• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.39-42
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• 2002

Cloride attack of concrete is one of the important causes of corrosion of reinforcing steel in concrete with carbonation and frost damage. In this paper, the effect of fly-ash on the cloride attack were investigated by varying water binder ratio and fly-ash contents according to the chloride ion penetrationa test. (ASTM C 1202-94) The principal conclusions from this research were as follows: 1) The compressive strength of concrete at large ages, depends more on $C_2$S contents of base cement than fly-ash contents. 2) On the other hand, the chloride ion penetration of concrete at large ages, principally depends on fly-ash contents and the influence of type of base cement is insignificant.

• 수산해양기술연구
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• 제38권3호
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• pp.234-240
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• 2002

본 연구에서는 전개판의 영각 변화에 따른 정적안정성에 관하여 이론적 해석을 하였다. 또한 전개판의 형상별 유체력에 의한 정적 안정성을 평가하기 위하여 종횡비가 다른 평판과 만곡도가 다른 종만곡판을 사용하여 회류수조에서 유체력 및 모벤트를 측정하고 형상별 압력중섬계수와 모멘트 계수를 계산하였다. 본 연구에서 얻어진 결과를 요약하면 다음과 같다. 1. 전개판의 영각($\alpha$) 변화에 따른 끌줄의 장력과 후릿줄의 장력에 의한 모멘트 변화는 전개판을 항상 정적 안정성을 가지도록 작용한다. 2. 종횡비(λ)가 0.5, 1.0, 1.5인 평판의 압력중심계 수는 영각의 증가와 함께 전연에서 중심쪽으로 이동한다. 이것은 유체력에 의한 모멘트는 항상 정적으로 안정하도록 작용한다는 것을 의미한다. 3. 종횡비가 일정(λ=1.5)하고, 만곡도(CR)가 5%, 10%, 15%, 20%인 만곡판의 유체력에 의한 압력중심계수는 영각의 증가와 함께 후연에서 전연쪽으로 이동한 다음, 다시 만곡판의 중심쪽으로 이동한다 만곡판에 작용하는 유체력에 의한 모멘트는 만곡도가 커질수록 정적으로 불안정한 영각의 범위가 증가한다.

• 한국통신학회논문지
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• 제37권2C호
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• pp.132-139
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• 2012

2011년 배우식 등은 해시함수 기반의 새로운 저비용 RFID 상호인증 프로토콜(NLMAP)을 제안하였다. 그들은 난수 발생 등 연산량을 최소화하며, 상호인증으로 재전송 공격, 스푸핑 공격, 트래픽 공격, 도청 공격 등에 안전하기 때문에 RFID 시스템에 적용 시 제작비의 절감 및 보안성이 우수한 장점이 있다고 주장하였다. 그러나 그들의 주장과는 달리 도청 공격으로 해시된 태그의 고유 식별 정보 H(IDt)를 획득할 수 있다. 그리고 공격자가 획득한 H(IDt)를 이용하여 위치추적과 스푸핑 공격이 가능함을 본 논문에서 증명한다. 더 나아가 해시함수와 CRC코드를 이용한 상호인증 프로토콜을 제안한다. 그리고 제안 프로토콜이 NLMAP보다 다양한 공격에 안전하고 연산량 측면에서 효율적임을 증명한다.

• Wind and Structures
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• 제37권1호
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• pp.15-23
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• 2023

The wake behavior of extended flat plate and serration in the trailing edge of S809 airfoil is presented in this experimental study using wind tunnel testing. The clustering of wind turbines in wind parks has recently been a pressing issue, due to the expected increase in power output and deciding the number of wind turbines to be installed. One of the prominent factors which influence the performance of the subsequent wind turbines is the downstream wake characteristics. A series of wind tunnel investigations were performed to assess the downstream near wake characteristics of the S809 airfoil at various angles of attack corresponding to the Reynolds Number Re = 2.02 × 105. These experimental results revealed the complex nature of the downstream near wake characteristics featuring substantial asymmetry arising out of the incoherent flow separations prevailing over the suction and the pressure sides of the airfoil. Based on the experimental results, it is found that the wake width and the downstream velocity ratio decrease with an increase in the angle of attack. Nonetheless, the dissipation length and downstream velocity ratio increases proportionally in the downstream direction. Additionally, attempts were made to understand the physical nature of the near wake characteristics at 1C, 2C, 3C and 4C downstream locations.

• 대한한방내과학회지
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• 제10권1호
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• pp.25-38
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• 1989

Clinical observation was done on 1092 cases of cerebrovascular disease which were confirmed by Brain CT scan in Oriental Medical Hospital in Kyung Hee Univ. from May 1987 to May 1988. Specially, clinical prognosis of 250 patients who had been hospitalized for over 4 weeks, were obserbed. The results were obtained as follows; 1. In this study, Occlusive CVD was 77.9%, Cerebral hemorrhage was 18.8%, Subarachnoid hemonhage was 0.8%. 2. The ratio of male to female was 1.4:1. In the age distribution, 60th decade, 50th decade, 40th decade, 30th's, 20th's were in order of frequency and specially 60th decade was 35.53% over 70th decade was 17.1% in ratio. 3. The most common preceding disease of CVD was hypertension (54.21%) and diabetes mellitus (19.96%) was second. 4. Almost, the duration of hospitalization was 2-4 weeks in 34.8%, within 4 weeks in 78.02%. 5. Primary attack was 75.7%, 2nd attack was 17.9%, over 3rd attack was 3.1% in ratio of recurrence. 6. The level of consciousness was Grade I in 96.4%, Grade II in 3.2%, Grade III in 1% at attack. 7. A few complications of C.V.A. were observed in the studies: pneumonia was noted frequently in 3.2%, bed sore, urinary tract infection, gastro intestinal bleeding in order of frequency. 8. The ratio of neurologic deficiency in occlusive CVD decreased from 51.9% to 29.3% in upper limb, 52.6% to 24.4% in lower limb, and that in cerebral hemorrhage decreased from 69.5% to 25% in upper limb, 50% to 20% in lower limb. 9. The ratio of left side hemiplegia to right was 1.04:1 in male, 1:1.18 in female. 10. The herb medications for C.V.A. were various Chungg-Paesagantang, Sunghanggeonggisan were used most frequently to Chungyeold, Geopung, Soongi, Haldam and Chungsimtang, the drugs for Bogiheol were used as discharge. In these oriental medical therapy of C.V.A. objective diagnosis and more various therapeutic method must be obtained through east-west medical co-operation.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.169-172
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• 2006

The IIA structures exposed to marine environment is subject to many different types of potential attack. The physical attack due to drying and wetting would increase the internal stress of concrete. The chemical attack resulting from the diffusion of ions$(Cl^-,SO_4^{2-},Mg^+)$ from seawater through the pores in concrete. Therefore the sea water resistance of concrete must be considered when it is used for structure in the ocean. The objective of this study is to evaluate chloride diffusion and corrosion characteristics of concrete when using the various concrete materials under marine environment. After 5 years of exposure, concrete incorporating 40% blast-furnace slag as replacement for type I cement with low w/c ratio of 0.42 and using the inhibitor shows excellent performance.

• 농약과학회지
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• 제7권2호
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• pp.155-158
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• 2003

2-Imino-1,3-thiazloine 1은 새로운 작용기작에 의하여 벼도열병원균에 대하여 선택적인 항균력을 나타낸다. 화합물 1의 C-2 위치의 imino기에 cyano 기가 치환된 새로운 화합물 2-cyanoimino-1,3-thiazoline 유도체 2를 합성하였다. Cyano 기의 강한 전자끌기와 더불어 1,3-thiazoline 고리의 황 및 질소원자의 비공유전자쌍은 2-imino-1,3-thiazloine 계열의 생물활성에 영향을 줄 것으로 예상되었다. Thiourea 4 의 $\gamma$-chloro-$\beta$-ketoacetoacetanilide 3에 대한 위치 특이적인 친핵적 공격 및 산촉매 하의 탈수에 의해서 2가 생성되었다.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.1047-1051
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• 2012

The nucleophilic substitution reactions of (2R,4R,5S)-(+)-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholidine 2-sulfide with X-pyridines are investigated kinetically in acetonitrile at $5.0^{\circ}C$. The free energy relationships for substituent X variations in the nucleophiles exhibit biphasic concave upwards with a break point at X = 3-Ac. Unusual positive $\rho_X$ (= +4.73) and negative ${\beta}_X$ (= -0.75) values are obtained with the weakly basic pyridines, and rationalized by the isokinetic relationship with isokinetic temperature at $t_{ISOKINETIC}=39.3^{\circ}C$. A concerted mechanism involving a change of nucleophilic attacking direction from a frontside attack with the strongly basic pyridines to a backside attack with the weakly basic pyridines is proposed on the basis of greater magnitudes of selectivity parameters ($\rho_X$ = -6.15 and ${\beta}_X$ = 1.11) with the strongly basic pyridines compared to those ($\rho_X$ = 4.73 and ${\beta}_X$ = -0.75) with the weakly basic pyridines.

• Bulletin of the Korean Chemical Society
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• 제32권8호
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• pp.2628-2632
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• 2011

The nucleophilic substitution reactions of Y-O-aryl phenyl phosphonochloridothioates with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are kinetically investigated in acetonitrile at $55.0^{\circ}C$. The deuterium kinetic isotope effects (DKIEs) invariably increase from an extremely large secondary inverse ($k_H/k_D$ = 0.439; min) to a primary normal ($k_H/k_D$ = 1.34; max) as both substituents of nucleophile (X) and substrate (Y) change from electron-donating to electron-withdrawing. These results are opposite to the DKIEs on Y-O-aryl methyl phosphonochloridothioates, and can be rationalized by the gradual transition state (TS) variation from backside to frontside attack. The trigonal bipyramidal pentacoordinate TS is proposed for a backside attack, while the hydrogen-bonded, four-center-type TS is proposed for a frontside attack. The negative values of the cross-interaction constants (${\rho}_{XY(H)}$ = -0.38 for $XC_6H_4NH_2$ and ${\rho}_{XY(D)}$ = -0.29 for $XC_6H_4ND_2$) indicate that the reactions proceed by a concerted $S_N2$ mechanism.

• Bulletin of the Korean Chemical Society
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• 제32권10호
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• pp.3743-3747
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• 2011

Kinetic studies on the reactions of Y-S-aryl phenyl phosphonochloridothioates with X-pyridines have been carried out in MeCN at $55.0^{\circ}C$. The Hammett and Bronsted plots for substituent X variations in the nucleophiles are biphasic concave upwards with a break point at X = H. The Hammett plots for substituent Y variations in the substrates are biphasic concave upwards with a break point at Y = H, and the sign of ${\rho}_Y$ is changed from unusual negative (${\rho}_Y$ < 0) with the weaker electrophiles to positive (${\rho}_Y$ > 0) with the stronger electrophiles. The stepwise mechanism is proposed on the basis of the ${\rho}_X$, ${\beta}_X$, and ${\rho}_{XY}$ values as follows: a ratelimiting leaving group departure from the intermediate involving a frontside attack and product-like TS for the stronger nucleophiles and weaker electrophiles; a rate-limiting leaving group departure from the intermediate involving a backside attack and product-like TS for the weaker nucleophiles and electrophiles; a rate-limiting bond formation involving a frontside attack for the stronger nucleophiles and electrophiles; a rate-limiting bond formation involving a backside attack for the weaker nucleophiles and stronger electrophiles. The substituent effects of X and Y on the pyridinolysis mechanisms of $R_1R_2P$(=S)Cl-type substrates are discussed.