mg%) and OH (187.12 mg%). Polyunsaturated fatty acid was the highest among fatty acids (66.9~70.1%), with higher content in the stem (753.89 mg%) than fruit (578.01 mg%) in OF, while higher in the fruit (1,093.63 mg%) than stem (475.07 mg%) in OH. Moisture, crude protein, Mg, Se and riboflavin was higher in OF than OH; whereas, crude lipid, insoluble dietary fiber, total dietary fiber and monounsaturated fatty acid were higher in OH than OF. These results indicated that OF and OH could be a good food source for Ca, K and Vitamin C. Also, different nutrient content by parts and varieties, can be helpful in choice of parts or varieties for consumer purposes.
The aim of this study is to investigate the relations among each white stone and their characteristics through the chemical and mineralogical analysis of them excavated from around some kilns in archaeological sites. Moreover it was intended to infer the function of kilns. Nine white stones were chosen from three different archaeological sites, the each name of which is Sanyang-ri, Youngdu-ri and Gwangdae-ri in Chungcheongnam-do. In the mineralogical characteristics of thin section, eight stones containing calcite are altered and recrystallized by metasomatism and hydrothermal process, and Calcites, major component minerals of limestone, were identified by the analysis of XRD. On the basis of this result, we can infer the stones to be classified into limestone groups. One the other hand, research revealed that one of the white stones was a white pelitic stone composed of quartz, microcline and muscovite. In the analysis of chemical composition, except for the white pelitic stone eight stones are mainly composed of CaO which is major component of Calcite. Besides, as a results of correlation analysis by using a chemical compositions of major and minor elements in white stones, little did each archaeological site have the relativity. In conclusion, each archaeological site was estimated that they would use a limestone ores extracted from different deposits, and there is a high possibility that the function of these kilns is to produce quicklime.
The parathion hydrolase (OPH) produced by Pseudomonas rhodesiae H5 was purified by ammonium sulfate precipitation, DEAE-Toyopearl 650M ion exchange chromatography and Sephadex gel filtration chromatography. Parathion hydrolase from crude extracts of P. rhodesiae H5 has two components designated as OPH $I_1$ and OPH $I_2$, Optimum pH and temperature of OPH $I_1$and OPH $I_2$ were pH 7.2 and $30^{\circ}C$, and pH 7.6 and $37^{\circ}C$, respectively. The activation energy of OPH $I_1$ for the hydrolysis of parathion was 3.01 ㎉/I, II, III in the temperature range of $4^{\circ}C$ to $30^{\circ}C$, and Michaelis constant ($K_m$) for parathion was 69.2 ${\mu}M$. The activation energy of OPH $I_2$ for the hydrolysis of parathion was 4.07㎉/㏖ in the temperature range of $4^{\circ}C$ to $37^{\circ}C$, and Michaelis constant for parathion was 150.9${\mu}M$. Furthermore OPH $I_1$ was completely inhibited by 1 mM $Ca^2+$, $Cu^2+$, $Mg^2+$, $Ni^2+$, but OPH $I_2$ was less inhibited than OPH $I_1$ by the metals used in this study.
This study was performed to determine the effect of brown algae on the egg quality of laying hens fed a non-supplemented diet (Control) and a diet supplemented with 10% Undaria pinnatifida (A), Laminaria religiosa (B), and Hijikia fusiforme (C), respectively. Isa Brown (28 weeks old) were raised for 8 weeks. The darkness, redness, and blueness of the egg yolks increased with the addition of brown algae, expecially Undaria pinnatifida (A). The fucoxanthin contents were observed to be only 21.3-34.8 mg% level in the brown algae but they were nearly traced in the egg yolks. Among the analyzed minerals, the Ca, Fe, K contents increased to 391.2, 6.3, and 450.5 mg%, respectively, but the amount of P was reduced to 110.5 mg%. The total mineral contents were higher in the egg yolk with Hijikia fusiforme (C) (1,155.1 mg%) than with any other supplement. The brown algae diet reduced the saturated fatty acid level from 38.3 to 32.1% but increased the unsaturated fatty acid level from 61.5 to 69.6% owing to the rise of the level of polyunsaturated fatty acids.
To determine food preferences and nutrients intake of nursery school children, 199 children, ages 1 to 6 years, were assessed with a structured questionnaire completed by their mothers. The questionnaire included questions related to dietary habits, mother's interest in the child's health, family history of diseases, etc. The nutrients intake was measured by 24-hour recall method. Children's weight and height were measured by trained investigators on the same day. For analysis purposes, the subjects were grouped into underweight, normal and overweight groups based on the z-score of weight for height. Only 58.3% of the subjects were grouped into the normal weight group. On the other hand, 19.1% were in the underweight group and 22.6% were in the overweight group. Forty four percent of them showed unbalanced dietary habits such as preference for picky foods, 40.0% of them disliked vegetables, and 46.7% disliked minor grains other than rice. Children in the underweight group showed a higher score of inappropriate dietary habits compared to those of normal or obese groups. The level of nutrients intake of the subjects was higher than the Korean RDA value in general, except for Ca, calories, and Zn. However, 87.4% of the children showed a higher intake level than 125% of KRDA in protein, and 18.2% and 41.4% of them showed a lower intake level than 75% of KRDA in Fe and Ca, respectively. Children in the underweight group showed a higher percentage of eating less than 75% KRDA in niacin compared to those of the normal or overweight group (p<0.05) and we found a similar tendency in Fe, Zn and Vitamin $B_1$ intake.
Journal of the Korean Crystal Growth and Crystal Technology
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v.13
no.4
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pp.199-204
/
2003
Microstructure and chemical analysis of sintered bricks containing recycled wastes were investigated by SEM and EDS. The recycled wastes for which substitute ceramic raw materials were EAF (electric arc furnace) dust, fly ash and stone ash. Yellowish and brownish regions on the surface and brownish and blackish regions in the inside of bricks were observed. Main component of yellowish region on the surface turned out to be Zn. No chemical difference between the black-core region and brownish matrix. Mullite crystallites of 1 fm size were distributed in the inside of bricks and enclosed by glass phases. It seems that alumine-silicate mixtures of kaolin and fly ash were transformed to mullite crystallites during the sintering. Relatively large pores ot several ten fm size were observed in the black-core region in the inside of bricks. The main components of the inside of brick were Al and Si. The minor components were C, Na, Mg, K, Ca, and Fe. Particularly, the precipitates of Fe-rich crystallites were observed in the amorphous matrix. These precipitates were formed due to the local reduction atmosphere in the inside of bricks. Zn-rich covers were found on the surface of bricks because Zn diffused from the inside of bricks to the surface under the reduction atmosphere.
Journal of The Korean Society of Grassland and Forage Science
/
v.16
no.3
/
pp.199-207
/
1996
This experiment was canied out to determine the effects of seeding method and seeding ratio in mixed cropping of forage rye and red clover on dry matter yield, nutritional yield and chemical characteristics of soil. The main treatment was two seeding methods(drilling and broadcasting) and the sub treatment was six seeding ratios between rye and red clover(T1; 150kg : 0 kg/ha, T2; 120 : 3, T3; 90 : 6, T4; 60 : 9, T5; 30 : 12, T6; 0 : 15). The experiment was performed at the College of Natural Science of Kon-Kuk University in Chungju in 1992. The results were summarized as follows; 1. Protein content was increased by increasing the seeding ratio of red clover, but content of NDF and ADF were decreased. 2. The seeding method did not affects significantly the dry matter yield, but broadcasting showed higher dry matter yield than drilling in the same seeding ratio. Especially, T3 of broadcasting was the highest yield of 13, 172 kg/ha The T3 of broadcasting and T4 of drilling showed hlghly crude protein yield of 1, 268 kgha and 1, 252 kg/ha, respectively. 3. Comparing the each seeding ratio of two seeding method, total nitrogen yield of shoot and root of drilling were higher than broadcasting. Especially, T2 and T4 of drilling were the highest in total nitrogen yield. 4. There were more increase in organic matter and nitrogen contents but decrease in K, Ca of soil by increasing the seeding ratio of red clover than soil before experiment. In the seeding methods, broadcasting was an effect of soil improvement.
Background: Primary hepatic neuroendocrine carcinoma (PHNEC) is rarer than extrahepatic gastrointestinal neuroendocrine carcinoma (NEC). It is difficult to make a correct diagnosis and poses a challenge for management. Materials and Methods: Ten PHNEC patients were admitted to our hospital from June 2006 to June 2011. Laboratory tests and imaging scans were performed for diagnosis and exclusion of extrahepatic NEC. All patients were AFP - and CA199-. Seven patients had solid tumors with cystic changes on ultrasonography, CT and/or MRI. For the initial treatment, four patients received combined-therapy and six monotherapy. Considering overall treatment, six patients received combined-therapy and four patients monotherapy. Staging criteria of primary hepatocellular carcinoma (PHC, AJCC 7th edition) were used to differentiate the stage of all patients: 3 patients were stage I, 2 stageII, 4 patients stageIII and 1 stageIV. All patients were followed up and clinical data were gathered. Results: The median follow-up duration was 38.5 months. The 1-year, 2-year, 3-year and 6-year disease-free survival was 80.0%, 46.2% and 46.2% and 0% respectively. The overall survival rates were 100%, 67.1%, 67.1% and 33.6% respectively. Patients in early-stages (I/II) had similar disease-free and overall survival as those in advanced-stages (III/IV). Patients with monotherapy had significant shorter disease-free and overall survival than the patients with combination-therapy. Conclusions: PHNEC has a unique specificity during its occurrence and development. The staging criteria of PHC might not be suitable for the PHENT. More convenient and effective features need to be found in imaging and laboratory detection. Surgical resection, TACE, chemotherapy and radiofrequency ablation should be performed in combination and actively for patients with PHNEC or recurrence to get the best effectiveness; they might extend the disease-free and overall survival.
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