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A Study of Nonstoichiometric Empirical Formulas for Semiconductive Metal Oxides

  • Kim, Kyung-Sun;Lee, Kwan-Hee;Cho, Ung-In;Choi, Jae-Shi
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.29-35
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    • 1986
  • An empirical formula for semiconductive metal oxides is proposed relating nonstoichiometric value x to a temperature or an oxygen partial pressure such that experimental data can be represented more accurately by the formula than by the well-known Arrhenius-type equation. The proposed empirical formula is log x = A + $B{\cdot}1000/T\;+\;C{\cdot}$exp$(-D{\cdot}1000/T)$ for a temperature dependence and $log\;{\times}\;=a\;+b{\cdot}log\;Po_2\;+\;c{\cdot}$exp$(-d{\cdot}log\;Po_2)$ for an oxygen partial pressure dependence. The A, B, C, D and a, b, c, d are parameters which are evaluated by means of a best-fitting method to experimental data. Subsequently, this empirical formula has been applied to the n-type metal oxides of $Zn_{1+x}O,\; Cd_{1+x}O,\;and\;PrO_{1.8003-x}$, and the p-type metal oxides of $CoO_{1+x},\; FeO_{1+x},\;and\;Cu_2O_{1+x}$. It gives a very good agreement with the experimental data through the best-fitted parameters within 6% of relative error. It is also possible to explain approximately qualitative characters of the parameters A, B, C, D and a, b, c, d from theoretical bases.

CIRCULAR DISTORTION AND THE DOUBLE DISK PROPERTY OF CURVES

  • Kim, Ki-Won
    • Journal of the Korean Mathematical Society
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    • v.34 no.1
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    • pp.43-55
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    • 1997
  • Suppose that D is a domain in the extended complex plane $\overline{C} = C \cup {\infty}$. For each $z_0 \in C$ and $C < r < \infty$, we let $B(z_0, r) = {z \in C : $\mid$z - z_0$\mid$ < r}$ and $S(z_0, r) = \partial B(z_0, r)$. For non-empty sets A, $B \subset \overling{C}$, diam (A) is the diameter of A and d(A, B) is the distance of A and B.

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Effects of Purple Sweet Potato intake and Aerobic Combined Exercise on Health Related Fitness, Blood lipid profile and Insulin resistance (자색고구마 섭취와 유산소 복합운동이 비만 여중생의 건강체력, 혈중지질 및 인슐린 저항성에 미치는 영향)

  • Son, Won-Mok;Kim, Do-Yeon;Sung, Ki-Dong;Baek, Young-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.11
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    • pp.7524-7533
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    • 2015
  • The purpose of this study was to investigate the effects of purple sweet potato(PSP) intake and aerobic combined exercise in obese middle school girls. Twenty-four, obese(%body fat > 30%) middle school girls composed of the purple sweet potato intake and aerobic combined exercise group(A, n=6), the aerobic combined exercise group(B, n=6), the purple sweet potato intake group(C, n=6), the control group(D, n=6). The variables of health related fitness, blood lipid profile, insulin resistance were measured in all the subjects before the start and after the end of 12 week aerobic combined exercise program(40~70%HRR, 3 times per week, 70 mins). The test data were analyzed by paired t-test and one way ANOVA, and the alpha level of p<.05 was set for all tests of significance. In the comparison within each group, %body fat[A(p<.01), C(p<.05) groups], TC[A(p<.05), B(p<.01), C(p<.01) groups] and insulin resistance[A(p<.05) group] were significantly decreased and LBM[A(p<.01), B(p<.01) groups], muscular strength[A(p<.01), B(p<.001), C(p<.05) groups], muscular endurance[A(p<.05), B(p<.001) groups], flexibility[A(p<.05), B(p<.01) groups] and cardiorespiratory endurance[A(p<.05), B(p<.001), C(p<.01) groups] were significantly increased. In the comparison between groups, A group was significantly decreased in %body fat, TC and TG than D group(p<.05). A group was significantly increased in muscular strength and cardiorespiratory endurance than C, D groups (p<.05). A group was significantly increased in muscular endurance and HDL-C than D group(p<.05). A, B groups were significantly increased in flexibility than D group(p<.05). A, B, C groups were significantly decreased in insulin resistance than D group(p<.05). In conclusion, purple sweet potato intake and aerobic combined exercise were effective in improving the health related fitness, blood lipid profile and insulin resistance in obese middle school girls.

Changes of chemical composition and enzyme activity of soybean by processing method (대두의 처리방법에 따른 일반성분과 효소활성변화)

  • Kim, Nam-Dae;Choi, Soon-Gon;Joo, Hyun-Kyu
    • Applied Biological Chemistry
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    • v.35 no.4
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    • pp.232-236
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    • 1992
  • In order to manufacture of soy paste, Changes of chemical composition and enzyme activity of soybean by different processing method were investigated. The results are summarized as follows: Changes of chemical compositions were; Raw(A) and soaked(B) soybeans contain about 2% of more crude fat than roasted(C) and steamed(D) soybeans, roasted and steamed soybeans contain $1.16{\sim}1.74%$ of more protein than those of raw and soaked soybeans, and Raw and roasted soybeans contain $0.11{\sim}0.41%$ of more crude fiber than those of soaked and steamed soybeans. ${\alpha}-amylase$, ${\beta}-amylase$, protease, lipase activity of raw and soaked soybeans were $2{\sim}5$ folds higher than those of roasted and steamed soybeans. Trypsin inhibitor activity of raw, soaked, roasted and steamed soybeans was indicated 56.7%, 42.9%, 32.9% and 20.8% in the order, respectively.

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Allelic Variation of Glutenin, Granule-Bound Starch Synthase l and Puroindoline in Korean Wheat Cultivar

  • Park, Chul-Soo;Pena, Roberto J.;Baik, Byung-Kee;Kang, Chon-Sik;Heo, Hwa-Young;Cheong, Young-Keun;Woo, Sun-Hee
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.2
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    • pp.181-191
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    • 2009
  • To investigate the genetic variation of high-and low-molecular-weight glutenin subunits (BMW-GS and LMW-GS), granule-bound starch synthase I (GBSSI) and puroindoline in 24 Korean wheat cultivars. At the BMW-GS compositions, three Glu-A1 alleles, five Glu-B1 alleles and three Glu-D1 alleles were identified. The high frequency of alleles at each locus was Glu-A1c allele (15 cultivars), Glu-B1b allele (16 cultivars) and Glu-D1f allele (16 cultivars). Four alleles were identified at the Glu-A3 and Glu-B3 loci and three at Glu-D3 locus and Glu-A3d, Glu-B3d and Glu-D3a were mainly found at each Glu-3 locus. Glu-A3d, Glu-B3d, Glu-D3b or c (4 cultivars, respectively) and Glu-A3d, Glu-B3d, Glu-D3a and Glu-A3c, Glu-B3d or h, Glu-D3a (3 cultivar, respectively) were predominantly found in Korean wheats. At the GBSS compositions, 2 waxy wheat cultivars, Shinmichal and Shinmichal1, showed null alleles on the Wx loci and other cultivars were wild type in GBSS compositions. At the puroindoline gene compositions, Korean wheat cultivars carried 3 genotypes, which 10 cultivars (41.7%) were Pina-D1a and Pinb-D1a, 11 cultivars (45.8%) had Pina-D1a and Pinb-D1b and 3 cultivars (12.5%) carried Pina-D1b and Pinb-D1a. These genetic variations could present the information to improve flour and end-use quality in Korean wheat breeding programs.

Changes in Aerodynamic Function and Closed Quotient with the Variable Pitch and Loudness in Male Classic Singers (남성 성악가의 음도고정시 강도 변화와 강도고정시 음도 변화의 공기역학 및 성대접촉율의 변화)

  • Nam, Do-Hyun;Paik, Jae-Yeon;Kim, Jae-Ok;Park, Sun-Young;Choi, Hong-Shik
    • Speech Sciences
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    • v.14 no.2
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    • pp.23-33
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    • 2007
  • This study examined the aerodynamic functions (mean airflow rate MFR, subglottal pressure Psub) and closed quotients (CQs) in the fixed pitch (C3, E3, G3, C4) with the variable loudness (70 and 80 dB) as well as in the fixed loudness at 70 dB and 80 dB with the variable pitch (C3, E3, G3, C4) in five classic male singers (Baritone). Results showed that MFR significantly increased at C3, E3, and G3 and Psub significantly increased at C4 when the loudness increased from 70 to 80 dB. At 70 dB, MFR and Psub significantly increased and CQ significantly decreased when the pitch increased from C3 to C4. At 80 dB, MFR significantly decreased when the pitch increased from C3 to G3. However, Psub showed the significant decrease with the pitch increased at 80 dB. In conclusion, as the loudness increases, the aerodynamic loss is getting higher and vocal efficiency becomes lower at low pitch than at higher pitch. At a low loudness level, the main mechanism to control loudness is the amount of medial compression of the vocal folds rather than the aerodynamic function. In addition, the aerodynamic function and medial compression of the vocal folds have a significant role in increasing the loudness level.

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Strength Performance Evaluation of Threaded Nail Joints of Wooden Retaining Wall Using Pitch Pine (Pinus rigida Miller) Square Timber (리기다 소나무 정각재를 사용한 목재옹벽의 직결나사못 접합부 내력 성능 평가)

  • Song, Yo-Jin;Kim, Keon-Ho;Lee, Dong-Heub;Hwang, Won-Joung;Hong, Soon-Il
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.1
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    • pp.53-59
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    • 2011
  • A connection was made between a single stretcher and 2 headers with 2 threaded nails (Type-A), and another one between 2 stretchers and 2 headers with 4 threaded nails (Type-B) to use as specimens. Type-C was the stretchers that are connected with 2 threaded nails by half lap joint at end-distance 5D to reinforce Type-B, Type-C1 the stretchers that are connected by half lap joint at end-distance 10D, and Type-C2 with 3 threaded nails at end-distance 10D. Compressive shear strength of Type-C, the supplementation of Type-B, was decreased by 30%, compared with that of Type-B. Those of Type-B and Type-C1 that used longer end-distance than Type-C were about the same, and that of Type-C2 connected with 3 threaded nails was 1.28-times stronger than that of Type-C1. Connection of the retaining wall using existing square timber has a problem between long and short stretchers and 2 headers. So it was investigated in the experiment to replace it. Therefore, if Type-B is replaced with Type-C2 in constructing the retaining wall, the crack and the rupture of timber caused by threaded nail as well as construction period can be reduced, and also it can be expected to increase their own strength.

Isolation and Properties of $\beta$-N-Acetyl-D-glucosaminidase B from Rat Uterus

  • Jung, Jin-Ha;Yang, Chul-Hak
    • Bulletin of the Korean Chemical Society
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    • v.4 no.3
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    • pp.139-143
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    • 1983
  • ${\beta}$-N-Acetyl-D-glucosaminidase B was highly purified with the following sequence of steps; DEAE-cellulose, CM-cellulose, and Sephadex G-200 gel filtration chromatograpies. The specific activity of the purified ${\beta}$ -N-acetyl-D-glucosaminidase B was 2.2 units/mg protein with 12.9 % yield and 196.2 fold purity. The purified ${\beta}$-N-acetyl-D-glucosaminidase B showed single band on polyacrylamide gel electrophoresis. The final preparation of ${\beta}$ -N-acetyl-D-glucosaminidase B was completely free friom arylsulfatase and ${\beta}$-glucuronidase. ${\beta}$ -N-Acetyl-D-glucosaminidase B had pH optimum of 4.5 in 0.5 M sodium citrate buffer. The molecular weight of ${\beta}$-N-acetyl-D-glucosaminidase B was 133,000 by Sephadex G-200 gel filtration. The Km value of ${\beta}$-N-acetyl-D-glucosaminidase B using p-nitrophenyl-N-acetyl-${\beta}$-D-glucosaminide as substrate was 1.0 mM and $V_{max}$ was 0.014 ${\mu}$ mole/min. ${\beta}$-N-Acetyl-D-glucosaminidase B was stable at $55^{circ}C$ for 70 minutes. The crude ${\beta}$ -N-acetyl-D-glucosamiinidase in 70 % ammonium sulfate retained 93 % activity after 7 months storage at -$55^{circ}C$. Bovine serum albumin, sodium chloride, and phosphate activated ${\beta}$ -N-Acetyl-D-glucosaminidase B. N-Acetyl-D-glucosamine, ${\alpha}$-methyl-D-mannoside, and acetate inhibited ${\beta}$ -N-acetyl-D-glucosaminidase B.

Performance Analysis of Multi-Carrier CDMA Trellis coded 16 QAM System with Near/Far Effect in Frequency Selective Multipath Fading Channel (주파수 선택성 다중경로 페이딩 채널에서 Near/Far 영향을 받는 Multi-Carrier CDMA Trellis Coded 16 QAM 시스템의 성능해석)

  • 노재성;강희조;김춘길;김언곤;조성준
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.3A
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    • pp.353-361
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    • 2000
  • The performance of a multi-carrier CDMA system is analyzed considering frequency selective multipath fading and Near/Far effects. The number of multicarrier, multiuser, and arms of RAKE receiver, and the decay ratio of frequency selective multipath fading are used as a parameter for the performance analysis. More over, the distribution and the strength of multiuser interference are also considered. To evaluated the Near/Far effects in a multi-carrier CDMA system, three distribution models are assumed. In the first model. interference to carrier Ratio, I/C, ranges form -4 dB to 4dB, and at each 2 dB interval 20 % of multiuser is assumed to be uniformly distributed. In the second one, I/C ranges from -2 dB to 2 dB, and 33.3% of multiuser is assumed to be equally dispersed at each 2dB interval. The third model is 0 dB of I/C, that is, with perfect power control, multiuser are assumed to be evenly located. In this paper, multi-carrier CDMA system adoption RAKE receiver is proposed to mitigate the frequency selective multipath fading. Form the results, the third model(i.e. perfect power control)shows the best performance, and the narrower range of I/C causes the less effects to the desired signal, which reads to the better performance.

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A Study on the Comfort, Physiological Responses and Microclimate in Beding Pad (온돌에서의 욕의 쾌적성에 관한 연구)

  • Lee Soon Won;Kweon Soo Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.14 no.1 s.33
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    • pp.44-54
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    • 1990
  • The purpose of this study was to investigate the effects of thickness of the sleeping pad on the physiological responses and the microclimate in the heating ondol room during sleeping time. The measuring points were skin temp., weight loss and body movement as physiological responses and the compression ratio, the temp. on/under the sleeping pad, the inside limp. of the sleeping quilts and subjective sence while 7 hours sleeping. Thickness of sleeping pads was 27.2 mm(A), 34.8 mm (B), 47.9 mm(C) used for 90 days and no used pad 60.7 mm(D). The floor surface temp. was keeping $29{\pm}1^{\circ}C$ while the environmental conditions was at $23{\pm}1^{\circ}C$ ($50{\pm}5\%$ R.H.) The results were as followings; 1) The mean compression ratio after using the sleeping pads for 45 days was about $70\%$ , and it wasn't increased any more thereafter 2) After 2 hours sleeping the temp. under the sleeping pads was shown that C and D were higher than A and B, and the temp. on the sleeping pads was shown that A and C pads were higher than B and D. But after 3-4 hours sleeping the skin temp. of legs was shown that B and D pads were higher than A and C. 3) Weight loss for C pad was significantly higher than others. Body movement and side position in tying was higher in A and C pads than B and D. 4) The inside temp. of quilt for A and C pads were higher in the early part of sleeping period than those of B and C pads and relative humidity was lower in C than others. 5) D pad was softer than others and fatigue degree was turned out to be lowest in D, the highest in A. From this point of view, we concluded that thickness of the sleeping Pad in the heating ondol room had different characteristic from that in no heating ondol room. And 35 mm used pad was turned out to be proper.

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