• Title/Summary/Keyword: C2 slope

Search Result 611, Processing Time 0.032 seconds

Fabrication of a Large-Area $Hg_{1-x}Cd_{x}$Te Photovoltaic Infrared Detector ($Hg_{1-x}Cd_{x}$Te photovoltaic 대형 적외선 감지 소자의 제작)

  • Chung, Han;Kim, Kwan;Lee, Hee-Chul;Kim, Jae-Mook
    • Journal of the Korean Institute of Telematics and Electronics A
    • /
    • v.31A no.2
    • /
    • pp.88-93
    • /
    • 1994
  • We fabricated a large-scale photovoltaic device for detecting-3-5$\mu$m IR, by forming of n$^{+}$-p junction in the $Hg_{1-x}Cd_{x}$Te (MCT) layer which was grown by LPE on CdTe substrate. The composition x of the MCT epitaxial layer was 0.295 and the hole concentration was 1.3${\times}10^{13}/cm^{4}$. The n$^{+}$-p junction was formed by B+ implantation at 100 keV with a does 3${\times}10^{11}/cm^{2}. The n$^{+}$ region has a circular shape with 2.68mm diameter. The vacuum-evaporated ZnS with resistivity of 2${\times}10^{4}{\Omega}$cm is used as an insulating layer over the epitaxial layer. ZnS plays the role of the anti-reflection coating transmitting more than 90% of 3~5$\mu$m IR. For ohmic contacts, gole was used for p-MCT and indium was used for n$^{+}$-MCT. The fabrication took 5 photolithographic masks and all the processing temperatures of the MCT wafer were below 90$^{\circ}C$. The R,A of the fabricated devices was 7500${\Omega}cm^{2}$. The carrier lifetime of the devices was estimated 2.5ns. The junction was linearly-graded and the concentration slope was measured to be 1.7${\times}10^{17}/{\mu}m$. the normalized detectivity in 3~5$\mu$m IR was 1${\times}10^{11}cmHz^{12}$/W, which is sufficient for real application.

  • PDF

Aminolyses of Y-substituted Phenyl 2-Furoates and Cinnamates: Effect of Nonleaving Group Substituent on Reactivity and Mechanism

  • Um, Ik-Hwan;Akhtar, Kalsoom;Park, Youn-Min;Khan, Sher Bahadar
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.8
    • /
    • pp.1353-1357
    • /
    • 2007
  • Second-order rate constants (kN) have been determined spectrophotometrically for reactions of Y-substituted phenyl 2-furoates (1a-h) with piperidine and morpholine in 80 mol % H2O/20 mol % DMSO at 25.0 ± 0.1 oC. The Brønsted-type plot exhibits a downward curvature for the reactions with strongly basic piperidine but is linear for the reactions with weakly basic morpholine. The slope of the curved Brønsted-type plot changes from -1.25 to ?0.28 as the pKa of the conjugate acid of the leaving aryloxides decreases. The pKa at the center of the Brønsted curvature, defined as pKa°, was determined to be 6.4. The aminolysis of 1a-h has been concluded to proceed through a stepwise mechanism on the basis of the curved Brønsted-type plot. The reactions of Ysubstituted phenyl cinnamates (2a-g) with piperidine resulted in a curved Brønsted-type plot with a pKa° values of 6.4. However, the curved Brønsted-type plot has been suggested to be not due to a change in the RDS but due to a normal Hammond effect of a concerted mechanism, since the Brønsted-type plot for the corresponding reactions with morpholine results in also a curved Brønsted-type plot with a pKa° values of 6.1. The furoates with a basic leaving group (i.e., 1b-g) are less reactive than the corresponding cinnamates (i.e., 2b-g). The k2/ k-1 ratios for the reactions of 1b-h are much smaller than unity, which has been suggested to be responsible for their low reactivity.

The Studies for the Malate Tissue Biosensor Using Malate Dehydrogenase(Decarboxylating) in the Bundle Sheath Cell of the Corn Leaf (옥수수잎의 유관속초세포내에 들어 있는 Malate Dehydrogenase(Decarboxylating)을 이용한 Malate 측정용 조직바이오센서에 관한 연구)

  • 김의락;노광수
    • KSBB Journal
    • /
    • v.9 no.3
    • /
    • pp.319-324
    • /
    • 1994
  • A biosensor for the measurement of malate has been constructed by the sodium-alginate immobilized bundle sheath cell tissue of corn leaf containing malate dehydrogenase (decarboxylating) (EC 1. 1. 1. 40) on the CO2 gas-sensing electrode. The proposed tissue sensor had the linear in the range of malate concentration $5.5{\times}10^{-5}M∼2.5{\times}10^{-2}M$ with a slope of 53.5 mV/decade in 0.02M Tris-HCl buffer solution at optimum pH 8.0, and $25^{\circ}C$. A response time was 16∼18min. The present L-malate sensing tissue sensor is stable for more than one week. At pH 7.4, Km value was $0.6{\times}10^{-5}M$. The various kinds of salt did not effect the signal of malate tissue biosensor as the inhibitor. We can measure the malate by the CO2 electrode at the pH=8.0. Thus, the proposed tissue sensor will be useful for the measurement of malate.

  • PDF

Intra-tracheal Administration of the Disinfectant Chloromethylisothiazolinone/methylisothiazolinone (CMIT/MIT) in a Mouse Model to Evaluate a Causal Association with Death (마우스의 기도 내 점적을 통한 가습기살균제 CMIT/MIT와 사망 간의 원인적 연관성에 관한 연구)

  • Kim, Hayoung;Chung, Yonghyun;Park, Yeongchul
    • Journal of Environmental Health Sciences
    • /
    • v.43 no.4
    • /
    • pp.247-256
    • /
    • 2017
  • Objectives: The deaths of Korean victims exposed to the disinfectant CMIT/MIT have remained unresolved. This is mainly due to a lack of concordance between the few available toxicity tests and the abundant epidemiological data, making it difficult to establish a cause-and-effect relationship. Therefore, this study was carried out to investigate any potential associations between CMIT/MIT exposure and death. Methods: Groups of experimental and control C57BL/6 mice were instilled (in the trachea) with chloromethylisothiazolinone/methylisothiazolinone (CMIT/MIT) using a visual instillobot. CMIT/MIT was instilled over a period of three days and eight weeks, respectively, to achieve acute and chronic exposures. A threshold dose-response model was applied for estimating the threshold level as one line of evidence for a causal association between CMIT/MIT and death. Results: An acute exposure of 1.2 mg ai/kg/day of CMIT/MIT was estimated to reflect the threshold for death. The dose-response curve with this threshold showed a very steep slope and a narrow range of CMIT/MIT exposures. The narrow range of CMIT/MIT exposures, in particular, indicated an evident boundary between survival and death, thus implicating a strong causal association. A similar threshold dose-response relationship observed following acute exposure was also seen following chronic exposure to CMIT/MIT. Airborne disinfectant exposure was visible as minimal or mild lung damage with no fibrosis, as shown by histopathological tests. However, many observations are considered to be functional respiratory tract or lung failure due to death, as observed in necropsies of the mice that died due to CMIT/MIT exposures. Conclusions: There are two strong lines of evidence for a causal association between death and CMIT/MIT exposure: 1) The threshold dose-response curve, with a very steep slope and a narrow range of CMIT/MIT exposures showing a visible boundary between survival and death; and 2) many cases of functional respiratory or lung failure.

Creation of an Environmental Forest as an Ecological Restoration

  • Lee, Chang-Seok;You, Young-Han
    • The Korean Journal of Ecology
    • /
    • v.24 no.2
    • /
    • pp.101-109
    • /
    • 2001
  • We created an environmental forest on the basis of ecological design around the incineration plant of Jindo Engineering and Construction Co., Ltd., which is located in Jeongwang-dong, Siheung-si, Kyunggi-do. To get ecological information of this site, physico-chemical properties of soil on salt marsh, which is located close to the syudy site and of forest soil transported from other sites for ecological restoration were analyzed. Texture of salt marsh and transported soils were loam and sandy loam, respectively. pH, organic matter, T-N, available P, and exchangeable K and Na contents of salt marsh and transported forest soils were 6.7 and 5.4, 4.1 and 0.4%, 1.0 and 0.3mg/g, 46.7 and 6.8ppm, 521 and 207ppm, and 3.8 and 0.5mg/g, respectively. Introduced plants were selected among the dominant species of forests and the species composing the potential natural vegetation around the present study site. Those plants were selected again by considering the tolerances to air pollution and to salt, and their availability. Selected trees were Pinus thunbergii, Sophora japonica, Celtis sinensis, Quercus aliena, Q. serrata, Q. dentata, and Q. acutissima. Selected sub-trees were Albizzia julibrissin, Koelreuteria poniculata, and Styrax japonica and shrubs were Rhododendron yedoense var. poukhanense, R. mucronulatum, Callicarpa japonica, Euonymus alatus, E. japonica, and R. schlippenbachii. On the other hand, introduction of herbs was not considered except for Liriope platyphylla, which was ornamentally planted in one site. Planting bed of mound type was adopted to provide the fine drainage system. Mound was designed to furnish litter, A, B, and C layers simuating the profile of forest soil. Slope of mound was mulched by rice straw of 2cm in thickness to prevent for sliding of litter and soil in cases of strong wind or heavy rain. Height of mound was designed to secure more than 1 m by combining A and B layers. Narrow zones, in which mound with stable slope degree cannot be prepared, was designed to equip the standard soil depth with the introduction of stone for supporting. On the other hand, plants with shallow root system were arranged in some zones, in which satisfactory soil depth cannot be ensured. Plants were arranged in the order of tree, sub-tree, and shrub from center to edge on the mound to make a mature forest of a dome shape in the future. Dispersion of plants was designed to be random pattern rather than clumped one. Problems on creation of the environmental forest by such ecological design were found to be management or inspection by non-specialized project operators and inspecting officers, and regulations for construction without ecological background. Alternative plans to solve such problems were suggested.

  • PDF

Real-time Control of Biological Animal Wastewater Treatment Process and Stability of Control Parameters (생물학적 축산폐수 처리공정의 자동제어 방법 및 제어 인자의 안정성)

  • Kim, W.Y.;Jung, J.H.;Ra, C.S.
    • Journal of Animal Science and Technology
    • /
    • v.46 no.2
    • /
    • pp.251-260
    • /
    • 2004
  • The feasibility and stability of ORP, pH(mV) and DO as a real-time control parameter for SBR process were evaluated in this study. During operation, NBP(nitrogen break point) and NKP(nitrate knee point), which reveal the biological and chemical changes of pollutants, were clearly observed on ORP and pH(mV)-time profiles, and those control points were easily detected by tracking the moving slope changes(MSC). However, when balance of aeration rate to loading rate, or to OUR(oxygen uptake rate), was not optimally maintained, either false NBP was occurred on ORP and DO curves before the appearance of real NBP or specific NBP feature was disappeared on ORP curve. Under that condition, however, very distinct NBP was found on pH(mV)-time profile, and stable detection of that point was feasible by tracking MSC. These results might mean that pH(mV) is superior real-time control parameter for aerobic process than ORP and DO. Meanwhile, as a real-time control parameter for anoxic process, ORP was very stable and more useful parameter than others. Based on these results, a stable real-time control of process can be achieved by using the ORP and pH(mv) parameters in combination rather than using separately. A complete removal of pollutants could be always ensured with this real-time control technology, despite the variations of wastewater and operation condition, as well as an optimization of treatment time and capacity could be feasible.

Site and Growth Characteristics of Cornus Controversa Growing at Mt. Gariwang and Mt. JoongWang Located in Pyungchang-gun, Kangwon-do (강원도(江原道) 평창군(平昌郡) 가리왕산(加里旺山) 및 중왕산(中王山) 지역(地域) 층층나무의 입지(立地) 및 성장(成長) 특성(特性))

  • Um, Tae Won;Lee, Don Koo
    • Journal of Korean Society of Forest Science
    • /
    • v.90 no.3
    • /
    • pp.363-372
    • /
    • 2001
  • The objective of this study was to investigate the site and growth characteristics of dominating Cornus controversa in the hardwood stands at Mt. Gariwang and Mt. Joongwang area located in Pyungchang-gun, Kangwon-do. The C. controversa was mainly distributed at the rather steep slope and aspect facing from northeast to northwest, and altitudes ranging from 800 to 1,100m. The C. controversa grew at relatively deep A soil layer with high moisture and nutrients. Major competing species in upper stories were Quercus mongolica, Acer mandshuricum, Salix hulteni, Acer pictum, and herb plants such as Polystichum tripteron, Dryopteris crassirhizoma, Meehania urticifolia, Pseudostellaria pahbiniana, Ligularia fischeri, Impatiens noli-tangere, Corydalis speciosa in the floor. The average annual diameter growth of C. controversa according to the altitude was $4.06({\pm}0.90)mm$ below 900m, $2.51({\pm}0.65)mm$ from 900 to 1,000m, $3.28({\pm}0.12)mm$ from 1,000m to 1,100m and $2.81({\pm}0.35)mm$ above 1,100m. Good annual growth was shown at northwest site, but no difference due to micro-topography.

  • PDF

Field Study on the Classroom Environment at School - Case study of Hansung Girls' Middle & High School In Seoul City - (학교(學校) 교실(敎室)의 실내환경(室內環境) 실태(實態) 조사(調査) 연구(硏究) - 서울시 한성여중.고교(漢城女中.高校) 사례(事例)를 중심(中心)으로 -)

  • Kim, Kang-Hwan;Lee, Hyoun-Young
    • Journal of the Korean Institute of Educational Facilities
    • /
    • v.7 no.3
    • /
    • pp.5-14
    • /
    • 2000
  • The purpose of this study is to analyze the environmental characteristics of Hansung Girls' Middle & High School located on the northern slope of Mt. Naksan in Seoul but sited at different aspects. The measured temperature and illumination in March, July and December were analysed. The proportion of window size and questionaries were used also. The results of observation are as follows: (1) The temperature of the southward classrooms was $3.6^{\circ}C$ higher than eastward or westward classrooms in March, but the difference of the both values in July were only $0.3^{\circ}C$ in the average. (2) The temperatures in December decreased in the order of aspects: southward, westward and eastward. (3) The highest values for illumination appeared in the classroom faced to the south and the values decreased from westward to eastward. (4) Temperatures and illumination were varied not only with the aspect but also with the number of story and the proportion of the window size. However, the heating facilities and illuminators are installed evenly without considering the condition of the buildings. The heating facilities should be installed differently according to the direction and height of the story of the building. The heating facilities should be installed sparsely for the classrooms faced southward, and more densely near the hallway side to achieve satisfaction of students and to save expenses of heating. It will be better that electric power switches for window side have to be set separately from hallway side. Improvement of the condition of illumination and temperatures will help students to promote their health and learning.

  • PDF

Effectiveness of Wave Resonator for Secondary Undulation under Real Sea Conditions (실해역에서 공진장치를 이용한 부진동의 제어)

  • Jeong, Jin-Woo;Kim, Do-Sam;Park, Jong-Bae;An, Sung-Wook
    • Journal of Ocean Engineering and Technology
    • /
    • v.24 no.6
    • /
    • pp.51-60
    • /
    • 2010
  • In this study, the performance evaluation of a conventional wave resonator at the entrance of a port or a pier against secondary undulation has been performed using 2D hydrodynamic modeling within port. A wave resonator has been designed for the attenuation of the secondary undulation induced by the long-periodic waves. The controlled performance of the wave resonator has been numerically investigated for CGWAVE MODULE of finite-element model of SMS (Surface water Modeling System) based on the elliptic mild-slope wave equation. SMS was verified though the comparisons with analytical solution performed by Ippen and Goda (1963). Also, It was confirmed that a wave resonator of a rectangular model harbor is effective enough to control the secondary undulation when it compares variation of water level with the case of no resonance system. From the above results, amplification phenomenon induced by long-period waves transferred from 1900 sec to 2100 sec when it applied a wave resonator in Busan Gamcheon Port which is a deep-sea. And it was confirmed that a wave resonator of Pohang New Port attenuates largely long-period waves which are within the range of 300 sec induced by long-period motion of the moored ship.

Design of the Green Wall System considering Distribution Effect of Earth Pressure by Soil Nail (네일의 토압분담 효과를 고려한 Green Wall 시스템의 설계)

  • Park, Si-Sam;Cho, Sung-Han;Yoo, Chan-Ho;Kim, Hong-Taek;Kim, Yong-Yeon
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2006.03a
    • /
    • pp.1038-1045
    • /
    • 2006
  • The Green Wall is highest eco-system among a segmental retaining wall systems. Recently, the demand of high segmental retaining wall (SRW) is increased in domestic. The soil nailing system is applied in order to maintain the high SRW stability for steeper slope. However, the proper design approach that can consider the earth pressure reduction effects in soil nailing system has not been proposed. This study was performed to introduce the design case by 'Two-Body Translation mechanism' to be able to consider distribution of earth pressure in the soil nailing when designing the green wall using soil nailing system. Also, this study attempts to evaluate the earth pressure change when advanced soil nailing system is constructed using $FLAC^{2D}$ ver. 3.30 program and 'Two-Body Translation mechanism'. Also in this study, various parametric studies using numerical methods as shear strength reduction (SSR) technique and limit equilibrium technique were carried out. In the parametric study, the length ratio and the bond ratio of the soil nailing were changed to identify the earth pressure reduction effect of the retaining wall reinforced by soil nailing.

  • PDF