• Title/Summary/Keyword: C9

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Structure of a Spiro Orthocarbonate, 3,3'-Spirobi[1H, 5H-naphtho [1,8-ef] [1,3] dioxocin] (Spiro Orthocarbonate, 3,3'-Spirobi[1H, 5H-naphtho[1,8-ef] [1,3] dioxocin]의 분자구조)

  • Young Mi Song;Jung Mi Shin;Young Ja Park
    • Journal of the Korean Chemical Society
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    • v.36 no.4
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    • pp.536-539
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    • 1992
  • Eight-membered ring spiro orthocarbonate (C$_{25}H_{20}O_4$, M$_r$ = 384) is monoclinic, space group C2/c, with a = 15.319(4), b = 9.057(3), c = 13.168(3)${\AA}$, ${\beta}$ = 98.53(3)$^{\circ}$, Z = 4, F(000) = 808, T = 290 K, ${\mu}$(Mo-K${\alpha}$) = 0.55 cm$_1$, D$_c$ = 1.36 g/cm$^3$ and D$_m$ = 1.40 g/cm$^3$. The intensity data were collected with Mo-K${\alpha}$ radiation (${\lambda}$ = 0.7107 ${\AA}$) on an automatic four-circle diffractometer with a graphite monochromater. The structure was solved by direct methods and refined by full matrix least-squares methods. The final R value was 0.052 for 1412 observed reflections. The molecule has C$_2$point symmetry. The eight-membered ring has a chair conformation with pseudo-C$_s$ symmetry. The naphthyl ring is planar with the C-C bond lengths being in the range of 1.352∼1.444${\AA}$ and bond angles of 117.2∼123.5$^{\circ}$. The bond lengths of C(1)-C(9), C(8)-C(9) and C(9)-C(10) are somewhat longer than those of the other C-C bonds.

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Comparison of Cardinal Temperatures of Lettuce Using Bilinear, Parabolic, and Beta Distribution Functions (선형, 쌍곡선과 Beta 함수를 이용한 상추의 주요 온도 비교)

  • Cha, Mi-Kyung;Kim, Chun-Sik;Austin, Jirapa;Cho, Young-Yeol
    • Journal of Bio-Environment Control
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    • v.23 no.1
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    • pp.39-42
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    • 2014
  • The objective of this study was to estimate cardinal temperatures for germination of lettuce (Lactuca sativar L.) using bilinear, parabolic, and beta distribution functions. Seeds of lettuce were germinated in a growth chamber at 7 constant temperatures: 10, 14, 16, 20, 24, 28, and $32^{\circ}C$. Four replicates of 100 seeds were placed on two layers of filter paper in a 9 cm petri-dish. Radicle emergence of 1 mm was scored as germination. The time course of germination was modeled using a logistic function. These minimum, optimum, and maximum temperatures were estimated by regression of the inverse of time to 50% germination rate against the temperature gradient. In bilinear function, minimum, optimum, and maximum temperatures were $7.9^{\circ}C$, $23.3^{\circ}C$, and $28.0^{\circ}C$, respectively. In parabolic function, minimum, optimum, and maximum temperatures were $9.7^{\circ}C$, $19.5^{\circ}C$, and $29.4^{\circ}C$, respectively. In beta distribution function, minimum, optimum, and maximum temperatures were $3.7^{\circ}C$, $20.7^{\circ}C$ and $32.0^{\circ}C$, respectively. Minimum, optimum, and maximum ranges of temperatures were $3.7{\sim}9.7^{\circ}C$, $19.5{\sim}23.3^{\circ}C$, and $28.0{\sim}32.0^{\circ}C$, respectively.

Effects of Dancheonhwan on Hydrogen Peroxide-induced Apoptosis of H9c2 Cardiomyoblasts (단천환이 Hydrogen Peroxide에 의한 심근세포 독성에 미치는 영향)

  • Na Yeong Hun;Bak Sang Beom;Jeong Seung Won;Yun Jong Min;Lee In;Moon Byung Soon
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.18 no.3
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    • pp.774-782
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    • 2004
  • The water extract of Dancheonhwan (DCH) has been used to treat ischemic brain and heart damage in oriental medicine. However, little is known about the mechanism by which the water extract of DCH rescues cells from ischemic damage. Therefore, this study was designed to investigate the protective mechanisms of DCH on the H₂O₂-induced toxicity in H9c2 cardiomyoblast cells. Treatment of H₂O₂ markedly decreased the viability of H9c2 cardiomyoblast in a dose-dependent and time-dependent manner. The nature of H₂O₂-induced toxicity of H9c2 cells resulted from apoptotic death confirmed with genomic DNA fragmentation. DCH increased the viability of H₂O₂-treated H9c2 cells by about 23%, and partially suppressed the genomic DNA fragmentation and PARP cleavage. H₂O₂ also activated caspase-3 protease and -9 protease, but not both caspase-6 protease and -8 protease. H₂O₂ induced the mitochondria dysfunction, including mitochondria membrane permeability transition (MPT) and cytosolic release of cytochrome c from mitochondria, which was prevented in part by pretreatment of DCH. N-acetylcystein (NAC), a free-radical scavenger, alone increased the viability of H₂O₂-treated H9c2 cells in a dose-dependent manner. Furthermore, the combination of NAC with DCH significantly increased the viability of the H₂O₂-treated H9c2 cells in a dose-dependent manner. These data indicate that DCH has the protective effect on ROS-induced apoptosis of cadiomyoblast H9c2 cells.

Characteristics of Squid Viscera Oil (오징어 내장의 지방질조성)

  • KIM Eun-Mi;JO Jin-Ho;OH Se-Wook;KIM Young-Myoung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.4
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    • pp.595-600
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    • 1997
  • The oil content and composition of squid visera were determined to obtain data for utilization of this by-product. There was no significant difference in the glycolipid (GL) and phospholipid (PL) content in Illex argentinus and Todarodes pacificus, but neutral lipid (NL) was different (p<0.05). The viscera oil of I. argentinus contained $30.50\%$ total lipid which consisted of $96.24\%$ NL, $2.63\%$ GL, $2.37\%$ PL, and contained $644mg\%$ cholesterol. The viscera oil of T. pacificus contained $30.20\%$ total lipid which consisted of $94.82\%$ NL, $2.85\%$ GL, $2.34\%$ PL, and contained $1,224\;mg\%$ cholesterol. The NL, GL and PL of viscera oil in I. argentinus mainly consist of triglyceride $(44.01\%)$, esterified steryl glycosides $(58.95\%)$ and phosphatidyl cholines $(32.36\%)$, respertively. Those of viscera oil in T. pacificus mainly consist of triglyceride $(39.63\%)$, monogalactosyl diglycerides $(51.67\%)$ and phosphatidyl cholines $(31.98\%)$, respectively. The major fatty acids of the viscera oil of I. argentinus and T. pacificus were C16 : 0, $C16\;:\;0,\;C18\;:\;1\omega9,\;C20\;:\;4\omega6,\;C20\;:\;5\omega3,\;C22\;:\;6\omega3$. In Illex argentinus, the fatty acids of NL mainly were $C16\;:\;0,\;C18\;:\;1\omega9,\;C20\;:\;4\omega6,\;C20\;:\;5\omega3,\;C22\;:\;6\omega3$. PL were $C16\;:\;1\omega7,\;C20\;:\;5\omega3,\;C22\;:\;6\omega3$ and GL were $C18\;:\;1\omega9,\;C20\;:\;5\omega3,\;22\;:\;6\omega3$. The major fatty acids of NL in T. pacificus were $C16\;:\;0,\;C18\;:\;1\omega9,\;C20\;:\;4\omega6,\;C20\;:\;5\omega3,\;C22\;:\;6\omega3$, PL were $C16\;:\;1\omega7,\;C20\;:\;5\omega3,\;C22\;:\;6\omega3$, and GL were $C18\;:\;1\omega9,\;C20\;:\;5\omega3,\;C22\;:\;6\omega3$.

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Effect of Water Temperature on the Embryonic Development of Slime Flounder Microstomus achne (수온이 찰가자미(Microstomus achne)의 난발생에 미치는 영향)

  • Byun, Soon-Gyu;Lee, Sung-Hun;Hwang, Jae-Ho;Han, Kyeong-Ho;Yeon, In-Ho;Kim, Jin-Do;Lee, Jong-Ha;Lee, Bae-Ik
    • Development and Reproduction
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    • v.13 no.4
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    • pp.265-270
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    • 2009
  • The fertilized eggs were obtained from mature adult slime flounder Microstomus achne to determine the water temperature effect on egg development. The lowest water temperature for the flounder egg development was $0.4^{\circ}C$ on average. The temperature-dependent duration from fertilization to hatching ranged 86.5 to 296.7 hours at $9\sim21^{\circ}C$ with an accelerated development at higher temperature. Agreeable hatching rates, 95.8~97.0%, were obtained at $12\sim18^{\circ}C$, while lower at both extremes, 86.9% at $9^{\circ}C$ and 9.3% at $21^{\circ}C$. The highest water temperature, $24^{\circ}C$, had the life of the fertilized eggs confined within 24 hours. Water temperature was a parameter that induced an abnormal egg development: with abnormalities of 88.3% at $21^{\circ}C$, 2.1% at $9^{\circ}C$ (P<0.05), and 0.4~0.8% at $12\sim18^{\circ}C$.

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The Deterioration Properties and Actual Conditions of Insulation Cover used at 22.9 kV Transformer Bushing (22.9 kV용 변압기 부싱 절연 커버의 실태 조사 및 열화 특성)

  • Choi, Chung-Seog;Kim, Hyang-Kon;Han, Woon-Ki;Lee, Ki-Yeon
    • Fire Science and Engineering
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    • v.20 no.3 s.63
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    • pp.35-41
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    • 2006
  • In this study, we presented the problems in the insulation cover of 22.9kV transformer bushing through investigating actual conditions. After thermal stress applied to the insulation cover, deterioration patterns, thermogravimetric and infrared characteristics were analyzed, and the results were applied to the cause analysis of accidents and judgement of safety. The insulation covers are used to protect exposed terminals of transformer, but they had improper size and length. Therefore, they could not show efficient insulation function. In case that thermal stress of $150^{\circ}C$ was applied to the insulation covers, plastic insulation covers(A, B, D, E) damaged severely, whereas rubber insulation cover(C) showed normal shapes. In the result of thermogravimetric analysis, the thermal gravity of plastic covers(A) decreased about 33.3% at $307.8^{\circ}C\;to\;405.9^{\circ}C$. and he thermal gravity of rubber covers (C) decreased about 53.7% at $258.8^{\circ}C\;to\;32.9^{\circ}C$. In the result of FT-IR analysis, plastic covers showed peaks characteristic of $CH_2,\;CH_3$, C=O and C=C bonds, whereas rubber covers showed peaks characteristic of OH, $CH_2,\;CH_3$, C=O, C=N and C=C bonds.