• Title/Summary/Keyword: C23O

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Fabrication of Nanostructures by Dry Etching Using Dewetted Pt Islands as Etch-masks (Dewetting된 Pt Islands를 Etch Mask로 사용한 GaN 나노구조 제작)

  • Kim, Taek-Seung;Lee, Ji-Myon
    • Korean Journal of Materials Research
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    • v.16 no.3
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    • pp.151-156
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    • 2006
  • A method for fabrication of nano-scale GaN structure by inductively coupled plasma etching is proposed, exploiting a thermal dewetting of Pt thin film as an etch mask. The nano-scale Pt metal islands were formed by the dewetting of 2-dimensional film on $SiO_2$ dielectric materials during rapid thermal annealing process. For the case of 30 nm thick Pt films, pattern formation and dewetting was initiated at temperatures greater $600^{\circ}C$. Controlling the annealing temperature and time as well as the thickness of the Pt metal film affected the size and density of Pt islands. The activation energy for the formation of Pt metal island was calculated to be 23.2 KJ/mole. The islands show good resistance to dry etching by a $CF_4$ based plasma for dielectric etching indicating that the metal islands produced by dewetting are suitable for use as an etch mask in the fabrication of nano-scale structures.

Cultural Condition for Biopolymer Production by Pseudomonas delafieldii (Pseudomonas delafieldii에 의한 Biopolymer 생산조건)

  • Yoo, Jin-Young;Chung, Dong-Hyo
    • Microbiology and Biotechnology Letters
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    • v.17 no.5
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    • pp.468-474
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    • 1989
  • The cultural condition for polysaccharide production by Pseudomonus detafietdii was studied. The optimal medium contains the following composition per liter of distilled water: glucose (25g/$\ell$), peptone (2.06g/$\ell$), KH$_2$PO$_4$(2g/$\ell$), MgSO$_4$.7$H_2O$ (2g/$\ell$), yeast extract (0.5g/$\ell$), CaCO$_3$(2.5g/$\ell$). The temperature and pH optimum were 3$0^{\circ}C$ and 6.5. The agitation speed was 300 rpm. 5.91g of polysaccharide was produced at the condition in flask culture.

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ON THE ADJOINT LINEAR SYSTEM

  • Kwan, Shin-Dong
    • Bulletin of the Korean Mathematical Society
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    • v.31 no.1
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    • pp.15-23
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    • 1994
  • Throughout this paper, we are working on the complex number field C. The aim of this paper is to explain the applications of Theorem 2 in .cint. 1. In the surface theory, the adjoint linear system has played important roles and many tools have been developed to understand it. In the cases of higher dimensional varieties, we don't have any useful tools so far. Theorem 2 implies that it is enough to compute the dimension of the adjoint linear system to check the birationality. We can compute, somehow, the dimension of the adjoint linear system. For example, we can get an information about $h^{0}$ (X, $O_{x}$( $K_{x}$ + D)) from Euler characteristic of vertical bar $K_{X}$ + D vertical bar and some vanishing theorems. We are going to show the applications of Theorem 2 to smooth three-folds and smooth fourfold, specially, of general type with a nef canonical divisor, smooth Fano variety, and Calabi-Yau manifold. Our main results are Theorem A and Theorem B. Most of birationality problems in Theorem A and Theorem B have been studied. (see Ando [1] and Matsuki [4] for the detail matters.) But Theorem 2 gives short and easy proofs in the cases of dimension 3 and improves the previously known results in the cases of dimension 4.4. 4.4.

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Pt/MOF-5 Hybrid Composite Encapsulated with Microporous Carbon Black to Improve Hydrogen Storage Capacity and Hydrostability

  • Yeo, Sin-Yeong;Gwak, Seung-Yeop
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.45.2-45.2
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    • 2011
  • Metal organic frameworks (MOF) have generated considerable interests as a potential candidate for hydrogen storage owing to their extremely high surface-to-volume ratio and low density. In this study, Pt nanoparticles of about 3 nm in size were introduced outside MOF-5 [$Zn_4O$(1,4-benzenedicarbocylate)3], which was then encapsulated with hydrophobic microporous carbon black (denoted CB@Pt/MOF-5) in order to enhance hydrogen uptake capacity without decreasing the specific surface area and hydrostability. To study the chemical composition, morphology, crystal information, and properties of the synthesized material, a variety of techniques is employed, including WXRD, XPS, ICP-AES, FE-SEM, HR-TEM, and N2 adsorption-desorption, confirming the formation of novel hybrid composite designated CB@Pt/MOF-5 with highly crystalline structure, large specific surface area and pore volume. In addition, $H_2$ storage capacity for resulting material was measured using magnetic suspension microbalance at 77 and 298 K under high-pressure condition, and the hydrostability was also tested by exposing the sample to 33% relative humidity at $23^{\circ}C$ and measuring XRD as a function of time.

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Phenylalanine Ammonia-Lyase Gene (NtPAL4) Induced by Abiotic Stresses in Tobacco (Nicotiana tabacum)

  • Han, Woong;Wang, Myeong-Hyeon
    • Korean Journal of Plant Resources
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    • v.23 no.6
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    • pp.535-540
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    • 2010
  • Phenylalanine ammonia-lyase (PAL), a key enzyme of the phenylpropanoid biosynthesis pathway, is activated by a number of developmental and environmental cues. The coding region of the NtPAL4 gene was 2,154 bp in length, and its deduced protein was composed of 717 amino acids. Sequence analysis of NtPAL4 cDNA from tobacco (Nicotiana tabacum L.) revealed high structural similarity to PAL genes of other plant species. The NtPAL4 gene exists as a single copy in the tobacco plant, and its transcripts were strongly expressed in flowers and leaves. NtPAL4 expression was significantly induced in response to NaCl, mannitol, and cold treatments, but it was not induced by abscisic acid (ABA). NtPAL4 expression decreased gradually after treatment with ABA and $H_2O_2$; however, NtPAL4 transcripts accumulated after treatment with methyl viologen (MV). Our results suggest that the NtPAL4 gene may function in response to abiotic stresses.

An Experimental Study on Hydration Heat Control in The Mass Concrete Using Oscillating Capillary Tube Heat Pipe (진동세관형 히트파이프(OCHP)를 이용한 매스콘크리트의 수화열 제어에 관한 실험적 연구)

  • Beak, Dong-Il;Kim, Myung-Sik;Lee, Moon-Sik;Kim, Kang-Min;Yum, Chi-Sun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.409-412
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    • 2006
  • In process of reinforced concrete(RC) box structure, the heat of hydration may cause serious thermal cracking problems. In order to eliminate hydration heat of mass concrete, this paper reports results of hydration heat control in mass concrete using the OCHP(Oscillating Capillary tube Heat Pipe). Recently OCHP is drawn special attention from these points of low cost as well as short construction schedule for the manufacturing of heat exchanger, flexibility, simplification and high performance. There were three RC box molds$(1.2{\times}1.2{\times}1.2m)$ which shows a difference as compared with each other. One was not equipped with OCHP. While others were equipped with OCHP and these were cooled with air natural convection and spraying water respectively. The OCHP was composed of copper pipe with 12 turns(O.D : 4mm, I.D : 2.8mm). The working fluid was R-22 and its charging ratio was 30(Vol. %). In order to analyze the distribution of temperature and index figure of thermal crack in sequential placement of mass concrete, we used HYCON of computer program. As a result of the experiment, the peak temperature decreased about $15.6\sim23.4^{\circ}C$ than the general specimen and the probability of thermal crack generated in mass concrete decreased up to 0%.

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Optimum culture conditions of cell growth and polysaccharide production by Paecilomyces japonicain batch culture

  • Park, Seok-Jae;Byeon, Hak-Gyu;Han, Dae-Seok;Hong, Eok-Gi
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.287-290
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    • 2000
  • To examine effects of agitation and aeration as well as adding of glucose and yeast extract on cell growth and polysaccharide production by Paecilomyces japonica, batch culture was carried out at 5L jar fermenter at $27^{\circ}C$ with the initial pH 7 for 7 days cultivation(innoculum size 2%, working volume 3L). Media compositions(g/L) were 30 glucose, 20 yeast extract, 0.5 $KH_2PO_4$, $0.1\;CuCl_2\;{\cdot}\;2H_2O$. Optimum culture conditions of agitation and aeration in batch culture were 400 rpm and 1.0 vvm, resulting in 23.1 g/L biomass and 2.5 g/L polysaccharide. Additional feeding of glucose and yeast extract with a pulse mode conferred an advantage on cell growth and polysaccharide production with showing the results of 29.2 g/L and 3.3 g/L, respectively.

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Influence of Oxygen Plasma Treatment on Impact Behaviors of Carbon Fibers-reinforced Composites (산소 플라즈마 처리가 탄소섬유강화 복합재료의 충격특성에 미치는 영향)

  • Oh, Jin-Seok;Lee, Jae-Rock;Park, Soo-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.23-26
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    • 2005
  • In this work, effects of oxygen plasma on surfc1ce characteristics of carbon fibers were investigated in impact strength of carbon fibers-reinforced composites. The surface properties of the carbon fibers were determined by acid/base values, FT-IR, and X-ray photoelectron spectroscopy (XPS). Also, the mechanical properties of the composites were studied by impact strength measurements. As experimental results, the $O_{IS}/C_{IS}$ ratio of the carbon fiber surfaces treated by oxygen plasma was increased compared to that of untreated ones, possibly due to development of oxygen-containing functional groups. The mechanical properties of the composites, including impact strength had been improved by the oxygen plasma on fibers. These results could be explained that the oxygen plasma resulted in the increase of the adhesion of between fibers and matrix in a composite system.

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Lignin Characterization of Waste Liquor by Modified Pulping Process (개량(改良)펄프화법(化法)으로 제조(製造)된 폐액(廢液)중의 리그닌의 특성(特性))

  • Hwang, Byung-Ho;Cho, Hern-Joung;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
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    • v.23 no.1
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    • pp.13-20
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    • 1995
  • This study was carried out to investigate the characterization of lignins from waste liquors in SP, KP, ASAM, and AS from Pinus densiflora, Quercus mongolica, and Betula ermanii. Spectroscopic study was applied to examine the lignins separated from different pulping process. Lignin contents in waste liqours increased in order of AS, ASAM, KP, and SP. UV spectra of three types of lignin except AS lignin showed similar pattern. IR spectra of AS lignin showed strong C=O absorptions in the range from 1730 to 1750$cm^{-1}$, where as those of KP, SP, and ASAM showed weak stretch in this region. NMR spectra of AS lignin showed strong characteristic chemical shifts of acetoxyl groups of acetylated aliphatic and aromatic hydroxyl groups at 2.0~2.5 ppm. Molecular weight of ASAM lignin from Pinus densiflora determined and found number average molecular weight 1,199, weight average molecular weight 5,458. z average molecular weight 17,242, and viscosity average molecular weight 5,457. It is considered from the results based on spectroscopic study of lignin that waste liquors (in SP, KP, ASAM and AS) from Pinus densiflora, Quercus mongolica, and Betula ermanii can be used for lignin utilization.

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Hydroquenation Effects on the Poly-Si TFT (다결정 실리콘 TFT에 대한 수소처리 영향)

  • 하형찬;이상규;고철기
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.1
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    • pp.23-30
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    • 1993
  • Hydrogenation on the top gate and bottom gate Poly-Si TET's was performed by using Nh$_{3}$ plasma and annealing SiN film deposited by PECVD and then the electric characteristics on Poly-Si TET were investigated. As the time of NA$_{3}$ plasma treatment increaes, on/off current ratio gradually increases and the swing value decreases. The trap densities of graim boundaries in Poly-Si decrease very much during the inital 20min of hydrogenation time, and the decreasing scale becomes smaller after 20 min. The electric characteristics of the top gate TFT are better than those of the bottom gate TFT, it is considered due to the defects at the interface between the Poly-Si and the underlayer, SiO$_{2}$. After NH$_{3}$ plasma was treated for 2 hours for the top gate TFT, as the aging time atroon temperature increases on current was not scacely changed and off current decreases more than 1 order. Gate current density recovers to original value after the aging treatment for 8 days and then the electric characteristics are finally improved. It is suggested that the degraded characteristics of gate oxide are improved, from the variations of C-V characteristics with aging time. For the hydrogenation of isothermal and isochronal annealing SiN film deposited by PECVD, the characteristics of Poly-Si TFT are improved with increasing annealing temperature and are not largely changed with increasing annealing time. This results is good in agreement with the hydrogen reduction in Sin film as variations of annealing temperature and time.

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