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The Structure of Tetra-tert-butyl-dipropionyloxy-dihydroxycalis[4]arene (Tetra-tert-butyl-dipropionyloxy-dihydroxycalis[4]arene 구조에 관한 연구)

  • 박영자
    • Korean Journal of Crystallography
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    • v.7 no.2
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    • pp.105-112
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    • 1996
  • The structure of the tetra-tert-butyl-dipropionyloxy-dihydroxycalis[4]arene (C50H64O6) has been determined by X-ray diffraction methods. The crystal is monoclinic, space group C2/c, unit cell constant a=16.067(2), b=26.391(17), c=10.335(1)Å, β=94.26(1)°, Z=4, V=4370.2(29)Å3, Dc=1.16, Dm=1.2 gcm-3. The intensity data were collected on an Enraf-Nonius CAD-4 Diffractometer with a graphite monochromated Cu-Kα radiation (λ=1.5418Å). The structure was solved by direct methods and refined by least-squares methods. The final R value was 0.07 for 2354 observed reflections. The molecule has the 1, 3-alternate conformation with own two-fold symmetry axis, : two propionyloxy phenyl groups are up and the other two hydroxy phenyl groups are down.

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CRESTIVE-DX: Design and Implementation of Distrusted Concolic Testing Tool for Embedded Software (CRESTIVE-DX: 임베디드 소프트웨어에 대해 테스트케이스 생성을 지원하는 분산 Concolic 테스팅 도구)

  • Leem, Hyerin;Choe, Hansol;Kim, Hyorim;Hong, Shin
    • KIPS Transactions on Software and Data Engineering
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    • v.9 no.8
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    • pp.229-234
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    • 2020
  • This paper presents the design and the implementation of CRESTIVE-DX, a concolic testing tool that distribute the concolic testing process over the embedded target system and the host system for efficient test generation of a target embedded program. CRESTIVE-DX conducts the execution of a target program on the target embedded system to consider possible machine-dependent behaviors of a target program execution, and conducts machine-independent parts, such as search-strategy heuristics, constraint solving, on host systems with high-speed computation unit, and coordinates their concurrent executions. CRESTIVE-DX is implemented by extending an existing concolic testing tool for C programs CREST. We conducted experiments with a test bed that consists of an embedded target system in the Arm Cortex A54 architecture and host systems in the x86-64 architecture. The results of experiments with Unix utility programs Grep, Busybox Awk, and Busybox Ed show that test input generation of CRESTIVE-DX is 1.59 to 2.64 times faster than that of CREST.

Low Temperature Sintering and Microwave Dielectric Properties of Ca[Ti1-x(Ni1/3Nb2/3)x]O3 Ceramics (Ca[Ti1-x(Ni1/3Nb2/3)x]O3 세라믹스의 저온소결 및 마이크로파 유전특성)

  • Lee, Young-Gyu;Kim, Hyo-Tae;Nam, Joong-Hee;Kim, Jong-hee;Paik, Ungyu
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.55-61
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    • 2006
  • The microwave dielectric properties and low temperature sintering of $Ca[Ti_{1-x}(Ni_{1/3}Nb_{2/3})_x]O_3$ system were investigated at the sintering temperature $1,200\~1,350^{\circ}C$. The density and quality factors $(Q{\times}f)$ increased while dielectric constants slightly decreased with the decrease of Ti. The dielectric constant, quality factor, and temperature coefficient of resonance frequency $(\tau_f)$ were 64, 17,000 GHz, and $-9.1\;ppm/^{\circ}C$ respectively, when $CaTi_{1/2}(Ni_{1/3}Nb_{2/3})_{1/2}O_3$ ceramics were sintered at $1,300^{\circ}C$ for 4 h. $2Li_2O-B_2O_3$ was added to $CaTi_{1/2}(Ni_{1/3}Nb_{2/3})_{1/2}O_3$ to decrease the sintering temperature for LTCC application. The microwave dielectric properties of the samples sintered at $925^{\circ}C$ for 2 h with the addition of $6\;wt\%\;2Li_2O-B_2O_3$ were $\varepsilon_r=48.7,\;Q{\times}f=8,460\;GHz$, and $\tau_f=+5.6ppm/^{\circ}C$. Compatibility test of the composition with silver electrode shows no reaction with silver electrode, implying the feasibility as a high-K LTCC material.

Crystallization and Preliminary X-ray diffraction Studies of Salmonella typhimurium Deoxy-Thymidine Diphosphate-D-Glucose-4, 6-Dehydratase (Salmonella typhimurium의 Deoxy-Thymidine Diphosphate-D-Glucose-4, 6-Dehydratase의 결정화와 X-선 회절에 관한 연구)

  • 최희욱;박교선
    • Korean Journal of Crystallography
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    • v.7 no.2
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    • pp.120-125
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    • 1996
  • Single crystals of deoxy-thymidine diphosphate-D-gluxose-4,6-dehydratase(abbreviated as dTDP-D-glucose dehydratase) from Escherichia coli Strain BL21 clone which harbors the gene of dTDP-D-glucose dehydratase in Salmonella typhimurium LT2 have been grown with and whithout substrates by sitting drop vapor diffusion at room temperature. The precipitating agent was 1.6 to 2.0 M Na, K phosphate buffer(pH 8.0). The crystals diffract to at least 2.5Å and belong to the hexagonal space group P61 with cell dimensions a=b=168.54Å, c=81.08Å. The asymmetric unit contains one dimer with a crystal volume per protein mass(VM) of 2.4Å3/Da and solvent content (Vsol) of 64% by volume.

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Assessment of the Organic and Nitrogen Fractions in the Sewage of the Different Sewer Network Types by Respirometric Method (미생물 호흡률 측정에 의한 관거시스템 유형별 하수의 기질 분율 평가)

  • Park, Jong-Bu;Hur, Hyung-Woo;Kang, Ho;Chang, Sung-Oun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.8
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    • pp.649-654
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    • 2009
  • Respirometric analysis of domestic sewage by measuring oxygen uptake rate(OUR) was carried out for the experimental assessment of the organic and biomass fractions. The data of the organic and biomass fractions in sewage is essential for the activated sludge model to optimize the biological treatment plant. As a result of this study, the fractions of readily biodegradable substrate($S_S$), slowly biodegradable substrate($X_S$), inert soluble substrate($S_I$), inert particular substrate($X_I$) and heterotrophic biomass($X_{HAB}$) were about 26.6%, 41.5%, 8.5%, 14.7% and 8.7% on the basis of chemical oxygen demand($COD_{Cr}$), respectively. And the fractions of nitrogen were also studied. The fractions of soluble nitrate nitrogen($S_{NO}$), soluble ammonia nitrogen($S_{NH}$), soluble nonbiodegradable organic nitrogen($S_{NI}$), soluble biodegradable organic nitrogen($S_{ND}$) and slowly biodegradable organic nitrogen($X_{ND}$) were about 3.7%, 64.9%, 4.7%, 9.4% and 17.4%, respectively.

A Study on Radition-Induced Current in Insulating Oil during X-ray Irradiation (방사선(放射線) 조사(照射) 중(中) 절연유(絶緣油)의 유기전류(誘起電流)에 관한 연구(硏究))

  • Kim, Young-Il;Lee, Duck-Chool;Chung, Yon-Tack
    • Journal of radiological science and technology
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    • v.11 no.1
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    • pp.33-41
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    • 1988
  • This study was measured the radiation-induced current - X-ray dose, dose rate, X-ray quality, time, temperature, electric field characteristics and the dependence of gap length in insulating oil under of D.C. Voltage before, during and after X-ray irradiation. The obtained results can be summarized as following. 1. The radiation - induced current is more the dependence of X-ray quality (tube voltage) than quantity (tube current), the dependence of quantity is appeared at the high than low X-.ay tube voltage. 2. The dependence of dose rate is appeared at the more dose rate, and ${\triangle}\;=\;0.64{\sim}0.74$. 3. The higher temperature of insulating oil and X-ray tube voltage (X-ray quality) is increased, at the low electric field, the more radiation-induced current. 4. $G_{eq}-G_{o}(={\triangle}G)$ is increased at the low than high temperature, high than low X-ray quality. 5. The dependence of temperature is appeared before than during X-ray irradiation. 6. The RIC saturation region is appeared at the high than low insulating oil temperature during (1000 V/cm above) than before (4000 V/cm above) X-ray irradiation.

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Monitoring on Alcohol Fermentation Properties of Apple Juice for Apple Vinegar (사과식초 제조를 위한 사과주스의 알코올발효 특성 모니터링)

  • Shin, Eun-Jeong;Kang, Bok-Hee;Lee, Sang-Han;Lee, Dong-Sun;Hur, Sang-Sun;Shin, Kee-Sun;Ki, Seong-Ho;Son, Seok-Min;Lee, Jin-Man
    • Food Science and Preservation
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    • v.18 no.6
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    • pp.986-992
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    • 2011
  • The alcohol fermentation of apple juice was optimized as a preliminary study for the production of natural apple cider vinegar. To gain an optimal fermentation yield, a central composite design was used to investigate the effects of the independent variables [initial Brix (12/14/16/18/20, $X_1$), fermentation time(48/54/60/66/72h, $X_2$), and fermentation temperature(24/26/28/30/$32^{\circ}C$, $X_3$)] on the dependent variables (alcohol content, reducing sugar, Brix, acidity). The alcohol content was 3.4-6.4%, the reducing sugar was 1.93-6.24%, and the Brix was $6.1-13.8^{\circ}$. The alcohol content was mainly affected by the fermentation temperature and increased along with the fermentation time and temperature. The amount of the reducing sugar was significantly affected by the initial Brix and fermentation temperature. The optimal conditions for the alcohol content were found to be 15.22 initial Brix, 64.97 h fermentation time, and $31.56^{\circ}C$ temperature.

A Research about Open Source Distributed Computing System for Realtime CFD Modeling (SU2 with OpenCL and MPI) (실시간 CFD 모델링을 위한 오픈소스 분산 컴퓨팅 기술 연구)

  • Lee, Jun-Yeob;Oh, Jong-woo;Lee, DongHoon
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.171-171
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    • 2017
  • 전산유체역학(CFD: Computational Fluid Dynamics)를 이용한 스마트팜 환경 내부의 정밀 제어 연구가 진행 중이다. 시계열 데이터의 난해한 동적 해석을 극복하기위해, 비선형 모델링 기법의 일종인 인공신경망을 이용하는 방안을 고려하였다. 선행 연구를 통하여 환경 데이터의 비선형 모델링을 위한 Tensorflow활용 방법이 하드웨어 가속 기능을 바탕으로 월등한 성능을 보임을 확인하였다. 그럼에도 오프라인 일괄(Offline batch)처리 방식의 한계가 있는 인공신경망 모델링 기법과 현장 보급이 불가능한 고성능 하드웨어 연산 장치에 대한 대안 마련이 필요하다고 판단되었다. CFD 해석을 위한 Solver로 SU2(http://su2.stanford.edu)를 이용하였다. 운영 체제 및 컴파일러는 1) Mac OS X Sierra 10.12.2 Apple LLVM version 8.0.0 (clang-800.0.38), 2) Windows 10 x64: Intel C++ Compiler version 16.0, update 2, 3) Linux (Ubuntu 16.04 x64): g++ 5.4.0, 4) Clustered Linux (Ubuntu 16.04 x32): MPICC 3.3.a2를 선정하였다. 4번째 개발환경인 병렬 시스템의 경우 하드웨어 가속는 OpenCL(https://www.khronos.org/opencl/) 엔진을 이용하고 저전력 ARM 프로세서의 일종인 옥타코어 Samsung Exynos5422 칩을 장착한 ODROID-XU4(Hardkernel, AnYang, Korea) SBC(Single Board Computer)를 32식 병렬 구성하였다. 분산 컴퓨팅을 위한 환경은 Gbit 로컬 네트워크 기반 NFS(Network File System)과 MPICH(http://www.mpich.org/)로 구성하였다. 공간 분해능을 계측 주기보다 작게 분할할 경우 발생하는 미지의 바운더리 정보를 정의하기 위하여 3차원 Kriging Spatial Interpolation Method를 실험적으로 적용하였다. 한편 병렬 시스템 구성이 불가능한 1,2,3번 환경의 경우 내부적으로 이미 존재하는 멀티코어를 활용하고자 OpenMP(http://www.openmp.org/) 라이브러리를 활용하였다. 64비트 병렬 8코어로 동작하는 1,2,3번 운영환경의 경우 32비트 병렬 128코어로 동작하는 환경에 비하여 근소하게 2배 내외로 연산 속도가 빨랐다. 실시간 CFD 수행을 위한 분산 컴퓨팅 기술이 프로세서의 속도 및 운영체제의 정보 분배 능력에 따라 결정된다고 판단할 수 있었다. 이를 검증하기 위하여 4번 개발환경에서 운영체제를 64비트로 개선하여 5번째 환경을 구성하여 검증하였다. 상반되는 결과로 64비트 72코어로 동작하는 분산 컴퓨팅 환경에서 단일 프로세서 기반 멀티 코어(1,2,3번) 환경보다 보다 2.5배 내외 연산속도 향상이 있었다. ARM 프로세서용 64비트 운영체제의 완성도가 낮은 시점에서 추후 성공적인 실시간 CFD 모델링을 위한 지속적인 검토가 필요하다.

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Negative Ion Generation Index according to Altitude in the Autumn of Pine Forest in Gyeongju Namsan (경주 남산 소나무림의 가을철 해발고도별 음이온 발생지수)

  • Kim, Jeong Ho;Yoon, Ji Hun;Lee, Sang Hoon;Choi, Won Jun;Yoon, Yong Han
    • Korean Journal of Environment and Ecology
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    • v.32 no.4
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    • pp.413-424
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    • 2018
  • The study analyzed the effects of topographic structures and altitude in mountainous parks in Mt. Namsan in Gyeongju on the generation of anions. The temperature was at ridge ($9.82^{\circ}C$) > valley ($8.44^{\circ}C$), the relative humidity valley (59.01 %) > ridge (58.64 %), the solar radiation ridge ($34.40W/m^2$) > valley($14.69W/m^2$), the wind speed ridge (0.63m/s) > valley(0.37m/s), and the negative ion valley($636.81ea/cm^3$) > ridge($580.04ea/cm^3$). In the valley, the correlation with altitude was verified for the temperature, relative humidity, solar radiation, and negative ion generation in the valley. The relative humidity, solar radiation, and negative ion indicated a positive correlation while the temperature had a negative correlation. In the ridge, the correlation with altitude was verified for the temperature, relative humidity, wind speed, solar radiation, and negative ion generation. The relative humidity, solar radiation, and negative ion generation indicated a positive correlation while the temperature and wind speed had a negative correlation. The regression analysis showed the prediction equation of y=-0.006x+9.663 (x=altitude, y=temperature) in the valley and y=-0.009x+11.595 (x=altitude, y=temperature) in the ridge for the temperature, y=0.027x+53.561 (x=altitude, y=relative humidity) in the valley and y=0.008x+56.646 (x=altitude, y=relative humidity) in the ridges for the relative humidity, and y=0.027x+53.561 (x=altitude, y=negative Ion generation) in the valley and y= 0.008x+56.646 (x=altitude, y=negative Ion generation) in the ridge for the negative ion generation.

Optimization of Ultrasonic-assisted Extraction Process for Inonotus obliquus Using Response Surface Methodology (반응표면분석법을 이용한 차가버섯의 초음파 추출공정 최적화)

  • Kim, Dong-Yeon;Teng, Hui;Choi, Yong-Hee
    • Current Research on Agriculture and Life Sciences
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    • v.30 no.2
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    • pp.68-75
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    • 2012
  • This study was conducted to monitor the yields of useful substances extracted from Inonotus obliquus. Optimization of ultrasonic-assisted extraction process was carried out by using response surface methodology under different extraction conditions. A central composite design was applied to investigate the effects of independent variables such as extraction time ($X_1$), ethanol concentration ($X_2$) and extraction temperature ($X_3$) on dependent variables such as soluble solid yield ($Y_1$), total phenol contents ($Y_2$), total flavonoid contents ($Y_3$) and browning color($Y_4$). Soluble solid yield was affected by ethanol concentration and extraction temperature. The maximum soluble solid yield was 18.02% at 20.47 min ($X_1$), 42.85% ($X_2$) and $69.57^{\circ}C$ ($X_3$) in saddle point. Total phenol contents were highly affected by ethanol concentration and extraction temperature. The maximum total phenol contents were 71.57mg GAE/g at 21.60min ($X_1$), 45.19% ($X_2$), $69.68^{\circ}C$ ($X_3$). The electron donating ability was affected by extraction temperature and extraction time. Total flavonoid contents were affected by only extraction temperature. The maximum total flavonoid contents were 35.98 mg RE/g at 22.53min ($X_1$), 46.37% ($X_2$), $69.56^{\circ}C$ ($X_3$) in saddle point. The browning color was highly affected by extraction time, ethanol concentration and extraction temperature. The maximum browning color was at 22.00 min ($X_1$), 46.89% ($X_2$), $69.71^{\circ}C$ ($X_3$) in saddle point. As a result, the optimum extraction conditions were predicted; extraction time of 21.50 min, ethanol concentration of 44.87% and extraction temperature of $69.635^{\circ}C$.

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