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Mechanical Properties of Fe-P-(Mo,Mn) Sintered Alloy Related with Si Contents (Fe-P-(Mo,Mn)계 소결분말 합금에서 Si 첨가에 따른 기계적 특성 변화에 대한 연구)

  • Jung, Woo-Young;Park, Dong-Kyu;Ko, Byung-Hyun;Park, Jin-Woo;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.23 no.5
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    • pp.397-401
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    • 2016
  • A lean alloy is defined as a low alloy steel with a minimum amount of the alloying element that maintains the characteristics of the sintered alloy. It is well known that the addition of elements such as Cr, P, Si, or Mn improves the mechanical characteristics of the alloy, but decreases the sinterability. The mother alloy is used to avoid an oxidation reaction with the alloying elements of Cr, P, Si or Mn. The purpose of this study is to determine the change in the mechanical properties of Fe-P-Mo and Fe-P-Mn alloys as a result of the addition of Si. In this article, the Fe-P-Mo and Fe-P-Mn alloys to which Si is added are compacted at $7.0g/cm^3$ and then sintered in $H_2-N_2$ at $1120^{\circ}C$. The P around the macropores and large grains reduces due to the formation of $SiO_2$ as the Si content increases. This is caused by the increase in strength owing to reducing intergranular fracture by suppressing the reaction with oxygen.

The Effect of Oxide Compound on Electrical Resistivity and Oxidation Stability in High-temperature for Ferritic P/M Stainless Steel (산화물 혼합상이 페라이트계 P/M스테인리스강의 고온산화 및 전기저항 안정성에 미치는 영향)

  • Park, Jin-Woo;Ko, Byung-Hyun;Jung, Woo-young;Park, Dong-Kyu;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.23 no.3
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    • pp.240-246
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    • 2016
  • In order to improve the high-temperature oxidation stability, sintered 434L stainless steel is studied, focusing on the effect of the addition of metallic oxides to form stable oxide films on the inner particle surface. The green compacts of Fecralloy powder or amorphous silica are added on STS434L and oxidized at $950^{\circ}C$ up to 210 h. The weight change ratio of 434L with amorphous silica is higher than that of 434L mixed with Fecralloy, and the weight increase follows a parabolic law, which implies that the oxide film grows according to oxide diffusion through the densely formed oxide film. In the case of 434L mixed with Fecralloy, the elements in the matrix diffuse through the grain boundaries and form $Al_2O_3$ and Fe-Cr oxides. Stable high temperature corrosion resistance and electrical resistivity are obtained for STS434L mixed with Fecralloy.

Feasibility Analysis for Introduction of Scaffolding with Advanced Guardrail System to Prevent Falls (비계작업의 추락재해예방을 위한 선행 안전난간 공법의 도입 타당성 분석)

  • Park, J.D.;Moon, S.O.;Lee, H.S.;Jeong, S.C.;Kwon, Y.J.;Jung, K.
    • Journal of the Korean Society of Safety
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    • v.35 no.4
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    • pp.23-31
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    • 2020
  • In the construction sector, there were 99 fatalities from falls associated with steel tube and system scaffolds for three years from 2016 to 2018 and out of which 27.3 percent (27 workers) were found to have occurred during installing and dismantling procedure. To erect scaffolding which is installed for the work at height, the work platforms are generally installed first and the safety guardrails are installed and vice versa to dismantle. As a result, workers are exposed to the risk of falling because they erect and dismantle scaffolding without guardrails. To minimize the risk of falling, it is necessary to study a new construction method that can erect or dismantle scaffolding while guardrails are installed (called advanced guardrail system). This study analyzed advanced guardrail system in terms of safety regulation, workability and economic efficiency by investigating the domestic situation on the use of scaffolding, reviewing domestic and foreign standards for guardrails and conducting economic feasibility study. The results of this study is expected to greatly contribute to preventing falls in scaffolding installation and dismantlement procedure. As a follow-up study, empirical research is required including physical test of scaffolding with advanced guardrail system and effectiveness analysis after trial applications.

'Kresek' Disease in Korea III. Varietal Resistance, and Relationship among Pathotype, Multiplication in the Tissue and Disease Development (한국에 있어서의 'Kresek'에 관한 연구 III. 품종저항성 및 균주에 따른 도체내에서의 균증식과 발병과의 관계)

  • Choi Y. C.;Cho Y. S.
    • Korean journal of applied entomology
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    • v.19 no.1 s.42
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    • pp.51-55
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    • 1980
  • The study has been carried to confirm pathogenesity among the isolates which obtained from leaf blight type symptoms and Kresek type symptoms, and also to observe varietal resistance among 29 varieties and/or lines through the introduction of two different pathotypes, of Xanthomonas oryzae, by the use of root clipping and pin prick methods. There was no significant differences among the isolates when their growth in plant tissue were compared. There was certain tendency, however, that the isolates from Kreseked plants showed longer lesion than those from blight type lesions. Both isolates from blight type and Kresek type induced the same degree of Kresek syptoms when they were introduced into plants by root cutting in the suspension prior to transplant. Varietal resistance to 'Kresek' appeared to be the same with those on leaf blight type though Wase Aikoku group varieties showed Kresek symptoms which is not the case with leaf blight type. IR 20 in Kogyoku group varieties showed highly resistant reaction to Kresek type. Root clipping method induced the more of Kresek than those by pin pricking method.

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Characterization of a QTL associated with chlorophyll content using progeny from an interspecific cross in rice (Oryza Sativa L.)

  • Shim, Kyu-Chan;Luong, Ngoc Ha;Kim, Sun Ha;Jeon, Yun-A;Lu, Xin;Ahn, Sang-Nag
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.23-23
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    • 2017
  • Rice (Oryza sativa L.) is the world's most important cereal crop. In crop plant, chlorophyll content and leaf senescence could affect grain filling and yield. We analyzed a QTL associated with chlorophyll content and delayed leaf senescence using high chlorophyll near isogenic line (HC-NIL). HC-NIL derived from a cross between Oryza sativa cv. Hwaseong as a recurrent parent and wild species O. grandiglumis as a donor parent showed higher chlorophyll content than Hwaseong. To identify QTL associated with chlorophyll content, 58 $F_3$ and 38 $F_4$ lines were developed from a cross between HC-NIL and Hwaseong. For QTL analysis, simple sequence repeat (SSR) markers were used for genotyping and one-way ANOVA was conducted. A QTL for chlorophyll content (qCC2) was detected in chromosome 2 and explained 24.63% of phenotypic variation. The senescence effect of the qCC2 was examined in dark-induced incubation (DII). Detached leaves from Hwaseong and HC-NIL were incubated on 3mM MES buffer (pH 5.8) at $27^{\circ}C$ under complete dark condition. After 3 days of incubation, the Hwaseong leaves turned yellow, but the HC-NIL leaves were green. HC-NIL has higher chlorophyll content with delayed senescence than Hwaseong. These results indicated that qCC2 is associated with stay-green phenotype. To know whether the qCC2 is responsible for leaf functionality, ion leakage test and Fv/Fm measurement were performed. Both experiment results showed that differences were observed between Hwaseong and HC-NIL but it was not statistically significant. These results might suggest that the qCC2 is possibly related to chlorophyll content and non-functional stay-green phenotype.

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Associated Anomaly of Esophageal Atresia (선천성 식도폐쇄 환아의 동반기형)

  • Baek, Jin-O;Jung, Eun-Young;Park, Woo-Hyun;Choi, Soon-Ok
    • Advances in pediatric surgery
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    • v.17 no.1
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    • pp.81-87
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    • 2011
  • This study was aimed to evaluate associated congenital anomalies in the patients with esophageal atresia with tracheoesophageal fistula (EA/TEF). Forty-two neonates with the diagnosis of EA/TEF treated over a 10 year period in a single institution were included in this study. The demography of EA/TEF was analyzed. Major associated anomalies including vertebral, anal, cardiac, renal, limb, neurologic and chromosome were reviewed and categorized. Males were slightly more dominant than females (1.47:1) and all patients had Gross type C EA/TEF. Only 19 % of the patients had solitary EA/TEF without associated anomalies. Cardiac anomalies were the most common associated congenital anomaly in patients with EA/TEF (73.8 %). But 47.6 % were cured spontaneously or did not affect patients' life. Atrial septal defect (ASD) was the most common cardiac anomaly followed by patent ductus arterious (PDA) and ventricular septal defect (VSD). Among gastrointestinal anomalies (23.8 %), anorectal malformations were the most frequent, 70 % Vertebral and limb abnormalities accounted for 11.9 % and urogenital malformations 9.5 % of the anomalies in patients with EA/TEF. VACTERL associated anomalies were 23.8 % and 1.8% had full VACTERL. Almost 12 % of EA/TEF had neurologic anomalies. Patients with EA/TEF require preoperative evaluation including neurologic evaluation to detect anomalies not related to VACTERL. Though associated cardiac anomaly occurred in 73.8 % of patients in our study, only 21.42 % needed surgical correction. The authors suggesrs further studies with large numbers of patients with EA/TEF.

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Recovery of manganese compounds from electric arc furnace dust by Aluminothermy Process (테르밋 반응을 이용한 페로망간 전기로 분진의 재활용에 관한 연구)

  • Ha, Tae-Young;Jo, Young-Min;Park, Young-Koo;Kim, Youn-Che
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.23-30
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    • 2015
  • The properties of dust collected from electric arc furnace of ferro manganese production units was investigated, and also the metallic manganese was recovered from the dust by aluminothermy process. The ferromanganese dust collected from electric arc furnace contained about 15% of manganese oxide ($Mn_3O_4$) and 9% of carbon as the contaminant, and have a 5um of 50% median diameter and irregular particle shape. The carbon contaminant in the dust could be reduced until about 0.1~0.5% level by roasting in the air at a temperature of 600~900C for 60minutes. The recovery of manganese could not be carried out using only ferromanganese dust from electric arc furnace by aluminothermy process, but the ferromanganese which contained manganese of about 92% and iron of about 5% could be obtained from the mixture of ferromanganese dusts from electric arc furnace and converter. The best mixing condition of dust fixed at electric arc furnace dust / converter dust ratio of 1:9 and 2:8, and the mixing rato of 3:7 or more could not separated the metal and slag from the reactant after aluminothermy reaction.

MEMS-Based Micro Sensor Detecting the Nitrogen Oxide Gases (산화질소 검출용 마이크로 가스센서 제조공정)

  • Kim, Jung-Sik;Yoon, Jin-Ho;Kim, Bum-Joon
    • Korean Journal of Materials Research
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    • v.23 no.6
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    • pp.299-303
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    • 2013
  • In this study, a micro gas sensor for $NO_x$ was fabricated using a microelectromechanical system (MEMS) technology and sol-gel process. The membrane and micro heater of the sensor platform were fabricated by a standard MEMS and CMOS technology with minor changes. The sensing electrode and micro heater were designed to have a co-planar structure with a Pt thin film layer. The size of the gas sensor device was about $2mm{\times}2mm$. Indium oxide as a sensing material for the $NO_x$ gas was synthesized by a sol-gel process. The particle size of synthesized $In_2O_3$ was identified as about 50 nm by field emission scanning electron microscopy (FE-SEM). The maximum gas sensitivity of indium oxide, as measured in terms of the relative resistance ($R_s=R_{gas}/R_{air}$), occurred at $300^{\circ}C$ with a value of 8.0 at 1 ppm $NO_2$ gas. The response and recovery times were within 60 seconds and 2 min, respectively. The sensing properties of the $NO_2$ gas showed good linear behavior with an increase of gas concentration. This study confirms that a MEMS-based gas sensor is a potential candidate as an automobile gas sensor with many advantages: small dimension, high sensitivity, short response time and low power consumption.

Effects of Sputter Deposition Sequence and Sulfurization Process of Cu, Zn, Sn on Properties of Cu2ZnSnS4 Solar Cell Material (Cu, Zn, Sn의 스퍼터링 적층방법과 황화 열처리공정이 Cu2ZnSnS4 태양전지재료 특성에 미치는 효과)

  • Park, Nam-Kyu;Arepalli, Vinaya Kumar;Kim, Eui-Tae
    • Korean Journal of Materials Research
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    • v.23 no.6
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    • pp.304-308
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    • 2013
  • The effect of a sputter deposition sequence of Cu, Zn, and Sn metal layers on the properties of $Cu_2ZnSnS_4$ (CZTS) was systematically studied for solar cell applications. The set of Cu/Sn/Zn/Cu multi metal films was deposited on a Mo/$SiO_2$/Si wafer using dc sputtering. CZTS films were prepared through a sulfurization process of the Cu/Sn/Zn/Cu metal layers at $500^{\circ}C$ in a $H_2S$ gas environment. $H_2S$ (0.1%) gas of 200 standard cubic centimeters per minute was supplied in the cold-wall sulfurization reactor. The metal film prepared by one-cycle deposition of Cu(360 nm)/Sn(400 nm)/Zn(400 nm)/Cu(440 nm) had a relatively rough surface due to a well-developed columnar structure growth. A dense and smooth metal surface was achieved for two- or three-cycle deposition of Cu/Sn/Zn/Cu, in which each metal layer thickness was decreased to 200 nm. Moreover, the three-cycle deposition sample showed the best CZTS kesterite structures after 5 hr sulfurization treatment. The two- and three-cycle Cu/Sn/Zn/Cu samples showed high-efficient photoluminescence (PL) spectra after a 3 hr sulfurization treatment, wheres the one-cycle sample yielded poor PL efficiency. The PL spectra of the three-cycle sample showed a broad peak in the range of 700-1000 nm, peaked at 870 nm (1.425 eV). This result is in good agreement with the reported bandgap energy of CZTS.

Characteristics of Ni1/3Co1/3Mn1/3(OH)2 Powders Prepared by Co-Precipitation in Air and Nitrogen Atmospheres (공기와 질소 분위기에서 공침법으로 합성된 Ni1/3Co1/3Mn1/3(OH)2 분말의 특성 비교)

  • Choi, Woonghee;Park, Se-Ryen;Kang, Chan Hyoung
    • Journal of Powder Materials
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    • v.23 no.2
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    • pp.136-142
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    • 2016
  • As precursors of cathode materials for lithium ion batteries, $Ni_{1/3}Co_{1/3}Mn_{1/3}(OH)_2$ powders are prepared in a continuously stirred tank reactor via a co-precipitation reaction between aqueous metal sulfates and NaOH in the presence of $NH_4OH$ in air or nitrogen ambient. Calcination of the precursors with $Li_2CO_3$ for 8 h at $1,000^{\circ}C$ in air produces dense spherical cathode materials. The precursors and final powders are characterized by X-ray diffraction (XRD), scanning electron microscopy, particle size analysis, tap density measurement, and thermal gravimetric analysis. The precursor powders obtained in air or nitrogen ambient show XRD patterns identified as $Ni_{1/3}Co_{1/3}Mn_{1/3}(OH)_2$. Regardless of the atmosphere, the final powders exhibit the XRD patterns of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ (NCM). The precursor powders obtained in air have larger particle size and lower tap density than those obtained in nitrogen ambient. NCM powders show similar tendencies in terms of particle size and tap density. Electrochemical characterization is performed after fabricating a coin cell using NCM as the cathode and Li metal as the anode. The NCM powders from the precursors obtained in air and those from the precursors obtained in nitrogen have similar initial charge/discharge capacities and cycle life. In conclusion, the powders co-precipitated in air can be utilized as precursor materials, replacing those synthesized in the presence of nitrogen injection, which is the usual industrial practice.